WARN Specified stream length 6928 is wrong. Fall back to reading stream until 'endstream'. WARN Specified stream length 29419 is wrong. Fall back to reading stream until 'endstream'. WARN Specified stream length 25193 is wrong. Fall back to reading stream until 'endstream'. WARN Did not found XRef object at specified startxref position 177465 WARN /Length of COSObject{5, 0} corrected from 3024 to 3065 WARN /Length of COSObject{10, 0} corrected from 7166 to 7262 WARN /Length of COSObject{11, 0} corrected from 338 to 344 WARN /Length of COSObject{15, 0} corrected from 3303 to 3348 WARN /Length of COSObject{17, 0} corrected from 7166 to 7262 WARN /Length of COSObject{20, 0} corrected from 3221 to 3265 WARN /Length of COSObject{22, 0} corrected from 7166 to 7262 WARN /Length of COSObject{25, 0} corrected from 3164 to 3207 WARN /Length of COSObject{27, 0} corrected from 7166 to 7262 WARN /Length of COSObject{30, 0} corrected from 3307 to 3352 WARN /Length of COSObject{35, 0} corrected from 3037 to 3078 WARN /Length of COSObject{32, 0} corrected from 7166 to 7262 WARN /Length of COSObject{37, 0} corrected from 7166 to 7262 WARN /Length of COSObject{42, 0} corrected from 7166 to 7262 WARN /Length of COSObject{40, 0} corrected from 3256 to 3300 WARN /Length of COSObject{47, 0} corrected from 7166 to 7262 WARN /Length of COSObject{45, 0} corrected from 3424 to 3470 WARN /Length of COSObject{50, 0} corrected from 2140 to 2170 WARN /Length of COSObject{55, 0} corrected from 1279 to 1297 WARN /Length of COSObject{52, 0} corrected from 7166 to 7262 WARN /Length of COSObject{57, 0} corrected from 7166 to 7262 WARN /Length of COSObject{60, 0} corrected from 275 to 280 WARN /Length of COSObject{70, 0} corrected from 615 to 625 WARN /Length of COSObject{65, 0} corrected from 696 to 707 OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 181251 US-US-4 Level: 1 Release Date: 2011-12-07 Page: 1 / FIR No.: 10 1. Product and Company Identification Product Name: Product Code: Application: Supplier: Emergency Telephone: Seam Sealer See Attachment Seam sealer Ford Motor Company Attention: MSDS Information, P.O. Box 1899 Dearborn, Michigan 48121 1-800-392-3673 Poison Control Center: 1-800-959-3673 CHEMTREC: U.S. and Canada: 1-800-424-9300 CHEMTREC: International: 1-703-527-3887 Chemical Name CAS Number Percent Concentration Hazard Classification XYLENE (ALL ISOMERS) PETROLEUM NAPHTHA, LIGHT AROMATIC ISOCYANIC ACID, METHYLENEDI- P-PHENYLENE ESTER 1330-20-7 64742-95-6 101-68-8 1-5 1-5 0.1-1 PEL/TLV-US HAZCOM DSL LISTED CAA-HAP ACGIH/OSHA HAZCOM DSL LISTED RSMS_D_ALL WHMIS 0.1 RSMS_D_ALL RQ PEL/TLV-US HAZCOM DSL LISTED ACGIH/OSHA CAA-HAP 2. Composition/Information on Ingredients This chemical product is a preparation. OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 181251 US-US-4 Level: 1 Release Date: 2011-12-07 Page: 2 / FIR No.: 10 Health: Physical and Chemical Hazards: Environment: Inhalation: Skin Contact: Eye Contact: Ingestion: Notes to a Physician: Extinguishing Media: Specific Methods: This product is irritating to the eyes, respiratory system and skin. Inhalation may cause allergic respiratory reaction in lungs. This product may cause an allergic skin reaction. This product may cause nervous system damage. This product is harmful by inhalation and if it is swallowed. Excessive inhalation of this material causes headache, dizziness, nausea and incoordination. If ingested, this product may cause gastrointestinal irritation. Overexposure may cause liver and kidney damage. This product is combustible at high temperatures. Vapor harmful. Material contains a chemical which is a Hazardous Air Pollutant (HAP), regulated by the United States Clean Air Act. If gas/fume/vapor/dust/mist from the material is inhaled, remove the affected person immediately to fresh air. If irritation persists, get medical attention. Wash skin with soap and water. If irritation persists, get medical attention. In case of contact with eyes, rinse immediately with plenty of water for at least 15 minutes and seek medical attention. If irritation persists, get medical attention. If the material is swallowed, get immediate medical attention or advice -- Do not induce vomiting. Certain pre-existing conditions may make workers particularly susceptible to the effects of this chemical: asthma, allergies, known sensitivity to diisocyanates impaired pulmonary function. Dry chemical, foam, carbon dioxide, water fog. Water may be used to cool exposed containers to prevent pressure build-up and explosion when exposed to extreme heat. 3. Hazards Identification 4. First-Aid Measures 5. Fire-Fighting Measures COMBUSTIBLE OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 181251 US-US-4 Level: 1 Release Date: 2011-12-07 Page: 3 / FIR No.: 10 Specific Hazards: Protection of Firefighters: Personal Precautions: Environmental Precautions: Methods for Cleaning Up: Handling: Storage: Due to pressure buildup, closed containers exposed to excess heat may explode. Empty containers may retain product residue including Flammable or Explosive vapors. Do not cut, drill, grind, or weld near full, partially full, or empty product containers. Irritating and/or toxic fumes and gases may be emitted upon the product's decomposition. Vapors are heavier than air and may travel along the ground to some distant source of ignition and flash back. Fire fighters should be equipped with NIOSH-approved, self-contained breathing apparatus (SCBA) and full protective clothing. Ventilate the contaminated area. Eliminate all sources of ignition or flammables that may come into contact with a spill of this material. Avoid inhalation of vapors and contact with skin and eyes. Wear appropriate protective equipment and clothing during clean-up. No available information. Absorb the spilled material with an inert absorbent (nonflammable) material. Keep this product from heat, sparks, or open flame. Avoid skin and eye contact. Do not puncture or incinerate container. Keep the container closed when not in use. Use with adequate ventilation. Do not reuse the empty container. Do not store near heat, spark or open flame. Keep the container tightly closed and in a cool, well-ventilated place. Store this product away from acids. Store this product away from strong oxidizing agents. Technical Measures: Precautions and Advice for Safe Handling: Technical Measures: Storage Conditions: 6. Accidental Release Measures 7. Handling and Storage OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 181251 US-US-4 Level: 1 Release Date: 2011-12-07 Page: 4 / FIR No.: 10 When using this material, do not eat, drink or smoke. Personal Protective Equipment: Hygiene Measures: If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, an approved respirator must be worn. Respirator selection, use and maintenance should be in accordance with the requirements of OSHA Respiratory Protection Standard 29 CFR 1910.134 and/or Canadian Standard CSA Z94.4. Use supplied-air respiratory equipment as required. The use of neoprene gloves is recommended. The use of nitrile-latex gloves is recommended. The use of natural rubber gloves is recommended. Wear safety glasses with side shields. Wear chemical goggles; face shield (if splashing is possible). Light protective clothing is recommended. Wash thoroughly after handling. Respiratory Protection: Hand Protection: Eye Protection: Skin and Body Protection: 8. Exposure Controls/Personal Protection Use adequate ventilation to control airborne concentrations below the exposure limits/guidelines. If user operations generate a vapor, dust, and/or mist, use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below the recommended exposure limits/guidelines. Engineering Measures: Exposure Limits: 100(ppm) C 0.02(ppm) 150(ppm) OSHA OSHA ISOCYANIC ACID, METHYLENEDI-P- PHENYLENE ESTER XYLENE (ALL ISOMERS) 0.005(ppm) 100(ppm) 150(ppm) ACGIH ACGIH Chemical Name TWA STEL/C References OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 181251 US-US-4 Level: 1 Release Date: 2011-12-07 Page: 5 / FIR No.: 10 9. Physical and Chemical Properties 10. Stability and Reactivity 1.19 @4?C LIQUID PASTE SOLVENT OFF-WHITE N.AP 68 ?C SCC ND >1 (AIR=1) INSOLUBLE IN WATER N.AP <1 (BuAc = 1) This is a stable material. Hazardous polymerization will not occur. Isocyanates may react with strong alkalies, acids, alcohols, primary or secondary amines, oxidizing agents, water. Foaming and spattering may occur on contact. This product may react with strong oxidizing agents (bleach--sodium hypochlorite, calcium hypochlorite, hydrogen peroxide, permanganate, nitric acid, concentrated OXYGEN, perchlorates). This product may react with strong acids. Static discharge, friction, sparks, open flames, heat and other sources of ignition. Carbon monoxide, carbon dioxide, and other low molecular weight hydrocarbons. Decomposition of this product may yield oxides of nitrogen upon decomposition. Irritating and toxic gases or fumes may be released during a fire. Specific Gravity: Physical State: Form: Odor: Color: pH: Temperature Range During which Changes in Physical State Occur: Flash Point: Explosion Properties: Vapor Pressure: Vapor Density: Solubility: Viscosity: Evaporation Rate: Stability: Conditions and Materials to Avoid: Hazardous Decomposition Products: 138.8-153.3 ?C 7 % 1 % Boiling Point: UEL: LEL: OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 181251 US-US-4 Level: 1 Release Date: 2011-12-07 Page: 6 / FIR No.: 10 11. Toxicological Information 1330-20-7 XYLENE (ALL ISOMERS) Inhalation, adult rat, LC50 = 5000 ppm (4 Hours) 1330-20-7 XYLENE (ALL ISOMERS) Oral, adult rat, LD50 = 4300 mg/kg 101-68-8 ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER Inhalation, adult rat, LC50 = 178 mg/m3 Excessive inhalation of this material causes headache, dizziness, nausea and incoordination. Prolonged and/or repeated skin contact with this product may cause irritation/dermatitis. Diisocyanates most notable toxic effect is the ability to sensitize people so that they develop asthma-like respiratory symptoms when subsequently exposed to very low levels of the chemical. Workplace exposures to surprisingly low concentrations, on the order of a few parts per billion, have triggered the appearance of the symptoms: a sensation of tightness of the chest, cough, difficulty in breathing, lung irritation; stomach or intestinal upset (nausea, vomiting, diarrhea); headache, central nervous system depression(dizziness, drowsiness, weakness, fatigue, nausea, unconsciousness);allergic reactions (causes narrowing of the air passage of the lungs, sweating, flushing, hives, rapid heart rate, and lowered blood pressure); narcosis (dazed or sluggish feeling). These attacks are potentially life threatening; may be delayed in onset (occurring some hours after exposure has taken place). Diisocyanates also may irritate the upper respiratory tract, eyes, and skin. THE IRRITATIVE EFFECTS OCCUR AT LEVELS FAR ABOVE THOSE WHICH BRING ON THE ASTHMA-LIKE ATTACKS IN DIISOCYANATE-SENSITIZED PEOPLE. Inhalation: Skin Contact: Sensitization: OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 181251 US-US-4 Level: 1 Release Date: 2011-12-07 Page: 7 / FIR No.: 10 12. Ecological Information 13. Disposal Considerations No specific aquatic data available for this product. A study by the International Isocyanate Institute suggests that prolonged exposure to high concentrations of polymeric methylene bisphenlisocyanate (MDI) may increase the incidence of tumors in the lungs. This study entailed a lifetime exposure of male and female rats to an aerosol of polymeric MDI at levels up to 6 mg/m3. The tumor effects noted in the study occurred at levels that would not be tolerated in a workplace due to the irritant and sensitizing properties of MDI and in the absence of prolonged high exposures leading to irritation and sensitization, it is unlikely that tumor formation would occur. However, this report emphasizes the need to maintain exposures below the recommended occupational exposure limits. Long-term overexposure may cause blood, liver and kidney effects. Prolonged or repeated contact may cause liver, kidney, and lung damage. Prolonged or repeated occupational overexposure to solvents has been linked to permanent brain and nervous system damage. This material contains butyl benzyl phthalate, prolonged or repeated overexposure to this product may damage the peripheral nerves and affect blood cells and liver function. Xylenes consist of a mixture of ortho, meta, and para xylene isomers and 5-15% ethylbenzene. Laboratory animal studies show that rats exposed to xylene vapor during pregnancy showed embryo/fetotoxic effects. Mice exposed orally to doses producing maternal toxicity also showed embryo/fetotoxic effects. Ethylbenzene has been shown to cause tumors in laboratory animals at HIGH inhalation exposures (750 ppm). Tumors were not observed in laboratoy animals at LOWER (<250 ppm). Human data is not available. Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulation. No consideration given when disposed of according to local, state, and Federal regulations. Chronic (Long Term) Toxicity: Waste from Residues: Contaminated Packaging: OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 181251 US-US-4 Level: 1 Release Date: 2011-12-07 Page: 8 / FIR No.: 10 14. Transport Information U.S. Department of Transportation (DOT) 49 - CFR 172.101 Canadian Transportation of Dangerous Goods (T.D.G.) - TDGR Schedule II Secretary of Communication and Transportation (SCT) - NOM-002-SCT2/1994 (Mexico) International and Domestic Air Transportation - ICAO & IATA Section 4.2 International Water Transportation - IMDG Code Amendment 31-02 This product is not regulated as a dangerous good. This product is not regulated as a dangerous good. This product is not regulated as a dangerous good. This product is not regulated as a dangerous good. This product is not regulated as a dangerous good. The components of this product are listed on the TSCA Inventory This product contains NONE of the substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372 California Proposition 65: WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. This product contains an ingredient(s) considered to be a "toxic or hazardous substance" by the Commonwealth of Massachussetts (Massachussetts Right to Know Law). This product contains an ingredient(s) considered to be a hazardous substance by the State of Pennsylvania (Pennsylvania Worker and Community Right to Know Act). This product contains an ingredient(s) considered to be an environmental hazardous substance(s) by the State of New Jersey. This product contains an ingredients(s) considered to be a hazardous substance(s) by the State of New Jersey. Material contains a chemical which is a Ford Motor Company Material of Concern. Use and release of this material should be minimized to the greatest extent possible. 15. Regulatory Information 16. Other Information Key/Legend: N.AP = Not applicable; N.AV = Not available; ND = Not determined or No data; TLV = Threshold limit value; TWA = Time-weighted average; STEL = Short-term exposure limit; C = Ceiling limit HMIS and NFPA Hazard Class Information: HMIS Hazard Class: NFPA Hazard Class: Health: 2 (Moderate) Flammability: 2 (Moderate) Physical Hazard: 1 (Slight) Health: 2 (Moderate) Flammability: 2 (Moderate) Instability: 1 (Slight) OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 181251 US-US-4 Level: 1 Release Date: 2011-12-07 Page: 9 / FIR No.: 10 8 2 16 15 The chemical identification and properties for this material were provided by the manufacturer. For Canadian locations, a manufacture's MSDS is available upon request. Health and safety information has been evaluated by the Occupational and Environmental Health Sciences Department, Ford Motor Company, Diagnostic Service Center II, 1800 Fairlane Drive, Allen Park, MI 48101, USA. The information on this data sheet represents our current data and is accurate to the best of our knowledge as to the proper handling of this product under normal conditions and in accordance with the application specified on the packaging and/or technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. The following sections contain revisions OR NEW statements. Preparation Information: Disclaimer: OO Owner: Ford Motor Company PRINTED DOCUMENT IS TRANSIENT Application: MATS Ford Proprietary Official Record Material Safety Data Sheet Version Number: 181251 US-US-4 Level: 1 Release Date: 2011-12-07 Page: 10 / FIR No.: 10 Product Code Container Size Part of Kit Kit Product Code TA-2 10.3 fl. oz. (305 mL) Attachment US-181251-US 1. Product and Company Identification 2. Composition/Information on Ingredients 3. Hazards Identification 4. First-Aid Measures 5. Fire-Fighting Measures 6. Accidental Release Measures 7. Handling and Storage 8. Exposure Controls/Personal Protection 9. Physical and Chemical Properties 10. Stability and Reactivity 11. Toxicological Information 12. Ecological Information 13. Disposal Considerations 14. Transport Information 15. Regulatory Information 16. Other Information Attachment