SAFETY DATA SHEET 1. Identification Product identifier R-1234yf Refrigerant POE Oil Other means of identification FIR No. 195622 Recommended use A/C refrigerant compressor oil Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Supplier Company Name Ford Motor Company Address Attention: MSDS Information, P.O. Box 1899 Dearborn, Michigan 48121 USA Telephone 1-800-392-3673 MSDS Information 1-800-448-2063 This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone numbers Poison Control Center: USA and Canada: 1-800-959-3673 INFOTRAC (Transportation): USA and Canada 1-800-535-5053 2. Hazard(s) identification Not classified.Physical hazards Category 1Specific target organ toxicity, single exposureHealth hazards Category 1Specific target organ toxicity, repeated exposure Category 2Hazardous to the aquatic environment, acute hazard Environmental hazards Category 2Hazardous to the aquatic environment, long-term hazard Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Causes damage to organs. Causes damage to organs through prolonged or repeated exposure. Toxic to aquatic life. Toxic to aquatic life with long lasting effects. Precautionary statement Prevention Do not breathe mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Avoid release to the environment. Response If exposed: Call a poison center/doctor. Collect spillage. Storage Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) May be harmful if swallowed. Direct contact with eyes may cause temporary irritation. May cause an allergic skin reaction. May be harmful if absorbed through skin. May be irritating to the skin. Supplemental information None. 3. Composition/information on ingredients Mixtures FIR No.: 195622 SDS US Issue Date: 10-19-2015 Version: 01 1 / 8 CAS number %Chemical name Common name and synonyms 26761-45-52,3-Epoxypropyl neodecanoate 1 - 5 1330-78-5Tris(methylphenyl) phosphate 1 - 5 128-37-02,6-DI-TERT-BUTYL-P-CRESOL < 1 Specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Move to fresh air. Call a physician if symptoms develop or persist. Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists. Eye contact Rinse with water. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Get medical attention if symptoms occur. Most important symptoms/effects, acute and delayed Prolonged exposure may cause chronic effects. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. General information If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical During fire, gases hazardous to health may be formed. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire fighting equipment/instructions Move containers from fire area if you can do so without risk. Move containers from fire area if you can do so without risk. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Avoid contact with eyes, skin, and clothing. Do not breathe mist or vapor. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up This material is classified as a water pollutant under the Clean Water Act and should be prevented from contaminating soil or from entering sewage and drainage systems which lead to waterways. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. 7. Handling and storage Precautions for safe handling Avoid contact with eyes, skin, and clothing. Do not breathe mist or vapor. When using, do not eat, drink or smoke. Provide adequate ventilation. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. See Section 8 of the SDS for Personal Protective Equipment. FIR No.: 195622 SDS US Issue Date: 10-19-2015 Version: 01 2 / 8 Conditions for safe storage, including any incompatibilities Store locked up. Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values ValueComponents FormType TWA 2 mg/m3 Inhalable fraction and vapor. 2,6-DI-TERT-BUTYL-P-CR ESOL (CAS 128-37-0) US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type TWA 10 mg/m32,6-DI-TERT-BUTYL-P-CR ESOL (CAS 128-37-0) Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering controls Use adequate ventilation to control airborne concentrations below the exposure limits/guidelines. If user operations generate a vapor, dust and/or mist, use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below the recommended exposure limits/guidelines. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Suitable chemical protective gloves should be worn when the potential exists for prolonged or repeated skin exposure. Butyl rubber gloves are recommended. Other Wear suitable protective clothing. Wear appropriate chemical resistant clothing if applicable. Respiratory protection If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, an approved respirator must be worn. Respirator selection, use and maintenance should be in accordance with the requirements of OSHA Respiratory Protection Standard 29 CFR 1910.134 and/or Canadian Standard CSA Z94.4. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Lubricant. Color Colorless to light yellow. Odor Slight. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range Not available. Flash point 392.0 ?F (200.0 ?C) Evaporation rate Not available. Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower (%) Not available. Flammability limit - upper (%) Not available. Explosive limit - lower (%) Not available. FIR No.: 195622 SDS US Issue Date: 10-19-2015 Version: 01 3 / 8 Explosive limit - upper (%) Not available. Vapor pressure Not available. Vapor density < 1 Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity 64 - 88 mm?/s Viscosity temperature 104 ?F (40 ?C) 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Conditions to avoid Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Acids. Halogens. Halogenated materials. Hazardous decomposition products Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 11. Toxicological information Information on likely routes of exposure Inhalation May cause damage to organs by inhalation. May cause damage to organs through prolonged or repeated exposure by inhalation. Skin contact May cause an allergic skin reaction. May be harmful in contact with skin. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion May be harmful if swallowed. Symptoms related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute toxicity May be harmful if swallowed. May irritate eyes and skin. May be harmful in contact with skin. May be harmful if inhaled. Species Calculated/Test ResultsComponents 2,6-DI-TERT-BUTYL-P-CRESOL (CAS 128-37-0) LD50 Guinea pig Oral Acute 10700 mg/kg Mouse 1040 mg/kg Rat 890 mg/kg Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization May cause sensitization by skin contact. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. FIR No.: 195622 SDS US Issue Date: 10-19-2015 Version: 01 4 / 8 IARC Monographs. Overall Evaluation of Carcinogenicity 2,6-DI-TERT-BUTYL-P-CRESOL (CAS 128-37-0) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Causes damage to organs. Nervous system. Specific target organ toxicity - repeated exposure Causes damage to organs through prolonged or repeated exposure. Nervous system. Aspiration hazard Not an aspiration hazard. Chronic effects Causes damage to organs through prolonged or repeated exposure. 12. Ecological information Ecotoxicity Toxic to aquatic life with long lasting effects. Ecotoxicity SpeciesComponents Calculated/Test Results 2,6-DI-TERT-BUTYL-P-CRESOL (CAS 128-37-0) Aquatic EC50Crustacea 1.44 mg/l, 48 hoursWater flea (Daphnia pulex) Tris(methylphenyl) phosphate (CAS 1330-78-5) Aquatic EC50Crustacea 2.3 - 4.5 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 0.21 - 0.32 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Tris(methylphenyl) phosphate 5.11 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Don't pollute. Conserve resources. Return used oil to collection centers. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN3082UN number Environmentally hazardous substances, liquid, n.o.s., MARINE POLLUTANTUN proper shipping name 9Class Transport hazard class(es) -Subsidiary risk 9Label(s) FIR No.: 195622 SDS US Issue Date: 10-19-2015 Version: 01 5 / 8 IIIPacking group YesMarine pollutant Environmental hazards Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 8, 146, 335, IB3, T4, TP1, TP29Special provisions 155Packaging exceptions 203Packaging non bulk 241Packaging bulk IATA UN3082UN number Environmentally hazardous substance, liquid, n.o.s.UN proper shipping name 9Class Transport hazard class(es) -Subsidiary risk IIIPacking group YesEnvironmental hazards 9LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Allowed.Passenger and cargo aircraft Other information Allowed.Cargo aircraft only IMDG UN3082UN number ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., MARINE POLLUTANTUN proper shipping name 9Class Transport hazard class(es) -Subsidiary risk IIIPacking group YesMarine pollutant Environmental hazards F-A, S-FEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Not established.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code DOT; IATA; IMDG Marine pollutant General information DOT Regulated Marine Pollutant. IMDG Regulated Marine Pollutant. FIR No.: 195622 SDS US Issue Date: 10-19-2015 Version: 01 6 / 8 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. Massachusetts RTK - Substance List 2,6-DI-TERT-BUTYL-P-CRESOL (CAS 128-37-0) US. New Jersey Worker and Community Right-to-Know Act 2,6-DI-TERT-BUTYL-P-CRESOL (CAS 128-37-0) Tris(methylphenyl) phosphate (CAS 1330-78-5) US. Pennsylvania Worker and Community Right-to-Know Law 2,6-DI-TERT-BUTYL-P-CRESOL (CAS 128-37-0) US. Rhode Island RTK Not regulated. US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. 16. Other information, including date of preparation or last revision Issue date 10-19-2015 Version # 01 HMIS? ratings Health: 2 Flammability: 1 Physical hazard: 0 FIR No.: 195622 SDS US Issue Date: 10-19-2015 Version: 01 7 / 8 NFPA ratings Health: 2 Flammability: 1 Instability: 0 Preparation Information and Disclaimer This document was prepared by FCSD-Toxicology, Ford Motor Company, Diagnostic Service Center II, 1800 Fairlane Drive, Allen Park, MI 48101, USA, based in part on information provided by the manufacturer. The information on this data sheet represents our current data and is accurate to the best of our knowledge as to the proper handling of this product under normal conditions and in accordance with the application specified on the packaging and/or technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. To the extent that there are any differences between this product?s Safety Data Sheet (SDS) and the consumer packaged product labels, the SDS should be followed. Part number(s) YN-34 FIR No.: 195622 SDS US Issue Date: 10-19-2015 Version: 01 8 / 8