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3M? Semi-Rigid Parts/SMC/Fiberglass Repair Adhesive-1 Minute PN 08235 09/10/15 ________________________________________________________________________________________________________ Page 1 of 2 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 27-4698-0 Version Number: 4.00 Issue Date: 09/10/15 Supercedes Date: 05/27/14 Product identifier 3M? Semi-Rigid Parts/SMC/Fiberglass Repair Adhesive-1 Minute PN 08235 ID Number(s): LB-K100-0747-1, 41-0003-8019-0, 41-9103-0463-7, 41-9103-0512-1, 60-4550-5032-2 Recommended use Automotive Supplier's details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AIL) for each of these components is included. Please do not separate the component documents from this cover page. The document numbers for components of this product are: 27-4349-0, 27-5349-9 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com 3M? Semi-Rigid Parts/SMC/Fiberglass Repair Adhesive-1 Minute PN 08235 09/10/15 ________________________________________________________________________________________________________ Page 2 of 2 3M? Semi-Rigid Parts/SMC/Fiberglass Repair Adhesive-1 Minute PN 08235 Part B 05/30/14 __________________________________________________________________________________________ Page 1 of 11 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 27-5349-9 Version Number: 2.01 Issue Date: 05/30/14 Supercedes Date: 05/23/14 SECTION 1: Identification 1.1. Product identifier 3M? Semi-Rigid Parts/SMC/Fiberglass Repair Adhesive-1 Minute PN 08235 Part B Product Identification Numbers LB-K100-0745-6, LB-K100-0910-6 1.2. Recommended use and restrictions on use Recommended use Automotive, Body and Structural Repair 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Serious Eye Damage/Irritation: Category 2B. Respiratory Sensitizer: Category 1B. Skin Sensitizer: Category 1B. Carcinogenicity: Category 2. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger Symbols 3M? Semi-Rigid Parts/SMC/Fiberglass Repair Adhesive-1 Minute PN 08235 Part B 05/30/14 __________________________________________________________________________________________ Page 2 of 11 Health Hazard | Pictograms Hazard Statements Causes eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Suspected of causing cancer. Causes damage to organs through prolonged or repeated exposure: respiratory system | Precautionary Statements Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. In case of inadequate ventilation wear respiratory protection. Wear protective gloves. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: If breathing is difficult, remove person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. Get medical advice/attention if you feel unwell. Storage: Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified None. 2% of the mixture consists of ingredients of unknown acute oral toxicity. 31% of the mixture consists of ingredients of unknown acute dermal toxicity. SECTION 3: Composition/information on ingredients 3M? Semi-Rigid Parts/SMC/Fiberglass Repair Adhesive-1 Minute PN 08235 Part B 05/30/14 __________________________________________________________________________________________ Page 3 of 11 Ingredient C.A.S. No. % by Wt Polyether Polyol (NJTSRN 04499600-6782) Trade Secret* 30 - 60 Trade Secret * Polyol (NJTSRN 04499600-6783) Trade Secret* 15 - 40 Trade Secret * Talc 14807-96-6 15 - 40 Trade Secret * Urethane Prepolymer (NJTSRN 04499600-6781) Trade Secret* 3 - 7 Trade Secret * Polypropylene Glycol Glycerol Triether 25791-96-2 1 - 5 Trade Secret * Clay 71011-24-0 1 - 5 Trade Secret * Piperazine 110-85-0 < 1 Trade Secret * Sodium Oxide Trade Secret* < 0.5 Trade Secret * Carbon Black 1333-86-4 < 0.5 Trade Secret * NJTS or NJTSRN: New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Hydrocarbons During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion 3M? Semi-Rigid Parts/SMC/Fiberglass Repair Adhesive-1 Minute PN 08235 Part B 05/30/14 __________________________________________________________________________________________ Page 4 of 11 Oxides of Nitrogen During Combustion 5.3. Special protective actions for fire-fighters No unusual fire or explosion hazards are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling For industrial or professional use only. Do not use in a confined area with minimal air exchange. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Keep container tightly closed to prevent contamination with water or air. If contamination is suspected, do not reseal container. Store away from acids. Store away from strong bases. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Ingredient C.A.S. No. Agency Limit type Additional Comments Piperazine 110-85-0 ACGIH TWA(as piperazine, inhalable fraction & vapor):0.03 ppm Sensitizer Carbon Black 1333-86-4 ACGIH TWA(inhalable fraction):3 mg/m3 Carbon Black 1333-86-4 CMRG TWA:0.5 mg/m3 Carbon Black 1333-86-4 OSHA TWA:3.5 mg/m3 Talc 14807-96-6 ACGIH TWA(respirable fraction):2 mg/m3 Talc 14807-96-6 CMRG TWA(as respirable dust):0.5 3M? Semi-Rigid Parts/SMC/Fiberglass Repair Adhesive-1 Minute PN 08235 Part B 05/30/14 __________________________________________________________________________________________ Page 5 of 11 mg/m3 Talc 14807-96-6 OSHA TWA concentration(as total dust):0.3 mg/m3;TWA concentration(respirable):0.1 mg/m3(2.4 millions of particles/cu. ft.);TWA:20 millions of particles/cu. ft. ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Wear protective gloves. Gloves made from the following material(s) are recommended: Nitrile Rubber If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron ? Nitrile Respiratory protection In case of inadequate ventilation wear respiratory protection. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Viscous Odor, Color, Grade: Slight ammonia like odor black color. Odor threshold No Data Available 3M? Semi-Rigid Parts/SMC/Fiberglass Repair Adhesive-1 Minute PN 08235 Part B 05/30/14 __________________________________________________________________________________________ Page 6 of 11 pH Not Applicable Melting point Not Applicable Boiling Point No Data Available Flash Point > 94 ?C [Test Method: Closed Cup] Evaporation rate < 1 [Ref Std: ETHER=1] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure <= 0.1 mmHg Vapor Density >= 1 [Ref Std: AIR=1] Density 1.2 g/ml Specific Gravity 1 - 1.2 [Ref Std: WATER=1] Solubility In Water No Data Available Solubility- non-water Negligible Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity No Data Available Hazardous Air Pollutants 0 % weight [Test Method: Calculated] Volatile Organic Compounds 0.07 lb/gal [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 9 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 0.7 % weight [Test Method: calculated per CARB title 2] Percent volatile 0.69 % VOC Less H2O & Exempt Solvents 9 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid High shear and high temperature conditions 10.5. Incompatible materials Strong acids Strong bases Strong oxidizing agents Alcohols Water 10.6. Hazardous decomposition products Substance Condition 3M? Semi-Rigid Parts/SMC/Fiberglass Repair Adhesive-1 Minute PN 08235 Part B 05/30/14 __________________________________________________________________________________________ Page 7 of 11 Aldehydes Not Specified Hydrogen Cyanide Not Specified Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest. Skin Contact: May be harmful in contact with skin. Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Target Organ Effects: Prolonged or repeated exposure may cause: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation Carbon Black 1333-86-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE 2,000 - 5,000 3M? Semi-Rigid Parts/SMC/Fiberglass Repair Adhesive-1 Minute PN 08235 Part B 05/30/14 __________________________________________________________________________________________ Page 8 of 11 mg/kg Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Polyether Polyol (NJTSRN 04499600-6782) Dermal Rat LD50 > 2,000 mg/kg Polyether Polyol (NJTSRN 04499600-6782) Ingestion Rat LD50 > 2,500 mg/kg Talc Dermal LD50 Not available Talc Ingestion LD50 Not available Polyol (NJTSRN 04499600-6783) Dermal Rabbit LD50 > 5,000 mg/kg Polyol (NJTSRN 04499600-6783) Ingestion Rat LD50 > 10,000 mg/kg Urethane Prepolymer (NJTSRN 04499600-6781) Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Polypropylene Glycol Glycerol Triether Dermal Rabbit LD50 > 2,000 mg/kg Polypropylene Glycol Glycerol Triether Inhalation- Dust/Mist (4 hours) Rat LC50 > 50 mg/l Polypropylene Glycol Glycerol Triether Ingestion Rat LD50 4,600 mg/kg Piperazine Dermal estimated to be > 5,000 mg/kg Piperazine Inhalation- Dust/Mist estimated to be > 12.5 mg/l Piperazine Inhalation- Vapor estimated to be > 50 mg/l Piperazine Ingestion estimated to be > 5,000 mg/kg Carbon Black Dermal Rabbit LD50 > 3,000 mg/kg Carbon Black Ingestion Rat LD50 > 8,000 mg/kg Sodium Oxide Ingestion LD50 estimated to be 50 - 300 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Talc Rabbit No significant irritation Carbon Black Rabbit No significant irritation Serious Eye Damage/Irritation Name Species Value Talc Rabbit No significant irritation Carbon Black Rabbit No significant irritation Skin Sensitization Name Species Value Respiratory Sensitization Name Species Value Talc Human Not sensitizing Germ Cell Mutagenicity Name Route Value Talc In Vitro Not mutagenic Talc In vivo Not mutagenic Carbon Black In Vitro Not mutagenic Carbon Black In vivo Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Talc Inhalation Rat Some positive data exist, but the data are not sufficient for classification Carbon Black Dermal Mouse Not carcinogenic Carbon Black Ingestion Mouse Not carcinogenic Carbon Black Inhalation Rat Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure 3M? Semi-Rigid Parts/SMC/Fiberglass Repair Adhesive-1 Minute PN 08235 Part B 05/30/14 __________________________________________________________________________________________ Page 9 of 11 Duration Talc Ingestion Not toxic to development Rat NOAEL 1,600 mg/kg during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Talc Inhalation pneumoconiosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Talc Inhalation pulmonary fibrosis | respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 18 mg/m3 113 weeks Carbon Black Inhalation pneumoconiosis Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Aspiration Hazard Name Value Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information 3M? Semi-Rigid Parts/SMC/Fiberglass Repair Adhesive-1 Minute PN 08235 Part B 05/30/14 __________________________________________________________________________________________ Page 10 of 11 For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 1 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 27-5349-9 Version Number: 2.01 Issue Date: 05/30/14 Supercedes Date: 05/23/14 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com 3M? Semi-Rigid Parts/SMC/Fiberglass Repair Adhesive-1 Minute PN 08235 Part B 05/30/14 __________________________________________________________________________________________ Page 11 of 11 3M? Semi-Rigid Parts Repair Adhesive Black-1 PN 08235 Part A 04/21/15 __________________________________________________________________________________________ Page 1 of 12 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 27-4349-0 Version Number: 4.01 Issue Date: 04/21/15 Supercedes Date: 05/23/14 SECTION 1: Identification 1.1. Product identifier 3M? Semi-Rigid Parts Repair Adhesive Black-1 PN 08235 Part A Product Identification Numbers LB-K100-0908-1, LB-K100-0736-5 1.2. Recommended use and restrictions on use Recommended use Automotive, Repair Adhesive 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Acute Toxicity (inhalation): Category 4. Serious Eye Damage/Irritation: Category 2A. Skin Corrosion/Irritation: Category 2. Respiratory Sensitizer: Category 1. Skin Sensitizer: Category 1. Specific Target Organ Toxicity (respiratory irritation): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger 3M? Semi-Rigid Parts Repair Adhesive Black-1 PN 08235 Part A 04/21/15 __________________________________________________________________________________________ Page 2 of 12 Symbols Exclamation mark | Health Hazard | Pictograms Hazard Statements Causes serious eye irritation. Causes skin irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Harmful if inhaled. May cause respiratory irritation. Causes damage to organs through prolonged or repeated exposure: respiratory system | Precautionary Statements Prevention: Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. In case of inadequate ventilation wear respiratory protection. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. 35% of the mixture consists of ingredients of unknown acute inhalation toxicity. 