PENRAY 4.0 CLEANER & LUBRICANT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. Date of issue: 01/26/2016 Revision date: 01/26/2016 Version: 1.0 01/26/2016 EN (English US) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : PENRAY 4.0 CLEANER & LUBRICANT Product code : 4616 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : CLEANER AND LUBRICANT 1.3. Details of the supplier of the safety data sheet The Penray Companies, Inc. 440 Denniston Ct. Wheeling, IL 60090 T (800) 373-6729 This email address is being protected from spambots. You need JavaScript enabled to view it. 1.4. Emergency telephone number Emergency number : (800) 373-6729 CHEMTREC (800) 424-9300 CHEMTREC International +1 (703) 527-3887 24 hr SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Compressed gas Skin Irrit. 2 Eye Irrit. 2A Asp. Tox. 1 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS04 GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Contains gas under pressure; may explode if heated. Causes skin irritation. Causes serious eye irritation. May be fatal if swallowed and enters airways. Precautionary statements (GHS-US) : Wash hands thoroughly after handling. Wear protective gloves/eye protection/face protection. If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Store locked up. Protect from sunlight. Store in a well- ventilated place. Dispose of contents/container in accordance with all local, state, provincial, and federal regulations. 2.3. Other hazards No additional information available. 2.4. Unknown acute toxicity (GHS US) Not applicable. SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable. PENRAY 4.0 CLEANER & LUBRICANT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 01/26/2016 EN (English US) 2/6 3.2. Mixture Name Product identifier % Petroleum distillates, hydrotreated light (CAS No) 64742-47-8 60 - 100 Diethylene glycol monobutyl ether (CAS No) 112-34-5 10 - 30 Carbon dioxide (CAS No) 124-38-9 1 - 5 * The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of ?1910.1200. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists. First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. If irritation persists, get medical attention. First-aid measures after ingestion : If swallowed, do NOT induce vomiting. Immediately call a poison center or doctor/physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause respiratory tract irritation. Intentional misuse of product by inhalation can result in asphyxiation or death. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. 4.3. Indication of any immediate medical attention and special treatment needed Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Carbon dioxide. Dry powder. Alcohol resistant foam. Water spray. Unsuitable extinguishing media : Do not use water jet. 5.2. Special hazards arising from the substance or mixture Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon, silicon oxides and formaldehyde. Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. 5.3. Advice for firefighters Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Use water spray to keep fire-exposed containers cool. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. 6.2. Methods and material for containment and cleaning up For containment : Eliminate sources of ignition. Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation. 6.3. Reference to other sections See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Pressurized container: Do not pierce or burn, even after use. PENRAY 4.0 CLEANER & LUBRICANT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 01/26/2016 EN (English US) 3/6 Precautions for safe handling : Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not swallow. Handle and open container with care. When using do not eat, drink or smoke. Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep out of the reach of children. Store locked up. Do not expose to temperatures exceeding 50 ?C/ 122 ?F. Store away from direct sunlight or other heat sources. Storage area : Store in a well-ventilated place. 7.3. Specific end use(s) Not available. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Petroleum distillates, hydrotreated light (64742-47-8) ACGIH Not applicable. OSHA Not applicable. Diethylene glycol monobutyl ether (112-34-5) ACGIH ACGIH TWA (ppm) 10 ppm (inhalable fraction and vapor) OSHA Not applicable. Carbon dioxide (124-38-9) ACGIH ACGIH TWA (ppm) 5000 ppm ACGIH ACGIH STEL (ppm) 30000 ppm OSHA OSHA PEL (TWA) (mg/m?) 9000 mg/m? OSHA OSHA PEL (TWA) (ppm) 5000 ppm 8.2. Exposure controls Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Hand protection : Wear chemically resistant protective gloves. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure controls : Maintain levels below Community environmental protection thresholds. Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Handle according to established industrial hygiene and safety practices. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Gas/Pressurized Liquid Appearance : Clear Color : Colorless Odor : Solvent Odor threshold : No data available pH : No data available Melting point : No data available Freezing point : No data available Boiling point : No data available Flash point : No data available Relative evaporation rate (butyl acetate=1) : No data available Flammability (solid, gas) : Not flammable Explosion limits : No data available Explosive properties : Pressurized container: may burst if heated. PENRAY 4.0 CLEANER & LUBRICANT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 01/26/2016 EN (English US) 4/6 Oxidizing properties : No data available Vapor pressure : No data available Relative density : No data available Relative vapor density at 20 ?C : No data available Solubility : No data available Partition coefficient: n-octanol/water : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available 9.2. Other information No additional information available. SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reaction known under conditions of normal use. 10.2. Chemical stability Stable under normal storage conditions. Contents under pressure. Container may explode if heated. Do not puncture. Do not burn. 10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 10.4. Conditions to avoid Heat. Incompatible materials. 10.5. Incompatible materials Strong oxidizers. Alkalis. 10.6. Hazardous decomposition products May include, and are not limited to: oxides of carbon, silicon oxides and formaldehyde. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified 4616 LD50 oral rat > 2000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat No data available Petroleum distillates, hydrotreated light (64742-47-8) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat > 5.2 mg/l/4h Diethylene glycol monobutyl ether (112-34-5) LD50 oral rat 5660 mg/kg LD50 dermal rabbit 2700 mg/kg Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitization : Based on available data, the classification criteria are not met. Germ cell mutagenicity : Based on available data, the classification criteria are not met. Carcinogenicity : Based on available data, the classification criteria are not met. Reproductive toxicity : Based on available data, the classification criteria are not met. Specific target organ toxicity (single exposure) : Based on available data, the classification criteria are not met. Specific target organ toxicity (repeated exposure) : Based on available data, the classification criteria are not met. Aspiration hazard : May be fatal if swallowed and enters airways. PENRAY 4.0 CLEANER & LUBRICANT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 01/26/2016 EN (English US) 5/6 Symptoms/injuries after inhalation : May cause respiratory tract irritation. Intentional misuse of product by inhalation can result in asphyxiation or death. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : May cause long-term adverse effects in the aquatic environment. 12.2. Persistence and degradability 4616 Persistence and degradability Not established. 12.3. Bioaccumulative potential 4616 Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available. 12.5. Other adverse effects Effect on the global warming : No known ecological damage caused by this product. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Container under pressure. Do not drill or burn even after use. This material must be disposed of in accordance with all local, state, provincial, and federal regulations. The generation of waste should be avoided or minimized wherever possible. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT UN-No.(DOT) : UN1950 Proper Shipping Name (DOT) : Aerosol, non-flammable Class (DOT) : 2.2 Hazard labels (DOT) : Additional information Other information : No supplementary information available. Special transport precautions : Do not handle until all safety precautions have been read and understood. SECTION 15: Regulatory information 15.1. US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory Diethylene glycol monobutyl ether (112-34-5) EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA Y2 - Y2 - indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule PENRAY 4.0 CLEANER & LUBRICANT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 01/26/2016 EN (English US) 6/6 15.3. US State regulations 4616 State or local regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm SECTION 16: Other information Date of issue : 01/26/2016 Revision date : 01/26/2016 Other information : None. Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user?s responsibility to satisfy oneself as to the suitability and completeness of this information for the user?s own particular use.