SAFETY DATA SHEET 1. Identification Product identifier Gold Concentrated Antifreeze/Coolant Other means of identification FIR No. 189062 Recommended use Engine antifreeze/coolant Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Supplier Company Name Ford Motor Company Address Attention: MSDS Information, P.O. Box 1899 Dearborn, Michigan 48121 USA Telephone 1-800-392-3673 MSDS Information 1-800-448-2063 This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone numbers Poison Control Center: USA and Canada: 1-800-959-3673 INFOTRAC (Transportation): USA and Canada 1-800-535-5053 2. Hazard(s) identification Not classified.Physical hazards Category 4Acute toxicity, oralHealth hazards Category 1Specific target organ toxicity, single exposure Category 1Specific target organ toxicity, repeated exposure Category 3Hazardous to the aquatic environment, acute hazard Environmental hazards Category 3Hazardous to the aquatic environment, long-term hazard Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Harmful if swallowed. Causes damage to organs. Causes damage to organs through prolonged or repeated exposure. Harmful to aquatic life. Harmful to aquatic life with long lasting effects. Precautionary statement Prevention Do not breathe mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Avoid release to the environment. Response If swallowed: Call a poison center/doctor if you feel unwell. If exposed: Call a poison center/doctor. Rinse mouth. Storage Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) Irritating to eyes, respiratory system and skin. Aspiration may cause pulmonary edema and pneumonitis. Components in this product have been shown to cause birth defects and reproductive disorders in laboratory animals. Supplemental information None. FIR No.: 189062 SDS US Issue Date: 11-02-2015 Version: 02 1 / 8 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 107-21-1Ethane-1,2-diol 80 - < 90 111-46-62,2'-Oxydiethanol 5 - < 10 12179-04-3BORON SODIUM OXIDE (B4NA2O7), PENTAHYDRATE 1 - < 3 7632-00-0sodium nitrite < 1 Specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Move to fresh air. Call a physician if symptoms develop or persist. Skin contact Take off immediately all contaminated clothing. Wash with plenty of soap and water. If irritation persists get medical attention. Eye contact Rinse immediately with plenty of water for at least 15 minutes. If irritation persists get medical attention. Ingestion Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Most important symptoms/effects, acute and delayed Abdominal pain. Convulsions. Decrease in motor functions. Edema. Behavioral changes. Narcosis. Dizziness. Nausea, vomiting. Coughing. Discomfort in the chest. Shortness of breath. Prolonged exposure may cause chronic effects. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim under observation. Symptoms may be delayed. General information If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. 5. Fire-fighting measures Suitable extinguishing media Powder. Alcohol resistant foam. Carbon dioxide (CO2). Water fog. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire fighting equipment/instructions Move containers from fire area if you can do so without risk. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Avoid contact with eyes. Do not breathe mist or vapor. Avoid skin contact and inhalation of vapors during disposal of spills. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up This product is miscible in water. Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent product from entering drains. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. FIR No.: 189062 SDS US Issue Date: 11-02-2015 Version: 02 2 / 8 Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. 7. Handling and storage Precautions for safe handling Avoid contact with eyes, skin, and clothing. Do not breathe mist or vapor. Do not taste or swallow. Avoid prolonged exposure. When using, do not eat, drink or smoke. Provide adequate ventilation. Keep away from heat, sparks and open flame. Avoid release to the environment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Wear appropriate personal protective equipment. See Section 8 of the SDS for Personal Protective Equipment. Conditions for safe storage, including any incompatibilities Store locked up. Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS). This product may react with strong oxidizing agents. 8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values ValueComponents FormType STEL 6 mg/m3 Inhalable fraction.BORON SODIUM OXIDE (B4NA2O7), PENTAHYDRATE (CAS 12179-04-3) TWA 2 mg/m3 Inhalable fraction. Ceiling 100 mg/m3 Aerosol.Ethane-1,2-diol (CAS 107-21-1) US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type TWA 1 mg/m3BORON SODIUM OXIDE (B4NA2O7), PENTAHYDRATE (CAS 12179-04-3) US. Workplace Environmental Exposure Level (WEEL) Guides ValueComponents Type TWA 10 mg/m32,2'-Oxydiethanol (CAS 111-46-6) Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering controls Use adequate ventilation to control airborne concentrations below the exposure limits/guidelines. If user operations generate a vapor, dust and/or mist, use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below the recommended exposure limits/guidelines. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Suitable chemical protective gloves should be worn when the potential exists for prolonged or repeated skin exposure. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Use protective gloves made of: Neoprene. Nitrile. Polyvinyl chloride (PVC). Other Wear suitable protective clothing. Wear appropriate chemical resistant clothing if applicable. Respiratory protection If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, an approved respirator must be worn. Respirator selection, use and maintenance should be in accordance with the requirements of OSHA Respiratory Protection Standard 29 CFR 1910.134 and/or Canadian Standard CSA Z94.4. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. FIR No.: 189062 SDS US Issue Date: 11-02-2015 Version: 02 3 / 8 Form Liquid. Color Yellow. Odor Characteristic. Odor threshold Not available. pH 8 ASTM D1293 pH concentration 33.3 % v/v Melting point/freezing point Not available. Initial boiling point and boiling range > 299.84 ?F (> 148.8 ?C) Flash point 249.8 ?F (121.0 ?C) COC Evaporation rate Not available. Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower (%) Not available. Flammability limit - upper (%) Not available. Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure Not available. Vapor density Not available. Relative density 1.14 Relative density temperature 60 ?F (15.56 ?C) Solubility(ies) Solubility (water) COMPLETE IN WATER Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Conditions to avoid Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Hazardous decomposition products Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 11. Toxicological information Information on likely routes of exposure Inhalation May cause damage to organs by inhalation. May cause damage to organs through prolonged or repeated exposure by inhalation. Prolonged inhalation may be harmful. May cause irritation to the respiratory system. Skin contact May be irritating to the skin. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion HARMFUL OR FATAL IF SWALLOWED. Symptoms related to the physical, chemical and toxicological characteristics Abdominal pain. Convulsions. Dizziness. Nausea, vomiting. Information on toxicological effects FIR No.: 189062 SDS US Issue Date: 11-02-2015 Version: 02 4 / 8 Acute toxicity HARMFUL OR FATAL IF SWALLOWED. Species Calculated/Test ResultsComponents 2,2'-Oxydiethanol (CAS 111-46-6) LD50 Rabbit Dermal Acute 11890 mg/kg LD50 Cat Oral 3300 mg/kg Dog 9000 mg/kg Guinea pig 8700 mg/kg Mouse 13.3 g/kg Rabbit 26.9 g/kg Rat 12565 mg/kg BORON SODIUM OXIDE (B4NA2O7), PENTAHYDRATE (CAS 12179-04-3) LD50 Rabbit Dermal Acute > 1055 mg/kg LC50 Rat Inhalation > 0.002 mg/l, 4 Hours LD50 Rat Oral 2660 mg/kg Ethane-1,2-diol (CAS 107-21-1) LD50 Rabbit Dermal Acute 9530 mg/kg LD50 Cat Oral 1650 mg/kg Dog 5500 mg/kg Guinea pig 8.2 g/kg Mouse 14.6 g/kg Rat 5.89 g/kg sodium nitrite (CAS 7632-00-0) LC50 Rat Inhalation Acute 5.5 mg/l, 4 Hours LD50 Mouse Oral 175 mg/kg Rabbit 186 mg/kg Rat 85 mg/kg Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. FIR No.: 189062 SDS US Issue Date: 11-02-2015 Version: 02 5 / 8 Reproductive toxicity Components in this product have been shown to cause birth defects and reproductive disorders in laboratory animals. Specific target organ toxicity - single exposure Causes damage to organs. Lungs. Central nervous system. Heart. Blood. Kidneys. Specific target organ toxicity - repeated exposure Causes damage to organs through prolonged or repeated exposure. Lungs. Central nervous system. Heart. Blood. Kidneys. Aspiration hazard If aspirated into lungs during swallowing or vomiting, may cause chemical pneumonia, pulmonary injury or death. Chronic effects Causes damage to organs through prolonged or repeated exposure. Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity Harmful to aquatic life with long lasting effects. Ecotoxicity SpeciesComponents Calculated/Test Results 2,2'-Oxydiethanol (CAS 111-46-6) Aquatic LC50Fish > 32000 mg/l, 96 hoursWestern mosquitofish (Gambusia affinis) BORON SODIUM OXIDE (B4NA2O7), PENTAHYDRATE (CAS 12179-04-3) Aquatic LC50Fish 104 mg/l, 96 hoursWestern mosquitofish (Gambusia affinis) Ethane-1,2-diol (CAS 107-21-1) Aquatic LC50Fish 8050 mg/l, 96 hoursFathead minnow (Pimephales promelas) sodium nitrite (CAS 7632-00-0) Aquatic EC50Crustacea 16.14 - 26.61 mg/l, 48 hoursGreasyback shrimp (Metapenaeus ensis) LC50Fish 0.15 - 0.25 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Ethane-1,2-diol -1.36 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. FIR No.: 189062 SDS US Issue Date: 11-02-2015 Version: 02 6 / 8 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Not established.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) sodium nitrite (CAS 7632-00-0) 1.0 % One-Time Export Notification only. CERCLA Hazardous Substance List (40 CFR 302.4) Ethane-1,2-diol (CAS 107-21-1) Listed. sodium nitrite (CAS 7632-00-0) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Chemical name CAS number % by wt. Ethane-1,2-diol 107-21-1 80 - < 90 sodium nitrite 7632-00-0 < 1 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Ethane-1,2-diol (CAS 107-21-1) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. Massachusetts RTK - Substance List BORON SODIUM OXIDE (B4NA2O7), PENTAHYDRATE (CAS 12179-04-3) Ethane-1,2-diol (CAS 107-21-1) sodium nitrite (CAS 7632-00-0) US. New Jersey Worker and Community Right-to-Know Act BORON SODIUM OXIDE (B4NA2O7), PENTAHYDRATE (CAS 12179-04-3) FIR No.: 189062 SDS US Issue Date: 11-02-2015 Version: 02 7 / 8 Ethane-1,2-diol (CAS 107-21-1) sodium nitrite (CAS 7632-00-0) US. Pennsylvania Worker and Community Right-to-Know Law 2,2'-Oxydiethanol (CAS 111-46-6) BORON SODIUM OXIDE (B4NA2O7), PENTAHYDRATE (CAS 12179-04-3) Ethane-1,2-diol (CAS 107-21-1) sodium nitrite (CAS 7632-00-0) US. Rhode Island RTK Ethane-1,2-diol (CAS 107-21-1) sodium nitrite (CAS 7632-00-0) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. International Inventories All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. 16. Other information, including date of preparation or last revision Issue date 11-02-2015 Revision date 11-02-2015 Version # 02 HMIS? ratings Health: 1 Flammability: 1 Physical hazard: 0 NFPA ratings Health: 1 Flammability: 1 Instability: 0 Preparation Information and Disclaimer This document was prepared by FCSD-Toxicology, Ford Motor Company, Diagnostic Service Center II, 1800 Fairlane Drive, Allen Park, MI 48101, USA, based in part on information provided by the manufacturer. The information on this data sheet represents our current data and is accurate to the best of our knowledge as to the proper handling of this product under normal conditions and in accordance with the application specified on the packaging and/or technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. To the extent that there are any differences between this product?s Safety Data Sheet (SDS) and the consumer packaged product labels, the SDS should be followed. Revision Information Product and Company Identification: Product and Company Identification Hazard(s) identification: Hazard(s) not otherwise classified (HNOC) Exposure controls/personal protection: Appropriate engineering controls Toxicological Information: Toxicological Data Regulatory information: California Prop 65 Part number(s) VC-7-B, VC-7-B1, VC-7-D FIR No.: 189062 SDS US Issue Date: 11-02-2015 Version: 02 8 / 8