JOHNSEN'S R134A 12 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 09/23/2014 : Version: 05/11/2014 EN (English US) 1/8 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Substance Trade name : JOHNSEN'S R134A 12 OZ. CAS No : 811-97-2 Product code : 6312 Formula : C2H2F4 Synonyms : 1,1,1,2-Tetrafluoroethane (refrigerant gas R134a) / ARCTON 134a / ethane, 1,1,1,2-tetrafluoro- / F 134a / FC 134a / formacel Z-4 blowing agent / FREON 134a / genetron 134a / HCFC-134a / HFA 134a / HFC-134a / HFC-134a tetrafluorethane / HFC-134a tetrafluoroethane / KHLADON 134a / norflurane / R134a / R134a COLD SHOT / refrigerant R134a / refrigerant R134a COLD SHOT / SUVA 134a / SUVA cold-mp / SUVA trans a/c / SUVA-134a tetrafluoroethane / tetrafluoroethane / TG 134a 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Refrigerant 1.3. Details of the supplier of the safety data sheet Technical Chemical Company P.O. BOX 139 Cleburne, Texas 76033 T 817-645-6088 1.4. Emergency telephone number Emergency number : CHEMTREC 24 Hour 1-800-424-9300, 1-703-527-3887 (International) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Liquefied gas H280 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS04 Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H280 - Contains gas under pressure; may explode if heated Precautionary statements (GHS-US) : P410+P403 - Protect from sunlight. Store in a well-ventilated place P251 - Pressurized container: Do not pierce or burn, even after use P501 - Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F 2.3. Other hazards Other hazards not contributing to the classification : Contains gas under pressure; may explode if heated. Intentional misuse and inhalation abuse may cause cardiac or central nervous systems effects. Warning. May Cause frostbite in contact with skin. (Liquid form can be ejected if the aerosol can is not held upright during use.) Warning. This product dispenses liquid. Liquid may drip onto skin causing frostbite, blistering, red skin. WARNING. . Asphyxiant in high concentrations. 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Name : 1,1,1,2-Tetrafluoroethane CAS No : 811-97-2 EC no : 212-377-0 JOHNSEN'S R134A 12 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2014 EN (English US) 2/8 Name Product identifier % Classification (GHS-US) 1,1,1,2-Tetrafluoroethane (Main constituent) (CAS No) 811-97-2 > 99 Liquefied gas, H280 Full text of H-phrases: see section 16 3.2. Mixture Not applicable SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with laboured breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on the victim's condition: doctor/hospital. Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service. Assure fresh air breathing. Allow the victim to rest. First-aid measures after skin contact : Rinse with water. Take victim to a doctor if irritation persists. In case of frostbites: Wash immediately with lots of water (15 minutes)/shower. Do not apply (chemical) neutralizing agents. Remove clothing while washing. Do not remove clothing if it sticks to the skin. Cover wounds with sterile bandage. Consult a doctor/medical service. If burned surface > 10%: take victim to hospital. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Thaw frosted parts with lukewarm water. Do no rub affected area. Get immediate medical advice/attention. First-aid measures after eye contact : Rinse immediately with plenty of water for 15 minutes. Do not apply neutralizing agents. Take victim to an ophthalmologist. Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Not applicable. Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. Symptoms/injuries after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Accelerated heart action. Disturbances of heart rate. Coordination disorders. Feeling of weakness. Respiratory difficulties. Vomiting. Nausea. Disturbances of consciousness. Risk of lung oedema. Respiratory collapse. Symptoms/injuries after skin contact : Red skin. Blisters. Frostbites. Symptoms/injuries after eye contact : Not applicable. Symptoms/injuries after ingestion : Not applicable. Chronic symptoms : No effects known. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : EXTINGUISHING MEDIA FOR SURROUNDING FIRES : Adapt extinguishing media to the environment. Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : No unsuitable extinguishing media known. Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : DIRECT FIRE HAZARD. Non combustible. Explosion hazard : INDIRECT EXPLOSION HAZARD. Heat may cause pressure rise in tanks/drums: explosion risk. Reactivity : On burning: release of toxic and corrosive gases/vapours (hydrofluoric acid, carbon monoxide - carbon dioxide, carbonylfluoride). Reacts with (some) acids. 5.3. Advice for firefighters Precautionary measures fire : Exposure to fire/heat: consider evacuation. Firefighting instructions : Cool tanks/drums with water spray/remove them into safety. Physical explosion risk: cool from behind cover. Do not move the load if exposed to heat. After cooling: persistant risk of physical explosion. Dilute toxic gases with water spray. Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Heat/fire exposure: compressed air/oxygen apparatus. Do not enter fire area without proper protective equipment, including respiratory protection. Other information : NFPA Aerosol Level 1. JOHNSEN'S R134A 12 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2014 EN (English US) 3/8 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Protective equipment : Insulating gloves. Protective clothing. Large spills/in enclosed spaces: compressed air apparatus. Emergency procedures : Keep upwind. Mark the danger area. Seal off low-lying areas. Close doors and windows of adjacent premises. No naked flames. Carry out specific temperature controls. Wash contaminated clothes. Large spills/in confined spaces: consider evacuation. Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Contain released substance, pump into suitable containers. Plug the leak, cut off the supply. Tip the container on one side to stop the leakage. Do not spray water on unheated tank walls. Methods for cleaning up : Damaged/cooled tanks must be emptied. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Pressurized container: Do not pierce or burn, even after use. Precautions for safe handling : Comply with the legal requirements. Handle and open the container with care. Thoroughly clean/dry the installation before use. Keep away from naked flames/heat. Observe normal hygiene standards. Carry operations in the open/under local exhaust/ventilation or with respiratory protection. Measure the oxygen concentration in the air. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Wash affected areas thoroughly after handling. Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Comply with applicable regulations. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Storage temperature : < 50 ?C Heat-ignition : KEEP SUBSTANCE AWAY FROM: heat sources. Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: (strong) acids. Storage area : Store in a cool area. Keep out of direct sunlight. Ventilation at floor level. Aboveground. Meet the legal requirements. Store in a well-ventilated place. Special rules on packaging : SPECIAL REQUIREMENTS: with pressure relief valve. clean. correctly labelled. meet the legal requirements. Packaging materials : SUITABLE MATERIAL: No data available. MATERIAL TO AVOID: No data available. 7.3. Specific end use(s) Follow Label Directions. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls : Local exhaust venilation, vent hoods. Personal protective equipment : Gloves. Safety glasses. Avoid all unnecessary exposure. JOHNSEN'S R134A 12 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2014 EN (English US) 4/8 Materials for protective clothing : GIVE GOOD RESISTANCE: neoprene. nitrile rubber. butyl rubber. Hand protection : Insulated gloves. Wear protective gloves. Eye protection : Safety glasses. Chemical goggles or safety glasses. Skin and body protection : Protective clothing. Respiratory protection : High vapour/gas concentration: self-contained respirator. Wear appropriate mask. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Gas Appearance : Liquefied gas. Molecular mass : 102.03 g/mol Color : Colourless. Odor : Ether-like odour. Odor threshold : No data available pH : No data available Relative evaporation rate (butyl acetate=1) : No data available Melting point : -101 ?C Freezing point : No data available Boiling point : -26 ?C Flash point : No data available Critical temperature : 101 ?C Auto-ignition temperature : > 743 ?C Decomposition temperature : 368 ?C Flammability (solid, gas) : No data available Vapor pressure : 6661 hPa @ 25 deg C Vapor pressure at 50 ?C : 13190 hPa Critical pressure : 40560 hPa Relative vapor density at 20 ?C : < 3.52 @ 20 deg C Relative density : 1.2 @ -27 deg C Specific gravity / density : 1206 kg/m? @ -27 deg C Solubility : Poorly soluble in water. Soluble in ethanol. Soluble in ether. Soluble in hexane. Water: 0.15 g/100ml @ 25 deg C Log Pow : 1.06 (OECD 107: Partition Coefficient (n-octanol/water): Shake Flask Method) Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information VOC content : 0 % Other properties : Gas/vapour heavier than air at 20?C. Substance has neutral reaction. May generate electrostatic charges. SECTION 10: Stability and reactivity 10.1. Reactivity On burning: release of toxic and corrosive gases/vapours (hydrofluoric acid, carbon monoxide - carbon dioxide, carbonylfluoride). Reacts with (some) acids. 10.2. Chemical stability Stable under normal conditions. Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. JOHNSEN'S R134A 12 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2014 EN (English US) 5/8 10.6. Hazardous decomposition products Toxic fume. . Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified JOHNSEN'S R134A 12 OZ. ( \f )811-97-2 LC50 inhalation rat (mg/l) > 2000 mg/l/4h (Rat; Literature study) LC50 inhalation rat (ppm) > 359300 ppm/4h (Rat; Literature study) Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Symptoms/injuries after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Accelerated heart action. Disturbances of heart rate. Coordination disorders. Feeling of weakness. Respiratory difficulties. Vomiting. Nausea. Disturbances of consciousness. Risk of lung oedema. Respiratory collapse. Symptoms/injuries after skin contact : Red skin. Blisters. Frostbites. Symptoms/injuries after eye contact : Not applicable. Symptoms/injuries after ingestion : Not applicable. Chronic symptoms : No effects known. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : No environmental hazard. Ecology - air : Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009). Included in the list of substances which may contribute to the greenhouse effect (Regulation (EC) No 842/2006). TA-Luft Klasse 5.2.5. Ecology - water : Mild water pollutant (surface water). Maximum concentration in drinking water: 1.5 mg/l (fluoride) (Directive 98/83/EC). Slightly harmful to fishes (LC50(96h) 100-1000 mg/l). Slightly harmful to invertebrates (Daphnia) (EC50 (48h): 100 - 1000 mg/l). JOHNSEN'S R134A 12 OZ. (811-97-2) LC50 fish 1 450 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) EC50 Daphnia 1 980 mg/l (48 h; Daphnia magna) 12.2. Persistence and degradability JOHNSEN'S R134A 12 OZ. (811-97-2) Persistence and degradability Not readily biodegradable in water. Not established. 12.3. Bioaccumulative potential JOHNSEN'S R134A 12 OZ. (811-97-2) BCF other aquatic organisms 1 5 - 58 (Estimated value) Log Pow 1.06 (OECD 107: Partition Coefficient (n-octanol/water): Shake Flask Method) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Other information : Avoid release to the environment. JOHNSEN'S R134A 12 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2014 EN (English US) 6/8 SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Remove waste in accordance with local and/or national regulations. Hazardous waste shall not be mixed together with other waste. Different types of hazardous waste shall not be mixed together if this may entail a risk of pollution or create problems for the further management of the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or handle hazardous waste shall take the necessary measures to prevent risks of pollution or damage to people or animals. Refer to manufacturer/supplier for information on recovery/ recycling. Dispose in a safe manner in accordance with local/national regulations. Additional information : LWCA (the Netherlands): KGA category 06. Hazardous waste according to Directive 2008/98/EC. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN US DOT (ground): UN3159, 1,1,1,2-Tetrafluoroethane, 2.2, Limited Quantity ICAO/IATA (air): UN3159, 1,1,1,2-Tetrafluoroethane, 2.2 , Limited Quantity IMO/IMDG (water): UN3159, 1,1,1,2-Tetrafluoroethane, 2.2 , Limited Quantity Special Provisions: DOT-SP 10232: In accordance with this special permit, the product container is marked with DOT-SP10232 instead of 2Q. This packaging is approved for shipping as a Consumer Commodity. T50 - When portable tank instruction T50 is referenced in Column (7) of the 172.101 Table, the applicable liquefied compressed gases are authorized to be transported in portable tanks in accordance with the requirements of 173.313 of this subchapter. Not applicable 14.2. UN proper shipping name Proper Shipping Name (DOT) : 1,1,1,2-Tetrafluoroethane Department of Transportation (DOT) Hazard Classes : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115 Hazard labels (DOT) : 2.2 - Non-flammable gas DOT Special Provisions (49 CFR 172.102) : DOT-SP 10232: In accordance with this special permit, the product container is marked with DOT-SP10232 instead of 2Q. This packaging is approved for shipping as a Consumer Commodity. T50 - When portable tank instruction T50 is referenced in Column (7) of the 172.101 Table, the applicable liquefied compressed gases are authorized to be transported in portable tanks in accordance with the requirements of 173.313 of this subchapter. DOT Packaging Exceptions (49 CFR 173.xxx) : 306 DOT Packaging Non Bulk (49 CFR 173.xxx) : 304 DOT Packaging Bulk (49 CFR 173.xxx) : 314;315 14.3. Additional information Other information : No supplementary information available. Overland transport Class (ADR) : 2 - Gases Hazard identification number (Kemler No.) : 20 Classification code (ADR) : 2A Hazard labels (ADR) : 2.2 - Non-flammable compressed gas Orange plates : Tunnel restriction code (ADR) : C/E JOHNSEN'S R134A 12 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2014 EN (English US) 7/8 Transport by sea DOT Vessel Stowage Location : A - The material may be stowed ??on deck?? or ??under deck?? on a cargo vessel and on a passenger vessel. EmS-No. (1) : F-C EmS-No. (2) : S-V Air transport DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : 75 kg DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : 150 kg SECTION 15: Regulatory information 15.1. US Federal regulations JOHNSEN'S R134A 12 OZ. (811-97-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Sudden release of pressure hazard Immediate (acute) health hazard 15.2. International regulations CANADA JOHNSEN'S R134A 12 OZ. (811-97-2) WHMIS Classification Class A - Compressed Gas EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Press. Gas Full text of H-phrases: see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified 15.2.2. National regulations No additional information available 15.3. US State regulations No additional information available SECTION 16: Other information Other information : None. Full text of H-phrases: see section 16: ------ Liquefied gas Gases under pressure Liquefied gas ------ H280 Contains gas under pressure; may explode if heated NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA fire hazard : 0 - Materials that will not burn. NFPA reactivity : 1 - Normally stable, but can become unstable at elevated temperatures and pressures or may react with water with some release of energy, but not violently. HMIS III Rating Health : 1 Slight Hazard - Irritation or minor reversible injury possible Flammability : 0 Minimal Hazard Physical : 1 Slight Hazard JOHNSEN'S R134A 12 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2014 EN (English US) 8/8 Personal Protection : B SDS US (GHS HazCom 2012) - TCC The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied.