SAFETY DATA SHEET 1. Identification Product identifier Specialty Green Engine Coolant with Bittering Agent Other means of identification FIR No. 184300 Recommended use Engine antifreeze/coolant Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Supplier Company Name Ford Motor Company Address Attention: MSDS Information, P.O. Box 1899 Dearborn, Michigan 48121 USA Telephone 1-800-392-3673 MSDS Information 1-800-448-2063 This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone numbers Poison Control Center: USA and Canada: 1-800-959-3673 INFOTRAC (Transportation): USA and Canada 1-800-535-5053 2. Hazard(s) identification Not classified.Physical hazards Category 4Acute toxicity, oralHealth hazards Category 1BReproductive toxicity (fertility) Category 1Specific target organ toxicity, single exposure Category 1Specific target organ toxicity, repeated exposure Category 3Hazardous to the aquatic environment, acute hazard Environmental hazards Category 3Hazardous to the aquatic environment, long-term hazard Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Harmful if swallowed. May damage fertility. Causes damage to organs. Causes damage to organs through prolonged or repeated exposure. Harmful to aquatic life. Harmful to aquatic life with long lasting effects. Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Response If swallowed: Call a poison center/doctor if you feel unwell. Rinse mouth. If exposed: Call a poison center/doctor. Storage Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. FIR No.: 184300 SDS US Issue Date: 11-20-2015 Version: 02 1 / 8 Hazard(s) not otherwise classified (HNOC) Aspiration may cause pulmonary edema and pneumonitis. HARMFUL OR FATAL IF SWALLOWED. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Inhalation of vapors/fumes generated by heating this product may cause respiratory irritation with throat discomfort, coughing or difficulty breathing. Causes skin and eye irritation. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 107-21-1Ethane-1,2-diol 80 - < 90 Trade SecretOrganic acid potassium salt 1 - 8 111-46-62,2'-Oxydiethanol <= 1 Specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Move to fresh air. Call a physician if symptoms develop or persist. Skin contact Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Eye contact Rinse with water. Get medical attention if irritation develops and persists. Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Most important symptoms/effects, acute and delayed Abdominal pain. Convulsions. Dizziness. Nausea, vomiting. Prolonged exposure may cause chronic effects. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim under observation. Symptoms may be delayed. General information IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. 5. Fire-fighting measures Suitable extinguishing media Powder. Alcohol resistant foam. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire fighting equipment/instructions Move containers from fire area if you can do so without risk. Move containers from fire area if you can do so without risk. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Avoid contact with eyes, skin, and clothing. Do not breathe mist or vapor. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. FIR No.: 184300 SDS US Issue Date: 11-20-2015 Version: 02 2 / 8 Methods and materials for containment and cleaning up This product is miscible in water. Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent product from entering drains. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. 7. Handling and storage Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid contact with eyes, skin, and clothing. Do not breathe mist or vapor. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke. Pregnant or breastfeeding women must not handle this product. Should be handled in closed systems, if possible. Provide adequate ventilation. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. See Section 8 of the SDS for Personal Protective Equipment. Conditions for safe storage, including any incompatibilities Store locked up. Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values ValueComponents FormType Ceiling 100 mg/m3 Aerosol.Ethane-1,2-diol (CAS 107-21-1) US. Workplace Environmental Exposure Level (WEEL) Guides ValueComponents Type TWA 10 mg/m32,2'-Oxydiethanol (CAS 111-46-6) Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering controls Use adequate ventilation to control airborne concentrations below the exposure limits/guidelines. If user operations generate a vapor, dust and/or mist, use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below the recommended exposure limits/guidelines. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Suitable chemical protective gloves should be worn when the potential exists for prolonged or repeated skin exposure. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Neoprene gloves are recommended. Nitrile gloves are recommended. Other Wear appropriate chemical resistant clothing if applicable. Respiratory protection If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, an approved respirator must be worn. Respirator selection, use and maintenance should be in accordance with the requirements of OSHA Respiratory Protection Standard 29 CFR 1910.134 and/or Canadian Standard CSA Z94.4. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. FIR No.: 184300 SDS US Issue Date: 11-20-2015 Version: 02 3 / 8 Form Liquid. Color Dark green. Odor Characteristic. Odor threshold Not available. pH 7.7 pH concentration 50 % v/v Melting point/freezing point < 5 ?F (< -15 ?C) (<5F) Initial boiling point and boiling range > 299.84 ?F (> 148.8 ?C) (>300F) Flash point 257.9 ?F (125.5 ?C) CALCULATED Evaporation rate Not available. Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower (%) Not available. Flammability limit - upper (%) Not available. Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure Not available. Vapor density Not available. Relative density 1.13 Relative density temperature 68 ?F (20 ?C) Solubility(ies) Solubility (water) COMPLETE Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Conditions to avoid Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Hazardous decomposition products Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 11. Toxicological information Information on likely routes of exposure Inhalation May cause damage to organs by inhalation. May cause damage to organs through prolonged or repeated exposure by inhalation. May cause irritation to the respiratory system. Prolonged inhalation may be harmful. Skin contact May be irritating to the skin. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion HARMFUL OR FATAL IF SWALLOWED. Symptoms related to the physical, chemical and toxicological characteristics Abdominal pain. Convulsions. Dizziness. Nausea, vomiting. Information on toxicological effects FIR No.: 184300 SDS US Issue Date: 11-20-2015 Version: 02 4 / 8 Acute toxicity HARMFUL OR FATAL IF SWALLOWED. May be fatal if swallowed and enters airways. May cause respiratory irritation. In high concentrations, vapors are anesthetic and may cause headache, fatigue, dizziness and central nervous system effects. Species Calculated/Test ResultsComponents 2,2'-Oxydiethanol (CAS 111-46-6) LD50 Rabbit Dermal Acute 11890 mg/kg LD50 Cat Oral 3300 mg/kg Dog 9000 mg/kg Guinea pig 8700 mg/kg Mouse 13.3 g/kg Rabbit 26.9 g/kg Rat 12565 mg/kg Ethane-1,2-diol (CAS 107-21-1) LD50 Rabbit Dermal Acute 9530 mg/kg LD50 Cat Oral 1650 mg/kg Dog 5500 mg/kg Guinea pig 8.2 g/kg Mouse 14.6 g/kg Rat 5.89 g/kg Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity Components in this product have been shown to cause birth defects and reproductive disorders in laboratory animals. May damage fertility. Specific target organ toxicity - single exposure Causes damage to organs. Lungs. Central nervous system. Heart. Blood. Kidneys. Specific target organ toxicity - repeated exposure Heart. Kidneys. Blood. Central nervous system. Lungs. Causes damage to organs through prolonged or repeated exposure. Aspiration hazard If aspirated into lungs during swallowing or vomiting, may cause chemical pneumonia, pulmonary injury or death. Chronic effects Causes damage to organs through prolonged or repeated exposure. Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity Harmful to aquatic life with long lasting effects. FIR No.: 184300 SDS US Issue Date: 11-20-2015 Version: 02 5 / 8 Ecotoxicity SpeciesComponents Calculated/Test Results 2,2'-Oxydiethanol (CAS 111-46-6) Aquatic LC50Fish > 32000 mg/l, 96 hoursWestern mosquitofish (Gambusia affinis) Ethane-1,2-diol (CAS 107-21-1) Aquatic LC50Fish 8050 mg/l, 96 hoursFathead minnow (Pimephales promelas) Organic acid potassium salt (CAS Trade Secret) Aquatic LC50Fish 4 mg/l, 96 hoursGoldfish (Carassius auratus) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Ethane-1,2-diol -1.36 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Not established.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Ethane-1,2-diol (CAS 107-21-1) Listed. SARA 304 Emergency release notification Not regulated. FIR No.: 184300 SDS US Issue Date: 11-20-2015 Version: 02 6 / 8 OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Chemical name CAS number % by wt. Ethane-1,2-diol 107-21-1 80 - < 90 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Ethane-1,2-diol (CAS 107-21-1) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. Massachusetts RTK - Substance List Ethane-1,2-diol (CAS 107-21-1) US. New Jersey Worker and Community Right-to-Know Act Ethane-1,2-diol (CAS 107-21-1) US. Pennsylvania Worker and Community Right-to-Know Law 2,2'-Oxydiethanol (CAS 111-46-6) Ethane-1,2-diol (CAS 107-21-1) US. Rhode Island RTK Ethane-1,2-diol (CAS 107-21-1) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. International Inventories All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. 16. Other information, including date of preparation or last revision Issue date 11-20-2015 Revision date 11-20-2015 Version # 02 HMIS? ratings Health: 1 Flammability: 1 Physical hazard: 0 NFPA ratings Health: 1 Flammability: 1 Instability: 0 FIR No.: 184300 SDS US Issue Date: 11-20-2015 Version: 02 7 / 8 Preparation Information and Disclaimer This document was prepared by FCSD-Toxicology, Ford Motor Company, Diagnostic Service Center II, 1800 Fairlane Drive, Allen Park, MI 48101, USA, based in part on information provided by the manufacturer. The information on this data sheet represents our current data and is accurate to the best of our knowledge as to the proper handling of this product under normal conditions and in accordance with the application specified on the packaging and/or technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. To the extent that there are any differences between this product?s Safety Data Sheet (SDS) and the consumer packaged product labels, the SDS should be followed. Revision Information Exposure controls/personal protection: Appropriate engineering controls Toxicological Information: Toxicological Data Regulatory information: California Prop 65 Part number(s) VC-10-A1, VC-10-A2 FIR No.: 184300 SDS US Issue Date: 11-20-2015 Version: 02 8 / 8