Olista Longtime 3 EP SAFETY DATA SHEET Product name Section 1. Identification SDS # Historic SDS #: 63103 Product use Grease for industrial applications. For specific application advice see appropriate Technical Data Sheet or consult our company representative. Code 451162-DE03 Manufacturer Castrol Industrial North America, Inc. 150 W. Warrenville Road Naperville, IL 60563 Supplier Castrol Industrial North America, Inc. 150 W. Warrenville Road Naperville, IL 60563 Product Information: +1-877-641-1600 EMERGENCY SPILL INFORMATION: 1 (800) 424-9300 CHEMTREC (USA) 451162 Relevant identified uses of the substance or mixture and uses advised against Section 2. Hazards identification SKIN SENSITIZATION - Category 1Classification of the substance or mixture Signal word Warning Hazard statements May cause an allergic skin reaction. Hazard pictograms Precautionary statements Prevention Wear protective gloves. Avoid breathing vapor. Contaminated work clothing should not be allowed out of the workplace. Response IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical attention. Storage Not applicable. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. GHS label elements OSHA/HCS status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Hazards not otherwise classified Defatting to the skin. Note: High Pressure Applications Injections through the skin resulting from contact with the product at high pressure constitute a major medical emergency. See 'Notes to physician' under First-Aid Measures, Section 4 of this Safety Data Sheet. Date of issue 04/09/2015. Page: 1/9Olista Longtime 3 EP ENGLISH (ENGLISH) Product name Product code Version 1 Format LanguageUS 451162-DE03 (US) FIR No. 183689 Section 3. Composition/information on ingredients There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Substance/mixture Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Highly refined mineral oil and additives Thickening agent. Base oil - highly refined Varies ?25 - <50 Base oil - highly refined 64742-65-0 ?25 - <50 Reaction product of ethoxylated fatty amine and ammonium compound Proprietary ?0.3 - <1 Phosphorous acid, decyl diphenyl ester. 26544-23-0 ?0.3 - <1 Ingredient name CAS number % Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Get medical attention if adverse health effects persist or are severe. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing. Check for and remove any contact lenses. Get medical attention. If inhaled, remove to fresh air. Get medical attention if symptoms occur. Section 4. First aid measures Eye contact Inhalation Ingestion Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician Treatment should in general be symptomatic and directed to relieving any effects. Note: High Pressure Applications Injections through the skin resulting from contact with the product at high pressure constitute a major medical emergency. Injuries may not appear serious at first but within a few hours tissue becomes swollen, discolored and extremely painful with extensive subcutaneous necrosis. Surgical exploration should be undertaken without delay. Thorough and extensive debridement of the wound and underlying tissue is necessary to minimize tissue loss and prevent or limit permanent damage. Note that high pressure may force the product considerable distances along tissue planes. Description of necessary first aid measures Specific treatments No specific treatment. Indication of immediate medical attention and special treatment needed, if necessary See Section 11 for more detailed information on health effects and symptoms. Most important symptoms/effects, acute and delayed Skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention. Section 5. Fire-fighting measures In case of fire, use water fog, alcohol resistant foam, dry chemical or carbon dioxide extinguisher or spray. Extinguishing media Suitable extinguishing media Do not use water jet.Unsuitable extinguishing media Date of issue 04/09/2015. Page: 2/9Olista Longtime 3 EP ENGLISH (ENGLISH) Product name Product code Version 1 Format LanguageUS 451162-DE03 (US) FIR No. 183689 Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous combustion products Specific hazards arising from the chemical Combustion products may include the following: carbon dioxide carbon monoxide phosphorus oxides metal oxide/oxides In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear. Special protective equipment for fire-fighters Special protective actions for fire-fighters Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Contaminated absorbent material may pose the same hazard as the spilled product. If emergency personnel are unavailable, contain spilled material. Suction or scoop the spill into appropriate disposal or recycling vessels, then cover spill area with oil absorbent. Dispose of via a licensed waste disposal contractor. No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Put on appropriate personal protective equipment. Floors may be slippery; use care to avoid falling. Contact emergency personnel. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders Entry into a confined space or poorly ventilated area contaminated with vapor, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work. Wear self-contained breathing apparatus. Wear a suitable chemical protective suit. Chemical resistant boots. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Wash thoroughly after handling. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Protective measures Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Avoid breathing vapor or mist. Do not ingest. Empty containers retain product residue and can be hazardous. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Do not reuse container. Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Precautions for safe handling Date of issue 04/09/2015. Page: 3/9Olista Longtime 3 EP ENGLISH (ENGLISH) Product name Product code Version 1 Format LanguageUS 451162-DE03 (US) FIR No. 183689 Section 7. Handling and storage Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Store and use only in equipment/containers designed for use with this product. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Base oil - highly refined ACGIH TLV (United States). TWA: 5 mg/m? 8 hours. Issued/Revised: 11/2009 Form: Inhalable fraction OSHA PEL (United States). TWA: 5 mg/m? 8 hours. Issued/Revised: 6/1993 Base oil - highly refined ACGIH TLV (United States). TWA: 5 mg/m? 8 hours. Issued/Revised: 11/2009 Form: Inhalable fraction OSHA PEL (United States). TWA: 5 mg/m? 8 hours. Issued/Revised: 6/1993 Section 8. Exposure controls/personal protection Ingredient name Exposure limits Safety glasses with side shields.Eye/face protection Environmental exposure controls Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls All activities involving chemicals should be assessed for their risks to health, to ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls) have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained. Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards. Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits. The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures Control parameters Individual protection measures Occupational exposure limits Skin protection While specific OELs for certain components may be shown in this section, other components may be present in any mist, vapor or dust produced. Therefore, the specific OELs may not be applicable to the product as a whole and are provided for guidance only. Date of issue 04/09/2015. Page: 4/9Olista Longtime 3 EP ENGLISH (ENGLISH) Product name Product code Version 1 Format LanguageUS 451162-DE03 (US) FIR No. 183689 Section 8. Exposure controls/personal protection Hand protection In case of insufficient ventilation, wear suitable respiratory equipment. The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application. Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions. Wear protective gloves if prolonged or repeated contact is likely. Wear chemical resistant gloves. Recommended: Nitrile gloves. The correct choice of protective gloves depends upon the chemicals being handled, the conditions of work and use, and the condition of the gloves (even the best chemically resistant glove will break down after repeated chemical exposures). Most gloves provide only a short time of protection before they must be discarded and replaced. Because specific work environments and material handling practices vary, safety procedures should be developed for each intended application. Gloves should therefore be chosen in consultation with the supplier/ manufacturer and with a full assessment of the working conditions. Respiratory protection Body protection Use of protective clothing is good industrial practice. Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots will be required. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Consult your supervisor or Standard Operating Procedure (S.O.P) for special handling instructions. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Vapor density Not available. Not available. Not available. Mild.Odor pH Brown. [Dark]Color Evaporation rate Not available. Auto-ignition temperature Flash point Not available. Closed cup: >150?C (>302?F) Not available. Not available. Viscosity Not available. Not available.Odor threshold Partition coefficient: n- octanol/water Appearance Boiling point Not available. Lower and upper explosive (flammable) limits Not available. Decomposition temperature Not available. Density Solubility <1000 kg/m? (<1 g/cm?) at 20?C insoluble in water. Grease Not applicable. Based on - Physical stateFlammability (solid, gas) Date of issue 04/09/2015. Page: 5/9Olista Longtime 3 EP ENGLISH (ENGLISH) Product name Product code Version 1 Format LanguageUS 451162-DE03 (US) FIR No. 183689 Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Incompatible materials Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur. Under normal conditions of storage and use, hazardous polymerization will not occur. Reactivity No specific test data available for this product. Refer to Conditions to avoid and Incompatible materials for additional information. Avoid all possible sources of ignition (spark or flame). Reactive or incompatible with the following materials: oxidizing materials. Section 11. Toxicological information Information on the likely routes of exposure No known significant effects or critical hazards.Ingestion Skin contact May cause an allergic skin reaction. No known significant effects or critical hazards.Eye contact No known significant effects or critical hazards.General No known significant effects or critical hazards.Carcinogenicity No known significant effects or critical hazards.Mutagenicity No known significant effects or critical hazards.Teratogenicity Developmental effects No known significant effects or critical hazards. Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion No specific data. Adverse symptoms may include the following: irritation redness dryness cracking Eye contact No specific data. Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Routes of entry anticipated: Dermal, Inhalation. Potential acute health effects Potential immediate effects Not available. Short term exposure Potential delayed effects Not available. Potential immediate effects Not available. Long term exposure Potential delayed effects Not available. Information on toxicological effects Inhalation Vapor inhalation under ambient conditions is not normally a problem due to low vapor pressure. Inhalation No specific data. Date of issue 04/09/2015. Page: 6/9Olista Longtime 3 EP ENGLISH (ENGLISH) Product name Product code Version 1 Format LanguageUS 451162-DE03 (US) FIR No. 183689 Section 11. Toxicological information Fertility effects No known significant effects or critical hazards. Numerical measures of toxicity Not available. Acute toxicity estimates Section 12. Ecological information Mobility Non-volatile. Grease insoluble in water. Bioaccumulative potential Other adverse effects No known significant effects or critical hazards. Toxicity Persistence and degradability Soil/water partition coefficient (KOC) Not available. Mobility in soil No testing has been performed by the manufacturer. Expected to be biodegradable. Not available. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal methods Section 14. Transport information - - - - - - Not regulated. - - Not regulated. Not regulated. DOT Classification IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group TDG Classification Not regulated. - - - Date of issue 04/09/2015. Page: 7/9Olista Longtime 3 EP ENGLISH (ENGLISH) Product name Product code Version 1 Format LanguageUS 451162-DE03 (US) FIR No. 183689 Section 14. Transport information - - -Additional information Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No. No. No. Not available. Not available. No. - Section 15. Regulatory information U.S. Federal regulations None of the components are listed.Massachusetts SARA 313 This product does not contain any hazardous ingredients at or above regulated thresholds. This product does not contain any hazardous ingredients at or above regulated thresholds. Form R - Reporting requirements Supplier notification New Jersey The following components are listed: MINERAL OIL (UNTREATED and MILDLY TREATED); MINERAL OIL (UNTREATED and MILDLY TREATED) Pennsylvania None of the components are listed. State regulations SARA 302/304 No products were found. Composition/information on ingredients SARA 311/312 Classification Immediate (acute) health hazard Other regulations All components are listed or exempted.United States inventory (TSCA 8b) All components are listed or exempted. All components are listed or exempted. At least one component is not listed. All components are listed or exempted. At least one component is not listed. China inventory (IECSC) Japan inventory (ENCS) Korea inventory (KECI) Philippines inventory (PICCS) Australia inventory (AICS) California Prop. 65 No products were found. Canada inventory At least one component is not listed. REACH Status The company, as identified in Section 1, sells this product in the EU in compliance with the current requirements of REACH. Taiwan inventory (CSNN) Not determined. Section 16. Other information Hazardous Material Information System (U.S.A.) 2 1 0 Health Flammability Physical hazards Personal protection X Date of issue 04/09/2015. Page: 8/9Olista Longtime 3 EP ENGLISH (ENGLISH) Product name Product code Version 1 Format LanguageUS 451162-DE03 (US) FIR No. 183689 Section 16. Other information History Date of issue/Date of revision Notice to reader Date of previous issue Indicates information that has changed from previously issued version. Key to abbreviations ACGIH = American Conference of Industrial Hygienists ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor CAS Number = Chemical Abstracts Service Registry Number GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) OEL = Occupational Exposure Limit SDS = Safety Data Sheet STEL = Short term exposure limit TWA = Time weighted average UN = United Nations UN Number = United Nations Number, a four digit number assigned by the United Nations Committee of Experts on the Transport of Dangerous Goods. 04/09/2015. No previous validation. 0 1 2 National Fire Protection Association (U.S.A.) Health Special Instability/Reactivity Flammability Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS? ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered mark of the National Paint & Coatings Association (NPCA). HMIS? materials may be purchased exclusively from J. J. Keller (800) 327-6868. All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet. The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from BP Group. It is the user?s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that this document is the most current available. Alteration of this document is strictly prohibited. Date of issue 04/09/2015. Page: 9/9Olista Longtime 3 EP ENGLISH (ENGLISH) Product name Product code Version 1 Format LanguageUS 451162-DE03 (US) FIR No. 183689