Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 1 Conforms to HazCom 2012/United States SAFETY DATA SHEET Lucas Semi-Synthetic 2-Cycle Oil Section 1. Identification GHS product identifier Other means of identification : Lucas Semi-Synthetic 2-Cycle Oil : Not available. Product number : 10058, 10059, 10110, 10115, 10120, 10125 Identified uses Fuel/Lubricating Oil Supplier's details : Lucas Oil Products, Inc 302 North Sheridan Street Corona, California 92880-2067 Toll Free: (800) 342-2512 Tel: (951) 270-0154 Fax: (951) 270-1902 Website: www.LucasOil.com Emergency telephone number (with hours of operation) : (951) 493-1149 (951) 847-5949 This email address is being protected from spambots. You need JavaScript enabled to view it. 7:00A.M. to 5:00P.M. Monday thru Friday Section 2. Hazards identification OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the substance or mixture : FLAMMABLE LIQUIDS - Category 4 ASPIRATION HAZARD - Category 1 GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : Combustible liquid. May be fatal if swallowed and enters airways. Precautionary statements General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Prevention : Wear protective gloves. Wear eye or face protection. Keep away from flames and hot surfaces. - No smoking. Response : IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 2 Lucas Semi-Synthetic 2-Cycle Oil Section 2. Hazards identification Storage : Store locked up. Store in a well-ventilated place. Keep cool. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified : None known. Section 3. Composition/information on ingredients Substance/mixture : Mixture Other means of identification : Not available. CAS number/other identifiers CAS number : Not applicable. Product code : 10058, 10059, 10110, 10115, 10120, 10125 Ingredient name % CAS number Solvent naphtha (petroleum), medium aliph. 10 - 30 64742-88-7 Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures Description of necessary first aid measures Eye contact Inhalation Skin contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention if irritation occurs. : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. : Flush contaminated skin with plenty of water. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Most important symptoms/effects, acute and delayed Potential acute health effects Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 3 Lucas Semi-Synthetic 2-Cycle Oil Section 4. First aid measures Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : May be fatal if swallowed and enters airways. Over-exposure signs/symptoms Eye contact : No known significant effects or critical hazards. Inhalation Skin contact Ingestion : No known significant effects or critical hazards. : No known significant effects or critical hazards. : Adverse symptoms may include the following: nausea or vomiting Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. See toxicological information (Section 11) Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Use dry chemical, CO2, water spray (fog) or foam. : Straight streams of water. Specific hazards arising from the chemical Hazardous thermal decomposition products : Combustible liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. : carbon monoxide, carbon dioxide and oxides of manganese. Special protective actions for fire-fighters Special protective equipment for fire-fighters : Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency personnel : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 4 Lucas Semi-Synthetic 2-Cycle Oil Section 6. Accidental release measures For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7. Handling and storage Precautions for safe handling Protective measures Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities : Put on appropriate personal protective equipment (see Section 8). Do not swallow. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Do not reuse container. : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures. : Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 5 Lucas Semi-Synthetic 2-Cycle Oil Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits Ingredient name Exposure limits Solvent naphtha (petroleum), medium aliph. OSHA PEL (United States, 2/2013). TWA: 100 ppm 8 hours. TWA: 400 mg/m? 8 hours. Appropriate engineering controls Environmental exposure controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection Skin protection Hand protection Body protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Use a properly fitted, air-purifying or supplied air respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 6 Lucas Semi-Synthetic 2-Cycle Oil Section 9. Physical and chemical properties Appearance Physical state Color Odor Odor threshold pH Melting point : Liquid. [Clear.] : Blue-Green. : Petroleum solvent : Not available. : Not available. : Not available. Boiling point : 191.11 to 211.11?C (376 to 412?F) Flash point Evaporation rate : Closed cup: 83.33?C (182?F) : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Not available. Vapor pressure Vapor density Relative density Solubility Partition coefficient: n- octanol/water Auto-ignition temperature : Not available. : Not available. : 0.866 : Negligible at 25oC : Not available. : Not available. Decomposition temperature : Not available. Viscosity : Kinematic (100?C (212?F)): 0.075 cm2/s (7.5 cSt) Section 10. Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to avoid : Excessive heat, flames and sparks. Incompatible materials : Reactive or incompatible with the following materials: Strong oxidizers, exposure to light. Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition products should not be produced. Section 11. Toxicological information Information on toxicological effects Acute toxicity There is no data available. Irritation/Corrosion There is no data available. Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 7 Lucas Semi-Synthetic 2-Cycle Oil Section 11. Toxicological information Sensitization There is no data available. Carcinogenicity There is no data available. Specific target organ toxicity (single exposure) There is no data available. Specific target organ toxicity (repeated exposure) There is no data available. Aspiration hazard Name Result Solvent naphtha (petroleum), medium aliph. ASPIRATION HAZARD - Category 1 Information on the likely routes of exposure Potential acute health effects : Dermal contact. Eye contact. Inhalation. Ingestion. Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : May be fatal if swallowed and enters airways. Symptoms related to the physical, chemical and toxicological characteristics Eye contact : No known significant effects or critical hazards. Inhalation Skin contact Ingestion : No known significant effects or critical hazards. : No known significant effects or critical hazards. : Adverse symptoms may include the following: nausea or vomiting Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate effects : No known significant effects or critical hazards. Potential delayed effects : No known significant effects or critical hazards. Long term exposure Potential immediate effects : No known significant effects or critical hazards. Potential delayed effects : No known significant effects or critical hazards. Potential chronic health effects General : Carcinogenicity : Mutagenicity : Teratogenicity : No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Lucas Semi-Synthetic 2-Cycle Oil Section 11. Toxicological information Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 8 Numerical measures of toxicity Acute toxicity estimates There is no data available. Section 12. Ecological information Toxicity There is no data available. Persistence and degradability There is no data available. Bioaccumulative potential There is no data available. Mobility in soil Soil/water partition coefficient (KOC) : There is no data available. Other adverse effects : No known significant effects or critical hazards. Section 13. Disposal considerations Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Section 14. Transport information DOT Classification IMDG IATA UN number NA1993 Not regulated. Not regulated. UN proper shipping name Transport hazard class(es) COMBUSTIBLE LIQUID, N.O.S. (Solvent - - naphtha (petroleum), medium aliph.) Combustible liquid. - - Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 9 Lucas Semi-Synthetic 2-Cycle Oil Section 14. Transport information Packing group Environmental hazards III - - No. No. No. Additional information Non-bulk packages (less than or equal to - - 119 gal) of combustible liquids are not regulated as hazardous materials. AERG : 128 Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code : Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. Section 15. Regulatory information U.S. Federal regulations : TSCA 8(a) CDR Exempt/Partial exemption: All components are listed or exempted. United States inventory (TSCA 8b): All components are listed or exempted. Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I Substances Clean Air Act Section 602 Class II Substances DEA List I Chemicals (Precursor Chemicals) DEA List II Chemicals (Essential Chemicals) SARA 302/304 : Not listed : Not listed : Not listed : Not listed : Not listed Composition/information on ingredients No products were found. SARA 304 RQ : Not applicable. SARA 311/312 Classification : Fire hazard Composition/information on ingredients State regulations Massachusetts : None of the components are listed. New York : None of the components are listed. New Jersey : The following components are listed: Distillates (petroleum), hydrotreated heavy paraffinic; Residual oils (petroleum), solvent-dewaxed; Residual oils (petroleum), hydrotreated; Distillates (petroleum), solvent-dewaxed heavy paraffinic Pennsylvania : None of the components are listed. California Prop. 65 Lucas Semi-Synthetic 2-Cycle Oil Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 10/10 Section 15. Regulatory information No products were found. Section 16. Other information Hazardous Material Information System (U.S.A.) Health : 1 * Flammability : 2 Physical hazards : 0 Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS? ratings are not required on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered mark of the National Paint & Coatings Association (NPCA). HMIS? materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. National Fire Protection Association (U.S.A.) Health : 1 Flammability : 2 Instability : 0 Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ?1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ?2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. History Date of issue mm/dd/yyyy : 05/15/2014 Version : 1 Revised Section(s) : Not applicable. Prepared by : KMK Regulatory Services Inc. Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.