1. Identification Product identifier Product Trade Name Description Details of the supplier of the safety data sheet 2. Hazard(s) Identification Classification of the substance or mixture GHS07 Label elements The product is classified and labeled according to the Globally Harmonized System (GHS). GHS label elements Hazard pictograms GHS07 WarningSignal word: Hazard statements Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. 8011293 Masterchem Stop Leak O-Ring & Seal Conditioner with Red Dye (0.005/1 Treat Rate) 1 / 9 A/C Seal Leak Stop with Red Dye (0.005/1 Treat Rate) OSHA HazCom Standard 29 CFR 1910.1200(g), Rev. 2012 and GHS Rev 03. Page 1 of 9 Revision Date 05/28/2015 P/N 8011293 SDS REVSION DATE: 05/28/2015 SAFETY DATA SHEET (SDS) MASTERCHEM STOP LEAK O-Ring & Seal Conditioner 24 HR. EMERGENCY TELEPHONE NUMBERS CHEMTREC: 800-424-9300 IDENTITY: GLOBAL PARTS DISTRIBUTORS, L.L.C. ADDRESS: COMPANY CITY: COMPANY PHONE: 3279 Avondale Mill Rd Macon, GA. 31216 1-478-781-9854 2. Hazard(s) Identification (continued) Precautionary statements Wear protective gloves. Wear eye protection / face protection. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If swallowed: Call a poison center/doctor if you feel unwell. Specific treatment (see on this label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Rinse mouth. If on skin: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. Dispose of contents/container in accordance with ocal/regional/national/international regulations. Classification system NFPA ratings (scale 0-4) Health=1; Fire=1; Reactivity=0 Health=1; Fire=1; Reactivity=0 3. Composition / Information on Ingredients MixturesChemical characterization: Dangerous Components NA Sulfur/Phosphorus Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2A, H319 4. First-aid Measures Description of first aid measures General information Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. In case of unconsciousness, place patient securely on side position for transportation.After inhalation After skin contact Immediately wash with water and soap and rinse thoroughly. If irritation occurs consult a doctor. After eye contact Rinse opened eye for at least 15 minutes under running water. If symptoms persist, consult a doctor. 5-10% 2 / 9 Page 2 of 9 Revision Date 05/28/2015 P/N 8011293 SDS REVSION DATE: 05/28/2015 SAFETY DATA SHEET (SDS) MASTERCHEM STOP LEAK O-Ring & Seal Conditioner 4. First-aid Measures (continued) After swallowing Most important symptoms and effects, both acute and delayed Indication of any immediate medical attention and special treatment needed Immediately call a doctor. No further relevant information available. No further relevant information available. 5. Fire-fighting Measures Advice for firefighters Protective equiptment As in any fire, wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent), and full protective gear to prevent contact with skin and eyes. 6. Accidental Release Measures Not required Personal precautions, protective equipment and emergency procedures Environmental precautions Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up Reference to other sections Absorb with liquid binding material (i.e. sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to section.Ensure adequate ventilation. Dispose of the collected material according to regulations. See Section 7 for information on safe handling. See Section 8 for information on personal See Section 13 for disposal information. 7. Handling and Storage Precautions for safe handling Information about protection against explosions and fires Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. No special measures required. Conditions for safe storage, including any incompatibilities Storage Requirements to be met by storerooms and receptacles: Further information about storage conditions Specific end use(s) No special requirements Keep receptacle tightly sealed No further relevant information available 3 / 9 Extinguishing media Suitable extinguishing agents Special hazards arising from the substance or mixture Use fire fighting measures that suit the environment. No further relevant information available. Page 3 of 9 Revision Date 05/28/2015 P/N 8011293 SDS REVSION DATE: 05/28/2015 SAFETY DATA SHEET (SDS) MASTERCHEM STOP LEAK O-Ring & Seal Conditioner 8. Exposure Controls / Personal Protection No further data. See section 7. 7Additional information about design of technical systems Control parameters The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. The lists that were valid during the creation were used as basis. Components with occupational exposure limits Additional information Exposure controls Personal protective equipment General protective and hygienic measures Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Not requiredBreathing equipment Protection of hands Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Select glove material based on penetration times, rates of diffusion and degradation. Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be FKeFNeG SUioU to tKe aSSOiFation 7Ke e[aFt EUeaN-tKUoXJK tiPe Kas to Ee GeteUPineG anG oEseUveG E\ tKe PanXIaFtXUeU oI tKe SUoteFtive JOoves? 7iJKtO\ seaOeG JoJJOes Penetration time of glove material Eye protection 4 / 9 Page 4 of 9 Revision Date 05/28/2015 P/N 8011293 SDS REVSION DATE: 05/28/2015 SAFETY DATA SHEET (SDS) MASTERCHEM STOP LEAK O-Ring & Seal Conditioner 9. Physical and Chemical Properties ,nIoUPation on EasiF SK\siFaO anG cKePiFaO SUoSeUties. *eneUaO ,nIoUPation ... eaUanFe FoUP &oOoU 2GoU /iTXiG 6ee SUoGXFt 0iOG 1ot GeteUPineG 1ot GeteUPineG 1ot aSSOiFaEOe !570F ?!2?8?C) !??0F ?!227?C) 1ot aSSOiFaEOe Not determined Not determined 1ot GeteUPineG Not determined Not determined 2GoU 7KUesKoOG S+-vaOXe &KanJe in FonGition 0eOtinJ Soint?0eOtinJ UanJe %oiOinJ Soint?%oiOinJ UanJe FOasK 3oint FOaPPaEiOit\ ?soOiG JaseoXs? ,Jnition tePSeUatXUe DeFoPSosition tePSeUatXUe $Xto-iJnitinJ DanJeU oI e[SOosion E[SOosion OiPits /oZeU USSeU VaSoU 3UessXUe @20 DE* & 5 / 9 Page 5 of 9 Revision Date 05/28/2015 P/N 8011293 SDS REVSION DATE: 05/28/2015 SAFETY DATA SHEET (SDS) MASTERCHEM STOP LEAK O-Ring & Seal Conditioner 10. Stability and Reactivity Reactivity Chemical stability Thermal decomposition / conditions to be avoided Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products No further relevant information available. Stable under normal conditions. No decomposition if used according to specifications. No dangerous reactions known. No further relevant information available. No further relevant information available. No dangerous decomposition products known. 11. Toxicological Information Information on toxicological effects Acute toxicity LD/LC50 values that are relevant for classification 90031-31-8 Sulfur/Phosphorus Oral: LD50 >300- <2000 mg/kg (rat) Dermal: LD50 >2000 mg/kg (rat) Primary irritant effect: On the skin On the eye Additional toxicological information Irritant to skin and mucous membranes. Irritating effect. Causes serious eye irritation. The product shows the following dangers according to internally approved calculation methods for preparations: Harmful. Irritant. Carcinogenic categories: IARC (International Agency for Research on Cancer) None of the ingredients are listed. Group 1 - Carcinogenic to humans. Group 2A - Probably carcinogenic to humans. Group 2B - Possibly carcinogenic to humans. Group 3 - Not classifiable as to its carcinogenicity to humans. Group 4 - Probably not carcinogenic to humans. None of the ingredients are listedNTP (National Toxicology Program) OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients are listed 12. Ecological Information No data is available on this product. No further relevant information available. No further relevant information available. No further relevant information available. No further relevant information available. Toxicity Aquatic toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Additional ecological information General notes Water hazard class 1 (Self-assessment): slightly hazardous for water. 6 / 9 Page 6 of 9 Revision Date 05/28/2015 P/N 8011293 SDS REVSION DATE: 05/28/2015 SAFETY DATA SHEET (SDS) MASTERCHEM STOP LEAK O-Ring & Seal Conditioner 12. Ecological Information (continued) Results of PBT and vPvB assessment PBT vPvB Other adverse effects Not applicable Not applicable No further relevant information available. 13. Disposal Considerations Uncleaned packagings Recommendation Disposal must be made according to official regulations. 14. Transportation Information Non-regulated material Non-regulated material Non-regulated material Non-regulated material No Not applicable Not applicable UN-Number DOT, ADR, ADN, IMDG, IATA UN proper shipping name DOT, ADR, ADN, IMDG, IATA Transport hazard class(es) DOT, ADR, ADN, IMDG, IATA Class Packing group DOT, ADR, IMDG, IATA Environmental hazards Marine pollutant Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code UN ?Model Regulation? ? 15. R egulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 Section 313 (Specific toxic chemical listings) None of the ingredients are listed. TSCA (Toxic Substances Control Act 68515-49-1: Diisodecyl Phthalate. 7 / 9 Proposition 65 Chemicals known to cause cancer None of the ingredients are listed. Section 355 (extremely hazardous substances) None of the ingredients are listed. Page 7 of 9 Revision Date 05/28/2015 P/N 8011293 SDS REVSION DATE: 05/28/2015 SAFETY DATA SHEET (SDS) MASTERCHEM STOP LEAK O-Ring & Seal Conditioner 15. Regulatory Information Chemicals known to cause reproductive toxicity for females None of the ingredients are listed. Chemicals known to cause reproductive toxicity for males Chemicals known to cause developmental toxicity Carcinogenic categories None of the ingredients are listed. 68515-49-1: Diisodecyl Phthalate EPA (Environmental Protection Agency) TLV (Threshold Limit Value established by ACGIH) None of the ingredients are listed. None of the ingredients are listed. NIOSH-Ca (National Institute for Occupational Safety and Health) GHS label elements None of the ingredients are listed. Non-regulated material. Hazard pictograms GHS07 Warning Sulfur/Phosphorus Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. Signal word Hazard-determining components of labeling Hazard statements Precautionary statements Wear protective gloves. Wear eye protection / face protection. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If swallowed: Call a poison center/doctor if you feel unwell. Specific treatment (see on this label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Rinse mouth. If on skin: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. Dispose of contents/container in accordance with local/regional/national/international regulations. National regulations The product is subject to be labeled according with the prevailing version of the regulations on hazardous substances. State Right to Know NA Sulfur/Phosphorus Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2A, H319 A chemical safety assessment has not been carried out 5-10% 8 / 9 Chemical safety assessment Page 8 of 9 Revision Date 05/28/2015 P/N 8011293 SDS REVSION DATE: 05/28/2015 SAFETY DATA SHEET (SDS) MASTERCHEM STOP LEAK O-Ring & Seal Conditioner 16. Other Information The information and recommendations in this safety data sheet are, to the best of our knowledge, accurate as of the date of issue. Nothing herein shall be deemed to create warranty, expressed or implied and shall not establish a legally valid contractual relationship. It is the responsibility of the user to determine applicability of this information and the suitability of the material or product for any particular purpose. Date of preparation / last revision 12/03/2014 / 1 Abbreviations and acronyms ADR: Accord europ?en sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) ADN: The European Agreement concerning the International Carriage of Danger-ous Goods by Inland Waterways IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Irrit. 2A: Serious eye damage/eye irritation, Hazard Category 2A Powered by TCPDF (www.tcpdf.org) 9 / 9 Page 1 of 9 Revision Date 05/28/2015 P/N 8011293 SDS REVSION DATE: 05/28/2015 SAFETY DATA SHEET (SDS) MASTERCHEM STOP LEAK O-Ring & Seal Conditioner