Lucas Synthetic SAE 20W-50 API SN Motor Oil Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 08/06/2015 Version: 1.0 08/06/2015 EN (English US) SDS ID: Lucas Syn 20W50 Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Identification Product form : Mixture Product name : Lucas Synthetic SAE 20W-50 API SN Motor Oil Product code : 10054, 10060, 10108, 10135, 10397 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Lubricants 1.3. Details of the supplier of the safety data sheet Lucas Oil Products, Inc 302 North Sheridan Street Corona, California 92880-2067 - USA T (951) 270-0154 - F (951) 270-1902 This email address is being protected from spambots. You need JavaScript enabled to view it. - www.LucasOil.com 1.4. Emergency telephone number Emergency number : (951) 493-1149 (951) 847-5949 7:00 A.M. to 5:00 P.M. Monday thru Friday SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture Classification (GHS-US) Repr. 2 H361 - Suspected of damaging fertility or the unborn child Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS08 Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H361 - Suspected of damaging fertility or the unborn child Precautionary statements (GHS-US) : P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P280 - Wear protective gloves P308+P313 - If exposed or concerned: Get medical advice/attention P405 - Store locked up P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation 2.3. Other hazards Other hazards not contributing to the classification : Harmful to aquatic life with long lasting effects. 2.4. Unknown acute toxicity (GHS US) 10 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Oral) 10 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Dermal) 10 percent of the mixture consists of ingredient(s) of unknown acute toxicity (Inhalation (Dust/Mist)) SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable Lucas Synthetic SAE 20W-50 API SN Motor Oil Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/06/2015 EN (English US) SDS ID: Lucas Syn 20W50 2/8 3.2. Mixture Name Product identifier % Classification (GHS-US) zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate) (CAS No) 2215-35-2 < 1.5 Skin Irrit. 2, H315 Eye Dam. 1, H318 Aquatic Chronic 2, H411 Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts (CAS No) 84605-29-8 < 1.5 Skin Irrit. 2, H315 Eye Dam. 1, H318 Aquatic Chronic 2, H411 Phenyl, dodecyl-,branched (CAS No) 121158-58-5 < 0.15 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Repr. 2, H361 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Diphenylamine (CAS No) 122-39-4 < 0.15 Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation), H331 STOT RE 2, H373 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : If inhaled and if breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. First-aid measures after skin contact : Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : If swallowed, rinse mouth with water (only if the person is conscious). Do NOT induce vomiting unless directed to do so by medical personnel. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries Chronic symptoms : May damage fertility. May damage the unborn child. 4.3. Indication of any immediate medical attention and special treatment needed All treatments should be based on observed signs and symptoms of distress in the patient. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : No particular fire or explosion hazard. Reactivity : The product is non-reactive under normal conditions of use, storage and transport. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Danger of slipping on leaked or spilled product. 6.1.1. For non-emergency personnel Emergency procedures : Stop leak, if possible without risk. Ventilate spillage area. 6.1.2. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". Emergency procedures : Ventilate area. Lucas Synthetic SAE 20W-50 API SN Motor Oil Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/06/2015 EN (English US) SDS ID: Lucas Syn 20W50 3/8 6.2. Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Other information : Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections Section 7: safe handling. Section 8: personal protective equipment. Section 13: disposal information. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Ensure good ventilation of the work station. Wear personal protective equipment. Hygiene measures : Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep only in the original container in a cool, well ventilated place away from: Incompatible materials. Keep container closed when not in use. Keep cool. Incompatible products : Strong oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Diphenylamine (122-39-4) ACGIH ACGIH TWA (mg/m?) 10 mg/m? ACGIH Remark (ACGIH) Liver & kidney dam; hematologic eff 8.2. Exposure controls Appropriate engineering controls : Ensure good ventilation of the work station. Hand protection : Wear protective gloves. nitrile rubber gloves. Eye protection : In case of splashing or aerosol production: protective goggles. Eye protection should only be necessary where liquid could be splashed or sprayed. Respiratory protection : No special respiratory protection equipment is recommended under normal conditions of use with adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Use an approved respirator equipped with oil/mist cartridges. Environmental exposure controls : Avoid release to the environment. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Amber viscous liquid. Color : Amber Odor : petroleum Odor threshold : No data available pH : No data available Melting point : No data available Freezing point : No data available Boiling point : No data available Flash point : 221 ?C Relative evaporation rate (butyl acetate=1) : No data available Flammability (solid, gas) : No data available Explosive limits : No data available Explosive properties : No data available Oxidizing properties : No data available Lucas Synthetic SAE 20W-50 API SN Motor Oil Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/06/2015 EN (English US) SDS ID: Lucas Syn 20W50 4/8 Vapor pressure : No data available Relative density : 0.865 Relative vapor density at 20 ?C : No data available Solubility : insoluble in water. Log Pow : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity : No data available Viscosity, kinematic : 158 cSt @ 40 ?C Viscosity, dynamic : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity The product is non-reactive under normal conditions of use, storage and transport. 10.2. Chemical stability Stable at ambient temperature and under normal conditions of use. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Extremely high or low temperatures. 10.5. Incompatible materials Strong oxidizing agents. 10.6. Hazardous decomposition products Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Likely routes of exposure : Dermal Acute toxicity : Not classified zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate) (2215-35-2) LD50 oral rat 2000 - 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg ATE US (oral) 2000.000 mg/kg bodyweight Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts (84605-29-8) LD50 oral rat 3100 mg/kg LD50 dermal rat > 2002 mg/kg LC50 inhalation rat (mg/l) > 2.3 mg/l/4h ATE US (oral) 3100.000 mg/kg bodyweight Diphenylamine (122-39-4) ATE US (oral) 100.000 mg/kg bodyweight ATE US (dermal) 300.000 mg/kg bodyweight ATE US (gases) 700.000 ppmV/4h ATE US (vapors) 3.000 mg/l/4h ATE US (dust, mist) 0.500 mg/l/4h Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified based on vendor mixture classification. Mixture rules not used. Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Lucas Synthetic SAE 20W-50 API SN Motor Oil Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/06/2015 EN (English US) SDS ID: Lucas Syn 20W50 5/8 Reproductive toxicity : Suspected of damaging fertility or the unborn child. Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and symptoms Chronic symptoms : May damage fertility. May damage the unborn child. SECTION 12: Ecological information 12.1. Toxicity Ecology - water : Harmful to aquatic life with long lasting effects. Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts (84605-29-8) LC50 fish 1 4.5 mg/l EC50 Daphnia 1 23 mg/l ErC50 (algae) 21 mg/l NOEC (acute) 1.8 mg/l NOEC chronic crustacea 0.8 mg/l Diphenylamine (122-39-4) LC50 fish 1 4.14 ppm EC50 Daphnia 1 2.46 mg/l EC50 other aquatic organisms 1 0.36 mg/l 12.2. Persistence and degradability Lucas Synthetic SAE 20W-50 API SN Motor Oil Persistence and degradability May cause long-term adverse effects in the environment. Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts (84605-29-8) Biodegradation 1.5 % 28 days Diphenylamine (122-39-4) Persistence and degradability Not established. 12.3. Bioaccumulative potential Lucas Synthetic SAE 20W-50 API SN Motor Oil Bioaccumulative potential Not established. Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts (84605-29-8) Log Kow 0.56 Diphenylamine (122-39-4) Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Effect on ozone layer : None known Effect on the global warming : None known Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector?s sorting instructions. Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. Lucas Synthetic SAE 20W-50 API SN Motor Oil Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/06/2015 EN (English US) SDS ID: Lucas Syn 20W50 6/8 SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not considered a dangerous good for transport regulations TDG No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate) (2215-35-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts (84605-29-8) Listed on the United States TSCA (Toxic Substances Control Act) inventory Phenyl, dodecyl-,branched (121158-58-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory Diphenylamine (122-39-4) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate) (2215-35-2) Listed on the Canadian DSL (Domestic Sustances List) Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts (84605-29-8) Listed on the Canadian DSL (Domestic Sustances List) Diphenylamine (122-39-4) Listed on the Canadian DSL (Domestic Sustances List) EU-Regulations No additional information available National regulations zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate) (2215-35-2) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on KECI (Korean Existing Chemicals Inventory) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on Taiwan National Chemical Inventory Listed on the AICS (Australian Inventory of Chemical Substances) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts (84605-29-8) Not listed on the Inventory of Existing Chemical Substances of China (IECSC). Listed on KECI (Korean Existing Chemicals Inventory) Listed on Taiwan National Chemical Inventory Listed on the AICS (Australian Inventory of Chemical Substances) Phenyl, dodecyl-,branched (121158-58-5) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on KECI (Korean Existing Chemicals Inventory) Listed on Taiwan National Chemical Inventory Listed on NZIoC (New Zealand Inventory of Chemicals) Lucas Synthetic SAE 20W-50 API SN Motor Oil Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/06/2015 EN (English US) SDS ID: Lucas Syn 20W50 7/8 Diphenylamine (122-39-4) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on KECI (Korean Existing Chemicals Inventory) Listed on Taiwan National Chemical Inventory Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on NZIoC (New Zealand Inventory of Chemicals) 15.3. US State regulations Diphenylamine (122-39-4) U.S. - Minnesota - Hazardous Substance List U.S. - New Jersey - Right to Know Hazardous Substance List SECTION 16: Other information Indication of changes : Original Document. Data sources : Component Supplier SDSs. European Chemicals Agency (ECHA) C&L Inventory database. Accessed at http://echa.europa.eu/web/guest/information-on-chemicals/cl-inventory-database. European Chemicals Agency (ECHA) Registered Substances list. European Standards: Personal Protective Equipment; accessed at: http://ec.europa.eu/enterprise/policies/european-standards/harmonised-standards/personal- protective-equipment/index_en.htm. Internal Company test data. Krister Forsberg and S.Z. Mansdorf, "Quick Selection Guide to Chemical Protective Clothing", Fifth Edition. Abbreviations and acronyms : ATE: Acute Toxicity Estimate. CAS (Chemical Abstracts Service) number. EC50: Environmental Concentration associated with a response by 50% of the test population. GHS: Globally Harmonized System (of Classification and Labeling of Chemicals). LD50: Lethal Dose for 50% of the test population. TWA: Time Weighted Average Full text of H-phrases: ------ Acute Tox. 3 (Dermal) Acute toxicity (dermal) Category 3 ------ Acute Tox. 3 (Inhalation) Acute toxicity (inhalation) Category 3 ------ Acute Tox. 3 (Oral) Acute toxicity (oral) Category 3 ------ Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category 1 ------ Aquatic Chronic 1 Hazardous to the aquatic environment - Chronic Hazard Category 1 ------ Aquatic Chronic 2 Hazardous to the aquatic environment - Chronic Hazard Category 2 ------ Eye Dam. 1 Serious eye damage/eye irritation Category 1 ------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A ------ Repr. 2 Reproductive toxicity Category 2 ------ Skin Irrit. 2 Skin corrosion/irritation Category 2 ------ STOT RE 2 Specific target organ toxicity (repeated exposure) Category 2 ------ H301 Toxic if swallowed ------ H311 Toxic in contact with skin ------ H315 Causes skin irritation ------ H318 Causes serious eye damage ------ H319 Causes serious eye irritation ------ H331 Toxic if inhaled ------ H361 Suspected of damaging fertility or the unborn child ------ H373 May cause damage to organs through prolonged or repeated exposure ------ H400 Very toxic to aquatic life ------ H410 Very toxic to aquatic life with long lasting effects ------ H411 Toxic to aquatic life with long lasting effects Lucas Synthetic SAE 20W-50 API SN Motor Oil Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/06/2015 EN (English US) SDS ID: Lucas Syn 20W50 8/8 SDS US (GHS HazCom 2012) SDS prepared by: The Redstone Group, LLC 6077 Frantz Rd. Suite 206 Dublin, OH USA 43017 T 614-923-7472 www.redstonegrp.com This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product