Page 1 of 10 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 06/20/2015 Reviewed on 06/22/2015 41.0 1 Identification ? Product identifier ? Trade name: Beck/Arnley Premium Antifreeze/Coolant Euro SF+ Concentrate (252-1021) ? Recommended use and restriction on use ? Recommended use: Coolant / Anti-freeze. ? Restrictions on use: Contact manufacturer. ? Details of the supplier of the Safety Data Sheet ? Manufacturer/Supplier: Beck/Arnley Inc. 2375 Midway Lane Smyrna, TN 37167 Telephone: 615-220-3200 Email: This email address is being protected from spambots. You need JavaScript enabled to view it. ? Emergency telephone number: INFOTRAC 1-800-535-5053 2 Hazard(s) identification ? Classification of the substance or mixture GHS08 Health hazard Repr. 2 H361 Suspected of damaging fertility or the unborn child. STOT RE 2 H373 May cause damage to the kidneys through prolonged or repeated exposure. Route of exposure: Oral. GHS07 Acute Tox. 4 H302 Harmful if swallowed. ? Additional information: There are no other hazards not otherwise classified that have been identified. 0 percent of the mixture consists of ingredient(s) of unknown toxicity. ? Label elements ? GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). ? Hazard pictograms GHS07 GHS08 ? Signal word Warning ? Hazard-determining components of labeling: ethanediol sodium 2-ethylhexanoate (Contd. on page 2) Page 2 of 10 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 06/20/2015 Reviewed on 06/22/2015 Trade name: Beck/Arnley Premium Antifreeze/Coolant Euro SF+ Concentrate (252-1021) (Contd. of page 1) 41.0 ? Hazard statements H302 Harmful if swallowed. H361 Suspected of damaging fertility or the unborn child. H373 May cause damage to the kidneys through prolonged or repeated exposure. Route of exposure: Oral. ? Precautionary statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapors/spray. P264 Wash thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P270 Do not eat, drink or smoke when using this product. P301+P312 If swallowed: Call a poison center/doctor if you feel unwell. P308+P313 IF exposed or concerned: Get medical advice/attention. P314 Get medical advice/attention if you feel unwell. P330 Rinse mouth. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. ? Hazard description: ? WHMIS-symbols: As of 11 February 2015, the current WHMIS system is being replaced by the GHS system. This is the classifcation under the older system. D2A - Very toxic material causing other toxic effects ? Classification system: ? NFPA ratings (scale 0 - 4) 0 1 0 Health = 0 Fire = 1 Reactivity = 0 ? HMIS-ratings (scale 0 - 4) HEALTH FIRE REACTIVITY *0 1 0 Health = *0 Fire = 1 Reactivity = 0 * - Indicates a long term health hazard from repeated or prolonged exposures. ? Other hazards ? Results of PBT and vPvB assessment ? PBT: Not applicable. ? vPvB: Not applicable. (Contd. on page 3) Page 3 of 10 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 06/20/2015 Reviewed on 06/22/2015 Trade name: Beck/Arnley Premium Antifreeze/Coolant Euro SF+ Concentrate (252-1021) (Contd. of page 2) 41.0 3 Composition/information on ingredients ? Chemical characterization: Mixtures ? Description: Mixture of the substances listed below with nonhazardous additions. ? Dangerous components: 107-21-1 ethanediol STOT RE 2, H373 Acute Tox. 4, H302 85-95% 19766-89-3 sodium 2-ethylhexanoate Repr. 2, H361 1-5% ? Additional information: For the listed ingredients, the identity and exact percentages are being withheld as a trade secret. 4 First-aid measures ? Description of first aid measures ? General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. ? After inhalation: Supply fresh air; consult doctor in case of complaints. ? After skin contact: Rinse with warm water. If skin irritation is experienced, consult a doctor. ? After eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. ? After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; immediately call for medical help. ? Information for doctor: ? Most important symptoms and effects, both acute and delayed Gastric or intestinal disorders when ingested. Nausea in case of ingestion. ? Danger Harmful if swallowed. May cause damage to the kidneys through prolonged or repeated exposure. Route of exposure: Oral. Suspected of damaging fertility or the unborn child. ? Indication of any immediate medical attention and special treatment needed Contains ethylene glycol / ethanediol. Consult literature for specific antidotes. Medical supervision for at least 48 hours. If medical advice is needed, have product container or label at hand. 5 Fire-fighting measures ? Extinguishing media ? Suitable extinguishing agents: Use fire fighting measures that suit the environment. ? For safety reasons unsuitable extinguishing agents: None. (Contd. on page 4) Page 4 of 10 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 06/20/2015 Reviewed on 06/22/2015 Trade name: Beck/Arnley Premium Antifreeze/Coolant Euro SF+ Concentrate (252-1021) (Contd. of page 3) 41.0 ? Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. ? Advice for firefighters ? Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. ? Additional information No further relevant information available. 6 Accidental release measures ? Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. For large spills, wear protective clothing. For large spills, use respiratory protective device against the effects of fumes/dust/aerosol. ? Environmental precautions: Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. ? Methods and material for containment and cleaning up: Absorb with non-combustible liquid-binding material (sand, diatomite, acid binders, universal binders). Dispose contaminated material as waste according to item 13. Send for recovery or disposal in suitable receptacles. ? Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage ? Handling: ? Precautions for safe handling Prevent formation of aerosols. Avoid splashes or spray in enclosed areas. Use only in well ventilated areas. ? Information about protection against explosions and fires: No special measures required. ? Conditions for safe storage, including any incompatibilities ? Storage: ? Requirements to be met by storerooms and receptacles: No special requirements. ? Information about storage in one common storage facility: Store away from foodstuffs. Store away from oxidizing agents. ? Further information about storage conditions: Keep containers tightly sealed. None. ? Specific end use(s) No further relevant information available. (Contd. on page 5) Page 5 of 10 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 06/20/2015 Reviewed on 06/22/2015 Trade name: Beck/Arnley Premium Antifreeze/Coolant Euro SF+ Concentrate (252-1021) (Contd. of page 4) 41.0 8 Exposure controls/personal protection ? Additional information about design of technical systems: No further data; see item 7. ? Control parameters ? Components with limit values that require monitoring at the workplace: 107-21-1 ethanediol TLV (USA) Long-term value: NIC-10* mg/m? Ceiling limit value: (100) mg/m? (H);*as inhalable fraction and vapor EL (Canada) Short-term value: 20** mg/m? Long-term value: 10** mg/m? Ceiling limit value: 100* mg/m?, 50*** ppm *Aerosol; **Particulate; ***Vapour EV (Canada) Ceiling limit value: 100 mg/m? LMPE (Mexico) Ceiling limit value: 100* mg/m? A4, *solo aerosol ? Additional information: No further relevant information available. ? Exposure controls ? Personal protective equipment: ? General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. ? Engineering controls: No further relevant information available. ? Breathing equipment: Not required under normal conditions of use. Use suitable respiratory protective device when aerosol or mist is formed. Use suitable respiratory protective device when high concentrations are present. ? Protection of hands: Rubber gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. ? Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. ? Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. ? Eye protection: Safety glasses ? Body protection: Protective work clothing (Contd. on page 6) Page 6 of 10 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 06/20/2015 Reviewed on 06/22/2015 Trade name: Beck/Arnley Premium Antifreeze/Coolant Euro SF+ Concentrate (252-1021) (Contd. of page 5) 41.0 ? Limitation and supervision of exposure into the environment No further relevant information available. 9 Physical and chemical properties ? Information on basic physical and chemical properties ? General Information ? Appearance: Form: Liquid Color: Violet ? Odor: Characteristic ? Odor threshold: Not determined. ? pH-value at 20 ?C (68 ?F): 7.5 - 9.0 (33% solution) ? Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: 120 ?C (248 ?F) ? Flash point: >100 ?C (>212 ?F) ? Flammability (solid, gaseous): Not applicable. ? Auto-ignition temperature: >400 ?C (>752 ?F) (DIN 51794) ? Decomposition temperature: Not determined. ? Auto igniting: Product is not self-igniting. ? Danger of explosion: Product does not present an explosion hazard. ? Explosion limits: Lower: Not determined. Upper: Not determined. ? Oxidizing properties Non-oxidizing. ? Vapor pressure at 20 ?C (68 ?F): <0.1 hPa (<0 mm Hg) ? Density at 20 ?C (68 ?F): 1.12 g/cm? (9.346 lbs/gal) ? Relative density Not determined. ? Vapour density Not determined. ? Evaporation rate Not determined. ? Solubility in / Miscibility with Water: Fully miscible. ? Partition coefficient (n-octanol/water): Not determined. ? Viscosity: Dynamic: Not determined. Kinematic at 20 ?C (68 ?F): 15 mm?/s ? Other information No further relevant information available. (Contd. on page 7) Page 7 of 10 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 06/20/2015 Reviewed on 06/22/2015 Trade name: Beck/Arnley Premium Antifreeze/Coolant Euro SF+ Concentrate (252-1021) (Contd. of page 6) 41.0 10 Stability and reactivity ? Reactivity ? Chemical stability ? Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications. ? Possibility of hazardous reactions Reacts with strong oxidizing agents. ? Conditions to avoid No further relevant information available. ? Incompatible materials: No further relevant information available. ? Hazardous decomposition products: Possible in traces. 11 Toxicological information ? Information on toxicological effects ? Acute toxicity: ? LD/LC50 values that are relevant for classification: 107-21-1 ethanediol Oral LD50 5840 mg/kg (rat) Dermal LD50 9530 mg/kg (rabbit) 19766-89-3 sodium 2-ethylhexanoate Oral LD50 2043 mg/kg (rat) Dermal LD50 >2000 mg/kg (rabbit) ? Primary irritant effect: ? on the skin: No irritant effect. ? on the eye: Slight irritant effect on eyes. ? Sensitization: No sensitizing effects known. ? Additional toxicological information: Toxic and/or corrosive effects may be delayed up to 24 hours. 0 percent of the mixture consists of ingredient(s) of unknown toxicity. ? Carcinogenic categories ? NTP (National Toxicology Program) None of the ingredients is listed. ? OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. ? Probable Routes of Exposure Ingestion. Inhalation. Eye contact. Skin contact. ? Acute effects (acute toxicity, irritation and corrosivity): Harmful if swallowed. ? Repeated Dose Toxicity: Possible risk of irreversible effects. ? CMR effects (carcinogenity, mutagenicity and toxicity for reproduction): Repr. 2 ? Germ cell mutagenicity Based on available data, the classification criteria are not met. (Contd. on page 8) Page 8 of 10 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 06/20/2015 Reviewed on 06/22/2015 Trade name: Beck/Arnley Premium Antifreeze/Coolant Euro SF+ Concentrate (252-1021) (Contd. of page 7) 41.0 ? Carcinogenicity Based on available data, the classification criteria are not met. ? Reproductive toxicity Suspected of damaging fertility or the unborn child. ? STOT-single exposure Based on available data, the classification criteria are not met. ? STOT-repeated exposure May cause damage to the kidneys through prolonged or repeated exposure. Route of exposure: Oral. ? Aspiration hazard Based on available data, the classification criteria are not met. 12 Ecological information ? Toxicity ? Aquatic toxicity: No further relevant information available. ? Persistence and degradability No further relevant information available. ? Behavior in environmental systems: ? Bioaccumulative potential No further relevant information available. ? Mobility in soil No further relevant information available. ? Additional ecological information: ? General notes: Do not allow product to reach ground water, water course or sewage system, even in small quantities. Due to available data on eliminability/decomposition and bioaccumulation potential prolonged term damage of the environment can not be excluded. ? Other adverse effects No further relevant information available. 13 Disposal considerations ? Waste treatment methods ? Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. The user of this material has the responsibility to dispose of unused material, residues and containers in compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and disposal for hazardous and nonhazardous wastes. Residual materials should be treated as hazardous. ? Uncleaned packagings: ? Recommendation: Disposal must be made according to official regulations. ? Recommended cleansing agent: Water, if necessary with cleansing agents. 14 Transport information ? UN-Number ? DOT, ADR, ADN, IMDG, IATA Not Regulated ? UN proper shipping name ? DOT, ADR, ADN, IMDG, IATA Not Regulated ? Transport hazard class(es) ? DOT, ADR, ADN, IMDG, IATA ? Class Not Regulated (Contd. on page 9) Page 9 of 10 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 06/22/2015 Reviewed on 06/22/2015 Trade name: Beck/Arnley Premium Antifreeze/Coolant Euro SF+ Concentrate (252-1021) (Contd. of page 8) 41.0 ? Packing group ? DOT, ADR, IMDG, IATA Not Regulated ? Environmental hazards: ? Marine pollutant: No ? Special precautions for user Not applicable. ? Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. ? UN "Model Regulation": - 15 Regulatory information ? Safety, health and environmental regulations/legislation specific for the substance or mixture ? United States (USA) ? SARA ? Section 355 (extremely hazardous substances): None of the ingredients is listed. ? Section 313 (Specific toxic chemical listings): 107-21-1 ethanediol ? TSCA (Toxic Substances Control Act): All ingredients are listed. ? Proposition 65 (California) ? Chemicals known to cause cancer: None of the ingredients are listed. ? Chemicals known to cause reproductive toxicity for females: None of the ingredients are listed. ? Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. ? Chemicals known to cause developmental toxicity: None of the ingredients is listed. ? Carcinogenic categories ? EPA (Environmental Protection Agency) None of the ingredients is listed. ? IARC (International Agency for Research on Cancer) None of the ingredients is listed. ? TLV (Threshold Limit Value established by ACGIH) 107-21-1 ethanediol A4 ? NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. ? State Right to Know Listings None of the ingredients is listed. (Contd. on page 10) Page 10 of 10 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 06/20/2015 Reviewed on 06/22/2015 Trade name: Beck/Arnley Premium Antifreeze/Coolant Euro SF+ Concentrate (252-1021) (Contd. of page 9) 41.0 ? Canadian substance listings: ? Canadian Domestic Substances List (DSL) All ingredients are listed. ? Canadian Ingredient Disclosure list (limit 0.1%) None of the ingredients is listed. ? Canadian Ingredient Disclosure list (limit 1%) 107-21-1 ethanediol ? Other regulations, limitations and prohibitive regulations This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations. ? Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. ? Date of preparation / last revision 06/16/2015 / - ? Abbreviations and acronyms: ADR: Accord europ?en sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) WHMIS: Workplace Hazardous Materials Information System (Canada) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Acute Tox. 4: Acute toxicity, Hazard Category 4 Repr. 2: Reproductive toxicity, Hazard Category 2 STOT RE 2: Specific target organ toxicity - Repeated exposure, Hazard Category 2 ? Sources SDS Prepared by: ChemTel Inc. 1305 North Florida Avenue Tampa, Florida USA 33602-2902 Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573 Website: www.chemtelinc.com