1. IDENTIFICATION Product identifier Product Name WHITE LITHIUM GREASE 10.75OZ AE Other means of identification Product Code 81981 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Aerosol Lubricant Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Aspiration toxicity Category 1 Label elements Emergency Overview _____________________________________________________________________________________________ Page 1 / 9 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Danger Flammable liquids Flammable aerosols May be fatal if swallowed and enters airways Category 1 Extremely flammable aerosol Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Revision Date 26-May-2015 SAFETY DATA SHEET Version 1 _____________________________________________________________________________________________ Precautionary Statements - Prevention Keep away from heat/sparks/open flames/hot surfaces. ? No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting Precautionary Statements - Storage Store locked up Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information Toxic to aquatic life with long lasting effects. The classification as a carcinogen need not apply if it can be shown that the substance contains less than 3 % DMSO extract as measured by IP 346. This note applies only to certain complex oil derived substances in Annex I. 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret DISTILLATES (PETROLEUM), SOLVENT-REFINED HEAVY NAPHTHENIC 64741-96-4 15 - 40 * DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC 64742-52-5 15 - 40 * PROPANE 74-98-6 10 - 30 * DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 10 - 30 * HEPTANE 142-82-5 5 - 10 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. _____________________________________________________________________________________________ Page 2 / 9 81981 - WHITE LITHIUM GREASE 10.75OZ AE Revision Date 26-May-2015 Appearance White Physical state Liquid Aerosol Odor Solvent _____________________________________________________________________________________________ Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical Extremely flammable. Keep product and empty container away from heat and sources of ignition. Vapors may travel to source of ignition and flash back. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Remove all sources of ignition. Contents under pressure. Do not puncture or incinerate cans. Environmental precautions Environmental precautions See Section 12 for additional ecological information. Do not flush into surface water or sanitary sewer system. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. _____________________________________________________________________________________________ Page 3 / 9 Revision Date 26-May-201581981 - WHITE LITHIUM GREASE 10.75OZ AE _____________________________________________________________________________________________ 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Take precautionary measures against static discharges. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Contents under pressure. Do not puncture or incinerate cans. Conditions for safe storage, including any incompatibilities Storage Conditions Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH PROPANE 74-98-6 TWA: 1000 ppm TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 HEPTANE 142-82-5 STEL: 500 ppm TWA: 400 ppm TWA: 500 ppm TWA: 2000 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 1600 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 2000 mg/m3 IDLH: 750 ppm Ceiling: 440 ppm 15 min Ceiling: 1800 mg/m3 15 min TWA: 85 ppm TWA: 350 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothingis recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid; Aerosol Appearance White _____________________________________________________________________________________________ Page 4 / 9 81981 - WHITE LITHIUM GREASE 10.75OZ AE Revision Date 26-May-2015 _____________________________________________________________________________________________ Odor Solvent Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 24.5% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Temperatures >50 ?C / 122 ?F. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. _____________________________________________________________________________________________ Page 5 / 9 Decomposition temperature No information available 81981 - WHITE LITHIUM GREASE 10.75OZ AE Kinematic viscosity No information available Flammability (solid, gas) No information available Dynamic viscosity No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available Values Lower flammability limit: No information available Revision Date 26-May-2015 Vapor pressure Not Determined Boiling point / boiling range > 38 ?C / >100 ?F No data available Vapor density >1 Remarks ? Method Air = 1 Relative density 0.905-0.915 Flash point Water solubility Negligible < -18 ?C / < 0 ?F Solubility in other solvents No information available Gives a flame projection at full valve opening or flashback at any degree of valve opening pH Partition coefficient No information available No information available Evaporation rate No information available Autoignition temperature No information available _____________________________________________________________________________________________ Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Potential for aspiration if swallowed. Aspiration may cause pulmonary edema and pneumonitis. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 PROPANE 74-98-6 - - = 658 mg/L ( Rat ) 4 h DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 5.2 mg/L ( Rat ) 4 h HEPTANE 142-82-5 - = 3000 mg/kg ( Rabbit ) = 103 g/m3 ( Rat ) 4 h Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA DISTILLATES (PETROLEUM), SOLVENT-REFINED HEAVY NAPHTHENIC 64741-96-4 A2 Group 1 - X DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC 64742-52-5 A2 Group 1 - X ACGIH (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Target Organ Effects Central nervous system, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 23833 mg/kg ATEmix (dermal) 8006 mg/kg ATEmix (inhalation-gas) 1824461 mg/l ATEmix (inhalation-dust/mist) 1373 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 20% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea DISTILLATES (PETROLEUM), SOLVENT-REFINED HEAVY NAPHTHENIC 64741-96-4 - 5000: 96 h Oncorhynchus mykiss mg/L LC50 1000: 48 h Daphnia magna mg/L EC50 DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC 64742-52-5 - 5000: 96 h Oncorhynchus mykiss mg/L LC50 1000: 48 h Daphnia magna mg/L EC50 _____________________________________________________________________________________________ Page 6 / 9 81981 - WHITE LITHIUM GREASE 10.75OZ AE Revision Date 26-May-2015 _____________________________________________________________________________________________ DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 - 45: 96 h Pimephales promelas mg/L LC50 flow-through 2.2: 96 h Lepomis macrochirus mg/L LC50 static 2.4: 96 h Oncorhynchus mykiss mg/L LC50 static 4720: 96 h Den-dronereides heteropoda mg/L LC50 HEPTANE 142-82-5 - 375.0: 96 h Cichlid fish mg/L LC50 10: 24 h Daphnia magna mg/L EC50 Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient PROPANE 74-98-6 2.3 HEPTANE 142-82-5 4.66 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not reuse container. US EPA Waste Number D001 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status HEPTANE 142-82-5 Toxic Ignitable 14. TRANSPORT INFORMATION DOT UN/ID no 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.1 Emergency Response Guide Number 126 IATA UN/ID no ID 8000 Proper shipping name: Consumer commodity Hazard Class 9 ERG Code 9L IMDG UN/ID no 1950 _____________________________________________________________________________________________ Page 7 / 9 Revision Date 26-May-201581981 - WHITE LITHIUM GREASE 10.75OZ AE _____________________________________________________________________________________________ Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.1 EmS-No F-D, S-U 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % ZINC OXIDE - 1314-13-2 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania PROPANE 74-98-6 X X X _____________________________________________________________________________________________ Page 8 / 9 Revision Date 26-May-201581981 - WHITE LITHIUM GREASE 10.75OZ AE _____________________________________________________________________________________________ HEPTANE 142-82-5 X X X ZINC OXIDE 1314-13-2 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 26-May-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 9 / 9 - Revision Date 26-May-2015 HMIS NFPA Health hazards 2 Flammability 4 Physical hazards 0 Personal protection B Health hazards 2 Flammability 4 81981 - WHITE LITHIUM GREASE 10.75OZ AE Instability 0