JOHNSEN'S DOT 5 BRAKE FLUID 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 09/10/2014 : Version: 07/08/2015 EN (English US) 1/7 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : JOHNSEN'S DOT 5 BRAKE FLUID 12 FL.OZ. Product code : 7012-6 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Silicone Brake Fluid 1.3. Details of the supplier of the safety data sheet Technical Chemical Company P.O. BOX 139 Cleburne, Texas 76033 T 817-645-6088 1.4. Emergency telephone number Emergency number : CHEMTREC 24 Hour 1-800-424-9300, 1-703-527-3887 (International) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Carc. 2 H351 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS08 Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H351 - Suspected of causing cancer Precautionary statements (GHS-US) : P201 - Obtain special instructions P202 - Do not handle until all safety precautions have been read and understood P280 - Wear protective gloves,protective clothing,eye protection,face protection P308+P313 - If exposed or concerned: Get medical advice/attention P405 - Store locked up P501 - Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. 2.3. Other hazards Other hazards not contributing to the classification : None under normal conditions. 2.4. Unknown acute toxicity (GHS US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification (GHS-US) Polydimethylsiloxane (CAS No) 63148-62-9 < 95 Not classified Bis(2-Ethylhexyl) Sebacate (CAS No) 122-62-3 3 - 7 Not classified Tributyl Phosphate (CAS No) 126-73-8 1 - 5 Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Carc. 2, H351 The exact percentage is a trade secret. JOHNSEN'S DOT 5 BRAKE FLUID 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 07/08/2015 EN (English US) 2/7 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). Suspected of causing cancer. First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : If you feel unwell, seek medical advice. Symptoms/injuries after inhalation : Coughing. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Symptoms/injuries after skin contact : Itching. Red skin. Skin rash/inflammation. Symptoms/injuries after eye contact : Irritation of the eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. 6.1.1. For non-emergency personnel Protective equipment : Gloves. Safety glasses. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers. Plug the leak, cut off the supply. Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Obtain special instructions . Do not handle until all safety precautions have been read and understood. Hygiene measures : Do not eat, drink or smoke when using this product. Wash affected areas thoroughly after handling. Wash contaminated clothing before reuse. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. JOHNSEN'S DOT 5 BRAKE FLUID 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 07/08/2015 EN (English US) 3/7 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Comply with applicable regulations. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. 7.3. Specific end use(s) Follow Label Directions. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls : Local exhaust venilation, vent hoods . Ensure good ventilation of the work station. Personal protective equipment : Gloves. Safety glasses. Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Respiratory protection : Wear appropriate mask. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Liquid. Color : Violet. Odor : Mild. Odor threshold : No data available pH : No data available Relative evaporation rate (butyl acetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : No data available Flash point : ? 206 ?C Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : No data available Relative vapor density at 20 ?C : No data available Relative density : 0.97 Solubility : Insoluble in water. Log Pow : No data available Log Kow : No data available Viscosity, kinematic : 45 cSt Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosion limits : No data available 9.2. Other information VOC content : 0 % SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available JOHNSEN'S DOT 5 BRAKE FLUID 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 07/08/2015 EN (English US) 4/7 10.2. Chemical stability Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Toxic fume. . Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified Polydimethylsiloxane (63148-62-9) LD50 oral rat > 15400 mg/kg body weight (Rat; Literature study) LD50 dermal rabbit > 2000 mg/kg body weight (Rabbit; Literature study) Bis(2-Ethylhexyl) Sebacate (122-62-3) LD50 oral rat > 2000 mg/kg (Rat) Tributyl Phosphate (126-73-8) LD50 oral rat 1552 mg/kg (Rat; Other; Experimental value) LD50 dermal rabbit > 3100 mg/kg (Rabbit; Experimental value; Other) LC50 inhalation rat (mg/l) > 4242 mg/l/4h (Rat; Experimental value) Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Suspected of causing cancer. Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Symptoms/injuries after inhalation : Coughing. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Symptoms/injuries after skin contact : Itching. Red skin. Skin rash/inflammation. Symptoms/injuries after eye contact : Irritation of the eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue. SECTION 12: Ecological information 12.1. Toxicity Polydimethylsiloxane (63148-62-9) LC50 fish 1 350 mg/l (LC50; 96 h; Pleuronectes platessa) EC50 Daphnia 1 > 200 mg/l (LC50; 48 h; Daphnia magna) Tributyl Phosphate (126-73-8) LC50 fish 2 4.2 - 11.8 mg/l (LC50; 96 h; Oncorhynchus mykiss; Static system; Fresh water) EC50 Daphnia 2 3.65 mg/l (EC50; 48 h; Daphnia magna) Threshold limit algae 2 2.8 mg/l (ErC50; DIN 38412-9; 72 h; Desmodesmus subspicatus; Fresh water) 12.2. Persistence and degradability JOHNSEN'S DOT 5 BRAKE FLUID 12 FL.OZ. Persistence and degradability Not established. Polydimethylsiloxane (63148-62-9) Persistence and degradability Biodegradability in water: no data available. Forming sediments in water. Biodegradable in the soil. No (test)data on mobility of the substance available. JOHNSEN'S DOT 5 BRAKE FLUID 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 07/08/2015 EN (English US) 5/7 Bis(2-Ethylhexyl) Sebacate (122-62-3) Persistence and degradability Readily biodegradable in water. Tributyl Phosphate (126-73-8) Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available. 12.3. Bioaccumulative potential JOHNSEN'S DOT 5 BRAKE FLUID 12 FL.OZ. Bioaccumulative potential Not established. Polydimethylsiloxane (63148-62-9) Bioaccumulative potential Not bioaccumulative. Bis(2-Ethylhexyl) Sebacate (122-62-3) Bioaccumulative potential No bioaccumulation data available. Tributyl Phosphate (126-73-8) BCF fish 1 5.5 - 20 (BCF; OECD 305: Bioconcentration: Flow-Through Fish Test; 6 weeks; Cyprinus carpio; Semi-static system; Fresh water; Experimental value; Fresh weight) Log Pow 4.0 (Experimental value; US EPA) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). 12.4. Mobility in soil Polydimethylsiloxane (63148-62-9) Ecology - soil Not toxic to plants. Tributyl Phosphate (126-73-8) Surface tension 0.029 N/m (20 ?C) 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN US DOT (ground): Not Regulated, ICAO/IATA (air): Not Regulated, IMO/IMDG (water): Not Regulated, Not applicable 14.2. UN proper shipping name Proper Shipping Name (DOT) : Not Regulated 14.3. Additional information Other information : No supplementary information available. Overland transport No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations JOHNSEN'S DOT 5 BRAKE FLUID 12 FL.OZ. Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard Immediate (acute) health hazard JOHNSEN'S DOT 5 BRAKE FLUID 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 07/08/2015 EN (English US) 6/7 15.2. International regulations CANADA JOHNSEN'S DOT 5 BRAKE FLUID 12 FL.OZ. Listed on the Canadian DSL (Domestic Sustances List) WHMIS Classification Class D Division 2 Subdivision B - Toxic material causing other toxic effects EU-Regulations JOHNSEN'S DOT 5 BRAKE FLUID 12 FL.OZ. Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Carc.Cat.3; R40 Full text of R-phrases: see section 16 15.2.2. National regulations JOHNSEN'S DOT 5 BRAKE FLUID 12 FL.OZ. Listed on KECI (Korean Existing Chemicals Inventory) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) 15.3. US State regulations JOHNSEN'S DOT 5 BRAKE FLUID 12 FL.OZ. U.S. - California - Proposition 65 - Carcinogens List No U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No Polydimethylsiloxane (63148-62-9) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) No No No No Bis(2-Ethylhexyl) Sebacate (122-62-3) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) No No No No Tributyl Phosphate (126-73-8) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) No No No No SECTION 16: Other information Other information : None. Full text of H-phrases: ------ Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4 ------ Carc. 2 Carcinogenicity Category 2 ------ Skin Irrit. 2 Skin corrosion/irritation Category 2 ------ H302 Harmful if swallowed ------ H315 Causes skin irritation ------ H351 Suspected of causing cancer JOHNSEN'S DOT 5 BRAKE FLUID 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 07/08/2015 EN (English US) 7/7 NFPA health hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health : 2 Moderate Hazard - Temporary or minor injury may occur Flammability : 1 Slight Hazard Physical : 0 Minimal Hazard Personal Protection : B SDS US (GHS HazCom 2012) - TCC The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied.