3M? Bare-Metal Seam Sealer- Beige PN 08310, 58310 08/31/15 ________________________________________________________________________________________________________ Page 1 of 2 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 22-8405-7 Version Number: 4.00 Issue Date: 08/31/15 Supercedes Date: 04/30/14 Product identifier 3M? Bare-Metal Seam Sealer- Beige PN 08310, 58310 ID Number(s): 41-3701-2168-7, 60-4550-3150-4, 60-4550-6990-0 Recommended use Sealant Supplier's details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AIL) for each of these components is included. Please do not separate the component documents from this cover page. The document numbers for components of this product are: 22-8167-3, 32-5666-6 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com 3M? Bare-Metal Seam Sealer- Beige PN 08310, 58310 08/31/15 ________________________________________________________________________________________________________ Page 2 of 2 3M? Bare-Metal Seam Sealer - Beige Part B (Base), PN 08310, 58310 04/30/14 __________________________________________________________________________________________ Page 1 of 12 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 22-8167-3 Version Number: 7.00 Issue Date: 04/30/14 Supercedes Date: 12/10/12 SECTION 1: Identification 1.1. Product identifier 3M? Bare-Metal Seam Sealer - Beige Part B (Base), PN 08310, 58310 1.2. Recommended use and restrictions on use Recommended use Sealant 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Serious Eye Damage/Irritation: Category 2B. Skin Sensitizer: Category 1. Reproductive Toxicity: Category 1B. Carcinogenicity: Category 1B. 2.2. Label elements Signal word Danger Symbols Exclamation mark | Health Hazard | Pictograms 3M? Bare-Metal Seam Sealer - Beige Part B (Base), PN 08310, 58310 04/30/14 __________________________________________________________________________________________ Page 2 of 12 Hazard Statements Causes eye irritation. May cause an allergic skin reaction. May damage fertility or the unborn child. May cause cancer. Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapors/spray. Wear protective gloves. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. Storage: Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified None. 22% of the mixture consists of ingredients of unknown acute oral toxicity. 89% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt 4,4'Isopropylidenediphenol-Epichlorohydrin Polymer 25068-38-6 40 - 70 Trade Secret * Epichlorohydrin-4,4'-(1- Methylethylidene)Biscyclohexanol Polymer 30583-72-3 10 - 30 Trade Secret * Dimethyl Siloxane, Reaction Product with Silica 67762-90-7 3 - 7 Trade Secret * Inorganic Filler Trade Secret* 1 - 5 Trade Secret * Inorganic Pigment (NJTSRNo. 04499600-6658) Trade Secret* 1 - 5 Trade Secret * 3M? Bare-Metal Seam Sealer - Beige Part B (Base), PN 08310, 58310 04/30/14 __________________________________________________________________________________________ Page 3 of 12 Epichlorohydrin 106-89-8 < 0.21 Trade Secret * NJTS or NJTSRN: New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. 5.3. Special protective actions for fire-fighters No unusual fire or explosion hazards are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate 3M? Bare-Metal Seam Sealer - Beige Part B (Base), PN 08310, 58310 04/30/14 __________________________________________________________________________________________ Page 4 of 12 authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Ingredient C.A.S. No. Agency Limit type Additional Comments Epichlorohydrin 106-89-8 Amer Conf of Gov. Indust. Hyg. TWA:0.5 ppm Skin Notation Epichlorohydrin 106-89-8 US Dept of Labor - OSHA TWA:19 mg/m3(5 ppm) Skin Notation Dimethyl Siloxane, Reaction Product with Silica 67762-90-7 Chemical Manufacturer Rec Guid CEIL:5 mg/m3 Inorganic Filler Trade Secret Chemical Manufacturer Rec Guid TWA(as respirable dust):3 mg/m3 Amer Conf of Gov. Indust. Hyg. : American Conference of Governmental Industrial Hygienists American Indust. Hygiene Assoc : American Industrial Hygiene Association Chemical Manufacturer Rec Guid : Chemical Manufacturer's Recommended Guidelines US Dept of Labor - OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Wear eye/face protection. Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the 3M? Bare-Metal Seam Sealer - Beige Part B (Base), PN 08310, 58310 04/30/14 __________________________________________________________________________________________ Page 5 of 12 results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Butyl Rubber Polymer laminate If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Solid Specific Physical Form: Paste Odor, Color, Grade: Beige. Epoxy odor. Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point Not Applicable Flash Point 239 ?F [Test Method: Estimated] Evaporation rate Not Applicable Flammability (solid, gas) Not Classified Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Vapor Pressure Not Applicable Vapor Density Not Applicable Density 1.16 - 1.18 g/cm3 Specific Gravity 1.16 [Ref Std: WATER=1] Solubility in Water Slight (less than 10%) Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Hazardous Air Pollutants 0.0000023 % weight [Test Method: Calculated] Volatile Organic Compounds 0.02 lb/gal [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 0.2 % weight [Test Method: calculated per CARB title 2] Volatile Organic Compounds 3 g/l [Test Method: calculated SCAQMD rule 443.1] Percent volatile 0.28 % VOC Less H2O & Exempt Solvents 3 g/l [Test Method: calculated SCAQMD rule 443.1] 3M? Bare-Metal Seam Sealer - Beige Part B (Base), PN 08310, 58310 04/30/14 __________________________________________________________________________________________ Page 6 of 12 SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat is generated during cure. Do not cure a mass larger than 50 grams in a confined space to prevent a premature exothermic reaction with production of intense heat and smoke. Sparks and/or flames 10.5. Incompatible materials Strong oxidizing agents Amines Strong acids 10.6. Hazardous decomposition products Substance Condition Aldehydes Not Specified Carbon monoxide Not Specified Carbon dioxide Not Specified Toxic Vapor, Gas, Particulate Not Specified SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. 3M? Bare-Metal Seam Sealer - Beige Part B (Base), PN 08310, 58310 04/30/14 __________________________________________________________________________________________ Page 7 of 12 Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation Epichlorohydrin 106-89-8 Anticipated human carcinogen National Toxicology Program Carcinogens Epichlorohydrin 106-89-8 Grp. 2A: Probable human carc. International Agency for Research on Cancer Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE 20 - 50 mg/l Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg 4,4'Isopropylidenediphenol-Epichlorohydrin Polymer Dermal Rat LD50 > 1,600 mg/kg 4,4'Isopropylidenediphenol-Epichlorohydrin Polymer Ingestion Rat LD50 > 1,000 mg/kg Dimethyl Siloxane, Reaction Product with Silica Dermal Rabbit LD50 > 5,000 mg/kg Dimethyl Siloxane, Reaction Product with Silica Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Dimethyl Siloxane, Reaction Product with Silica Ingestion Rat LD50 > 5,110 mg/kg Inorganic Filler Dermal Rabbit LD50 > 5,000 mg/kg Inorganic Filler Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Inorganic Filler Ingestion Rat LD50 > 5,110 mg/kg Epichlorohydrin Dermal Rabbit LD50 755 mg/kg Epichlorohydrin Inhalation- Vapor (4 hours) Rat LC50 1.7 mg/l Epichlorohydrin Ingestion Rat LD50 260 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value 4,4'Isopropylidenediphenol-Epichlorohydrin Polymer Rabbit Mild irritant Dimethyl Siloxane, Reaction Product with Silica Rabbit No significant irritation Inorganic Filler Rabbit No significant irritation Epichlorohydrin Human and animal Corrosive Serious Eye Damage/Irritation Name Species Value 4,4'Isopropylidenediphenol-Epichlorohydrin Polymer Rabbit Moderate irritant Dimethyl Siloxane, Reaction Product with Silica Rabbit No significant irritation Inorganic Filler Rabbit No significant irritation Epichlorohydrin Rabbit Corrosive 3M? Bare-Metal Seam Sealer - Beige Part B (Base), PN 08310, 58310 04/30/14 __________________________________________________________________________________________ Page 8 of 12 Skin Sensitization Name Species Value 4,4'Isopropylidenediphenol-Epichlorohydrin Polymer Human and animal Sensitizing Dimethyl Siloxane, Reaction Product with Silica Human and animal Not sensitizing Inorganic Filler Human and animal Not sensitizing Epichlorohydrin Human and animal Sensitizing Respiratory Sensitization Name Species Value 4,4'Isopropylidenediphenol-Epichlorohydrin Polymer Human Some positive data exist, but the data are not sufficient for classification Germ Cell Mutagenicity Name Route Value 4,4'Isopropylidenediphenol-Epichlorohydrin Polymer In vivo Not mutagenic 4,4'Isopropylidenediphenol-Epichlorohydrin Polymer In Vitro Some positive data exist, but the data are not sufficient for classification Dimethyl Siloxane, Reaction Product with Silica In Vitro Not mutagenic Inorganic Filler In Vitro Not mutagenic Epichlorohydrin In Vitro Some positive data exist, but the data are not sufficient for classification Epichlorohydrin In vivo Mutagenic Carcinogenicity Name Route Species Value 4,4'Isopropylidenediphenol-Epichlorohydrin Polymer Dermal Mouse Some positive data exist, but the data are not sufficient for classification Dimethyl Siloxane, Reaction Product with Silica Not Specified Mouse Some positive data exist, but the data are not sufficient for classification Inorganic Filler Not Specified Mouse Some positive data exist, but the data are not sufficient for classification Epichlorohydrin Dermal Mouse Not carcinogenic Epichlorohydrin Ingestion Rat Carcinogenic Epichlorohydrin Inhalation Rat Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration 4,4'Isopropylidenediphenol- Epichlorohydrin Polymer Ingestion Not toxic to female reproduction Rat NOAEL 750 mg/kg/day 2 generation 4,4'Isopropylidenediphenol- Epichlorohydrin Polymer Ingestion Not toxic to male reproduction Rat NOAEL 750 mg/kg/day 2 generation 4,4'Isopropylidenediphenol- Epichlorohydrin Polymer Dermal Not toxic to development Rabbit NOAEL 300 mg/kg/day during organogenesi s 4,4'Isopropylidenediphenol- Epichlorohydrin Polymer Ingestion Not toxic to development Rat NOAEL 750 mg/kg/day 2 generation Dimethyl Siloxane, Reaction Product with Silica Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation Dimethyl Siloxane, Reaction Product with Silica Ingestion Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Dimethyl Siloxane, Reaction Product with Silica Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s Inorganic Filler Ingestion Not toxic to female reproduction Rat NOAEL 509 1 generation 3M? Bare-Metal Seam Sealer - Beige Part B (Base), PN 08310, 58310 04/30/14 __________________________________________________________________________________________ Page 9 of 12 mg/kg/day Inorganic Filler Ingestion Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Inorganic Filler Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s Epichlorohydrin Inhalation Not toxic to female reproduction Rat NOAEL 0.2 mg/l 10 weeks Epichlorohydrin Inhalation Not toxic to development Multiple animal species NOAEL 0.09 mg/l during organogenesi s Epichlorohydrin Ingestion Some positive developmental data exist, but the data are not sufficient for classification Multiple animal species NOAEL 160 mg/kg/day during gestation Epichlorohydrin Ingestion Toxic to male reproduction Rat LOAEL 6.25 mg/kg/day 23 days Epichlorohydrin Inhalation Toxic to male reproduction Rat NOAEL 0.02 mg/l 10 weeks Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Epichlorohydrin Inhalation respiratory irritation May cause respiratory irritation Human NOAEL not available occupational exposure Epichlorohydrin Inhalation liver Some positive data exist, but the data are not sufficient for classification Human NOAEL not available occupational exposure Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration 4,4'Isopropylidenediphenol -Epichlorohydrin Polymer Dermal liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,000 mg/kg/day 2 years 4,4'Isopropylidenediphenol -Epichlorohydrin Polymer Dermal nervous system All data are negative Rat NOAEL 1,000 mg/kg/day 13 weeks 4,4'Isopropylidenediphenol -Epichlorohydrin Polymer Ingestion auditory system | heart | endocrine system | hematopoietic system | liver | eyes | kidney and/or bladder All data are negative Rat NOAEL 1,000 mg/kg/day 28 days Dimethyl Siloxane, Reaction Product with Silica Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure Inorganic Filler Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure Epichlorohydrin Inhalation liver Causes damage to organs through prolonged or repeated exposure Rat NOAEL 0.21 mg/l 19 days Epichlorohydrin Inhalation kidney and/or bladder May cause damage to organs though prolonged or repeated exposure Rat NOAEL 0.04 mg/l 136 weeks Epichlorohydrin Inhalation endocrine system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.377 mg/l 4 weeks Epichlorohydrin Inhalation immune system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 0.211 mg/l 4 weeks Epichlorohydrin Inhalation heart Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.02 mg/l 98 days 3M? Bare-Metal Seam Sealer - Beige Part B (Base), PN 08310, 58310 04/30/14 __________________________________________________________________________________________ Page 10 of 12 Epichlorohydrin Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL .002 mg/l 98 days Epichlorohydrin Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 0.02 mg/l 13 weeks Epichlorohydrin Inhalation blood All data are negative Rat NOAEL 0.189 mg/l 90 days Epichlorohydrin Ingestion heart | blood Some positive data exist, but the data are not sufficient for classification Rat NOAEL 80 mg/kg/day 12 weeks Epichlorohydrin Ingestion liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 25 mg/kg/day 90 days Aspiration Hazard Name Value Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of handling halogenated materials. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 3M? Bare-Metal Seam Sealer - Beige Part B (Base), PN 08310, 58310 04/30/14 __________________________________________________________________________________________ Page 11 of 12 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - Yes Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Epichlorohydrin 106-89-8 < 0.21 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification Methyl Alcohol 67-56-1 Developmental Toxin Epichlorohydrin 106-89-8 Male reproductive toxin Epichlorohydrin 106-89-8 Carcinogen WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. WARNING: This product contains a chemical known to the State of California to cause cancer. 15.3. Chemical Inventories The components of this material are in compliance with the provisions of Japan Industrial Safety and Health Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Japan Chemical Substance Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 1 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 22-8167-3 Version Number: 7.00 Issue Date: 04/30/14 Supercedes Date: 12/10/12 3M? Bare-Metal Seam Sealer - Beige Part B (Base), PN 08310, 58310 04/30/14 __________________________________________________________________________________________ Page 12 of 12 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com 3M? Bare-Metal Seam Sealer - Beige PN 08310, 58310 Part A 04/30/14 __________________________________________________________________________________________ Page 1 of 9 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 32-5666-6 Version Number: 2.00 Issue Date: 04/30/14 Supercedes Date: 08/26/13 SECTION 1: Identification 1.1. Product identifier 3M? Bare-Metal Seam Sealer - Beige PN 08310, 58310 Part A 1.2. Recommended use and restrictions on use Recommended use Automotive, Seam Sealer Accelerator to be used with Seam Sealer Base 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Serious Eye Damage/Irritation: Category 2A. 2.2. Label elements Signal word Warning Symbols Exclamation mark | Pictograms 3M? Bare-Metal Seam Sealer - Beige PN 08310, 58310 Part A 04/30/14 __________________________________________________________________________________________ Page 2 of 9 Hazard Statements Causes serious eye irritation. Precautionary Statements General: Keep out of reach of children. Prevention: Wear eye/face protection. Wash thoroughly after handling. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. 2.3. Hazards not otherwise classified None. 93% of the mixture consists of ingredients of unknown acute oral toxicity. 93% of the mixture consists of ingredients of unknown acute dermal toxicity. 98% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Mercaptan-Terminated Epoxy Curing Agent Trade Secret* 60 - 100 Trade Secret * Proprietary Polyamine-Polymercaptan Blend Trade Secret* 7 - 13 Trade Secret * Dimethyl Siloxane, Reaction Product with Silica 67762-90-7 3 - 7 Trade Secret * Zinc Phosphate 7779-90-0 0.1 - 1 Trade Secret * Bis(Dimethylaminoethyl) Ether 3033-62-3 0.1 - 1 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. 3M? Bare-Metal Seam Sealer - Beige PN 08310, 58310 Part A 04/30/14 __________________________________________________________________________________________ Page 3 of 9 If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. 5.3. Special protective actions for fire-fighters No unusual fire or explosion hazards are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid eye contact. Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Ingredient C.A.S. No. Agency Limit type Additional Comments Bis(Dimethylaminoethyl) Ether 3033-62-3 Amer Conf of Gov. Indust. Hyg. TWA:0.05 ppm;STEL:0.15 ppm Skin Notation 3M? Bare-Metal Seam Sealer - Beige PN 08310, 58310 Part A 04/30/14 __________________________________________________________________________________________ Page 4 of 9 Dimethyl Siloxane, Reaction Product with Silica 67762-90-7 Chemical Manufacturer Rec Guid CEIL:5 mg/m3 SILICA, AMORPHOUS 67762-90-7 US Dept of Labor - OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. Amer Conf of Gov. Indust. Hyg. : American Conference of Governmental Industrial Hygienists American Indust. Hygiene Assoc : American Industrial Hygiene Association Chemical Manufacturer Rec Guid : Chemical Manufacturer's Recommended Guidelines US Dept of Labor - OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Wear eye/face protection. Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Solid Specific Physical Form: Paste Odor, Color, Grade: Off-white. Mercaptan odor. Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point Not Applicable Flash Point No flash point 3M? Bare-Metal Seam Sealer - Beige PN 08310, 58310 Part A 04/30/14 __________________________________________________________________________________________ Page 5 of 9 Evaporation rate Not Applicable Flammability (solid, gas) Not Classified Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Vapor Pressure Not Applicable Vapor Density Not Applicable Density 1.180 g/cm3 Specific Gravity 1.180 [Ref Std: WATER=1] Solubility in Water Slight (less than 10%) Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Hazardous Air Pollutants 0.67 % weight [Test Method: Calculated] Volatile Organic Compounds 0.17 lb/gal [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 1 % weight [Test Method: calculated per CARB title 2] Volatile Organic Compounds 20 g/l [Test Method: calculated SCAQMD rule 443.1] Percent volatile 1.7 % VOC Less H2O & Exempt Solvents 20 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat is generated during cure. Do not cure a mass larger than 50 grams in a confined space to prevent a premature exothermic reaction with production of intense heat and smoke. 10.5. Incompatible materials Strong acids Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified Oxides of Nitrogen Not Specified Oxides of Sulfur Not Specified Toxic Vapor, Gas, Particulate Not Specified 3M? Bare-Metal Seam Sealer - Beige PN 08310, 58310 Part A 04/30/14 __________________________________________________________________________________________ Page 6 of 9 SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE > 5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE > 50 mg/l Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Dimethyl Siloxane, Reaction Product with Silica Dermal Rabbit LD50 > 5,000 mg/kg Dimethyl Siloxane, Reaction Product with Silica Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Dimethyl Siloxane, Reaction Product with Silica Ingestion Rat LD50 > 5,110 mg/kg Zinc Phosphate Ingestion Rat LD50 > 5,000 mg/kg Bis(Dimethylaminoethyl) Ether Dermal Rabbit LD50 238 mg/kg Bis(Dimethylaminoethyl) Ether Inhalation- Vapor (4 hours) Rat LC50 2.2 mg/l Bis(Dimethylaminoethyl) Ether Ingestion Rat LD50 570 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Dimethyl Siloxane, Reaction Product with Silica Rabbit No significant irritation Serious Eye Damage/Irritation Name Species Value Dimethyl Siloxane, Reaction Product with Silica Rabbit No significant irritation 3M? Bare-Metal Seam Sealer - Beige PN 08310, 58310 Part A 04/30/14 __________________________________________________________________________________________ Page 7 of 9 Skin Sensitization Name Species Value Dimethyl Siloxane, Reaction Product with Silica Human and animal Not sensitizing Respiratory Sensitization Name Species Value Germ Cell Mutagenicity Name Route Value Dimethyl Siloxane, Reaction Product with Silica In Vitro Not mutagenic Carcinogenicity Name Route Species Value Dimethyl Siloxane, Reaction Product with Silica Not Specified Mouse Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Dimethyl Siloxane, Reaction Product with Silica Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation Dimethyl Siloxane, Reaction Product with Silica Ingestion Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Dimethyl Siloxane, Reaction Product with Silica Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Dimethyl Siloxane, Reaction Product with Silica Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure Aspiration Hazard Name Value Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. 3M? Bare-Metal Seam Sealer - Beige PN 08310, 58310 Part A 04/30/14 __________________________________________________________________________________________ Page 8 of 9 Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of waste product in a permitted industrial waste facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 1 Flammability: 1 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. 3M? Bare-Metal Seam Sealer - Beige PN 08310, 58310 Part A 04/30/14 __________________________________________________________________________________________ Page 9 of 9 Document Group: 32-5666-6 Version Number: 2.00 Issue Date: 04/30/14 Supercedes Date: 08/26/13 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com