3M? Semi-Rigid Parts Repair Adhesive Black-1 PN 08235 Part A 04/21/15 __________________________________________________________________________________________ Page 3 of 12 SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Methylene Phenylene Isocyanate 101-68-8 25 - 60 Trade Secret * Urethane Prepolymer (NJTSRN 04499600-6779) Trade Secret* 15 - 40 Trade Secret * Diisocyanate Polymer Trade Secret* 5 - 20 Trade Secret * Aluminum Silicate (NJTSRN 04499600-6789) Trade Secret* 7 - 13 Trade Secret * Talc 14807-96-6 7 - 13 Trade Secret * Aluminum Oxide (non-fibrous) Trade Secret* 1 - 7 SODIUM OXIDE Trade Secret* 1 - 5 Thickening Agent (NJTSRN 04499600-6784) Trade Secret* 1 - 5 Trade Secret * CALCIUM OXIDE Trade Secret* 1 - 5 NJTS or NJTSRN: New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media DO NOT USE WATER 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion 3M? Semi-Rigid Parts Repair Adhesive Black-1 PN 08235 Part A 04/21/15 __________________________________________________________________________________________ Page 4 of 12 Hydrogen Cyanide During Combustion Oxides of Nitrogen During Combustion 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Contain spill. Pour isocyanate decontaminant solution (90% water, 8% concentrated ammonia, 2% detergent) on spill and allow to react for 10 minutes. Or pour water on spill and allow to react for more than 30 minutes. Cover with absorbent material. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a container approved for transportation by appropriate authorities, but do not seal the container for 48 hours to avoid pressure build-up. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling For industrial or professional use only. Do not use in a confined area with minimal air exchange. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed to prevent loss of stabilizing materials. Keep container tightly closed to prevent contamination with water or air. If contamination is suspected, do not reseal container. Store away from heat. Store away from acids. Store away from strong bases. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments FREE ISOCYANATES 101-68-8 Manufacturer determined TWA:0.005 ppm;STEL:0.02 ppm Methylene Phenylene Isocyanate 101-68-8 ACGIH TWA:0.005 ppm Methylene Phenylene Isocyanate 101-68-8 OSHA CEIL:0.2 mg/m3(0.02 ppm) Talc 14807-96-6 ACGIH TWA(respirable fraction):2 mg/m3 A4: Not class. as human carcin Talc 14807-96-6 CMRG TWA(as respirable dust):0.5 mg/m3 3M? Semi-Rigid Parts Repair Adhesive Black-1 PN 08235 Part A 04/21/15 __________________________________________________________________________________________ Page 5 of 12 Talc 14807-96-6 OSHA TWA concentration(as total dust):0.3 mg/m3;TWA concentration(respirable):0.1 mg/m3(2.4 millions of particles/cu. ft.);TWA:20 millions of particles/cu. ft. Aluminum Oxide (non-fibrous) Trade Secret ACGIH TWA(respirable fraction):1 mg/m3 A4: Not class. as human carcin Aluminum Oxide (non-fibrous) Trade Secret CMRG TWA:1 fiber/cc Aluminum Oxide (non-fibrous) Trade Secret OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Aluminum Silicate (NJTSRN 04499600-6789) Trade Secret CMRG TWA(as respirable dust):3 mg/m3 Aluminum Silicate (NJTSRN 04499600-6789) Trade Secret OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. CALCIUM OXIDE Trade Secret ACGIH TWA:2 mg/m3 CALCIUM OXIDE Trade Secret OSHA TWA:5 mg/m3 Thickening Agent (NJTSRN 04499600-6784) Trade Secret OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Provide ventilated enclosure for heat curing. Curing enclosures must be exhausted to outdoors or to a suitable emission control device. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Nitrile Rubber 3M? Semi-Rigid Parts Repair Adhesive Black-1 PN 08235 Part A 04/21/15 __________________________________________________________________________________________ Page 6 of 12 If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron ? Nitrile Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Odor, Color, Grade: White, slight isocyanate odor pH Not Applicable Melting point Not Applicable Boiling Point No Data Available Flash Point > 383 ?F [Test Method: Closed Cup] Evaporation rate < 1 [Ref Std: ETHER=1] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure .010 mmHg [Details: @77.00 F for product] Vapor Density < 1 [Ref Std: AIR=1] Density 10.72 lb/gal Specific Gravity 1.288 [Ref Std: WATER=1] Solubility In Water No Data Available Partition coefficient: n-octanol/ water No Data Available Viscosity No Data Available Hazardous Air Pollutants 0.779 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 0 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 0 % weight [Test Method: calculated per CARB title 2] Percent volatile 0 % weight VOC Less H2O & Exempt Solvents 0 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization may occur. 10.4. Conditions to avoid Heat Sparks and/or flames 3M? Semi-Rigid Parts Repair Adhesive Black-1 PN 08235 Part A 04/21/15 __________________________________________________________________________________________ Page 7 of 12 10.5. Incompatible materials Strong acids Strong bases Water 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest. May cause additional health effects (see below). Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: May be harmful if swallowed. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Additional Health Effects: Prolonged or repeated exposure may cause target organ effects: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests. Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. 3M? Semi-Rigid Parts Repair Adhesive Black-1 PN 08235 Part A 04/21/15 __________________________________________________________________________________________ Page 8 of 12 Additional Information: Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE 10 - 20 mg/l Overall product Ingestion No data available; calculated ATE 2,000 - 5,000 mg/kg Methylene Phenylene Isocyanate Inhalation- Vapor LC50 estimated to be 10 - 20 mg/l Methylene Phenylene Isocyanate Dermal Rabbit LD50 > 5,000 mg/kg Methylene Phenylene Isocyanate Inhalation- Dust/Mist (4 hours) Rat LC50 0.369 mg/l Methylene Phenylene Isocyanate Ingestion Rat LD50 31,600 mg/kg Urethane Prepolymer (NJTSRN 04499600-6779) Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Diisocyanate Polymer Inhalation- Vapor LC50 estimated to be 10 - 20 mg/l Diisocyanate Polymer Dermal Rabbit LD50 > 5,000 mg/kg Diisocyanate Polymer Inhalation- Dust/Mist (4 hours) Rat LC50 0.369 mg/l Diisocyanate Polymer Ingestion Rat LD50 31,600 mg/kg Talc Dermal LD50 Not available Talc Ingestion LD50 Not available Aluminum Silicate (NJTSRN 04499600-6789) Dermal Rabbit LD50 > 5,000 mg/kg Aluminum Silicate (NJTSRN 04499600-6789) Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Aluminum Silicate (NJTSRN 04499600-6789) Ingestion Rat LD50 > 5,110 mg/kg Aluminum Oxide (non-fibrous) Dermal LD50 estimated to be > 5,000 mg/kg Aluminum Oxide (non-fibrous) Inhalation- Dust/Mist (4 hours) Rat LC50 > 2.3 mg/l Aluminum Oxide (non-fibrous) Ingestion Rat LD50 > 5,000 mg/kg SODIUM OXIDE Ingestion LD50 estimated to be 50 - 300 mg/kg CALCIUM OXIDE Ingestion Rat LD50 > 2,500 mg/kg Thickening Agent (NJTSRN 04499600-6784) Dermal Rabbit LD50 > 5,000 mg/kg Thickening Agent (NJTSRN 04499600-6784) Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Thickening Agent (NJTSRN 04499600-6784) Ingestion Rat LD50 > 5,110 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Methylene Phenylene Isocyanate official classifica tion Irritant Diisocyanate Polymer official classifica tion Irritant Talc Rabbit No significant irritation Aluminum Silicate (NJTSRN 04499600-6789) Rabbit No significant irritation Aluminum Oxide (non-fibrous) Rabbit No significant irritation CALCIUM OXIDE Human Corrosive Thickening Agent (NJTSRN 04499600-6784) Rabbit No significant irritation 3M? Semi-Rigid Parts Repair Adhesive Black-1 PN 08235 Part A 04/21/15 __________________________________________________________________________________________ Page 9 of 12 Serious Eye Damage/Irritation Name Species Value Methylene Phenylene Isocyanate official classifica tion Severe irritant Diisocyanate Polymer official classifica tion Severe irritant Talc Rabbit No significant irritation Aluminum Silicate (NJTSRN 04499600-6789) Rabbit No significant irritation Aluminum Oxide (non-fibrous) Rabbit No significant irritation CALCIUM OXIDE Rabbit Corrosive Thickening Agent (NJTSRN 04499600-6784) Rabbit No significant irritation Skin Sensitization Name Species Value Methylene Phenylene Isocyanate official classifica tion Sensitizing Diisocyanate Polymer official classifica tion Sensitizing Aluminum Silicate (NJTSRN 04499600-6789) Human and animal Not sensitizing Thickening Agent (NJTSRN 04499600-6784) Human and animal Not sensitizing Respiratory Sensitization Name Species Value Methylene Phenylene Isocyanate Human Sensitizing Diisocyanate Polymer Human Sensitizing Talc Human Not sensitizing Germ Cell Mutagenicity Name Route Value Methylene Phenylene Isocyanate In Vitro Some positive data exist, but the data are not sufficient for classification Diisocyanate Polymer In Vitro Some positive data exist, but the data are not sufficient for classification Talc In Vitro Not mutagenic Talc In vivo Not mutagenic Aluminum Silicate (NJTSRN 04499600-6789) In Vitro Not mutagenic Aluminum Oxide (non-fibrous) In Vitro Not mutagenic CALCIUM OXIDE In Vitro Not mutagenic Thickening Agent (NJTSRN 04499600-6784) In Vitro Not mutagenic Carcinogenicity Name Route Species Value Methylene Phenylene Isocyanate Inhalation Rat Some positive data exist, but the data are not sufficient for classification Diisocyanate Polymer Inhalation Rat Some positive data exist, but the data are not sufficient for classification Talc Inhalation Rat Some positive data exist, but the data are not sufficient for classification Aluminum Silicate (NJTSRN 04499600-6789) Not Specified Mouse Some positive data exist, but the data are not sufficient for classification Aluminum Oxide (non-fibrous) Inhalation Rat Not carcinogenic Thickening Agent (NJTSRN 04499600-6784) Not Specified Mouse Some positive data exist, but the data are not sufficient for classification 3M? Semi-Rigid Parts Repair Adhesive Black-1 PN 08235 Part A 04/21/15 __________________________________________________________________________________________ Page 10 of 12 Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Methylene Phenylene Isocyanate Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 0.004 mg/l during organogenesi s Diisocyanate Polymer Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 0.004 mg/l during organogenesi s Talc Ingestion Not toxic to development Rat NOAEL 1,600 mg/kg during organogenesi s Aluminum Silicate (NJTSRN 04499600- 6789) Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation Aluminum Silicate (NJTSRN 04499600- 6789) Ingestion Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Aluminum Silicate (NJTSRN 04499600- 6789) Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s Thickening Agent (NJTSRN 04499600- 6784) Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation Thickening Agent (NJTSRN 04499600- 6784) Ingestion Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Thickening Agent (NJTSRN 04499600- 6784) Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Methylene Phenylene Isocyanate Inhalation respiratory irritation May cause respiratory irritation official classifica tion NOAEL Not available Diisocyanate Polymer Inhalation respiratory irritation May cause respiratory irritation official classifica tion NOAEL Not available CALCIUM OXIDE Inhalation respiratory irritation May cause respiratory irritation Not available NOAEL Not available occupational exposure Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Methylene Phenylene Isocyanate Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.004 mg/l 13 weeks Diisocyanate Polymer Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.004 mg/l 13 weeks Talc Inhalation pneumoconiosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Talc Inhalation pulmonary fibrosis | respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 18 mg/m3 113 weeks Aluminum Silicate (NJTSRN 04499600-6789) Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure Aluminum Oxide (non- fibrous) Inhalation pneumoconiosis | pulmonary fibrosis Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Thickening Agent (NJTSRN 04499600-6784) Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure 3M? Semi-Rigid Parts Repair Adhesive Black-1 PN 08235 Part A 04/21/15 __________________________________________________________________________________________ Page 11 of 12 Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - Yes Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Methylene Phenylene Isocyanate 101-68-8 25 - 60 Methylene Phenylene Isocyanate (Benzene, 1,1'- methylenebis[4-isocyanato-) 101-68-8 25 - 60 Methylene Phenylene Isocyanate (DIISOCYANATES (CERTAIN CHEMICALS ONLY)) 101-68-8 25 - 60 3M? Semi-Rigid Parts Repair Adhesive Black-1 PN 08235 Part A 04/21/15 __________________________________________________________________________________________ Page 12 of 12 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 1 Instability: 1 Special Hazards: Reacts with Water National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 27-4349-0 Version Number: 4.01 Issue Date: 04/21/15 Supercedes Date: 05/23/14 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com