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3M? Channel Bonding & Sidelite Adhesive PN 08641 04/27/15 ________________________________________________________________________________________________________ Page 1 of 2 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 28-0991-1 Version Number: 2.01 Issue Date: 04/27/15 Supercedes Date: 03/03/15 Product identifier 3M? Channel Bonding & Sidelite Adhesive PN 08641 ID Number(s): 41-0003-6766-8, 41-0003-7994-5, 60-4550-5244-3 Recommended use Automotive Supplier's details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AIL) for each of these components is included. Please do not separate the component documents from this cover page. The document numbers for components of this product are: 10-5979-9, 10-5978-1 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M? Channel Bonding & Sidelite Adhesive PN 08641 04/27/15 ________________________________________________________________________________________________________ Page 2 of 2 3M USA SDSs are available at www.3M.com 3M? Channel Bonding & Sidelite Adhesive PN 08641 Part B (BASE) 04/27/15 __________________________________________________________________________________________ Page 1 of 10 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 10-5978-1 Version Number: 40.01 Issue Date: 04/27/15 Supercedes Date: 03/03/15 SECTION 1: Identification 1.1. Product identifier 3M? Channel Bonding & Sidelite Adhesive PN 08641 Part B (BASE) Product Identification Numbers LB-K100-0780-1, LB-K100-0129-7 1.2. Recommended use and restrictions on use Recommended use Automotive, Adhesive for bonding automotive side glass. 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Serious Eye Damage/Irritation: Category 2B. Skin Sensitizer: Category 1. Carcinogenicity: Category 2. 2.2. Label elements Signal word Warning Symbols Exclamation mark | Health Hazard | Pictograms 3M? Channel Bonding & Sidelite Adhesive PN 08641 Part B (BASE) 04/27/15 __________________________________________________________________________________________ Page 2 of 10 Hazard Statements Causes eye irritation. May cause an allergic skin reaction. Suspected of causing cancer. Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapors/spray. Wear protective gloves. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. Storage: Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified None. 96% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Bisphenol A-Epichlorohydrin Copolymer 25068-38-6 90 - 100 Trade Secret * Dimethyl Siloxane, Reaction Product With Silica 67762-90-7 3 - 7 Trade Secret * Carbon Black 1333-86-4 1 - 5 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 3M? Channel Bonding & Sidelite Adhesive PN 08641 Part B (BASE) 04/27/15 __________________________________________________________________________________________ Page 3 of 10 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Aldehydes During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Toxic Vapor, Gas, Particulate During Combustion 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic 3M? Channel Bonding & Sidelite Adhesive PN 08641 Part B (BASE) 04/27/15 __________________________________________________________________________________________ Page 4 of 10 absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities No special storage requirements. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Carbon Black 1333-86-4 ACGIH TWA(inhalable fraction):3 mg/m3 A3: Confirmed animal carcin. Carbon Black 1333-86-4 CMRG TWA:0.5 mg/m3 Carbon Black 1333-86-4 OSHA TWA:3.5 mg/m3 Dimethyl Siloxane, Reaction Product With Silica 67762-90-7 CMRG CEIL:5 mg/m3 SILICA, AMORPHOUS 67762-90-7 OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles 3M? Channel Bonding & Sidelite Adhesive PN 08641 Part B (BASE) 04/27/15 __________________________________________________________________________________________ Page 5 of 10 Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Nitrile Rubber Polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Paste Odor, Color, Grade: Black, epoxy odor. Odor threshold No Data Available pH Not Applicable Melting point Not Applicable Boiling Point > 260 ?C [Details: Calc from RMs] Flash Point 249 ?C [Test Method: Closed Cup] [Details: Calc from RMs] Evaporation rate Not Applicable Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure 0.03 mbar [Details: at 77 Deg. C] Vapor Density Not Applicable Density 9.8 lb/gal Specific Gravity 1.180 [Ref Std: WATER=1] Solubility in Water Slight (less than 10%) Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Hazardous Air Pollutants 0.0002 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 1 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 0.1 % weight [Test Method: calculated per CARB title 2] Percent volatile 0.1 VOC Less H2O & Exempt Solvents 1 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability Stable. 3M? Channel Bonding & Sidelite Adhesive PN 08641 Part B (BASE) 04/27/15 __________________________________________________________________________________________ Page 6 of 10 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 10.5. Incompatible materials None known. 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. Vapors released during curing may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Additional Health Effects: Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation Carbon Black 1333-86-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Toxicological Data 3M? Channel Bonding & Sidelite Adhesive PN 08641 Part B (BASE) 04/27/15 __________________________________________________________________________________________ Page 7 of 10 If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Inhalation- Dust/Mist(4 hr) No data available; calculated ATE 5 - 12.5 mg/l Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Bisphenol A-Epichlorohydrin Copolymer Dermal Rat LD50 > 1,600 mg/kg Bisphenol A-Epichlorohydrin Copolymer Ingestion Rat LD50 > 1,000 mg/kg Dimethyl Siloxane, Reaction Product With Silica Dermal Rabbit LD50 > 5,000 mg/kg Dimethyl Siloxane, Reaction Product With Silica Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Dimethyl Siloxane, Reaction Product With Silica Ingestion Rat LD50 > 5,110 mg/kg Carbon Black Dermal Rabbit LD50 > 3,000 mg/kg Carbon Black Ingestion Rat LD50 > 8,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Bisphenol A-Epichlorohydrin Copolymer Rabbit Mild irritant Dimethyl Siloxane, Reaction Product With Silica Rabbit No significant irritation Carbon Black Rabbit No significant irritation Serious Eye Damage/Irritation Name Species Value Bisphenol A-Epichlorohydrin Copolymer Rabbit Moderate irritant Dimethyl Siloxane, Reaction Product With Silica Rabbit No significant irritation Carbon Black Rabbit No significant irritation Skin Sensitization Name Species Value Bisphenol A-Epichlorohydrin Copolymer Human and animal Sensitizing Dimethyl Siloxane, Reaction Product With Silica Human and animal Not sensitizing Respiratory Sensitization Name Species Value Bisphenol A-Epichlorohydrin Copolymer Human Some positive data exist, but the data are not sufficient for classification Germ Cell Mutagenicity Name Route Value Bisphenol A-Epichlorohydrin Copolymer In vivo Not mutagenic Bisphenol A-Epichlorohydrin Copolymer In Vitro Some positive data exist, but the data are not sufficient for classification Dimethyl Siloxane, Reaction Product With Silica In Vitro Not mutagenic Carbon Black In Vitro Not mutagenic Carbon Black In vivo Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Bisphenol A-Epichlorohydrin Copolymer Dermal Mouse Some positive data exist, but the data are not 3M? Channel Bonding & Sidelite Adhesive PN 08641 Part B (BASE) 04/27/15 __________________________________________________________________________________________ Page 8 of 10 sufficient for classification Dimethyl Siloxane, Reaction Product With Silica Not Specified Mouse Some positive data exist, but the data are not sufficient for classification Carbon Black Dermal Mouse Not carcinogenic Carbon Black Ingestion Mouse Not carcinogenic Carbon Black Inhalation Rat Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Bisphenol A-Epichlorohydrin Copolymer Ingestion Not toxic to female reproduction Rat NOAEL 750 mg/kg/day 2 generation Bisphenol A-Epichlorohydrin Copolymer Ingestion Not toxic to male reproduction Rat NOAEL 750 mg/kg/day 2 generation Bisphenol A-Epichlorohydrin Copolymer Dermal Not toxic to development Rabbit NOAEL 300 mg/kg/day during organogenesi s Bisphenol A-Epichlorohydrin Copolymer Ingestion Not toxic to development Rat NOAEL 750 mg/kg/day 2 generation Dimethyl Siloxane, Reaction Product With Silica Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation Dimethyl Siloxane, Reaction Product With Silica Ingestion Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Dimethyl Siloxane, Reaction Product With Silica Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure For the component/components, either no data are currently available or the data are not sufficient for classification. Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Bisphenol A- Epichlorohydrin Copolymer Dermal liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,000 mg/kg/day 2 years Bisphenol A- Epichlorohydrin Copolymer Dermal nervous system All data are negative Rat NOAEL 1,000 mg/kg/day 13 weeks Bisphenol A- Epichlorohydrin Copolymer Ingestion auditory system | heart | endocrine system | hematopoietic system | liver | eyes | kidney and/or bladder All data are negative Rat NOAEL 1,000 mg/kg/day 28 days Dimethyl Siloxane, Reaction Product With Silica Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure Carbon Black Inhalation pneumoconiosis Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. 3M? Channel Bonding & Sidelite Adhesive PN 08641 Part B (BASE) 04/27/15 __________________________________________________________________________________________ Page 9 of 10 SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. If no other disposal options are available, waste product that has been completely cured or polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification LEAD 7439-92-1 Female reproductive toxin LEAD 7439-92-1 Male reproductive toxin LEAD 7439-92-1 Carcinogen LEAD 7439-92-1 Developmental Toxin Carbon Black 1333-86-4 Carcinogen WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. WARNING: This product contains a chemical known to the State of California to cause cancer. 3M? Channel Bonding & Sidelite Adhesive PN 08641 Part B (BASE) 04/27/15 __________________________________________________________________________________________ Page 10 of 10 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 1 Instability: 1 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 10-5978-1 Version Number: 40.01 Issue Date: 04/27/15 Supercedes Date: 03/03/15 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com 3M?Channel Bonding & Sidelite Adhesive PN 08641 - Part A 04/27/15 __________________________________________________________________________________________ Page 1 of 11 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 10-5979-9 Version Number: 45.01 Issue Date: 04/27/15 Supercedes Date: 03/03/15 SECTION 1: Identification 1.1. Product identifier 3M?Channel Bonding & Sidelite Adhesive PN 08641 - Part A Product Identification Numbers LB-K100-0780-2, LB-K100-0129-8 1.2. Recommended use and restrictions on use Recommended use Automotive, Adhesive for bonding automotive side glass. 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Specific Target Organ Toxicity (single exposure): Category 1. 2.2. Label elements Signal word Danger Symbols Health Hazard | Pictograms 3M?Channel Bonding & Sidelite Adhesive PN 08641 - Part A 04/27/15 __________________________________________________________________________________________ Page 2 of 11 Hazard Statements Causes damage to organs: cardiovascular system | nervous system | kidney/urinary tract | respiratory system | Precautionary Statements General: Keep out of reach of children. Prevention: Do not breathe dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF exposed: Call a POISON CENTER or doctor/physician. Specific treatment (see Notes to Physician on this label). Storage: Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: This product contains ethylene glycol. If there is reasonable suspicion of ethylene glycol poisoning, intravenous (IV) administration with either fomepizole (preferred) or ethanol (if fomepizole is unavailable) should be considered as part of the medical management. 2.3. Hazards not otherwise classified None. 93% of the mixture consists of ingredients of unknown acute oral toxicity. 93% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Mercaptan-Terminated Epoxy Curing Agent NJ 800938- 5952 Trade Secret* 60 - 100 Trade Secret * Dimethyl Siloxane, Reaction Product With Silica 67762-90-7 3 - 7 Trade Secret * Ethylene Glycol 107-21-1 1 - 5 Trade Secret * NJTS or NJTSRN: New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade 3M?Channel Bonding & Sidelite Adhesive PN 08641 - Part A 04/27/15 __________________________________________________________________________________________ Page 3 of 11 secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required This product contains ethylene glycol. If there is reasonable suspicion of ethylene glycol poisoning, intravenous (IV) administration with either fomepizole (preferred) or ethanol (if fomepizole is unavailable) should be considered as part of the medical management. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. 3M?Channel Bonding & Sidelite Adhesive PN 08641 - Part A 04/27/15 __________________________________________________________________________________________ Page 4 of 11 SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. 7.2. Conditions for safe storage including any incompatibilities No special storage requirements. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Ethylene Glycol 107-21-1 ACGIH CEIL(as aerosol):100 mg/m3 A4: Not class. as human carcin Ethylene Glycol 107-21-1 CMRG CEIL(as vapor and aerosol):100 mg/m3 Dimethyl Siloxane, Reaction Product With Silica 67762-90-7 CMRG CEIL:5 mg/m3 SILICA, AMORPHOUS 67762-90-7 OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety Glasses with side shields Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Nitrile Rubber 3M?Channel Bonding & Sidelite Adhesive PN 08641 - Part A 04/27/15 __________________________________________________________________________________________ Page 5 of 11 Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Paste Odor, Color, Grade: White, pungent odor. Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point No Data Available Boiling Point Not Applicable Flash Point > 200 ?F [Test Method: Pensky-Martens Closed Cup] Evaporation rate Not Applicable Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure Not Applicable Vapor Density Not Applicable Density 9.8 lb/gal Specific Gravity 1.180 [Ref Std: WATER=1] Solubility in Water Slight (less than 10%) Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Hazardous Air Pollutants 2.17 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 23 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 1.9 % weight [Test Method: calculated per CARB title 2] Percent volatile 1.90 % weight VOC Less H2O & Exempt Solvents 23 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 3M?Channel Bonding & Sidelite Adhesive PN 08641 - Part A 04/27/15 __________________________________________________________________________________________ Page 6 of 11 10.5. Incompatible materials None known. 10.6. Hazardous decomposition products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified Oxides of Nitrogen Not Specified Oxides of Sulfur Not Specified Toxic Vapor, Gas, Particulate Not Specified SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. Vapors released during curing may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Contact with the skin during product use is not expected to result in significant irritation. Eye Contact: Vapors released during curing may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Cardiac Effects: Signs/symptoms may include irregular heartbeat (arrhythmia), changes in heart rate, damage to heart muscle, heart attack, and may be fatal. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, 3M?Channel Bonding & Sidelite Adhesive PN 08641 - Part A 04/27/15 __________________________________________________________________________________________ Page 7 of 11 bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Inhalation- Dust/Mist(4 hr) No data available; calculated ATE 5 - 12.5 mg/l Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Dimethyl Siloxane, Reaction Product With Silica Dermal Rabbit LD50 > 5,000 mg/kg Dimethyl Siloxane, Reaction Product With Silica Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Dimethyl Siloxane, Reaction Product With Silica Ingestion Rat LD50 > 5,110 mg/kg Ethylene Glycol Ingestion Human LD50 1,600 mg/kg Ethylene Glycol Inhalation- Dust/Mist (4 hours) Other LC50 estimated to be 5 - 12.5 mg/l Ethylene Glycol Dermal Rabbit 9,530 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Dimethyl Siloxane, Reaction Product With Silica Rabbit No significant irritation Ethylene Glycol Rabbit Minimal irritation Serious Eye Damage/Irritation Name Species Value Dimethyl Siloxane, Reaction Product With Silica Rabbit No significant irritation Ethylene Glycol Rabbit Mild irritant Skin Sensitization Name Species Value Dimethyl Siloxane, Reaction Product With Silica Human and animal Not sensitizing Ethylene Glycol Human Some positive data exist, but the data are not sufficient for classification Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Dimethyl Siloxane, Reaction Product With Silica In Vitro Not mutagenic Ethylene Glycol In Vitro Not mutagenic Ethylene Glycol In vivo Not mutagenic Carcinogenicity Name Route Species Value Dimethyl Siloxane, Reaction Product With Silica Not Specified Mouse Some positive data exist, but the data are not sufficient for classification Ethylene Glycol Ingestion Multiple Not carcinogenic 3M?Channel Bonding & Sidelite Adhesive PN 08641 - Part A 04/27/15 __________________________________________________________________________________________ Page 8 of 11 animal species Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Dimethyl Siloxane, Reaction Product With Silica Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation Dimethyl Siloxane, Reaction Product With Silica Ingestion Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Dimethyl Siloxane, Reaction Product With Silica Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s Ethylene Glycol Ingestion Not toxic to female reproduction Multiple animal species NOAEL 1,000 mg/kg/day 2 years Ethylene Glycol Ingestion Not toxic to male reproduction Multiple animal species NOAEL 1,000 mg/kg/day 2 years Ethylene Glycol Dermal Some positive developmental data exist, but the data are not sufficient for classification Mouse NOAEL 3,549 mg/kg/day during organogenesi s Ethylene Glycol Ingestion Some positive developmental data exist, but the data are not sufficient for classification Mouse LOAEL 750 mg/kg/day during organogenesi s Ethylene Glycol Inhalation Some positive developmental data exist, but the data are not sufficient for classification Mouse NOAEL 1,000 mg/kg/day during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Ethylene Glycol Ingestion heart | nervous system | kidney and/or bladder | respiratory system Causes damage to organs Human NOAEL Not available poisoning and/or abuse Ethylene Glycol Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Ethylene Glycol Ingestion liver Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available poisoning and/or abuse Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Dimethyl Siloxane, Reaction Product With Silica Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure Ethylene Glycol Ingestion kidney and/or bladder | vascular system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 200 mg/kg/day 2 years Ethylene Glycol Ingestion heart | hematopoietic system | liver | immune system | muscles Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,000 mg/kg/day 2 years Ethylene Glycol Ingestion respiratory system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 12,000 mg/kg/day 2 years Ethylene Glycol Ingestion skin | endocrine system | bone, teeth, nails, and/or hair | All data are negative Multiple animal species NOAEL 1,000 mg/kg/day 2 years 3M?Channel Bonding & Sidelite Adhesive PN 08641 - Part A 04/27/15 __________________________________________________________________________________________ Page 9 of 11 nervous system | eyes Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of waste product in a permitted industrial waste facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Ethylene Glycol 107-21-1 1 - 5 15.2. State Regulations Contact 3M for more information. 3M?Channel Bonding & Sidelite Adhesive PN 08641 - Part A 04/27/15 __________________________________________________________________________________________ Page 10 of 11 California Proposition 65 Ingredient C.A.S. No. Classification CHROMIUM (HEXAVALENT COMPOUNDS) None Female reproductive toxin CHROMIUM (HEXAVALENT COMPOUNDS) None Male reproductive toxin CHROMIUM (HEXAVALENT COMPOUNDS) None Carcinogen CHROMIUM (HEXAVALENT COMPOUNDS) None Developmental Toxin LEAD 7439-92-1 Female reproductive toxin LEAD 7439-92-1 Male reproductive toxin LEAD 7439-92-1 Carcinogen LEAD 7439-92-1 Developmental Toxin CADMIUM 7440-43-9 Male reproductive toxin CADMIUM 7440-43-9 Carcinogen CADMIUM 7440-43-9 Developmental Toxin WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. WARNING: This product contains a chemical known to the State of California to cause cancer. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 1 Instability: 1 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 10-5979-9 Version Number: 45.01 Issue Date: 04/27/15 Supercedes Date: 03/03/15 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M?Channel Bonding & Sidelite Adhesive PN 08641 - Part A 04/27/15 __________________________________________________________________________________________ Page 11 of 11 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com