MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Premium Starting Fluid 50% MSDS NO. 6732 Revision Date: 04/14/2009 Date Printed 04/14/2009 Page 1 of 6 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Trade Name: Johnsens Premium Starting Fluid 50% Chemical Family: ETHER Synonyms: None Emergency Telephone (24 hr.): 24-Hour Emergency Information: CHEMTREC (800) 424-9300 Supplier: Technical Chemical Company, P.O. Box 139, Cleburne, Texas 76033 2. COMPOSITION/INFORMATION ON INGREDIENTS Component Weight % OSHA TWA OSHA STEL OSHA SKIN Ethyl Ether 60-29-7 49-60 Not Listed Not Listed Not Listed Heptane 142-82-5 20-30 Not Listed Not Listed Not Listed Propane 74-98-6 5-15 Not Listed Not Listed Not Listed Carbon Dioxide 124-38-9 2-10 Not Listed Not Listed Not Listed Iso-Butane 75-28-5 2-10 Not Listed Not Listed Not Listed Lubricating Oil 64742-52-5 .5-5 Not Listed Not Listed Not Listed Component Weight % OSHA Z PEL OSHA Z TWA OSHA Z Ceiling Ethyl Ether 60-29-7 49-60 1200 mg/m3 400 ppm 1200 mg/m3 400 ppm Not Listed Heptane 142-82-5 20-30 2000 mg/m3 500 ppm 1600 mg/m3 400 ppm Not Listed Propane 74-98-6 5-15 1800 mg/m3 1000 ppm 1800 mg/m3 1000 ppm Not Listed Carbon Dioxide 124-38-9 2-10 9000 mg/m3 5000 ppm 18000 mg/m3 10000 ppm Not Listed Iso-Butane 75-28-5 2-10 Not Listed Not Listed Not Listed Lubricating Oil 64742-52-5 .5-5 2000 mg/m3 500 ppm 1600 mg/m3 400 ppm Not Listed MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Premium Starting Fluid 50% MSDS NO. 6732 Revision Date: 04/14/2009 Date Printed 04/14/2009 Page 2 of 6 Component ACGIH TLV TWA ACGIH TLV STEL ACGIH TLV Ceiling Ethyl Ether 60-29-7 400 ppm 500 ppm Not Listed Heptane 142-82-5 400 ppm 500 ppm Not Listed Propane 74-98-6 1000 ppm Not Listed Not Listed Carbon Dioxide 124-38-9 5000 ppm 30000 ppm Not Listed Iso-Butane 75-28-5 1000 ppm Not Listed Not Listed Lubricating Oil 64742-52-5 Not Listed Not Listed Not Listed Other: This product contains trace amounts of (<15 ppm) of Butylated hydroxytoluene (BHT) as an inhibitor to prevent or reduce the formation of potentially explosive peroxides. 3. HAZARDS IDENTIFICATION Emergency Overview: Danger: Extremely flammable. Breathing high concentrations of vapor or mist may cause nausea, vomiting, central nervous system (CNS) depression and asphyxiation. Symptoms may include headache, diziness, blurred vision, slurred speech, memory loss, confusion, faigue, loss of consciousness, convulsions, paralysis, or coma. This material is irritating to skin, eyes and respiratory tract. Keep away from heat, sparks and flame. Prolonged or repeated inhalation or ingestion may result in kidney and liver changes. HMIS Classification: Health: *2 Flammability: 4 Physical Hazard: 2 NFPA Rating: Health: 2 Flammability: 4 Reactivity: 1 4. FIRST AID MEASURES Eye Contact: In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing. Do not permit victim to rub eyes. Ingestion: If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person. Get medical attention! If vomiting occurs, keep head lower than hips to prevent aspiration. Inhalation: If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention. Skin Contact: Wash with soap and water for 15 minutes. If irritation persists or signs of toxicity occur, seek medical attention. Remove contaminated clothing and shoes, and launder before reuse. 5. FIRE FIGHTING MEASURES Flammable Properties Flash Point ?F(?C): -76 F Flash Point Method: TAG Closed Cup Flammable Limits in Air - Lower (%): 1.2% (Lowest Component) Flammable Limits in Air - Upper (%): 6.7% (Lowest Component) Autoignition Temperature ?F(?C): 356 F (Lowest Component) Extinguishing Media: Dry chemical. Carbon dioxide. Alcohol foam. Use water spray to keep containers cool that are exposed to heat or flames. Protection Of Fire-Fighters: Special Fire-Fighting Procedures: Wear approved positive-pressure self-contained breathing apparatus and protective clothing. Vapor may cause flash fire. Fight from a maximum distance or use unmanned hose holders or monitor nozzles. Containers can build up pressure if exposed to heat; cool with flooding quantities of water until well after the fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of vessel. Hazardous Combustion Products: Carbon Dioxide. Carbon Monoxide. Aerosol Comments: NFPA Level 3 Aerosol MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Premium Starting Fluid 50% MSDS NO. 6732 Revision Date: 04/14/2009 Date Printed 04/14/2009 Page 3 of 6 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Wear appropriate protective clothing and equipment to prevent skin and eye contact. Spill Procedures: Contain any liquid from leaking containers. Avoid all sources of ignition; heat, sparks and open flames. Action to be taken if material is released or spilled: Do not puncture or incinerate container. Contents under pressure. Wear proper protective equipment as specified in the protective equipment section. Remove sources of ignition. Leaking containers should be removed to an isolated, well-ventilated area and transferred to other suitable containers. Wipe, scrape, or soak up in an inert material and put in a container intended for flammable materials for disposal. Environmental Precautions: Do not allow to enter sanitary drains, sewer or surface and subsurface waters. Keep out of lakes, ponds or streams. 7. HANDLING AND STORAGE Handling and Storage: Caution: Contents under pressure. Keep away from heat and open flame. Use only in a well ventilated area. Avoid breathing vapors, if exposed to high vapor concentration, leave area at once. Avoid contact with skin and eyes. Do not puncture, incinerate or store above 120 F. Exposure to high temperatures may cuase bursting. DO NOT store in the passenger compartment of an automobile. Store in a cool, dry place, out of direct sunlight. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls: Use in a well ventilated area. Local exhaust ventilation as necessary to maintain exposures to within applicable limits. Eyes: Chemical goggles; also wear a face shield if splashing hazard exists. Skin Protection: Avoid skin contact. Wear protective clothing and gloves. Respiratory Protection: Do not breath mist or vapor. Use in a well ventilated area. Appropriate respiratory protection shall be worn when applied engineering controls are not adequate to protect against inhalation exposure. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Colorless to pale yellow liquid Odor: PUNGENT SWEET pH Value: Not Determined Vapor Pressure: Not Determined Vapor Density (Air=1): >1.5 Approximate Boiling Point (?F): -44 F (Lowest Component) Melting/Freezing Point: Freezing -176F (Ether) Solubility in Water: PARTLY SOLUBLE Bulk Density at 20?C: Not Determined Molecular Weight: Mixture Specific Gravity (H20=1): Not Determined Viscosity: Not Determined. Evaporation Rate: Not Determined VOC Content(%): Not determined. Decomposition Temperature: Not Determined 10. STABILITY AND REACTIVITY Chemical Stability: Stable under normal conditions of handling, use and transportation. Conditions to Avoid: Keep away from heat,sparks and flame. Avoid any source of ignition. Do not expose to heat or store at temperatures above 120 F. Materials to Avoid: Contact with oxidizing agents. Concentrated oxygen. Nitric acid. Avoid contact with chlorine in the presence of light. Hazardous Decomposition Products: Carbon monoxide. and other asphxiants. Explosive peroxides. Will react with nitric acid to form explosive nitrates. Hazardous Polymerization: WILL NOT OCCUR 11. TOXICOLOGICAL INFORMATION Toxicological Data: MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Premium Starting Fluid 50% MSDS NO. 6732 Revision Date: 04/14/2009 Date Printed 04/14/2009 Page 4 of 6 Component Route Species Dose Ethyl Ether 60-29-7 Inhalation Mice LC50 31000 ppm/30M Heptane 142-82-5 Inhalation Rats LC50 103 gm/m3/4H Propane 74-98-6 NA NA Not known. Carbon Dioxide 124-38-9 NA NA Not known. Iso-Butane 75-28-5 Inhalation Rats LC50 57 pph/15M Lubricating Oil 64742-52-5 NA NA Not known. Carcinogenicity: Component IARC NTP OSHA Ethyl Ether 60-29-7 Not Listed Not Listed Not Listed Heptane 142-82-5 Not Listed Not Listed Not Listed Propane 74-98-6 Not Listed Not Listed Not Listed Carbon Dioxide 124-38-9 Not Listed Not Listed Not Listed Iso-Butane 75-28-5 Not Listed Not Listed Not Listed Lubricating Oil 64742-52-5 Not Listed Not Listed Not Listed 12. ECOLOGICAL INFORMATION Remarks: Ecological testing has not been conducted on this product. 13. DISPOSAL CONSIDERATION Waste Classification: Residues and spilled material are hazardous waste due to ignitability. Waste Management: Not determined. Disposal Method: Disposal should be made in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION U.S. DOT: Proper Shipping Name: Consumer Commodity Hazard Class: ORM-D UN/NA Number: Not Applicable DOT Packing Group: Not Applicable IMDG: Proper Shipping Name: Aerosols Hazard Class: 2 Hazard Subclass: 2.1 UN No.: UN 1950 Packing Group: Not Applicable Marine Pollutant: No MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Premium Starting Fluid 50% MSDS NO. 6732 Revision Date: 04/14/2009 Date Printed 04/14/2009 Page 5 of 6 15. REGULATORY INFORMATION US Federal Regulations: Component SARA 313 SARA 302 TPQ RQ Ethyl Ether 60-29-7 Not Listed Not Listed Not Listed Not Listed Heptane 142-82-5 Not Listed Not Listed Not Listed Not Listed Propane 74-98-6 Not Listed Not Listed Not Listed Not Listed Carbon Dioxide 124-38-9 Not Listed Not Listed Not Listed Not Listed Iso-Butane 75-28-5 Not Listed Not Listed Not Listed Not Listed Lubricating Oil 64742-52-5 Not Listed Not Listed Not Listed Not Listed US OSHA HEALTH CLASSIFICATION: Hazardous per OSHA 29 CFR 1910.1200 SARA 311/312 Hazard Catagories: Immediate/Acute, Delayed/Chronic, Fire State Regulations: Component California Prop. 65 Cancer list California - Prop 65 Developmental Toxicity California Prop. 65 Reproductive Female California Prop. 65 Reproductive Male Ethyl Ether 60-29-7 Not Listed Not Listed Not Listed Not Listed Heptane 142-82-5 Not Listed Not Listed Not Listed Not Listed Propane 74-98-6 Not Listed Not Listed Not Listed Not Listed Carbon Dioxide 124-38-9 Not Listed Not Listed Not Listed Not Listed Iso-Butane 75-28-5 Not Listed Not Listed Not Listed Not Listed Lubricating Oil 64742-52-5 Not Listed Not Listed Not Listed Not Listed MATERIAL SAFETY DATA SHEET Trade Name: Johnsens Premium Starting Fluid 50% MSDS NO. 6732 Revision Date: 04/14/2009 Date Printed 04/14/2009 Page 6 of 6 Component New Jersey Right-to-Know List: Ethyl Ether 60-29-7 Substance no. 0701 Substance no. 2422 Substance no. 2423 Substance no. 2425 Substance no. 2426 Substance no. 2427 Substance no. 2428 Substance no. 2429 Substance no. 2430 Heptane 142-82-5 Substance no. 2422 Substance no. 2423 Substance no. 2425 Substance no. 2426 Substance no. 2427 Substance no. 2428 Substance no. 2429 Substance no. 2430 Substance no. 1339 Propane 74-98-6 Substance no. 2422 Substance no. 2423 Substance no. 2425 Substance no. 2426 Substance no. 2427 Substance no. 2428 Substance no. 2429 Substance no. 2430 Substance no. 1594 Carbon Dioxide 124-38-9 Substance no. 0343 Iso-Butane 75-28-5 Substance no. 2422 Substance no. 2423 Substance no. 2425 Substance no. 2426 Substance no. 2427 Substance no. 2428 Substance no. 2429 Substance no. 2430 Substance no. 1040 U.S. TSCA: The components of this product are listed on the TSCA Inventory. Canadian Inventory: The components of this product are listed on the Canadian DSL or NDSL Inventory. Consumer Product Safety Improvement Act of 2008 General Conformity Certification The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product container. 16. OTHER INFORMATION General Notes: Do not allow undiluted material or large quantities to reach groundwater, bodies of water or sewer system. Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied.