SAFETY DATA SHEET 1. Identification Product identifier Rear Window Defroster Repair Other means of identification FIR No. 191008 Recommended use rear window defroster repair Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Supplier Company Name Ford Motor Company Address Attention: MSDS Information, P.O. Box 1899 Dearborn, Michigan 48121 USA Telephone 1-800-392-3673 MSDS Information 1-800-448-2063 This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone numbers Poison Control Center: USA and Canada: 1-800-959-3673 INFOTRAC (Transportation): USA and Canada 1-800-535-5053 2. Hazard(s) identification Category 2Flammable liquidsPhysical hazards Category 4Acute toxicity, inhalationHealth hazards Category 2Serious eye damage/eye irritation Category 2Carcinogenicity Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure Category 1Hazardous to the aquatic environment, acute hazard Environmental hazards Category 1Hazardous to the aquatic environment, long-term hazard Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Highly flammable liquid and vapor. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation. Suspected of causing cancer. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. FIR No.: 191008 SDS US Issue Date: 05-16-2015 Version: 01 1 / 9 Response If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. If exposed or concerned: Get medical advice/attention. Call a poison center/doctor if you feel unwell. In case of fire: Use appropriate media to extinguish. Collect spillage. Storage Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) May be irritating to the skin. May be harmful if absorbed through skin. May cause an allergic skin reaction. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 108-10-14-METHYLPENTAN-2-ONE 40 - < 50 7440-22-4SILVER 40 - < 50 Specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or artificial respiration if needed. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical attention if irritation develops and persists. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. Most important symptoms/effects, acute and delayed Headache. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim warm. Keep victim under observation. Symptoms may be delayed. General information Take off all contaminated clothing immediately. IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire fighting equipment/instructions In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards Highly flammable liquid and vapor. FIR No.: 191008 SDS US Issue Date: 05-16-2015 Version: 01 2 / 9 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid contact with eyes, skin, and clothing. Avoid inhalation of vapors and spray mists. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. The product is immiscible with water and will sediment in water systems. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Prevent product from entering drains. Following product recovery, flush area with water. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. 7. Handling and storage Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. When using do not smoke. Explosion-proof general and local exhaust ventilation. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Avoid inhalation of vapors and spray mists. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Should be handled in closed systems, if possible. Use only outdoors or in a well-ventilated area. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in a cool, dry place out of direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Keep in an area equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 410 mg/m34-METHYLPENTAN-2-ONE (CAS 108-10-1) 100 ppm PEL 0.01 mg/m3SILVER (CAS 7440-22-4) US. ACGIH Threshold Limit Values ValueComponents FormType STEL 75 ppm4-METHYLPENTAN-2-ONE (CAS 108-10-1) TWA 20 ppm TWA 0.1 mg/m3 Dust and fume.SILVER (CAS 7440-22-4) US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents FormType STEL 300 mg/m34-METHYLPENTAN-2-ONE (CAS 108-10-1) 75 ppm FIR No.: 191008 SDS US Issue Date: 05-16-2015 Version: 01 3 / 9 US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents FormType TWA 205 mg/m3 50 ppm TWA 0.01 mg/m3 Dust.SILVER (CAS 7440-22-4) Biological limit values ACGIH Biological Exposure Indices ValueComponents Determinant Specimen Sampling Time 1 mg/l Methyl isobutyl ketone Urine *4-METHYLPENTAN-2-ONE (CAS 108-10-1) * - For sampling details, please see the source document. Appropriate engineering controls Explosion-proof general and local exhaust ventilation. Provide eyewash station. Eye wash fountain and emergency showers are recommended. Use adequate ventilation to control airborne concentrations below the exposure limits/guidelines. If user operations generate a vapor, dust and/or mist, use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below the recommended exposure limits/guidelines. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Suitable chemical protective gloves should be worn when the potential exists for prolonged or repeated skin exposure. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Polyvinyl alcohol (PVA) gloves are recommended. Other Wear suitable protective clothing. Wear appropriate chemical resistant clothing if applicable. Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, an approved respirator must be worn. Respirator selection, use and maintenance should be in accordance with the requirements of OSHA Respiratory Protection Standard 29 CFR 1910.134 and/or Canadian Standard CSA Z94.4. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Liquid. Color Silver. Odor Solvent. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 243.5 ?F (117.5 ?C) Flash point 57.2 ?F (14.0 ?C) CCC Evaporation rate Not available. Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Explosive limit - lower (%) 1.2 % Explosive limit - upper (%) 8 % Vapor pressure Not available. Vapor density Not available. FIR No.: 191008 SDS US Issue Date: 05-16-2015 Version: 01 4 / 9 Relative density 1.63 Relative density temperature 68 ?F (20 ?C) Solubility(ies) Solubility (water) INSOLUBLE Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 860 ?F (460 ?C) Decomposition temperature Not available. Viscosity Not available. Other information VOC (Weight %) 41.7 % 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Ammonia. Chlorine. Hazardous decomposition products Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 11. Toxicological information Information on likely routes of exposure Inhalation Harmful if inhaled. May cause irritation to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Skin contact May be harmful in contact with skin. May be irritating to the skin. May cause an allergic skin reaction. Eye contact Causes serious eye irritation. Ingestion May cause discomfort if swallowed. Symptoms related to the physical, chemical and toxicological characteristics Headache. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Information on toxicological effects Acute toxicity Harmful if inhaled. May cause respiratory irritation. Species Calculated/Test ResultsComponents 4-METHYLPENTAN-2-ONE (CAS 108-10-1) LD50 Rabbit Dermal Acute > 16000 mg/kg LC50 Rat Inhalation 8.2 mg/l, 4 Hours LD50 Rat Oral 2080 mg/kg SILVER (CAS 7440-22-4) LD50 Rat Dermal Acute > 2000 mg/kg LD50 Rat Oral > 5000 mg/kg Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. FIR No.: 191008 SDS US Issue Date: 05-16-2015 Version: 01 5 / 9 Serious eye damage/eye irritation Causes serious eye irritation. Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization May cause an allergic skin reaction. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity Suspected of causing cancer. IARC Monographs. Overall Evaluation of Carcinogenicity 4-METHYLPENTAN-2-ONE (CAS 108-10-1) 2B Possibly carcinogenic to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity Components in this product have been shown to cause birth defects and reproductive disorders in laboratory animals. Specific target organ toxicity - single exposure May cause respiratory irritation. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Chronic effects Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects. 12. Ecological information Ecotoxicity Very toxic to aquatic life with long lasting effects. Ecotoxicity SpeciesComponents Calculated/Test Results 4-METHYLPENTAN-2-ONE (CAS 108-10-1) Aquatic LC50Fish 492 - 593 mg/l, 96 hoursFathead minnow (Pimephales promelas) SILVER (CAS 7440-22-4) Aquatic EC50Crustacea 0.0002 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 0.0023 - 0.0033 mg/l, 96 hoursFathead minnow (Pimephales promelas) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) 4-METHYLPENTAN-2-ONE 1.31 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. FIR No.: 191008 SDS US Issue Date: 05-16-2015 Version: 01 6 / 9 14. Transport information DOT UN1263UN number PAINTUN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIPacking group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IATA UN1263UN number PAINTUN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIPacking group No.Environmental hazards Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Forbidden.Passenger and cargo aircraft Other information Forbidden.Cargo aircraft only IMDG UN1263UN number PAINTUN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIPacking group No.Marine pollutant Environmental hazards Not available.EmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Not established.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code DOT FIR No.: 191008 SDS US Issue Date: 05-16-2015 Version: 01 7 / 9 IATA; IMDG 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) 4-METHYLPENTAN-2-ONE (CAS 108-10-1) Listed. SILVER (CAS 7440-22-4) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Chemical name CAS number % by wt. 4-METHYLPENTAN-2-ONE 108-10-1 40 - < 50 SILVER 7440-22-4 40 - < 50 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List 4-METHYLPENTAN-2-ONE (CAS 108-10-1) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number 4-METHYLPENTAN-2-ONE (CAS 108-10-1) 6715 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) 4-METHYLPENTAN-2-ONE (CAS 108-10-1) 35 %WV DEA Exempt Chemical Mixtures Code Number 4-METHYLPENTAN-2-ONE (CAS 108-10-1) 6715 US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. Massachusetts RTK - Substance List 4-METHYLPENTAN-2-ONE (CAS 108-10-1) SILVER (CAS 7440-22-4) FIR No.: 191008 SDS US Issue Date: 05-16-2015 Version: 01 8 / 9 US. New Jersey Worker and Community Right-to-Know Act 4-METHYLPENTAN-2-ONE (CAS 108-10-1) SILVER (CAS 7440-22-4) US. Pennsylvania Worker and Community Right-to-Know Law 4-METHYLPENTAN-2-ONE (CAS 108-10-1) SILVER (CAS 7440-22-4) US. Rhode Island RTK 4-METHYLPENTAN-2-ONE (CAS 108-10-1) SILVER (CAS 7440-22-4) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. International Inventories All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. 16. Other information, including date of preparation or last revision Issue date 05-16-2015 Version # 01 HMIS? ratings Health: 2 Flammability: 3 Physical hazard: 0 NFPA ratings Health: 2 Flammability: 3 Instability: 0 Preparation Information and Disclaimer This document was prepared by FCSD-Toxicology, Ford Motor Company, Diagnostic Service Center II, 1800 Fairlane Drive, Allen Park, MI 48101, USA, based in part on information provided by the manufacturer. The information on this data sheet represents our current data and is accurate to the best of our knowledge as to the proper handling of this product under normal conditions and in accordance with the application specified on the packaging and/or technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. To the extent that there are any differences between this product?s Safety Data Sheet (SDS) and the consumer packaged product labels, the SDS should be followed. Part number(s) PM-11 FIR No.: 191008 SDS US Issue Date: 05-16-2015 Version: 01 9 / 9