SAFETY DATA SHEET 1. Identification Product identifier Choke and Linkage Cleaner Other means of identification FIR No. 187068 Recommended use Choke and Linkage Cleaner Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Supplier Company Name Ford Motor Company Address Attention: MSDS Information, P.O. Box 1899 Dearborn, Michigan 48121 USA Telephone 1-800-392-3673 MSDS Information 1-800-448-2063 This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone numbers Poison Control Center: USA and Canada: 1-800-959-3673 INFOTRAC (Transportation): USA and Canada 1-800-535-5053 2. Hazard(s) identification Category 1Flammable aerosolsPhysical hazards Compressed gasGases under pressure Category 2Skin corrosion/irritationHealth hazards Category 2ASerious eye damage/eye irritation Category 2Reproductive toxicity (the unborn child) Category 3 narcotic effectsSpecific target organ toxicity, single exposure Category 2Specific target organ toxicity, repeated exposure Category 2Hazardous to the aquatic environment, acute hazard Environmental hazards Category 2Hazardous to the aquatic environment, long-term hazard Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness. Suspected of damaging the unborn child. May cause damage to organs through prolonged or repeated exposure. Toxic to aquatic life. Toxic to aquatic life with long lasting effects. Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe mist or vapor. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. FIR No.: 187068 SDS US Issue Date: 05-16-2015 Version: 01 1 / 10 Response If on skin: Wash with plenty of water. If skin irritation occurs: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. If exposed or concerned: Get medical advice/attention. Call a poison center/doctor if you feel unwell. Take off contaminated clothing and wash before reuse. Collect spillage. Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from sunlight. Store in a well-ventilated place. Protect from sunlight. Do not expose to temperatures exceeding 50?C/122?F. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) May cause irritation of respiratory tract. May be harmful if swallowed. May be harmful if absorbed through skin. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 67-64-1ACETONE 80 - < 90 124-38-9CARBON DIOXIDE 5 - < 10 108-88-3TOLUENE 5 - < 10 142-82-5HEPTANE 1 - < 3 Specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth. Do not induce vomiting. Most important symptoms/effects, acute and delayed May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Prolonged exposure may cause chronic effects. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. General information IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. 5. Fire-fighting measures Suitable extinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical Contents under pressure. Pressurized container may explode when exposed to heat or flame. During fire, gases hazardous to health may be formed. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Special protective equipment and precautions for firefighters Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Fire fighting equipment/instructions In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed to heat. If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also consider initial evacuation for 800 meters (1/2 mile) in all directions. ALWAYS stay away from tanks engulfed in flame. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. FIR No.: 187068 SDS US Issue Date: 05-16-2015 Version: 01 2 / 10 Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. General fire hazards Extremely flammable aerosol. Contents under pressure. Pressurized container may explode when exposed to heat or flame. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Avoid contact with eyes, skin, and clothing. Do not breathe mist or vapor. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Large Spills: Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Scoop up used absorbent into drums or other appropriate container. Prevent product from entering drains. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. 7. Handling and storage Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not breathe mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Pregnant or breastfeeding women must not handle this product. Should be handled in closed systems, if possible. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50?C/122 ?F. Keep away from heat, sparks and open flame. This material can accumulate static charge which may cause spark and become an ignition source. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Secure cylinders in an upright position at all times, close all valves when not in use. Store in original tightly closed container. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 2400 mg/m3ACETONE (CAS 67-64-1) 1000 ppm PEL 9000 mg/m3CARBON DIOXIDE (CAS 124-38-9) 5000 ppm PEL 2000 mg/m3HEPTANE (CAS 142-82-5) 500 ppm FIR No.: 187068 SDS US Issue Date: 05-16-2015 Version: 01 3 / 10 US. OSHA Table Z-2 (29 CFR 1910.1000) ValueComponents Type Ceiling 300 ppmTOLUENE (CAS 108-88-3) TWA 200 ppm US. ACGIH Threshold Limit Values ValueComponents Type STEL 750 ppmACETONE (CAS 67-64-1) TWA 500 ppm STEL 30000 ppmCARBON DIOXIDE (CAS 124-38-9) TWA 5000 ppm STEL 500 ppmHEPTANE (CAS 142-82-5) TWA 400 ppm TWA 20 ppmTOLUENE (CAS 108-88-3) US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type TWA 590 mg/m3ACETONE (CAS 67-64-1) 250 ppm STEL 54000 mg/m3CARBON DIOXIDE (CAS 124-38-9) 30000 ppm TWA 9000 mg/m3 5000 ppm Ceiling 1800 mg/m3HEPTANE (CAS 142-82-5) 440 ppm TWA 350 mg/m3 85 ppm STEL 560 mg/m3TOLUENE (CAS 108-88-3) 150 ppm TWA 375 mg/m3 100 ppm Biological limit values ACGIH Biological Exposure Indices ValueComponents Determinant Specimen Sampling Time 50 mg/l Acetone Urine *ACETONE (CAS 67-64-1) 0.3 mg/g o-Cresol, with hydrolysis Creatinine in urine *TOLUENE (CAS 108-88-3) 0.03 mg/l Toluene Urine * 0.02 mg/l Toluene Blood * * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation TOLUENE (CAS 108-88-3) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies TOLUENE (CAS 108-88-3) Skin designation applies. Appropriate engineering controls Use adequate ventilation to control airborne concentrations below the exposure limits/guidelines. If user operations generate a vapor, dust and/or mist, use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below the recommended exposure limits/guidelines. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). FIR No.: 187068 SDS US Issue Date: 05-16-2015 Version: 01 4 / 10 Skin protection Hand protection Suitable chemical protective gloves should be worn when the potential exists for prolonged or repeated skin exposure. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. The use of Silver Shield? gloves is recommended. Other Wear appropriate chemical resistant clothing. Wear appropriate chemical resistant clothing if applicable. Respiratory protection If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, an approved respirator must be worn. Respirator selection, use and maintenance should be in accordance with the requirements of OSHA Respiratory Protection Standard 29 CFR 1910.134 and/or Canadian Standard CSA Z94.4. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Aerosol. Color Colorless. Odor Aromatic. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range Not available. Flash point 1.4 ?F (-17.0 ?C) PMCC Evaporation rate > 1 (ETHER=1) Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Explosive limit - lower (%) 1 % Explosive limit - upper (%) 12.8 % Vapor pressure Not available. Vapor density > 1 (AIR=1) Relative density 0.8 Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information VOC (Weight %) 10 % 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid Heat. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Incompatible materials Acids. Strong oxidizing agents. Aluminum. FIR No.: 187068 SDS US Issue Date: 05-16-2015 Version: 01 5 / 10 Hazardous decomposition products Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 11. Toxicological information Information on likely routes of exposure Inhalation May cause damage to organs through prolonged or repeated exposure by inhalation. May cause drowsiness and dizziness. Headache. Nausea, vomiting. May cause irritation to the respiratory system. Prolonged inhalation may be harmful. Skin contact May be harmful in contact with skin. Causes skin irritation. Eye contact Causes serious eye irritation. Ingestion May be harmful if swallowed. Symptoms related to the physical, chemical and toxicological characteristics Headache. May cause drowsiness and dizziness. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Information on toxicological effects Acute toxicity Narcotic effects. Species Calculated/Test ResultsComponents ACETONE (CAS 67-64-1) LD50 Rabbit Dermal Acute 20000 mg/kg 20 ml/kg LC50 Rat Inhalation 76 mg/l, 4 Hours 50.1 mg/l, 8 Hours LD50 Mouse Oral 3000 mg/kg Rabbit 5340 mg/kg Rat 5800 mg/kg HEPTANE (CAS 142-82-5) LC50 Rat Inhalation Acute 103 mg/l, 4 Hours LD50 Mouse 75 mg/l, 2 Hours TOLUENE (CAS 108-88-3) LD50 Rabbit Dermal Acute 12124 mg/kg 14.1 ml/kg LC50 Mouse Inhalation 5320 ppm, 8 Hours 400 ppm, 24 Hours Rat 26700 ppm, 1 Hours 12200 ppm, 2 Hours 8000 ppm, 4 Hours LD50 Rat Oral 2.6 g/kg Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye irritation Causes serious eye irritation. FIR No.: 187068 SDS US Issue Date: 05-16-2015 Version: 01 6 / 10 Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity TOLUENE (CAS 108-88-3) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity Suspected of damaging the unborn child. Specific target organ toxicity - single exposure May cause drowsiness and dizziness. Specific target organ toxicity - repeated exposure Heart. Liver. Urinary system. Vascular system. Reproductive organs. May cause damage to organs through prolonged or repeated exposure. Aspiration hazard Not an aspiration hazard. Chronic effects May cause damage to organs through prolonged or repeated exposure. Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity Toxic to aquatic life with long lasting effects. Ecotoxicity SpeciesComponents Calculated/Test Results ACETONE (CAS 67-64-1) Aquatic EC50Crustacea 21.6 - 23.9 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 4740 - 6330 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) HEPTANE (CAS 142-82-5) Aquatic LC50Fish 375 mg/l, 96 hoursMozambique tilapia (Tilapia mossambica) TOLUENE (CAS 108-88-3) Aquatic EC50Crustacea 5.46 - 9.83 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 8.11 mg/l, 96 hoursCoho salmon,silver salmon (Oncorhynchus kisutch) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) ACETONE -0.24 HEPTANE 4.66 TOLUENE 2.73 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. FIR No.: 187068 SDS US Issue Date: 05-16-2015 Version: 01 7 / 10 Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. 14. Transport information DOT UN1950UN number AEROSOLSUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk 2.1Label(s) Not applicable.Packing group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IATA UN1950UN number AEROSOLS, FLAMMABLEUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk 2.1Label(s) Not applicable.Packing group No.Environmental hazards Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Forbidden.Passenger and cargo aircraft Other information Forbidden.Cargo aircraft only IMDG UN1950UN number AEROSOLSUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk 2.1Label(s) Not applicable.Packing group No.Marine pollutant Environmental hazards Not available.EmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Not established.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code FIR No.: 187068 SDS US Issue Date: 05-16-2015 Version: 01 8 / 10 DOT IATA; IMDG 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) ACETONE (CAS 67-64-1) Listed. HEPTANE (CAS 142-82-5) Listed. TOLUENE (CAS 108-88-3) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Chemical name CAS number % by wt. TOLUENE 108-88-3 5 - < 10 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List TOLUENE (CAS 108-88-3) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number ACETONE (CAS 67-64-1) 6532 TOLUENE (CAS 108-88-3) 6594 FIR No.: 187068 SDS US Issue Date: 05-16-2015 Version: 01 9 / 10 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) ACETONE (CAS 67-64-1) 35 %WV TOLUENE (CAS 108-88-3) 35 %WV DEA Exempt Chemical Mixtures Code Number ACETONE (CAS 67-64-1) 6532 TOLUENE (CAS 108-88-3) 594 US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. Massachusetts RTK - Substance List ACETONE (CAS 67-64-1) CARBON DIOXIDE (CAS 124-38-9) HEPTANE (CAS 142-82-5) TOLUENE (CAS 108-88-3) US. New Jersey Worker and Community Right-to-Know Act ACETONE (CAS 67-64-1) CARBON DIOXIDE (CAS 124-38-9) HEPTANE (CAS 142-82-5) TOLUENE (CAS 108-88-3) US. Pennsylvania Worker and Community Right-to-Know Law ACETONE (CAS 67-64-1) CARBON DIOXIDE (CAS 124-38-9) HEPTANE (CAS 142-82-5) TOLUENE (CAS 108-88-3) US. Rhode Island RTK ACETONE (CAS 67-64-1) TOLUENE (CAS 108-88-3) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. International Inventories All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. 16. Other information, including date of preparation or last revision Issue date 05-16-2015 Version # 01 HMIS? ratings Health: 2 Flammability: 3 Physical hazard: 0 NFPA ratings Health: 2 Flammability: - Instability: 0 Preparation Information and Disclaimer To the extent that there are any differences between this product?s Safety Data Sheet (SDS) and the consumer packaged product labels, the SDS should be followed. To the extent that there are any differences between this product?s Safety Data Sheet (SDS) and the consumer packaged product labels, the SDS should be followed. This document was prepared by FCSD-Toxicology, Ford Motor Company, Diagnostic Service Center II, 1800 Fairlane Drive, Allen Park, MI 48101, USA, based in part on information provided by the manufacturer. The information on this data sheet represents our current data and is accurate to the best of our knowledge as to the proper handling of this product under normal conditions and in accordance with the application specified on the packaging and/or technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. To the extent that there are any differences between this product?s Safety Data Sheet (SDS) and the consumer packaged product labels, the SDS should be followed. Part number(s) PM-14 FIR No.: 187068 SDS US Issue Date: 05-16-2015 Version: 01 10 / 10