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Page: 1 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 1 / 24 29 CFR 1910.1200 (OSHA HazCom 2012) SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Trade name : Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER Recommended use of the chemical and restrictions on use Details of the supplier of the safety data sheet Niteo Products, LLC P.O. Box 191629 Dallas TX 75219 United States of America Emergency telephone number CHEMTREC DIRECT 1-800-424-9300 Product Information 1-844-696-4836 SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable aerosols : Category 1 Acute toxicity (Oral) : Category 4 Acute toxicity (Inhalation) : Category 4 Acute toxicity (Dermal) : Category 4 Skin irritation : Category 2 Eye irritation : Category 2A Specific target organ systemic toxicity - single exposure : Category 1 (Central nervous system, Eyes) Specific target organ systemic toxicity - single exposure : Category 3 (Respiratory system, Central nervous system) Specific target organ systemic toxicity - repeated exposure : Category 2 (Auditory system) Page: 2 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 2 / 24 Aspiration hazard : Category 1 GHS Label element Hazard pictograms : Signal Word : Danger Hazard Statements : Extremely flammable aerosol. Harmful if swallowed, in contact with skin or if inhaled. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Causes damage to organs (Central nervous system, Eyes). May cause damage to organs (Auditory system) through prolonged or repeated exposure. Precautionary Statements : Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear eye protection/ face protection. Wear protective gloves/ protective clothing. Response: IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or doctor/ physician if you feel unwell. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed: Call a POISON CENTER or doctor/ physician. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Take off contaminated clothing and wash before reuse. Storage: Store in a well-ventilated place. Keep container tightly closed. Page: 3 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 3 / 24 Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/ 122 ?F. Disposal: Dispose of contents/ container to an approved waste disposal plant. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Chemical nature : Static Accumulator Chemical nature : Defatter Hazardous components Chemical Name CAS-No. Classification Concentration (%) ACETONE 67-64-1 Flam. Liq. 2; H225 Eye Irrit. 2A; H319 STOT SE 3; H336 51.80 METHANOL 67-56-1 Flam. Liq. 2; H225 Acute Tox. 3; H301 Acute Tox. 3; H331 Acute Tox. 3; H311 STOT SE 1; H370 22.07 XYLENE 1330-20-7 Flam. Liq. 3; H226 Acute Tox. 4; H332 Acute Tox. 4; H312 Skin Irrit. 2; H315 20.12 Page: 4 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 4 / 24 Eye Irrit. 2A; H319 STOT SE 3; H335, H336 Asp. Tox. 1; H304 ETHYL BENZENE 100-41-4 Flam. Liq. 2; H225 Acute Tox. 4; H332 Skin Irrit. 2; H315 Eye Irrit. 2A; H319 STOT RE 2; H373 Asp. Tox. 1; H304 6.03 CARBON DIOXIDE 124-38-9 Press. Gas Liquefied gas; H280 6.00 SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Call a POISON CENTRE or doctor/physician if exposed or you feel unwell. Show this safety data sheet to the doctor in attendance. Symptoms of poisoning may appear several hours later. Do not leave the victim unattended. If inhaled : Move to fresh air. Keep patient warm and at rest. If unconscious place in recovery position and seek medical advice. Consult a physician after significant exposure. In case of skin contact : Remove contaminated clothing. If irritation develops, get medical attention. If on skin, rinse well with water. Wash contaminated clothing before re-use. Page: 5 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 5 / 24 In case of eye contact : Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. If swallowed : Obtain medical attention. Do NOT induce vomiting. Rinse mouth with water. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Most important symptoms and effects, both acute and delayed : This material (or a component) has produced hyperglycemia and ketosis following substantial ingestion. This product contains methanol which can cause intoxication and central nervous system depression. Methanol is metabolized to formic acid and formaldehyde. These metabolites can cause metabolic acidosis, visual disturbances and blindness. Since metabolism is required for these toxic symptoms, their onset may be delayed from 6 to 30 hours following ingestion. Ethanol competes for the same metabolic pathway and has been used to prevent methanol metabolism. Ethanol administration is indicated in symptomatic patients or at blood methanol concentrations above 20 ug/dl. Methanol is effectively removed by hemodialysis. Inhalation of high concentrations of this material, as could occur in enclosed spaces or during deliberate abuse, may be associated with cardiac arrhythmias. Sympathomimetic drugs may initiate cardiac arrhythmias in persons exposed to this material. Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include: redness of the skin stomach or intestinal upset (nausea, vomiting, diarrhea) irritation (nose, throat, airways) discomfort in the chest effects on memory muscle cramps pain in the abdomen and lower back Blurred vision Shortness of breath confusion irregular heartbeat cyanosis (causes blue coloring of the skin and nails from lack of oxygen) visual impairment (including blindness) Harmful if swallowed, in contact with skin or if inhaled May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Page: 6 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 6 / 24 Causes damage to organs. May cause damage to organs through prolonged or repeated exposure. Notes to physician : No hazards which require special first aid measures. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray Foam Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : High volume water jet Specific hazards during firefighting : Never use welding or cutting torch on or near drum (even empty) because product (even just residue) can ignite explosively. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products : carbon dioxide and carbon monoxide Hydrocarbons Aldehydes Specific extinguishing methods : Product is compatible with standard fire-fighting agents. Further information : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Use a water spray to cool fully closed containers. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Evacuate personnel to safe areas. Remove all sources of ignition. Use personal protective equipment. Page: 7 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 7 / 24 Ensure adequate ventilation. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Other information : Comply with all applicable federal, state, and local regulations. Suppress (knock down) gases/vapours/mists with a water spray jet. SECTION 7. HANDLING AND STORAGE Advice on safe handling : Open drum carefully as content may be under pressure. Provide sufficient air exchange and/or exhaust in work rooms. Do not breathe vapours/dust. Do not smoke. Container hazardous when empty. Take precautionary measures against static discharges. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. Smoking, eating and drinking should be prohibited in the application area. For personal protection see section 8. Dispose of rinse water in accordance with local and national regulations. Container may be opened only under exhaust ventilation hood. Conditions for safe storage : BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 ?C. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. No smoking. Electrical installations / working materials must comply with the technological safety standards. Page: 8 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 8 / 24 SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis ACETONE 67-64-1 TWA 500 ppm ACGIH STEL 750 ppm ACGIH REL 250 ppm 590 mg/m3 NIOSH/GUID E PEL 1,000 ppm 2,400 mg/m3 OSHA_TRA NS TWA 250 ppm ACGIHLIS_P STEL 500 ppm ACGIHLIS_P TWA 750 ppm 1,800 mg/m3 Z1A STEL 1,000 ppm 2,400 mg/m3 Z1A METHANOL 67-56-1 TWA 200 ppm ACGIH STEL 250 ppm ACGIH REL 200 ppm 260 mg/m3 NIOSH/GUID E STEL 250 ppm 325 mg/m3 NIOSH/GUID E PEL 200 ppm 260 mg/m3 OSHA_TRA NS TWA 200 ppm 260 mg/m3 TN OEL STEL 250 ppm 325 mg/m3 TN OEL XYLENE 1330-20-7 TWA 100 ppm ACGIH STEL 150 ppm ACGIH PEL 100 ppm 435 mg/m3 OSHA_TRA NS REL 100 ppm 435 mg/m3 NIOSH/GUID E STEL 150 ppm 655 mg/m3 NIOSH/GUID E ETHYL BENZENE 100-41-4 TWA 20 ppm ACGIH REL 100 ppm 435 mg/m3 NIOSH/GUID E STEL 125 ppm 545 mg/m3 NIOSH/GUID E PEL 100 ppm 435 mg/m3 OSHA_TRA NS CARBON DIOXIDE 124-38-9 TWA 5,000 ppm ACGIH STEL 30,000 ppm ACGIH REL 5,000 ppm NIOSH/GUID Page: 9 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 9 / 24 9,000 mg/m3 E STEL 30,000 ppm 54,000 mg/m3 NIOSH/GUID E PEL 5,000 ppm 9,000 mg/m3 OSHA_TRA NS Biological occupational exposure limits Components CAS-No. Control parameters Biological specimen Sampling time Permissible concentration Basis ACETONE 67-64-1 acetone Urine Sampling time: End of shift. 