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3M(TM) SILICONE LUBRICANT PLUS; PN 08877 06/16/14 __________________________________________________________________________________________ Page 1 of 10 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 19-7433-6 Version Number: 4.00 Issue Date: 06/16/14 Supercedes Date: 07/05/12 SECTION 1: Identification 1.1. Product identifier 3M(TM) SILICONE LUBRICANT PLUS; PN 08877 Product Identification Numbers 60-4100-0944-7, 60-4550-6905-8 1.2. Recommended use and restrictions on use Recommended use Automotive, High Solids Silicone Lubricant 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Aerosol: Category 1. Aspiration Hazard: Category 1. Simple Asphyxiant. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (central nervous system): Category 3. 2.2. Label elements Signal word Danger Symbols 3M(TM) SILICONE LUBRICANT PLUS; PN 08877 06/16/14 __________________________________________________________________________________________ Page 2 of 10 Flame | Exclamation mark | Health Hazard | Pictograms Hazard Statements Extremely flammable aerosol. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. May displace oxygen and cause rapid suffocation. Causes damage to organs: cardiovascular system | Precautionary Statements General: Keep out of reach of children. Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF exposed: Call a POISON CENTER or doctor/physician. Do NOT induce vomiting. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Specific treatment (see Notes to Physician on this label). Call a POISON CENTER or doctor/physician if you feel unwell. Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 2.3. Hazards not otherwise classified None. SECTION 3: Composition/information on ingredients 3M(TM) SILICONE LUBRICANT PLUS; PN 08877 06/16/14 __________________________________________________________________________________________ Page 3 of 10 Ingredient C.A.S. No. % by Wt Isobutane 75-28-5 50 - 60 Trade Secret * Hydrotreated Light Petroleum Distillates 64742-47-8 20 - 40 Trade Secret * Poly(Dimethylsiloxane) 63148-62-9 7 - 13 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. Get medical attention. Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Do not induce vomiting. Get immediate medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. 3M(TM) SILICONE LUBRICANT PLUS; PN 08877 06/16/14 __________________________________________________________________________________________ Page 4 of 10 Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Vapors may travel long distances along the ground or floor to an ignition source and flash back. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Ingredient C.A.S. No. Agency Limit type Additional Comments Hydrotreated Light Petroleum Distillates 64742-47-8 CMRG TWA:165 ppm Isobutane 75-28-5 ACGIH STEL:1000 ppm ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. 3M(TM) SILICONE LUBRICANT PLUS; PN 08877 06/16/14 __________________________________________________________________________________________ Page 5 of 10 If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: As a good industrial hygiene practice: Wear eye/face protection. Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Wear protective gloves. Gloves made from the following material(s) are recommended: Butyl Rubber Nitrile Rubber Respiratory protection In case of inadequate ventilation wear respiratory protection. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece supplied-air respirator For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Aerosol Odor, Color, Grade: transparent, solvent odor Odor threshold No Data Available pH Not Applicable Melting point Not Applicable Flash Point -50.00 ?F [Details: Flash point of propellant] Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Density >=1 [Ref Std: AIR=1] Density 0.65 g/ml Specific Gravity 0.65 [Ref Std: WATER=1] Solubility in Water Nil Solubility- non-water No Data Available 3M(TM) SILICONE LUBRICANT PLUS; PN 08877 06/16/14 __________________________________________________________________________________________ Page 6 of 10 Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity No Data Available Hazardous Air Pollutants 0 % weight [Test Method: Calculated] Volatile Organic Compounds 60 % weight [Test Method: calculated per CARB title 2] Volatile Organic Compounds 390 g/l [Test Method: calculated SCAQMD rule 443.1] Percent volatile 60 % weight VOC Less H2O & Exempt Solvents 390 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat Sparks and/or flames 10.5. Incompatible materials Not determined 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Intentional concentration and inhalation may be harmful or fatal. 3M(TM) SILICONE LUBRICANT PLUS; PN 08877 06/16/14 __________________________________________________________________________________________ Page 7 of 10 Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache, incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Ingestion: Chemical (Aspiration) Pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth, difficulty breathing, bluish colored skin (cyanosis), and may be fatal. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause target organ effects after ingestion. Target Organ Effects: Single exposure may cause: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Isobutane Inhalation- Gas (4 hours) Rat LC50 276,000 ppm Hydrotreated Light Petroleum Distillates Dermal Rabbit LD50 > 3,160 mg/kg Hydrotreated Light Petroleum Distillates Inhalation- Dust/Mist (4 hours) Rat LC50 > 3.0 mg/l Hydrotreated Light Petroleum Distillates Ingestion Rat LD50 > 5,000 mg/kg Poly(Dimethylsiloxane) Dermal Rabbit LD50 > 19,400 mg/kg Poly(Dimethylsiloxane) Ingestion Rat LD50 > 17,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Isobutane No significant irritation Hydrotreated Light Petroleum Distillates Rabbit Mild irritant Poly(Dimethylsiloxane) Rabbit No significant irritation Serious Eye Damage/Irritation 3M(TM) SILICONE LUBRICANT PLUS; PN 08877 06/16/14 __________________________________________________________________________________________ Page 8 of 10 Name Species Value Isobutane No significant irritation Hydrotreated Light Petroleum Distillates Rabbit Mild irritant Poly(Dimethylsiloxane) Rabbit No significant irritation Skin Sensitization Name Species Value Hydrotreated Light Petroleum Distillates Guinea pig Not sensitizing Respiratory Sensitization Name Species Value Germ Cell Mutagenicity Name Route Value Isobutane In Vitro Not mutagenic Hydrotreated Light Petroleum Distillates In Vitro Not mutagenic Carcinogenicity Name Route Species Value Hydrotreated Light Petroleum Distillates Dermal Mouse Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Isobutane Inhalation cardiac sensitization Causes damage to organs Multiple animal species NOAEL Not available Isobutane Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Isobutane Inhalation respiratory irritation All data are negative Mouse NOAEL Not available Hydrotreated Light Petroleum Distillates Inhalation central nervous system depression May cause drowsiness or dizziness NOAEL Not available Hydrotreated Light Petroleum Distillates Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Isobutane Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 4,500 ppm 13 weeks Aspiration Hazard Name Value Hydrotreated Light Petroleum Distillates Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information 3M(TM) SILICONE LUBRICANT PLUS; PN 08877 06/16/14 __________________________________________________________________________________________ Page 9 of 10 on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information 3M(TM) SILICONE LUBRICANT PLUS; PN 08877 06/16/14 __________________________________________________________________________________________ Page 10 of 10 NFPA Hazard Classification Health: 2 Flammability: 4 Instability: 0 Special Hazards: None Aerosol Storage Code: 3 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 19-7433-6 Version Number: 4.00 Issue Date: 06/16/14 Supercedes Date: 07/05/12 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com