SAFETY DATA SHEET 1. Identification Product identifier Metal Bonding Adhesive Other means of identification FIR No. 156626 Recommended use Metal bonding adhesive Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Supplier Company Name Ford Motor Company Address Attention: MSDS Information, P.O. Box 1899 Dearborn, Michigan 48121 USA Telephone 1-800-392-3673 MSDS Information 1-800-448-2063 This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone numbers Poison Control Center: USA and Canada: 1-800-959-3673 INFOTRAC (Transportation): USA and Canada 1-800-535-5053 2. Hazard(s) identification Category 2Flammable liquidsPhysical hazards Category 3Acute toxicity, dermalHealth hazards Category 4Acute toxicity, inhalation Category 2Skin corrosion/irritation Category 1Serious eye damage/eye irritation Category 1Sensitization, skin Category 2Carcinogenicity Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure Not classified.Environmental hazards Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Highly flammable liquid and vapor. Toxic in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. Harmful if inhaled. May cause respiratory irritation. Suspected of causing cancer. Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. FIR No.: 156626 SDS US Issue Date: 05-20-2015 Version: 01 1 / 10 Response If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation or rash occurs: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Take off immediately all contaminated clothing and wash it before reuse. In case of fire: Use appropriate media to extinguish. Storage Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) May be harmful if swallowed. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 80-62-6METHYL METHACRYLATE 30 - < 40 101-43-9CYCLOHEXYL METHACRYLATE 3 - < 5 79-41-4METHACRYLIC ACID 3 - < 5 121-69-7N,N-DIMETHYLANILINE < 1 Specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or artificial respiration if needed. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Get medical advice/attention if you feel unwell. In case of eczema or other skin disorders: Seek medical attention and take along these instructions. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. Ingestion Rinse mouth. Call a physician or poison control center immediately. Do not induce vomiting. Most important symptoms/effects, acute and delayed Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. May cause respiratory irritation. Skin irritation. May cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim warm. Keep victim under observation. Symptoms may be delayed. General information Take off immediately all contaminated clothing. IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Water. Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed. Container may explode in heat of fire. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire fighting equipment/instructions In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards Highly flammable liquid and vapor. FIR No.: 156626 SDS US Issue Date: 05-20-2015 Version: 01 2 / 10 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid contact with eyes, skin, and clothing. Avoid inhalation of vapors and spray mists. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. The product is immiscible with water and will sediment in water systems. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Following product recovery, flush area with water. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Cleansurface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Take precautionary measures against static discharges. Do not get this material in contact with eyes. Avoid inhalation of vapors and spray mists. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. When using, do not eat, drink or smoke. Use only outdoors or in a well-ventilated area. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Wash contaminated clothing before reuse. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in a cool, dry place out of direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Keep in an area equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 410 mg/m3METHYL METHACRYLATE (CAS 80-62-6) 100 ppm PEL 25 mg/m3N,N-DIMETHYLANILINE (CAS 121-69-7) 5 ppm US. ACGIH Threshold Limit Values ValueComponents Type TWA 20 ppmMETHACRYLIC ACID (CAS 79-41-4) STEL 100 ppmMETHYL METHACRYLATE (CAS 80-62-6) TWA 50 ppm STEL 10 ppmN,N-DIMETHYLANILINE (CAS 121-69-7) TWA 5 ppm FIR No.: 156626 SDS US Issue Date: 05-20-2015 Version: 01 3 / 10 US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type TWA 70 mg/m3METHACRYLIC ACID (CAS 79-41-4) 20 ppm TWA 410 mg/m3METHYL METHACRYLATE (CAS 80-62-6) 100 ppm STEL 50 mg/m3N,N-DIMETHYLANILINE (CAS 121-69-7) 10 ppm TWA 25 mg/m3 5 ppm Biological limit values No biological exposure limits noted for the ingredient(s). Exposure guidelines US - California OELs: Skin designation METHACRYLIC ACID (CAS 79-41-4) Can be absorbed through the skin. N,N-DIMETHYLANILINE (CAS 121-69-7) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies N,N-DIMETHYLANILINE (CAS 121-69-7) Skin designation applies. US - Tennessee OELs: Skin designation METHACRYLIC ACID (CAS 79-41-4) Can be absorbed through the skin. N,N-DIMETHYLANILINE (CAS 121-69-7) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation N,N-DIMETHYLANILINE (CAS 121-69-7) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation METHACRYLIC ACID (CAS 79-41-4) Can be absorbed through the skin. N,N-DIMETHYLANILINE (CAS 121-69-7) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) N,N-DIMETHYLANILINE (CAS 121-69-7) Can be absorbed through the skin. Appropriate engineering controls Explosion-proof general and local exhaust ventilation. Use adequate ventilation to control airborne concentrations below the exposure limits/guidelines. If user operations generate a vapor, dust and/or mist, use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below the recommended exposure limits/guidelines. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles) and a face shield. Wear safety glasses with side shields (or goggles). Skin protection Hand protection Suitable chemical protective gloves should be worn when the potential exists for prolonged or repeated skin exposure. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Use protective gloves made of: Nitrile. Neoprene. Rubber gloves. Other Wear appropriate chemical resistant clothing. Wear appropriate chemical resistant clothing if applicable. Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, an approved respirator must be worn. Respirator selection, use and maintenance should be in accordance with the requirements of OSHA Respiratory Protection Standard 29 CFR 1910.134 and/or Canadian Standard CSA Z94.4. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace. 9. Physical and chemical properties Appearance Physical state Liquid. FIR No.: 156626 SDS US Issue Date: 05-20-2015 Version: 01 4 / 10 Form Paste. Color Off-white. Odor Sweet. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 140 - 321.98 ?F (60 - 161.1 ?C) (140-322F) Flash point 59.0 ?F (15.0 ?C) SETAFLASH Evaporation rate < 1 (BuAc=1) Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Explosive limit - lower (%) 1.6 % Explosive limit - upper (%) 8.8 % Vapor pressure Not available. Vapor density > 1 (AIR=1) Relative density 1.13 Relative density temperature 39.2 ?F (4 ?C) Solubility(ies) Solubility (water) INSOLUBLE IN WATER Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Incompatible materials Acids. Strong oxidizing agents. Nitrates. Amines. Peroxides. Fluorine. Chlorine. Hazardous decomposition products Irritating and/or toxic fumes and gases may be emitted upon the products decomposition. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 11. Toxicological information Information on likely routes of exposure Inhalation Harmful if inhaled. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Skin contact Toxic in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Eye contact Causes serious eye damage. Ingestion However, ingestion is not likely to be a primary route of occupational exposure. Symptoms related to the physical, chemical and toxicological characteristics Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. May cause respiratory irritation. Skin irritation. May cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash. Information on toxicological effects Acute toxicity Toxic in contact with skin. Harmful if inhaled. May cause an allergic skin reaction. May cause respiratory irritation. FIR No.: 156626 SDS US Issue Date: 05-20-2015 Version: 01 5 / 10 Species Calculated/Test ResultsComponents METHACRYLIC ACID (CAS 79-41-4) LD50 Guinea pig Dermal Acute 1 g/kg Rabbit 500 mg/kg LC50 Rat Inhalation 7.1 mg/l, 4 Hours LD50 Mouse Oral 1250 mg/kg Rabbit 1200 mg/kg Rat 1060 mg/kg METHYL METHACRYLATE (CAS 80-62-6) LC50 Mouse Inhalation Acute 18.5 mg/l, 2 Hours Rat 3750 ppm, 8 Hours LD50 Mouse Oral 5.5 ml/kg Rabbit 6000 mg/kg Rat 7800 mg/kg N,N-DIMETHYLANILINE (CAS 121-69-7) LD50 Rabbit Dermal Acute 1770 mg/kg LD50 Rat Oral 1.41 ml/kg Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye irritation Causes serious eye damage. Respiratory or skin sensitization ACGIH sensitization METHYL METHACRYLATE (CAS 80-62-6) Sensitizer. Respiratory sensitization Not a respiratory sensitizer. Skin sensitization May cause an allergic skin reaction. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity Suspected of causing cancer. IARC Monographs. Overall Evaluation of Carcinogenicity METHYL METHACRYLATE (CAS 80-62-6) 3 Not classifiable as to carcinogenicity to humans. N,N-DIMETHYLANILINE (CAS 121-69-7) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure May cause respiratory irritation. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Chronic effects Prolonged inhalation may be harmful. FIR No.: 156626 SDS US Issue Date: 05-20-2015 Version: 01 6 / 10 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Ecotoxicity SpeciesComponents Calculated/Test Results METHYL METHACRYLATE (CAS 80-62-6) Aquatic LC50Fish 136.3 - 183.4 mg/l, 96 hoursFathead minnow (Pimephales promelas) N,N-DIMETHYLANILINE (CAS 121-69-7) Aquatic EC50Crustacea 1.7 - 3.1 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 52.6 mg/l, 96 hoursFathead minnow (Pimephales promelas) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) METHACRYLIC ACID 0.93 METHYL METHACRYLATE 1.38 N,N-DIMETHYLANILINE 2.31 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN1133UN number ADHESIVESUN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIPacking group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IATA UN1133UN number ADHESIVESUN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIPacking group No.Environmental hazards FIR No.: 156626 SDS US Issue Date: 05-20-2015 Version: 01 7 / 10 Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Forbidden.Passenger and cargo aircraft Other information Forbidden.Cargo aircraft only IMDG UN1133UN number ADHESIVESUN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIPacking group No.Marine pollutant Environmental hazards Not available.EmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Not established.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code DOT IATA; IMDG 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) METHYL METHACRYLATE (CAS 80-62-6) Listed. N,N-DIMETHYLANILINE (CAS 121-69-7) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. FIR No.: 156626 SDS US Issue Date: 05-20-2015 Version: 01 8 / 10 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Chemical name CAS number % by wt. METHYL METHACRYLATE 80-62-6 30 - < 40 N,N-DIMETHYLANILINE 121-69-7 < 1 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List METHYL METHACRYLATE (CAS 80-62-6) N,N-DIMETHYLANILINE (CAS 121-69-7) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. Massachusetts RTK - Substance List METHACRYLIC ACID (CAS 79-41-4) METHYL METHACRYLATE (CAS 80-62-6) N,N-DIMETHYLANILINE (CAS 121-69-7) US. New Jersey Worker and Community Right-to-Know Act METHACRYLIC ACID (CAS 79-41-4) METHYL METHACRYLATE (CAS 80-62-6) N,N-DIMETHYLANILINE (CAS 121-69-7) US. Pennsylvania Worker and Community Right-to-Know Law METHACRYLIC ACID (CAS 79-41-4) METHYL METHACRYLATE (CAS 80-62-6) N,N-DIMETHYLANILINE (CAS 121-69-7) US. Rhode Island RTK METHYL METHACRYLATE (CAS 80-62-6) N,N-DIMETHYLANILINE (CAS 121-69-7) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer. International Inventories All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. 16. Other information, including date of preparation or last revision Issue date 05-20-2015 Version # 01 HMIS? ratings Health: 2 Flammability: 3 Physical hazard: 1 NFPA ratings Health: 1 Flammability: 3 Instability: 0 FIR No.: 156626 SDS US Issue Date: 05-20-2015 Version: 01 9 / 10 Preparation Information and Disclaimer This document was prepared by FCSD-Toxicology, Ford Motor Company, Diagnostic Service Center II, 1800 Fairlane Drive, Allen Park, MI 48101, USA, based in part on information provided by the manufacturer. The information on this data sheet represents our current data and is accurate to the best of our knowledge as to the proper handling of this product under normal conditions and in accordance with the application specified on the packaging and/or technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. To the extent that there are any differences between this product?s Safety Data Sheet (SDS) and the consumer packaged product labels, the SDS should be followed. Part number(s) TA-1, TA-1-B FIR No.: 156626 SDS US Issue Date: 05-20-2015 Version: 01 10 / 10