50 mg/l Remarks: Nonspecific METHANOL 67-56-1 methanol Urine Sampling time: End of shift. 15 mg/l Remarks: Background, Nonspecific XYLENE 1330-20- 7 Methylhippu ric acids Creatinine in urine Sampling time: End of shift. 1.5 g/g ETHYL BENZENE 100-41-4 Sum of mandelic acid and phenylglyox ylic acid Creatinine in urine Sampling time: End of shift. 0.15 g/g ACGIH BEI Remarks: Nonspecific Engineering measures : Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Personal protective equipment Respiratory protection : In the case of vapour formation use a respirator with an approved filter. In the case of dust or aerosol formation use respirator with an approved filter. A NIOSH-approved air-purifying respirator with an appropriate cartridge and/or filter may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits (if applicable) or if overexposure has otherwise been determined. Protection provided by air- purifying respirators is limited. Use a positive pressure, air- supplied respirator if there is any potential for uncontrolled release, exposure levels are not known or any other circumstances where an air-purifying respirator may not provide adequate protection. Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Page: 10 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 10 / 24 Eye protection : Wear chemical splash goggles when there is the potential for exposure of the eyes to liquid, vapor or mist. Skin and body protection : Wear as appropriate: impervious clothing Safety shoes Flame-resistant clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. Discard gloves that show tears, pinholes, or signs of wear. Wear resistant gloves (consult your safety equipment supplier). Hygiene measures : Wash hands before breaks and at the end of workday. When using do not eat or drink. When using do not smoke. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state : aerosol Odour : No data available Odour Threshold : No data available pH : No data available : No data available Boiling point/boiling range : 133 ?F / 56 ?C (1,013.232 hPa) Calculated Phase Transition Liquid/Gas Flash point : -4 ?F / -20 ?C Evaporation rate : No data available Flammability (solid, gas) : No data available No data available Flammability (liquids) : Static Accumulating liquid Flammability (liquids) : Flammability (liquids) : Upper explosion limit : 36 %(V) Calculated Explosive Limit Lower explosion limit : 1 %(V) Calculated Explosive Limit Page: 11 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 11 / 24 Vapour pressure : 307.9692 hPa (25 ?C) Calculated Vapor Pressure Relative vapour density : No data available Relative density : No data available Density : 0.8132 g/cm3 (15.56 ?C) Solubility(ies) Water solubility : No data available Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Thermal decomposition : No data available Viscosity Viscosity, dynamic : No data available Viscosity, kinematic : No data available Oxidizing properties : No data available Heat of combustion : Estimated 30.0 kJ/g SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. Chemical stability : Stable under recommended storage conditions. Possibility of hazardous reactions : Vapours may form explosive mixture with air. Conditions to avoid : Heat, flames and sparks. excessive heat Incompatible materials : Acids alkalis aluminum Amines Ammonia halogens Lead peroxides Page: 12 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 12 / 24 Reducing agents sodium strong bases Strong oxidizing agents Zinc Peroxides Hazardous decomposition products carbon dioxide and carbon monoxide formaldehyde-like Hydrocarbons SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation Skin contact Eye Contact Ingestion Acute toxicity Harmful if swallowed, in