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SAFETY DATA SHEET 1. Identification Product identifier Gasket Maker Other means of identification FIR No. 014716 Recommended use Flexible, anaerobic gasketing material Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Supplier Company Name Ford Motor Company Address Attention: MSDS Information, P.O. Box 1899 Dearborn, Michigan 48121 USA Telephone 1-800-392-3673 MSDS Information 1-800-448-2063 This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone numbers Poison Control Center: USA and Canada: 1-800-959-3673 INFOTRAC (Transportation): USA and Canada 1-800-535-5053 2. Hazard(s) identification Not classified.Physical hazards Category 2Skin corrosion/irritationHealth hazards Category 1Serious eye damage/eye irritation Category 1Sensitization, skin Category 2Specific target organ toxicity, repeated exposure Category 3Hazardous to the aquatic environment, acute hazard Environmental hazards Category 3Hazardous to the aquatic environment, long-term hazard Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. May cause damage to organs through prolonged or repeated exposure. Harmful to aquatic life. Harmful to aquatic life with long lasting effects. Precautionary statement Prevention Do not breathe mist or vapor. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Avoid release to the environment. Wear protective gloves. Wear eye/face protection. Response If on skin: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice/attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Take off contaminated clothing and wash before reuse. Storage Store away from incompatible materials. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. FIR No.: 014716 SDS US Issue Date: 05-16-2015 Version: 01 1 / 8 Hazard(s) not otherwise classified (HNOC) May be harmful if absorbed through skin. May cause irritation of respiratory tract. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 868-77-92-hydroxyethyl methacrylate 3 - < 5 80-15-9.ALPHA.,.ALPHA.-DIMETHYLBENZ YL HYDROPEROXIDE 1 - < 3 79-10-7ACRYLIC ACID < 1 Specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Move to fresh air. Call a physician if symptoms develop or persist. Skin contact Remove contaminated clothing immediately and wash skin with soap and water. In case of eczema or other skin disorders: Seek medical attention and take along these instructions. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. Most important symptoms/effects, acute and delayed Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. Skin irritation. May cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash. Prolonged exposure may cause chronic effects. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. General information If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical During fire, gases hazardous to health may be formed. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire fighting equipment/instructions Move containers from fire area if you can do so without risk. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Avoid contact with eyes, skin, and clothing. Do not breathe mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. FIR No.: 014716 SDS US Issue Date: 05-16-2015 Version: 01 2 / 8 Methods and materials for containment and cleaning up This product is miscible in water. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent product from entering drains. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. 7. Handling and storage Precautions for safe handling Do not breathe mist or vapor. Do not get this material in contact with eyes. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Provide adequate ventilation. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values ValueComponents Type TWA 2 ppmACRYLIC ACID (CAS 79-10-7) US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type TWA 6 mg/m3ACRYLIC ACID (CAS 79-10-7) 2 ppm US. Workplace Environmental Exposure Level (WEEL) Guides ValueComponents Type TWA 6 mg/m3.ALPHA.,.ALPHA.-DIMETH YLBENZYL HYDROPEROXIDE (CAS 80-15-9) 1 ppm Biological limit values No biological exposure limits noted for the ingredient(s). Exposure guidelines US - California OELs: Skin designation ACRYLIC ACID (CAS 79-10-7) Can be absorbed through the skin. US - Tennessee OELs: Skin designation ACRYLIC ACID (CAS 79-10-7) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation ACRYLIC ACID (CAS 79-10-7) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation ACRYLIC ACID (CAS 79-10-7) Can be absorbed through the skin. US WEEL Guides: Skin designation .ALPHA.,.ALPHA.-DIMETHYLBENZYL HYDROPEROXIDE (CAS 80-15-9) Can be absorbed through the skin. Appropriate engineering controls Use adequate ventilation to control airborne concentrations below the exposure limits/guidelines. If user operations generate a vapor, dust and/or mist, use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below the recommended exposure limits/guidelines. FIR No.: 014716 SDS US Issue Date: 05-16-2015 Version: 01 3 / 8 Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles) and a face shield. Wear safety glasses with side shields (or goggles). Skin protection Hand protection Suitable chemical protective gloves should be worn when the potential exists for prolonged or repeated skin exposure. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Neoprene gloves are recommended. Nitrile gloves are recommended. Other Wear appropriate chemical resistant clothing. Wear appropriate chemical resistant clothing if applicable. Respiratory protection If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, an approved respirator must be worn. Respirator selection, use and maintenance should be in accordance with the requirements of OSHA Respiratory Protection Standard 29 CFR 1910.134 and/or Canadian Standard CSA Z94.4. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace. 9. Physical and chemical properties Appearance Physical state Liquid. Form Liquid. Color Red. Odor Mild. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range > 302 ?F (> 150 ?C) Flash point > 203.0 ?F (> 95.0 ?C) ASTM D93 Evaporation rate Not available. Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower (%) Not available. Flammability limit - upper (%) Not available. Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure < 5 mm Hg Vapor pressure temp. 69.8 ?F (21 ?C) Vapor density > 1 (AIR=1) Relative density 1.08 - 1.18 Relative density temperature 39.2 ?F (4 ?C) Solubility(ies) Solubility (water) SLIGHT Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. FIR No.: 014716 SDS US Issue Date: 05-16-2015 Version: 01 4 / 8 Other information VOC (Weight %) 1.5 % CAM310 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Amines. Hazardous decomposition products Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 11. Toxicological information Information on likely routes of exposure Inhalation May cause damage to organs through prolonged or repeated exposure by inhalation. Prolonged inhalation may be harmful. May cause irritation to the respiratory system. Skin contact Causes skin irritation. May cause an allergic skin reaction. Eye contact Causes serious eye damage. Ingestion May be harmful if swallowed. Symptoms related to the physical, chemical and toxicological characteristics Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. Skin irritation. May cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash. Information on toxicological effects Acute toxicity May cause an allergic skin reaction. Species Calculated/Test ResultsComponents .ALPHA.,.ALPHA.-DIMETHYLBENZYL HYDROPEROXIDE (CAS 80-15-9) LD50 Rat Dermal Acute 0.5 ml/kg LC50 Mouse Inhalation 200 mg/l, 4 Hours 2-hydroxyethyl methacrylate (CAS 868-77-9) LD50 Mouse Oral Acute 3275 mg/kg 5.1 ml/kg Rat 5050 mg/kg ACRYLIC ACID (CAS 79-10-7) LC50 Rat Inhalation Acute 1200 mg/l, 4 Hours LD50 Mouse Oral 2400 mg/kg Rat 33.5 mg/kg Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye irritation Causes serious eye damage. Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization May cause an allergic skin reaction. FIR No.: 014716 SDS US Issue Date: 05-16-2015 Version: 01 5 / 8 Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity ACRYLIC ACID (CAS 79-10-7) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure May cause damage to organs through prolonged or repeated exposure. Eyes. Skin. Respiratory tract. Aspiration hazard Not an aspiration hazard. Chronic effects May cause damage to organs through prolonged or repeated exposure. Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity Harmful to aquatic life with long lasting effects. Ecotoxicity SpeciesComponents Calculated/Test Results 2-hydroxyethyl methacrylate (CAS 868-77-9) Aquatic LC50Fish 213 - 242 mg/l, 96 hoursFathead minnow (Pimephales promelas) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) 2-hydroxyethyl methacrylate 0.47 ACRYLIC ACID 0.35 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. FIR No.: 014716 SDS US Issue Date: 05-16-2015 Version: 01 6 / 8 IMDG Not regulated as dangerous goods. Not established.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) .ALPHA.,.ALPHA.-DIMETHYLBENZYL HYDROPEROXIDE (CAS 80-15-9) Listed. ACRYLIC ACID (CAS 79-10-7) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Chemical name CAS number % by wt. .ALPHA.,.ALPHA.-DIMETHYLBENZYL HYDROPEROXIDE 80-15-9 1 - < 3 ACRYLIC ACID 79-10-7 < 1 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List ACRYLIC ACID (CAS 79-10-7) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. Massachusetts RTK - Substance List .ALPHA.,.ALPHA.-DIMETHYLBENZYL HYDROPEROXIDE (CAS 80-15-9) ACRYLIC ACID (CAS 79-10-7) US. New Jersey Worker and Community Right-to-Know Act .ALPHA.,.ALPHA.-DIMETHYLBENZYL HYDROPEROXIDE (CAS 80-15-9) ACRYLIC ACID (CAS 79-10-7) US. Pennsylvania Worker and Community Right-to-Know Law .ALPHA.,.ALPHA.-DIMETHYLBENZYL HYDROPEROXIDE (CAS 80-15-9) ACRYLIC ACID (CAS 79-10-7) US. Rhode Island RTK .ALPHA.,.ALPHA.-DIMETHYLBENZYL HYDROPEROXIDE (CAS 80-15-9) FIR No.: 014716 SDS US Issue Date: 05-16-2015 Version: 01 7 / 8 ACRYLIC ACID (CAS 79-10-7) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. 16. Other information, including date of preparation or last revision Issue date 05-16-2015 Version # 01 HMIS? ratings Health: 2 Flammability: 1 Physical hazard: 0 NFPA ratings Health: 2 Flammability: 1 Instability: 0 Preparation Information and Disclaimer This document was prepared by FCSD-Toxicology, Ford Motor Company, Diagnostic Service Center II, 1800 Fairlane Drive, Allen Park, MI 48101, USA, based in part on information provided by the manufacturer. The information on this data sheet represents our current data and is accurate to the best of our knowledge as to the proper handling of this product under normal conditions and in accordance with the application specified on the packaging and/or technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. To the extent that there are any differences between this product?s Safety Data Sheet (SDS) and the consumer packaged product labels, the SDS should be followed. Part number(s) TA-16 FIR No.: 014716 SDS US Issue Date: 05-16-2015 Version: 01 8 / 8