SAFETY DATA SHEET 1. Identification Product identifier Ultra-Clear Spray Glass Cleaner Other means of identification FIR No. 019761 Recommended use Glass Cleaner Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Supplier Company Name Ford Motor Company Address Attention: MSDS Information, P.O. Box 1899 Dearborn, Michigan 48121 USA Telephone 1-800-392-3673 MSDS Information 1-800-448-2063 This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone numbers Poison Control Center: USA and Canada: 1-800-959-3673 INFOTRAC (Transportation): USA and Canada 1-800-535-5053 2. Hazard(s) identification Dissolved gasGases under pressurePhysical hazards Not classified.Health hazards Not classified.Environmental hazards Not classified.OSHA defined hazards Label elements Signal word Warning Hazard statement Contains gas under pressure; may explode if heated. Precautionary statement Prevention Observe good industrial hygiene practices. Response Wash hands after handling. Storage Protect from sunlight. Store in a well-ventilated place. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise classified (HNOC) May cause irritation of respiratory tract. May irritate eyes and skin. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 67-63-0PROPAN-2-OL 3 - < 5 106-97-8BUTANE 1 - < 3 Specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. FIR No.: 019761 SDS US Issue Date: 05-16-2015 Version: 01 1 / 8 4. First-aid measures Inhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a physician if symptoms develop or persist. Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation develops and persists. Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. Most important symptoms/effects, acute and delayed Direct contact with eyes may cause temporary irritation. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical During fire, gases hazardous to health may be formed. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire fighting equipment/instructions In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed to heat. If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also consider initial evacuation for 800 meters (1/2 mile) in all directions. ALWAYS stay away from tanks engulfed in flame. Move containers from fire area if you can do so without risk. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards Contents under pressure. Pressurized container may explode when exposed to heat or flame. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Remove all possible sources of ignition in the surrounding area. Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Avoid contact with eyes, skin, and clothing. Avoid inhalation of vapors or mists. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid contact with eyes, skin, and clothing. Avoid breathing mist or vapor. Avoid prolonged exposure. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Store in a cool, dry place out of direct sunlight. Secure cylinders in an upright position at all times, close all valves when not in use. Store in original tightly closed container. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Store in accordance with local/regional/national/international regulation. FIR No.: 019761 SDS US Issue Date: 05-16-2015 Version: 01 2 / 8 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 980 mg/m3PROPAN-2-OL (CAS 67-63-0) 400 ppm US. ACGIH Threshold Limit Values ValueComponents Type STEL 1000 ppmBUTANE (CAS 106-97-8) STEL 400 ppmPROPAN-2-OL (CAS 67-63-0) TWA 200 ppm US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type TWA 1900 mg/m3BUTANE (CAS 106-97-8) 800 ppm STEL 1225 mg/m3PROPAN-2-OL (CAS 67-63-0) 500 ppm TWA 980 mg/m3 400 ppm Biological limit values ACGIH Biological Exposure Indices ValueComponents Determinant Specimen Sampling Time 40 mg/l Acetone Urine *PROPAN-2-OL (CAS 67-63-0) * - For sampling details, please see the source document. Appropriate engineering controls Use adequate ventilation to control airborne concentrations below the exposure limits/guidelines. If user operations generate a vapor, dust and/or mist, use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below the recommended exposure limits/guidelines. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Suitable chemical protective gloves should be worn when the potential exists for prolonged or repeated skin exposure. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Nitrile gloves are recommended. Other Wear suitable protective clothing. Wear appropriate chemical resistant clothing if applicable. Respiratory protection If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, an approved respirator must be worn. Respirator selection, use and maintenance should be in accordance with the requirements of OSHA Respiratory Protection Standard 29 CFR 1910.134 and/or Canadian Standard CSA Z94.4. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Aerosol. Color Clear. Odor Alcoholic. Odor threshold Not available. FIR No.: 019761 SDS US Issue Date: 05-16-2015 Version: 01 3 / 8 pH 10 ASTM D1293 pH concentration 100 % v/v Melting point/freezing point Not available. Initial boiling point and boiling range < -0.4 ?F (< -18 ?C) Flash point -20.2 ?F (-29.0 ?C) PMCC Evaporation rate > 1 (Ether=1) Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Explosive limit - lower (%) 1.9 % Explosive limit - upper (%) 12.7 Vapor pressure Not available. Vapor density > 1 (AIR=1) Relative density 0.95 Relative density temperature 68 ?F (20 ?C) Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Heat of combustion 2.95 kJ/g VOC (Weight %) 8 % 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid Heat. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Hazardous decomposition products Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 11. Toxicological information Information on likely routes of exposure Inhalation Prolonged inhalation may be harmful. May cause irritation to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Skin contact Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion May be harmful if swallowed. Symptoms related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute toxicity FIR No.: 019761 SDS US Issue Date: 05-16-2015 Version: 01 4 / 8 Species Calculated/Test ResultsComponents BUTANE (CAS 106-97-8) LC50 Mouse Inhalation Acute 680 mg/l, 2 Hours Rat 658 mg/l, 4 Hours PROPAN-2-OL (CAS 67-63-0) LD50 Rabbit Dermal Acute 12800 mg/kg LD50 Dog Oral 4797 mg/kg Mouse 3600 mg/kg Rabbit 5.03 g/kg Rat 4.7 g/kg Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Ecotoxicity SpeciesComponents Calculated/Test Results PROPAN-2-OL (CAS 67-63-0) Aquatic LC50Fish > 1400 mg/l, 96 hoursBluegill (Lepomis macrochirus) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) BUTANE 2.89 PROPAN-2-OL 0.05 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. FIR No.: 019761 SDS US Issue Date: 05-16-2015 Version: 01 5 / 8 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN1950UN number AEROSOLSUN proper shipping name 2.2Class Transport hazard class(es) -Subsidiary risk 2.2Label(s) Not applicable.Packing group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IATA UN1950UN number AEROSOLS, NON-FLAMMABLEUN proper shipping name 2.2Class Transport hazard class(es) -Subsidiary risk 2.2Label(s) Not applicable.Packing group No.Environmental hazards Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Forbidden.Passenger and cargo aircraft Other information Forbidden.Cargo aircraft only IMDG UN1950UN number AEROSOLSUN proper shipping name 2.2Class Transport hazard class(es) -Subsidiary risk Not applicable.Packing group No.Marine pollutant Environmental hazards Not available.EmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Not established.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code FIR No.: 019761 SDS US Issue Date: 05-16-2015 Version: 01 6 / 8 DOT IATA; IMDG 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) BUTANE (CAS 106-97-8) Listed. PROPAN-2-OL (CAS 67-63-0) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Chemical name CAS number % by wt. PROPAN-2-OL 67-63-0 3 - < 5 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) BUTANE (CAS 106-97-8) Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. FIR No.: 019761 SDS US Issue Date: 05-16-2015 Version: 01 7 / 8 US. Massachusetts RTK - Substance List BUTANE (CAS 106-97-8) PROPAN-2-OL (CAS 67-63-0) US. New Jersey Worker and Community Right-to-Know Act BUTANE (CAS 106-97-8) PROPAN-2-OL (CAS 67-63-0) US. Pennsylvania Worker and Community Right-to-Know Law BUTANE (CAS 106-97-8) PROPAN-2-OL (CAS 67-63-0) US. Rhode Island RTK BUTANE (CAS 106-97-8) PROPAN-2-OL (CAS 67-63-0) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. International Inventories All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. 16. Other information, including date of preparation or last revision Issue date 05-16-2015 Version # 01 HMIS? ratings Health: 2 Flammability: 2 Physical hazard: 0 NFPA ratings Health: 2 Flammability: - Instability: 0 Preparation Information and Disclaimer This document was prepared by FCSD-Toxicology, Ford Motor Company, Diagnostic Service Center II, 1800 Fairlane Drive, Allen Park, MI 48101, USA, based in part on information provided by the manufacturer. The information on this data sheet represents our current data and is accurate to the best of our knowledge as to the proper handling of this product under normal conditions and in accordance with the application specified on the packaging and/or technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. To the extent that there are any differences between this product?s Safety Data Sheet (SDS) and the consumer packaged product labels, the SDS should be followed. Part number(s) ZC-23 FIR No.: 019761 SDS US Issue Date: 05-16-2015 Version: 01 8 / 8