SAFETY DATA SHEET 1. Identification Product identifier Pressurized Fuel Injector Cleaner Other means of identification FIR No. 045361 Recommended use Fuel injector cleaner Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Supplier Company Name Ford Motor Company Address Attention: MSDS Information, P.O. Box 1899 Dearborn, Michigan 48121 USA Telephone 1-800-392-3673 MSDS Information 1-800-448-2063 This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone numbers Poison Control Center: USA and Canada: 1-800-959-3673 INFOTRAC (Transportation): USA and Canada 1-800-535-5053 2. Hazard(s) identification Category 1Flammable aerosolsPhysical hazards Dissolved gasGases under pressure Category 2Skin corrosion/irritationHealth hazards Category 2Serious eye damage/eye irritation Category 3Hazardous to the aquatic environment, acute hazard Environmental hazards Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin irritation. Causes serious eye irritation. Harmful to aquatic life. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash thoroughly after handling. Avoid release to the environment. Wear protective gloves. Wear eye/face protection. Response If on skin: Wash with plenty of water. If skin irritation occurs: Get medical advice/attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Storage Protect from sunlight. Do not expose to temperatures exceeding 50?C/122?F. Store in a well-ventilated place. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) HARMFUL OR FATAL IF SWALLOWED. May cause irritation of respiratory tract. Toxic in contact with skin. Aspiration may cause pulmonary edema and pneumonitis. FIR No.: 045361 SDS US Issue Date: 05-20-2015 Version: 01 1 / 10 Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 64741-66-8Naphtha (petroleum), light alkylate 40 - < 50 64742-95-6Solvent naphtha (petroleum), light arom. 10 - < 20 108-11-24-METHYLPENTAN-2-OL 5 - < 10 111-76-22-BUTOXYETHANOL 3 - < 5 64742-52-5Distillates (petroleum), hydrotreated heavy naphthenic 3 - < 5 64742-53-6Distillates (petroleum), hydrotreated light naphthenic 3 - < 5 7727-37-9NITROGEN 1 - < 3 1336-21-6Ammonia, aqueous solution < 1 Specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. 4. First-aid measures Inhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a physician if symptoms develop or persist. Skin contact Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth. Do not induce vomiting. Most important symptoms/effects, acute and delayed Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical Contents under pressure. Pressurized container may explode when exposed to heat or flame. During fire, gases hazardous to health may be formed. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Special protective equipment and precautions for firefighters Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Fire fighting equipment/instructions In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed to heat. If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also consider initial evacuation for 800 meters (1/2 mile) in all directions. ALWAYS stay away from tanks engulfed in flame. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. General fire hazards Extremely flammable aerosol. Contents under pressure. Pressurized container may explode when exposed to heat or flame. FIR No.: 045361 SDS US Issue Date: 05-20-2015 Version: 01 2 / 10 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Avoid inhalation of vapors. Avoid contact with eyes. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Large Spills: Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Scoop up used absorbent into drums or other appropriate container. Prevent product from entering drains. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. 7. Handling and storage Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Ground and bond containers when transferring material. Do not get in eyes, on skin, or on clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50?C/122 ?F. Keep away from heat, sparks and open flame. This material can accumulate static charge which may cause spark and become an ignition source. Secure cylinders in an upright position at all times, close all valves when not in use. Store in original tightly closed container. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Store in accordance with local/regional/national/international regulation. 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents FormType PEL 240 mg/m32-BUTOXYETHANOL (CAS 111-76-2) 50 ppm PEL 100 mg/m34-METHYLPENTAN-2-OL (CAS 108-11-2) 25 ppm PEL 35 mg/m3Ammonia, aqueous solution (CAS 1336-21-6) 50 ppm PEL 5 mg/m3 Mist.Distillates (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5) 2000 mg/m3 500 ppm PEL 5 mg/m3 Mist.Distillates (petroleum), hydrotreated light naphthenic (CAS 64742-53-6) 2000 mg/m3 500 ppm FIR No.: 045361 SDS US Issue Date: 05-20-2015 Version: 01 3 / 10 US. ACGIH Threshold Limit Values ValueComponents Type TWA 20 ppm2-BUTOXYETHANOL (CAS 111-76-2) STEL 40 ppm4-METHYLPENTAN-2-OL (CAS 108-11-2) TWA 25 ppm STEL 35 ppmAmmonia, aqueous solution (CAS 1336-21-6) TWA 25 ppm US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents FormType TWA 24 mg/m32-BUTOXYETHANOL (CAS 111-76-2) 5 ppm STEL 165 mg/m34-METHYLPENTAN-2-OL (CAS 108-11-2) 40 ppm TWA 100 mg/m3 25 ppm STEL 27 mg/m3Ammonia, aqueous solution (CAS 1336-21-6) 35 ppm TWA 18 mg/m3 25 ppm STEL 10 mg/m3 Mist.Distillates (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5) TWA 5 mg/m3 Mist. STEL 10 mg/m3 Mist.Distillates (petroleum), hydrotreated light naphthenic (CAS 64742-53-6) TWA 5 mg/m3 Mist. Biological limit values ACGIH Biological Exposure Indices ValueComponents Determinant Specimen Sampling Time 200 mg/g Butoxyacetic acid (BAA), with hydrolysis Creatinine in urine *2-BUTOXYETHANOL (CAS 111-76-2) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation 2-BUTOXYETHANOL (CAS 111-76-2) Can be absorbed through the skin. 4-METHYLPENTAN-2-OL (CAS 108-11-2) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies 2-BUTOXYETHANOL (CAS 111-76-2) Skin designation applies. 4-METHYLPENTAN-2-OL (CAS 108-11-2) Skin designation applies. US - Tennessee OELs: Skin designation 2-BUTOXYETHANOL (CAS 111-76-2) Can be absorbed through the skin. 4-METHYLPENTAN-2-OL (CAS 108-11-2) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation 4-METHYLPENTAN-2-OL (CAS 108-11-2) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation 2-BUTOXYETHANOL (CAS 111-76-2) Can be absorbed through the skin. 4-METHYLPENTAN-2-OL (CAS 108-11-2) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 2-BUTOXYETHANOL (CAS 111-76-2) Can be absorbed through the skin. 4-METHYLPENTAN-2-OL (CAS 108-11-2) Can be absorbed through the skin. FIR No.: 045361 SDS US Issue Date: 05-20-2015 Version: 01 4 / 10 Appropriate engineering controls Use adequate ventilation to control airborne concentrations below the exposure limits/guidelines. If user operations generate a vapor, dust and/or mist, use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below the recommended exposure limits/guidelines. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Eye wash fountain and emergency showers are recommended. Skin protection Hand protection Suitable chemical protective gloves should be worn when the potential exists for prolonged or repeated skin exposure. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Nitrile gloves are recommended. Neoprene gloves are recommended. Other Wear appropriate chemical resistant clothing. Wear appropriate chemical resistant clothing if applicable. Respiratory protection If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, an approved respirator must be worn. Respirator selection, use and maintenance should be in accordance with the requirements of OSHA Respiratory Protection Standard 29 CFR 1910.134 and/or Canadian Standard CSA Z94.4. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Aerosol. Color Amber. Odor Aromatic. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range Not available. Flash point 48.2 ?F (9.0 ?C) TCC Evaporation rate < 1 (BuAc=1) Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower (%) Not available. Flammability limit - upper (%) Not available. Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure Not available. Vapor density > 1 (AIR=1) Relative density 0.78 - 0.84 Relative density temperature 59 ?F (15 ?C) Solubility(ies) Solubility (water) SLIGHT IN WATER Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. FIR No.: 045361 SDS US Issue Date: 05-20-2015 Version: 01 5 / 10 Other information Flame projection Not Applicable Heat of combustion 34.7 kJ/g Kinematic viscosity < 14 cSt Kinematic viscosity temperature 104 ?F (40 ?C) VOC (Weight %) 78 % CAM310 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid Heat. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Hazardous decomposition products At thermal decomposition temperatures, carbon monoxide and carbon dioxide. Phosphorus compounds. Sulfur compounds. Nitrogen compounds. 11. Toxicological information Information on likely routes of exposure Inhalation May cause irritation to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. Skin contact Causes skin irritation. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Eye contact Causes serious eye irritation. Ingestion HARMFUL OR FATAL IF SWALLOWED. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. However, ingestion is not likely to be a primary route of occupational exposure. Symptoms related to the physical, chemical and toxicological characteristics Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Information on toxicological effects Acute toxicity Species Calculated/Test ResultsComponents 2-BUTOXYETHANOL (CAS 111-76-2) LD50 Rabbit Dermal Acute 400 mg/kg LC50 Mouse Inhalation 700 ppm, 7 Hours Rat 450 ppm, 4 Hours LD50 Guinea pig Oral 1.2 g/kg Mouse 1.2 g/kg Rabbit 0.32 g/kg Rat 560 mg/kg 4-METHYLPENTAN-2-OL (CAS 108-11-2) LD50 Rabbit Dermal Acute 3.56 ml/kg FIR No.: 045361 SDS US Issue Date: 05-20-2015 Version: 01 6 / 10 Species Calculated/Test ResultsComponents LD50 Rat Oral 2.6 g/kg Ammonia, aqueous solution (CAS 1336-21-6) LD50 Rat Oral Acute 350 mg/kg Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye irritation Causes serious eye irritation. Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity 2-BUTOXYETHANOL (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity Components in this product have been shown to cause birth defects and reproductive disorders in laboratory animals. Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard If aspirated into lungs during swallowing or vomiting, may cause chemical pneumonia, pulmonary injury or death. Chronic effects May be harmful if absorbed through skin. Prolonged inhalation may be harmful. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. 12. Ecological information Ecotoxicity Harmful to aquatic life. Ecotoxicity SpeciesComponents Calculated/Test Results 2-BUTOXYETHANOL (CAS 111-76-2) Aquatic LC50Fish 1250 mg/l, 96 hoursInland silverside (Menidia beryllina) Ammonia, aqueous solution (CAS 1336-21-6) Aquatic LC50Fish 15 mg/l, 96 hoursWestern mosquitofish (Gambusia affinis) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) 2-BUTOXYETHANOL 0.83 4-METHYLPENTAN-2-OL 1.43 NITROGEN 0.67 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. FIR No.: 045361 SDS US Issue Date: 05-20-2015 Version: 01 7 / 10 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. 14. Transport information DOT UN1950UN number AEROSOLSUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk 2.1Label(s) Not applicable.Packing group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IATA UN1950UN number AEROSOLS, FLAMMABLEUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk 2.1Label(s) Not applicable.Packing group No.Environmental hazards Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Forbidden.Passenger and cargo aircraft Other information Forbidden.Cargo aircraft only IMDG UN1950UN number AEROSOLSUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk 2.1Label(s) Not applicable.Packing group No.Marine pollutant Environmental hazards Not available.EmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Not established.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code FIR No.: 045361 SDS US Issue Date: 05-20-2015 Version: 01 8 / 10 DOT IATA; IMDG 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) 2-BUTOXYETHANOL (CAS 111-76-2) Listed. Ammonia, aqueous solution (CAS 1336-21-6) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Chemical name CAS number % by wt. 2-BUTOXYETHANOL 111-76-2 3 - < 5 Ammonia, aqueous solution 1336-21-6 < 1 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. FIR No.: 045361 SDS US Issue Date: 05-20-2015 Version: 01 9 / 10 US. Massachusetts RTK - Substance List 2-BUTOXYETHANOL (CAS 111-76-2) 4-METHYLPENTAN-2-OL (CAS 108-11-2) Ammonia, aqueous solution (CAS 1336-21-6) Distillates (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5) Distillates (petroleum), hydrotreated light naphthenic (CAS 64742-53-6) NITROGEN (CAS 7727-37-9) US. New Jersey Worker and Community Right-to-Know Act 2-BUTOXYETHANOL (CAS 111-76-2) 4-METHYLPENTAN-2-OL (CAS 108-11-2) Ammonia, aqueous solution (CAS 1336-21-6) NITROGEN (CAS 7727-37-9) US. Pennsylvania Worker and Community Right-to-Know Law 2-BUTOXYETHANOL (CAS 111-76-2) 4-METHYLPENTAN-2-OL (CAS 108-11-2) Ammonia, aqueous solution (CAS 1336-21-6) NITROGEN (CAS 7727-37-9) US. Rhode Island RTK 2-BUTOXYETHANOL (CAS 111-76-2) Ammonia, aqueous solution (CAS 1336-21-6) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. 16. Other information, including date of preparation or last revision Issue date 05-20-2015 Version # 01 HMIS? ratings Health: 2 Flammability: 4 Physical hazard: 1 NFPA ratings Health: 2 Flammability: - Instability: 1 Preparation Information and Disclaimer This document was prepared by FCSD-Toxicology, Ford Motor Company, Diagnostic Service Center II, 1800 Fairlane Drive, Allen Park, MI 48101, USA, based in part on information provided by the manufacturer. The information on this data sheet represents our current data and is accurate to the best of our knowledge as to the proper handling of this product under normal conditions and in accordance with the application specified on the packaging and/or technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. To the extent that there are any differences between this product?s Safety Data Sheet (SDS) and the consumer packaged product labels, the SDS should be followed. Part number(s) CM-1001 FIR No.: 045361 SDS US Issue Date: 05-20-2015 Version: 01 10 / 10