MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Radiator Flush MSDS NO. 4917 Revision Date: 05/26/2009 Date Printed 05/26/2009 Page 1 of 6 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Trade Name: Johnsens Radiator Flush Chemical Family: ALKALI Synonyms: None Emergency Telephone (24 hr.): CHEMTREC 1-800-424-9300 Supplier: Technical Chemical Company, P.O. Box 139, Cleburne, Texas 76033 2. COMPOSITION/INFORMATION ON INGREDIENTS Component Weight % OSHA TWA OSHA STEL OSHA SKIN Sodium 2- mercaptobenzothiazole 2492-26-4 6-8 Not Listed Not Listed Not Listed Sodium tetraborate 1330-43-4 3-4 Not Listed Not Listed Not Listed Sodium orthophosphate 7601-54-9 1-2 Not Listed Not Listed Not Listed Sodium hydroxide 1310-73-2 1-2 Not Listed Not Listed Not Listed Sodium nitrate 7631-99-4 .5-1 Not Listed Not Listed Not Listed Sodium metasilicate 6834-92-0 .1-1 Not Listed Not Listed Not Listed Polyoxyethylene- polyoxypropylene glycol 9003-11-6 .1-.5 Not Listed Not Listed Not Listed Component Weight % OSHA Z PEL OSHA Z TWA OSHA Z Ceiling Sodium 2- mercaptobenzothiazole 2492-26-4 6-8 Not Listed Not Listed Not Listed Sodium tetraborate 1330-43-4 3-4 Not Listed 10 mg/m3 Not Listed Sodium orthophosphate 7601-54-9 1-2 Not Listed Not Listed Not Listed Sodium hydroxide 1310-73-2 1-2 2 mg/m3 Not Listed Not Listed Sodium nitrate 7631-99-4 .5-1 Not Listed Not Listed Not Listed Sodium metasilicate 6834-92-0 .1-1 Not Listed Not Listed Not Listed Polyoxyethylene- polyoxypropylene glycol 9003-11-6 .1-.5 Not Listed Not Listed Not Listed MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Radiator Flush MSDS NO. 4917 Revision Date: 05/26/2009 Date Printed 05/26/2009 Page 2 of 6 Component ACGIH TLV TWA ACGIH TLV STEL ACGIH TLV Ceiling Sodium 2- mercaptobenzothiazole 2492-26-4 Not Listed Not Listed Not Listed Sodium tetraborate 1330-43-4 2 mg/m3 Inhalable fraction. 6 mg/m3 Inhalable fraction. Not Listed Sodium orthophosphate 7601-54-9 Not Listed Not Listed Not Listed Sodium hydroxide 1310-73-2 Not Listed Not Listed 2 mg/m3 Sodium nitrate 7631-99-4 Not Listed Not Listed Not Listed Sodium metasilicate 6834-92-0 Not Listed Not Listed Not Listed Polyoxyethylene- polyoxypropylene glycol 9003-11-6 Not Listed Not Listed Not Listed 3. HAZARDS IDENTIFICATION Emergency Overview: Avoid breathing vapors. Causes respiratory irritation. DANGER: CORROSIVE Avoid contact with skin and eyes. Causes severe eye irritation. Will damage tissue. HMIS Classification: Health: 3 Flammability: 1 Physical Hazard: 1 NFPA Rating: Health: 1 Flammability: 1 Reactivity: 0 4. FIRST AID MEASURES Eye Contact: In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing. Ingestion: If swallowed, do NOT induce vomiting. Call a physician immediately. Never give anything by mouth to an unconscious person. Inhalation: If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention. Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. 5. FIRE FIGHTING MEASURES Flammable Properties Flash Point ?F(?C): Not Determined Flash Point Method: Not Applicable Flammable Limits in Air - Lower (%): Not Determined Flammable Limits in Air - Upper (%): Not Determined Autoignition Temperature ?F(?C): Not Determined Extinguishing Media: Foam. Water. Dry chemical. Protection Of Fire-Fighters: Special Fire-Fighting Procedures: Wear approved positive-pressure self-contained breathing apparatus and protective clothing. Do not direct a solid stream of water or foam into hot, burning pools; this may cause frothing and increase fire intensity. Hazardous Combustion Products: Fumes and Smoke. Carbon Monoxide. Oxides of carbon, nitrogen and phosphorus. Sulfur oxides. Aerosol Comments: Not Applicable 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Wear appropriate protective clothing and equipment to prevent skin and eye contact. Spill Procedures: Contain any liquid from leaking containers. Action to be taken if material is released or spilled: Wear proper protective equipment as specified in the protective equipment section. Increase area ventilation. Absorb spills on inert material such as perlite, vermiculite, sand or dirt. Place in double polyethylene bags. Isolate from other waste materials. Environmental Precautions: Do not allow to enter sanitary drains, sewer or surface and subsurface waters. MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Radiator Flush MSDS NO. 4917 Revision Date: 05/26/2009 ted 05/26/2009 Page 3 of 6 Date Prin 7. HANDLING AND STORAGE Handling and Storage: Keep container closed when not in use. Avoid breathing vapors, if exposed to high vapor concentration, leave area at once. Avoid contact with skin and eyes. Use only in a well ventilated area. Keep away from food and smoking materials. Wash hands before eating and smoking. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls: Showers. Eyewash stations. Use in a well ventilated area. Eyes: Wear safety glasses or goggles to protect against exposure. Skin Protection: Use chemical resistant gloves for prolonged skin contact. Wash hands and other exposed areas with mild soap and water before eating, drinking, smoking and when leaving work. Respiratory Protection: Use in a well ventilated area. Use approved NIOSH respiratory protection if TLV exceeded..... Or over exposure is likely. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Liquid Odor: UNKNOWN pH Value: 10.8-11.2 Vapor Pressure: Not Determined Vapor Density (Air=1): Not Determined Boiling Point (?F): 212F Melting/Freezing Point: Not determined. Solubility in Water: SOLUBLE Bulk Density at 20?C: Not Determined Molecular Weight: Mixture Specific Gravity (H20=1): not determined Viscosity: Not determined. Evaporation Rate: Not Determined VOC Content(%): Not determined. Decomposition Temperature: Not Known 10. STABILITY AND REACTIVITY Chemical Stability: STABLE. Conditions to Avoid: Excessive heat. Incompatible materials. Materials to Avoid: Strong oxidizing agents. Strong acids. Flammables. Nitro and chloro organic compounds,metals (aluminum), and nitrous compounds Hazardous Decomposition Products: Carbon monoxide. Carbon dioxide. Oxides of nitrogen. Oxides of sulfur. Oxides of sodium. Oxides of phosphorus. Hazardous Polymerization: WILL NOT OCCUR 11. TOXICOLOGICAL INFORMATION Toxicological Data: MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Radiator Flush MSDS NO. 4917 Revision Date: 05/26/2009 Date Printed 05/26/2009 Page 4 of 6 Component Route Species Dose Sodium 2- mercaptobenzothiazole 2492-26-4 Oral Rats LD50 5200 mg/kg Sodium tetraborate 1330-43-4 Oral Rats LD50 3200 mg/kg Sodium orthophosphate 7601-54-9 Inhalation Rats Not known. Sodium hydroxide 1310-73-2 Oral Rats LD50 100 mg/kg Sodium nitrate 7631-99-4 Oral Rats LD50 4.3 grams/kg Sodium metasilicate 6834-92-0 Oral Rats LD50 770 mg/kg Polyoxyethylene- polyoxypropylene glycol 9003-11-6 Oral Rats LD50 1.72 grams/kg Carcinogenicity: Component IARC NTP OSHA Sodium 2- mercaptobenzothiazole 2492-26-4 Not Listed Not Listed Not Listed Sodium tetraborate 1330-43-4 Not Listed Not Listed Not Listed Sodium orthophosphate 7601-54-9 Not Listed Not Listed Not Listed Sodium hydroxide 1310-73-2 Not Listed Not Listed Not Listed Sodium nitrate 7631-99-4 Not Listed Not Listed Not Listed Sodium metasilicate 6834-92-0 Not Listed Not Listed Not Listed Polyoxyethylene- polyoxypropylene glycol 9003-11-6 Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Remarks: Ecological testing has not been conducted on this product. 13. DISPOSAL CONSIDERATION Waste Classification: Not determined. Waste Management: Not determined. Disposal Method: Disposal should be made in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION U.S. DOT: Proper Shipping Name: Not Regulated Hazard Class: Not Applicable UN/NA Number: Not Applicable DOT Packing Group: Not Applicable MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Radiator Flush MSDS NO. 4917 Revision Date: 05/26/2009 Date Printed 05/26/2009 Page 5 of 6 14. TRANSPORTATION INFORMATION IMDG: Proper Shipping Name: Not Regulated Hazard Class: Not Applicable Hazard Subclass: Not Applicable UN No.: Not Applicable Packing Group: Not Applicable Marine Pollutant: No 15. REGULATORY INFORMATION US Federal Regulations: Component SARA 313 SARA 302 TPQ RQ Sodium 2- mercaptobenzothiazole 2492-26-4 Not Listed Not Listed Not Listed Not Listed Sodium tetraborate 1330-43-4 Not Listed Not Listed Not Listed Not Listed Sodium orthophosphate 7601-54-9 Not Listed Not Listed Not Listed Not Listed Sodium hydroxide 1310-73-2 Not Listed Not Listed Not Listed Not Listed Sodium nitrate 7631-99-4 Listed. Not Listed Not Listed Not Listed Sodium metasilicate 6834-92-0 Not Listed Not Listed Not Listed Not Listed Polyoxyethylene- polyoxypropylene glycol 9003-11-6 Not Listed Not Listed Not Listed Not Listed SARA 311/312 Hazard Catagories: Not Determined. State Regulations: Component California Prop. 65 Cancer list California - Prop 65 Developmental Toxicity California Prop. 65 Reproductive Female California Prop. 65 Reproductive Male Sodium 2- mercaptobenzothiazole 2492-26-4 Not Listed Not Listed Not Listed Not Listed Sodium tetraborate 1330-43-4 Not Listed Not Listed Not Listed Not Listed Sodium orthophosphate 7601-54-9 Not Listed Not Listed Not Listed Not Listed Sodium hydroxide 1310-73-2 Not Listed Not Listed Not Listed Not Listed Sodium nitrate 7631-99-4 Not Listed Not Listed Not Listed Not Listed Sodium metasilicate 6834-92-0 Not Listed Not Listed Not Listed Not Listed Polyoxyethylene- polyoxypropylene glycol 9003-11-6 Not Listed Not Listed Not Listed Not Listed MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Radiator Flush MSDS NO. 4917 Revision Date: 05/26/2009 Date Printed 05/26/2009 Page 6 of 6 Component New Jersey Right-to-Know List: Sodium orthophosphate 7601-54-9 Substance no. 1724 Sodium hydroxide 1310-73-2 Substance no. 1706 Sodium nitrate 7631-99-4 Substance no. 1711 U.S. TSCA: The components of this product are listed on the TSCA Inventory. Canadian Inventory: One or more components of this product is not listed on the Canadian DSL or NDSL Inventory. Consumer Product Safety Improvement Act of 2008 General Conformity Certification The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product container. 16. OTHER INFORMATION General Notes: Do not allow undiluted material or large quantities to reach groundwater, bodies of water or sewer system. Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied.