MATERIAL SAFETY DATA SHEET Trade Name: Johnsens All Purpose Cleaner 12/19 oz MSDS NO. 4722 Revision Date: Date Printed 12/02/2010 Page 1 of 5 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Trade Name: Johnsens All Purpose Cleaner 12/19 oz Synonyms: None Emergency Telephone (24 hr.): CHEMTREC 1-800-424-9300 Supplier: Technical Chemical Company, P.O. Box 139, Cleburne, Texas 76033 2. COMPOSITION/INFORMATION ON INGREDIENTS Component Weight % OSHA TWA OSHA STEL OSHA SKIN Butane 106-97-8 1-5 Not Listed Not Listed Not Listed Glycol Ether EB 111-76-2 2-4 Not Listed Not Listed 50 ppm Propane 74-98-6 1-5 Not Listed Not Listed Not Listed Component Weight % OSHA Z PEL OSHA Z TWA OSHA Z Ceiling Butane 106-97-8 1-5 Not Listed 1900 mg/m3 800 ppm Not Listed Glycol Ether EB 111-76-2 2-4 Not Listed Not Listed 120 mg/m3 25 ppm Propane 74-98-6 1-5 1800 mg/m3 1000 ppm 1800 mg/m3 1000 ppm Not Listed Component ACGIH TLV TWA ACGIH TLV STEL ACGIH TLV Ceiling Butane 106-97-8 1000 ppm Not Listed Not Listed Glycol Ether EB 111-76-2 20 ppm Not Listed Not Listed Propane 74-98-6 1000 ppm Not Listed Not Listed 3. HAZARDS IDENTIFICATION Emergency Overview: Keep away from heat, sparks and flame. Content under pressure. Ingestion of this product may cause gastrointestinal distress with symptoms of nausea, vomiting, diarrhea and abdominal pain. Gross inhalation overexposure may cause: respiratory track irritation, kidney damage, blood, liver damage, lung damage and central nervous system depression. Causes severe respiratory irritation. HMIS Classification: FLAMMABILITY 4 , REACTIVITY 0 , HEALTH 1 NFPA Rating: HEALTH 1, FLAMMABILITY 4 , REACTIVITY 0 4. FIRST AID MEASURES Eye Contact: In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing. Ingestion: If swallowed, induce vomiting immediately by giving two glasses of water and sticking fingers down throat; never give anything to an unconscious person. Get medical attention. Inhalation: If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention. Skin Contact: In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. Get medical attention. MATERIAL SAFETY DATA SHEET Trade Name: Johnsens All Purpose Cleaner 12/19 oz MSDS NO. 4722 Revision Date: Date Printed 12/02/2010 Page 2 of 5 5. FIRE FIGHTING MEASURES Flammable Properties Flash Point ?F(?C): <0 F (<-17 C) (propellant) Flash Point Method: Not Determined Flammable Limits in Air - Lower (%): NT Flammable Limits in Air - Upper (%): Not Determined Autoignition Temperature ?F(?C): Not Determined Extinguishing Media: Alcohol foam. Protection Of Fire-Fighters: Special Fire-Fighting Procedures: Wear approved positive-pressure self-contained breathing apparatus and protective clothing. Hazardous Combustion Products: Not determined. Aerosol Comments: NFPA Level 1 Aerosol 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Wear appropriate protective clothing and equipment to prevent skin and eye contact. Spill Procedures: Wear protective equipment specified. Avoid the generation of dust. Sweep, vacuum, or shovel and place into closable container for disposal. Action to be taken if material is released or spilled: Neutralize with suitable neutralizing agent after diluting with water. Environmental Precautions: Keep away from drains. 7. HANDLING AND STORAGE Handling and Storage: Use ground strap. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls: Exhaust ventilation. Eyes: Wear safety glasses or goggles to protect against exposure. Skin Protection: Not Determined Respiratory Protection: Use in a well ventilated area. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Liquid Odor: MILD AMMONIA pH Value: Not Determined Vapor Pressure: Not Determined Vapor Density (Air=1): Not Determined Boiling Point (?F): Not determined. Melting/Freezing Point: Not determined. Solubility in Water: Not Determined Bulk Density at 20?C: Not Determined Molecular Weight: Not Determined Specific Gravity (H20=1): Not determined. Viscosity: Not determined. Evaporation Rate: Not Determined VOC Content(%): Not determined. Decomposition Temperature: Not Known 10. STABILITY AND REACTIVITY Chemical Stability: STABLE. Conditions to Avoid: Keep away from any contact with water. Materials to Avoid: Contact with oxidizing agents. Hazardous Decomposition Products: Carbon monoxide. Hazardous Polymerization: WILL NOT OCCUR MATERIAL SAFETY DATA SHEET Trade Name: Johnsens All Purpose Cleaner 12/19 oz MSDS NO. 4722 Revision Date: Date Printed 12/02/2010 Page 3 of 5 11. TOXICOLOGICAL INFORMATION Toxicological Data: Component Route Species Dose Butane 106-97-8 Inhalation Rats LC50, 658 gm/m3/4H Glycol Ether EB 111-76-2 Inhalation Rats LC50 450 ppm/4H Propane 74-98-6 NA NA Not known. Carcinogenicity: Component IARC NTP OSHA Butane 106-97-8 Not Listed Not Listed Not Listed Glycol Ether EB 111-76-2 Not Listed Not Listed Not Listed Propane 74-98-6 Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATION Waste Classification: Not determined. Waste Management: Not determined. Disposal Method: Disposal should be made in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION U.S. DOT: Proper Shipping Name: CONSUMER COMMODITY Hazard Class: ORM-D UN/NA Number: Not Applicable DOT Packing Group: Not Applicable IMDG: Proper Shipping Name: Aerosols Hazard Class: 2.1 Hazard Subclass: Not determined. UN No.: Not determined. Packing Group: PGII Marine Pollutant: No 15. REGULATORY INFORMATION US Federal Regulations: MATERIAL SAFETY DATA SHEET Trade Name: Johnsens All Purpose Cleaner 12/19 oz MSDS NO. 4722 Revision Date: Date Printed 12/02/2010 Page 4 of 5 Component SARA 313 SARA 302 TPQ RQ Butane 106-97-8 Not Listed Not Listed Not Listed Not Listed Glycol Ether EB 111-76-2 Not Listed Not Listed Not Listed Not Listed Propane 74-98-6 Not Listed Not Listed Not Listed Not Listed SARA 311/312 Hazard Catagories: Not Determined. State Regulations: Component California Prop. 65 Cancer list California - Prop 65 Developmental Toxicity California Prop. 65 Reproductive Female California Prop. 65 Reproductive Male Butane 106-97-8 Not Listed Not Listed Not Listed Not Listed Glycol Ether EB 111-76-2 Not Listed Not Listed Not Listed Not Listed Propane 74-98-6 Not Listed Not Listed Not Listed Not Listed Component New Jersey Right-to-Know List: Butane 106-97-8 Substance no. 0273 Substance no. 2422 Substance no. 2423 Substance no. 2425 Substance no. 2426 Substance no. 2427 Substance no. 2428 Substance no. 2429 Substance no. 2430 Glycol Ether EB 111-76-2 Substance no. 0275 Propane 74-98-6 Substance no. 2422 Substance no. 2423 Substance no. 2425 Substance no. 2426 Substance no. 2427 Substance no. 2428 Substance no. 2429 Substance no. 2430 Substance no. 1594 U.S. TSCA: The components of this product are listed on the TSCA Inventory. Canadian Inventory: The components of this product are listed on the Canadian DSL or NDSL Inventory. Consumer Product Safety Improvement Act of 2008 General Conformity Certification The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product container. 16. OTHER INFORMATION General Notes: Do not allow undiluted material or large quantities to reach groundwater, bodies of water or sewer system. MATERIAL SAFETY DATA SHEET Trade Name: Johnsens All Purpose Cleaner 12/19 oz MSDS NO. 4722 Revision Date: Date Printed 12/02/2010 Page 5 of 5 16. OTHER INFORMATION Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied.