SAFETY DATA SHEET Per OSHA HCS PAGE 1 Date SDS Printed & Reviewed: 06/03/15 Last Formula Revision Date: 06/13/14 (APF) SECTION 1: IDENTIFICATION PRODUCT IDENTIFIER: GM VEHICLE CARE GLASS ADHESION PROMOTER 1#12378555 USE BY XX/XX/XX OTHER MEANS OF IDENTIFICATION (FOR CHEMTREC): FORMULA # 30N024N11B RECOMMENDED USE OF THE CHEMICAL: AEROSOL SPRAY SUPPLIER DETAILS: MANUFACTURED BY: Custom-Pak Products Inc. N118 W18981 Bunsen Drive Germantown, WI 53022 (262) 251-6180 EMERGENCY TELEPHONE NUMBERS: Chemtrec 24-hour Emergency Phone: (800) 424-9300 Chemtrec Foreign Emergency Phone: (703) 527-3887 SECTION 2: HAZARDS IDENTIFICATION CLASSIFICATION OF THE SUBSTANCE OF MIXTURE: Flammable Aerosols, Category 1 Gasses Under Pressure, Category Compressed Liquid Skin Corrosion/Irritation, Category 2 Serious Eye Damage/Eye Irritation, Category 2A Specific Target Organ Toxicity - Single Exposure, Category 3 HAZARD PICTOGRAMS: GHS02 Flame, GHS04 Gas Cylinder, GHS07 Exclamation Mark SIGNAL WORD: DANGER HAZARD STATEMENTS: H222 Extremely flammable aerosol. H280 Contains gas under pressure; may explode if heated. H315 Causes skin irritation. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. PRECAUTIONARY STATEMENTS: GENERAL & PREVENTION: P102 Keep out of reach of children. P210 Keep away from heat/sparks/open flames/other ignition sources. No smoking. P211 Do not spray on an open flame or other ignition source. P251 Pressurized container: Do not pierce or burn, even after use. P261 Avoid breathing vapor/spray. P264 Wash hands thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear eye protection. RESPONSE: P302+P352 IF ON SKIN: Wash with plenty of soap and water. CONTINUED--> 10-1011, 12378555 - ACDelco Glass Adhesion Promoter SAFETY DATA SHEET Per OSHA HCS PAGE 2 PRODUCT IDENTIFIER: GM VEHICLE CARE GLASS ADHESION PROMOTER 1#12378555 USE BY XX/XX/XX ----------------------------------------------------------------------------------------------- P304+P340 IF INHALED: Remove victim to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. P312 Call a POISON CENTER/doctor if you feel unwell. P337+P313 If eye irritation persists: Get medical advice/attention. STORAGE: P403+P233 Store in a well-ventilated place. Keep container tightly closed when not in use. P410+P403 Protect from sunlight. Store in a well-ventilated place. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 degrees C/122 degrees F. DISPOSAL: P501 Dispose of contents/container in accordance with local/regional/national regulations. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS # COMPONENT CAS# % by WT. 1 ISOPROPYL ALCOHOL 67-63-0 75.6 2 PROPANE 74-98-6 16.3 3 N-BUTANE 106-97-8 7.7 4 SILANE 2530-83-8 0.4 SECTION 4 - FIRST AID MEASURES Inhalation: If inhaled: Move person to fresh air and keep in comfortable position for breathing. If breathing difficulty persists: Get medical advice/attention. Skin Contact: If on skin: Wash with plenty of soap and water. Remove contaminated clothing and wash before reuse. If skin irritation persists: Get medical advice/attention. Eye Contact: If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion: If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting unless directed to do so by medical personnel. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED: See Section 11: Toxicological Information and effects. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT REQUIRED: Treat symptomatically. SECTION 5 - FIRE-FIGHTING MEASURES Suitable Extinguishing Media: CO2 (Carbon Dioxide), dry chemical, or water fog. Unsuitable Extinguishing Media: Water spray may be unsuitable. However, if water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible explosion when exposed to extreme heat. Specific Hazards Arising From the Chemical: Closed containers exposed to heat from fire may build pressure and explode. Products of combustion may include but are not limited to: oxides of carbon. Special Protective Equipment and Precautions for Fire-Fighters: Full protective equipment including self-contained breathing apparatus should be used. SECTION 6 - ACCIDENTAL RELEASE MEASURES CONTINUED--> SAFETY DATA SHEET Per OSHA HCS PAGE 3 PRODUCT IDENTIFIER: GM VEHICLE CARE GLASS ADHESION PROMOTER 1#12378555 USE BY XX/XX/XX ----------------------------------------------------------------------------------------------- Personal Precautions: Use personal protection recommended in Section 8. Environmental Precautions: Prevent contamination of soil/ground, waterways, drains, and sewers. Methods of Containment: Absorb spilled liquid in suitable material. Methods for Clean-Up: Use spark-proof tools to sweep or scrape up, containerize, and dispose of properly. Other Information: Ensure adequate ventilation. SECTION 7 - HANDLING AND STORAGE Precautions for Safe Handling: Vapors may ignite explosively. Prevent buildup of vapors. Keep from sparks, heat, flame or other heat sources. Do not smoke. Turn off pilot lights, heaters, electric motors and other sources of ignition during use and until all vapors are gone. Do not puncture or incinerate/burn container. Keep container tightly closed while not in use. Conditions for Safe Storage, Including Any Incompatibilities: Store in dry, well-ventilated area and in accordance with federal, state, and local regulations. Do not expose to heat or store at temperatures above 50 degrees C / 122 degrees F. If storing in cold temperatures, allow product to warm to room temperature before use. Keep container tightly closed and away from heat and sunlight when not in use. SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION CONTROL PARAMETERS # COMPONENT ACGIH TLV-STEL ACGIH TLV-TWA OSHA PEL-TWA 1 ISOPROPYL ALCOHOL 400 ppm 200 ppm 400 ppm 2 PROPANE 1800 ppm 2500 ppm 1000 ppm 3 N-BUTANE N/E 800 ppm 800 ppm 4 SILANE 250 ppm 200 ppm 200 ppm APPROPRIATE ENGINEERING CONTROLS: Provide adequate ventilation to keep air contamination below OSHA permissible exposure limits and ACGIH TLV exposure levels. EYE/FACE PROTECTION: Wear safety glasses with side shields. Have eye wash facilities immediately available. SKIN PROTECTION: Wear chemical resistant gloves if contact is likely. RESPIRATORY PROTECTION: Use NIOSH-approved air-purifying respirator with organic cartridge or canister if exposure cannot be controlled within applicable limits with ventilation. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Aerosol - Pressurized Liquid COLOR: See product identification ODOR: SOLVENT ODOR ODOR THRESHOLD: No data available pH: No data available FREEZING POINT: Not Established (mixture) BOILING POINT: Not Applicable (pressurized mixture) FLASH POINT: <-18 degrees C (<-0.4 degrees F), c.c. EVAPORATION RATE: Faster than ether UPPER FLAMMABILITY LIMIT: Not Established (mixture) LOWER FLAMMABILITY LIMIT: Not Established (mixture) CONTINUED--> SAFETY DATA SHEET Per OSHA HCS PAGE 4 PRODUCT IDENTIFIER: GM VEHICLE CARE GLASS ADHESION PROMOTER 1#12378555 USE BY XX/XX/XX ----------------------------------------------------------------------------------------------- VAPOR PRESSURE: Not Established (pressurized mixture) SPECIFIC GRAVITY: 0.708 SOLUBILITY (WATER): Negligible VOC PERCENT BY WEIGHT: 99.6 HAPS PERCENT BY WEIGHT: 0 SECTION 10: STABILITY AND REACTIVITY CHEMICAL STABILITY: Stable under normal conditions. POSSIBILITY OF HAZARDOUS REACTIONS: Will not occur. CONDITIONS TO AVOID: Keep away from heat, sparks, and flames. INCOMPATIBLE MATERIALS: Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: by fire - Carbon Dioxide and Carbon Monoxide SECTION 11: TOXICOLOGICAL INFORMATION LIKELY ROUTES OF ENTRY: Skin contact, Inhalation, Eye contact, Ingestion SIGNS AND SYMPTOMS OF EXPOSURE: Skin Contact: Signs/symptoms may include localized redness, itching, drying and cracking of skin. Inhalation: Intentional concentration and inhalation may be harmful or fatal. Eye Contact: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. TARGET ORGANS POTENTIALLY AFFECTED BY EXPOSURE: Central nervous system, kidneys, lungs, liver, eyes, skin, brain, respiratory tract, urinary tract, reproductive system, cardiovascular system TOXICOLOGICAL DATA: # COMPONENT LD50 ORAL LD50 DERMAL 1. ISOPROPYL ALCOHOL 4700 13000 2. PROPANE 1000 1800 3. N-BUTANE N/E N/E 4. SILANE N/E N/E SECTION 12: ECOLOGICAL INFORMATION No data available. SECTION 13: DISPOSAL CONSIDERATIONS Dispose of container and its contents in accordance with federal, state, and local regulations. Do not puncture, incinerate, or place container in trash compactor. SECTION 14: TRANSPORTATION INFORMATION GROUND (D.O.T./49 CFR): CONTINUED--> SAFETY DATA SHEET Per OSHA HCS PAGE 5 PRODUCT IDENTIFIER: GM VEHICLE CARE GLASS ADHESION PROMOTER 1#12378555 USE BY XX/XX/XX ----------------------------------------------------------------------------------------------- UN I.D. Number: UN1950 Transport Hazard Class: 2.1 Packing Group: - (not applicable) Proper Shipping Name: AEROSOLS (",FLAMMABLE" is optional to add after AEROSOLS) Hazard label: Limited Quantity (LTD QTY) label -- see 49 CFR 172.315 Shipping papers format: UN1950, AEROSOLS, 2.1, LTD QTY (can add ",FLAMMABLE" after AEROSOLS) AIR (IATA): UN I.D. Number: UN1950 Transport Hazard Class: 2.1 Packing Group: - (not applicable) Proper Shipping Name: AEROSOLS, FLAMMABLE Packing Instruction: Y203 Hazard labels: LTD QTY label with "Y" in it, and Flammable Gas label Shipping papers format: UN1950, AEROSOLS, FLAMMABLE, 2.1 (Note LTD QTY not needed on papers) WATER (IMDG): UN I.D. Number: UN1950 Transport Hazard Class: 2.1 Packing Group: - (not applicable) Proper Shipping Name: AEROSOLS Hazard label: LTD QTY label (see IMDG 3.4.5.1) Packing Instruction: P003,LP02 EmS: F-D,S-U Stowage and Segregation: Category A Shipping papers format: UN1950, AEROSOLS, 2.1, (-18 C c.c.), LTD QTY No component of this product is a listed Marine Pollutant (49 CFR 172,101,Appendix B). SECTION 15: REGULATORY INFORMATION International Chemical Inventory All components of this product are listed on or exempt from the following inventories: TSCA (United States), CEPA/DSL (Canada), AICS (Australia), IECSC (China) SECTION 16: OTHER INFORMATION REVISION DATE: 06/13/14 HMIS & NFPA Hazard Scale: 0=minimal, 1=slight, 2=moderate, 3=serious, 4=severe HMIS(American Coatings Association?s Hazardous Material Identification System): Health = 2 Flammability = 4 Physical Hazard = 1 NFPA 704(National Fire Protection Association?s Hazard Identification Ratings System): Health = 2 Flammability = 4 Instablity = 1 This SDS is based on information believed to be reliable and accurate. Because of changing reporting requirements and other variables it is impossible to guarantee with complete accuracy all the information contained in this document. It is the responsibility of the user to determine proper personal protection based on actual condition of use and to comply with all federal, state, and local laws and regulations.