SAFETY DATA SHEET 1. Identification Product identifier Premium Windshield Wash [0 ?F] Other means of identification FIR No. 189615 Recommended use Premium Windshield Wash Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Supplier Company Name Ford Motor Company Address Attention: MSDS Information, P.O. Box 1899 Dearborn, Michigan 48121 USA Telephone 1-800-392-3673 MSDS Information 1-800-448-2063 This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone numbers Poison Control Center: USA and Canada: 1-800-959-3673 INFOTRAC (Transportation): USA and Canada 1-800-535-5053 2. Hazard(s) identification Category 3Flammable liquidsPhysical hazards Category 3Acute toxicity, oralHealth hazards Category 3Acute toxicity, dermal Category 3Acute toxicity, inhalation Category 1BReproductive toxicity Category 1Specific target organ toxicity, single exposure Category 1Specific target organ toxicity, repeated exposure Not classified.Environmental hazards Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Flammable liquid and vapor. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. May damage fertility or the unborn child. Causes damage to organs. Causes damage to organs through prolonged or repeated exposure. Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. FIR No.: 189615 SDS US Issue Date: 05-15-2015 Version: 01 1 / 9 Response If swallowed: Immediately call a poison center/doctor. Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor. Take off immediately all contaminated clothing and wash it before reuse. In case of fire: Use appropriate media to extinguish. Storage Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) May be fatal or cause blindness if swallowed. Cannot be made nonpoisonous. May irritate eyes and skin. May cause irritation of respiratory tract. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Aspiration may cause pulmonary edema and pneumonitis. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 67-56-1METHANOL 20 - < 30 Specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a physician if symptoms develop or persist. Skin contact Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical advice/attention if you feel unwell. Get medical attention if irritation develops and persists. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Most important symptoms/effects, acute and delayed Direct contact with eyes may cause temporary irritation. Prolonged exposure may cause chronic effects. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim warm. Keep victim under observation. Symptoms may be delayed. General information Take off immediately all contaminated clothing. IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse. 5. Fire-fighting measures Suitable extinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire fighting equipment/instructions In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards Flammable liquid and vapor. FIR No.: 189615 SDS US Issue Date: 05-15-2015 Version: 01 2 / 9 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid contact with eyes, skin, and clothing. Do not breathe mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Following product recovery, flush area with water. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof general and local exhaust ventilation. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Do not breathe mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke. Pregnant or breastfeeding women must not handle this product. Should be handled in closed systems, if possible. Use only outdoors or in a well-ventilated area. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Wash contaminated clothing before reuse. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in a cool, dry place out of direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Keep in an area equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 260 mg/m3METHANOL (CAS 67-56-1) 200 ppm US. ACGIH Threshold Limit Values ValueComponents Type STEL 250 ppmMETHANOL (CAS 67-56-1) TWA 200 ppm US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type STEL 325 mg/m3METHANOL (CAS 67-56-1) 250 ppm TWA 260 mg/m3 200 ppm FIR No.: 189615 SDS US Issue Date: 05-15-2015 Version: 01 3 / 9 Biological limit values ACGIH Biological Exposure Indices ValueComponents Determinant Specimen Sampling Time 15 mg/l Methanol Urine *METHANOL (CAS 67-56-1) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation METHANOL (CAS 67-56-1) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies METHANOL (CAS 67-56-1) Skin designation applies. US - Tennessee OELs: Skin designation METHANOL (CAS 67-56-1) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation METHANOL (CAS 67-56-1) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation METHANOL (CAS 67-56-1) Can be absorbed through the skin. Appropriate engineering controls Explosion-proof general and local exhaust ventilation. Use adequate ventilation to control airborne concentrations below the exposure limits/guidelines. If user operations generate a vapor, dust and/or mist, use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below the recommended exposure limits/guidelines. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Suitable chemical protective gloves should be worn when the potential exists for prolonged or repeated skin exposure. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Nitrile or butyl rubber gloves are recommended. Other Wear appropriate chemical resistant clothing. Wear appropriate chemical resistant clothing if applicable. Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, an approved respirator must be worn. Respirator selection, use and maintenance should be in accordance with the requirements of OSHA Respiratory Protection Standard 29 CFR 1910.134 and/or Canadian Standard CSA Z94.4. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Liquid. Color Blue. Odor Alcoholic. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 183.92 - 185.9 ?F (84.4 - 85.5 ?C) Flash point 102.9 ?F (39.4 ?C) COC Evaporation rate > 1 (BuAc=1) Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits FIR No.: 189615 SDS US Issue Date: 05-15-2015 Version: 01 4 / 9 Explosive limit - lower (%) 6 % Explosive limit - upper (%) 36 % Vapor pressure 37.2 mm Hg Vapor pressure temp. 68 ?F (20 ?C) Vapor density > 1 (AIR=1) Relative density 0.97 Relative density temperature 68 ?F (20 ?C) Solubility(ies) Solubility (water) SOLUBLE Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Kinematic viscosity < 10 cSt Kinematic viscosity temperature 104 ?F (40 ?C) VOC (Weight %) 22.74 % 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Hazardous decomposition products Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 11. Toxicological information Information on likely routes of exposure Inhalation Toxic if inhaled. May cause damage to organs by inhalation. May cause damage to organs through prolonged or repeated exposure by inhalation. May cause irritation to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Skin contact Toxic in contact with skin. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Toxic if swallowed. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. May be fatal or cause blindness if swallowed. Symptoms related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute toxicity Toxic if inhaled. Toxic in contact with skin. Toxic if swallowed. Species Calculated/Test ResultsComponents METHANOL (CAS 67-56-1) LD50 Rabbit Dermal Acute 15800 mg/kg LC50 Cat Inhalation 85.41 mg/l, 4.5 Hours FIR No.: 189615 SDS US Issue Date: 05-15-2015 Version: 01 5 / 9 Species Calculated/Test ResultsComponents 43.68 mg/l, 6 Hours Rat 64000 ppm, 4 Hours 87.5 mg/l, 6 Hours LD50 Dog Oral 8000 mg/kg Monkey 2 g/kg Mouse 7300 mg/kg Rabbit 14.4 g/kg Rat 5628 mg/kg Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity May damage fertility or the unborn child. Specific target organ toxicity - single exposure Causes damage to organs. Central nervous system. Liver. Optic nerves. Specific target organ toxicity - repeated exposure Causes damage to organs through prolonged or repeated exposure. Central nervous system. Liver. Kidneys. Optic nerves. Aspiration hazard If aspirated into lungs during swallowing or vomiting, may cause chemical pneumonia, pulmonary injury or death. Chronic effects Causes damage to organs through prolonged or repeated exposure. Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Ecotoxicity SpeciesComponents Calculated/Test Results METHANOL (CAS 67-56-1) Aquatic EC50Crustacea > 10000 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish > 100 mg/l, 96 hoursFathead minnow (Pimephales promelas) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) METHANOL -0.77 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. FIR No.: 189615 SDS US Issue Date: 05-15-2015 Version: 01 6 / 9 Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN1993UN number FLAMMABLE LIQUIDS, N.O.S. (METHYL ALCOHOL)UN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIIPacking group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IATA UN1993UN number FLAMMABLE LIQUIDS, N.O.S. (METHYL ALCOHOL)UN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIIPacking group No.Environmental hazards Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Forbidden.Passenger and cargo aircraft Other information Forbidden.Cargo aircraft only IMDG UN1993UN number FLAMMABLE LIQUIDS, N.O.S. (METHYL ALCOHOL)UN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIIPacking group No.Marine pollutant Environmental hazards Not available.EmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Not established.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code FIR No.: 189615 SDS US Issue Date: 05-15-2015 Version: 01 7 / 9 DOT IATA; IMDG 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) METHANOL (CAS 67-56-1) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Chemical name CAS number % by wt. METHANOL 67-56-1 20 - < 30 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List METHANOL (CAS 67-56-1) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. Massachusetts RTK - Substance List METHANOL (CAS 67-56-1) FIR No.: 189615 SDS US Issue Date: 05-15-2015 Version: 01 8 / 9 US. New Jersey Worker and Community Right-to-Know Act METHANOL (CAS 67-56-1) US. Pennsylvania Worker and Community Right-to-Know Law METHANOL (CAS 67-56-1) US. Rhode Island RTK METHANOL (CAS 67-56-1) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. International Inventories All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. 16. Other information, including date of preparation or last revision Issue date 05-15-2015 Version # 01 HMIS? ratings Health: 1 Flammability: 2 Physical hazard: 0 NFPA ratings Health: 1 Flammability: 2 Instability: 0 Preparation Information and Disclaimer This document was prepared by FCSD-Toxicology, Ford Motor Company, Diagnostic Service Center II, 1800 Fairlane Drive, Allen Park, MI 48101, USA, based in part on information provided by the manufacturer. The information on this data sheet represents our current data and is accurate to the best of our knowledge as to the proper handling of this product under normal conditions and in accordance with the application specified on the packaging and/or technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. To the extent that there are any differences between this product?s Safety Data Sheet (SDS) and the consumer packaged product labels, the SDS should be followed. Part number(s) ZC-32Z-FG FIR No.: 189615 SDS US Issue Date: 05-15-2015 Version: 01 9 / 9