contact with skin or if inhaled Components: ACETONE: Acute oral toxicity : LD 50 (Rat, female): 5,800 mg/kg Acute inhalation toxicity : LC 50 (Rat, female): 76 mg/l Exposure time: 4 h Acute dermal toxicity : LD 50 (Rabbit): > 7,426 mg/kg METHANOL: Acute oral toxicity : LD L0 (Human): 300 mg/kg Assessment: The component/mixture is classified as acute oral toxicity, category 3. Acute inhalation toxicity : LC 50 (Rat): 64000 ppm Exposure time: 4 h Assessment: The component/mixture is classified as acute inhalation toxicity, category 3. Remarks: Slightly toxic by inhalation Acute dermal toxicity : LD 50 (Rabbit): 12,800 mg/kg Assessment: The component/mixture is classified as acute dermal toxicity, category 3. XYLENE: Acute oral toxicity : LD 50 (Rat): 3,523 - 8,600 mg/kg Acute inhalation toxicity : LC 50 (Rat): 6700 ppm Page: 13 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 13 / 24 Exposure time: 4 h Test atmosphere: vapour Assessment: The component/mixture is classified as acute inhalation toxicity, category 4. Acute dermal toxicity : LD 50 (Rabbit): 1,700 mg/kg ETHYL BENZENE: Acute oral toxicity : LD 50 (Rat): ca. 3,500 mg/kg Acute inhalation toxicity : LC50 (Rat): 4000 ppm Exposure time: 4 h Test atmosphere: vapour Acute dermal toxicity : LD 50 (Rabbit): 17,800 mg/kg Skin corrosion/irritation Causes skin irritation. Product: Remarks: May cause skin irritation and/or dermatitis. Result: Repeated exposure may cause skin dryness or cracking. Components: ACETONE: Result: Mildly irritating to skin Result: Repeated exposure may cause skin dryness or cracking. METHANOL: Species: Rabbit Result: Not irritating to skin XYLENE: Result: Irritating to skin ETHYL BENZENE: Result: Irritating to skin CARBON DIOXIDE: Result: Not irritating to skin Serious eye damage/eye irritation Causes serious eye irritation. Product: Remarks: Vapours may cause irritation to the eyes, respiratory system and the skin., Causes serious eye irritation. Components: ACETONE: Page: 14 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 14 / 24 Result: Irritating to eyes METHANOL: Species: Rabbit Result: Mildly irritating to eyes XYLENE: Result: Irritating to eyes ETHYL BENZENE: Result: Irritating to eyes Remarks: Exposure to a concentration of 5000 ppm causes intolerable irritation of the eyes CARBON DIOXIDE: Result: Not irritating to eyes Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information. Components: METHANOL: Test Type: Maximisation Test (GPMT) Species: Guinea pig Assessment: Does not cause skin sensitisation. Method: OECD Test Guideline 406 Germ cell mutagenicity Not classified based on available information. Carcinogenicity Not classified based on available information. Reproductive toxicity Not classified based on available information. STOT - single exposure May cause respiratory irritation. May cause drowsiness or dizziness. Causes damage to organs (Central nervous system, Eyes). Components: ACETONE: Exposure routes: Inhalation Target Organs: Nervous system Assessment: May cause drowsiness or dizziness. METHANOL: Target Organs: Central nervous system, Eyes Assessment: The substance or mixture is classified as specific target organ toxicant, single exposure, category 1. XYLENE: Assessment: May cause respiratory irritation., May cause drowsiness or dizziness. STOT - repeated exposure May cause damage to organs (Auditory system) through prolonged or repeated exposure. Page: 15 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 15 / 24 Components: ETHYL BENZENE: Target Organs: Auditory system Assessment: May cause damage to organs through prolonged or repeated exposure. Aspiration toxicity May be fatal if swallowed and enters airways. Product: May be fatal if swallowed and enters airways. Components: ACETONE: May be harmful if swallowed and enters airways. XYLENE: May be fatal if swallowed and enters airways. ETHYL BENZENE: May be fatal if swallowed and enters airways. Further information Product: Remarks: Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting., Concentrations substantially above the TLV value may cause narcotic effects., Solvents may degrease the skin. Components: METHANOL: Remarks: Central nervous system ETHYL BENZENE: Remarks: Central nervous system Carcinogenicity: IARC Group 2B: Possibly carcinogenic to humans ETHYL BENZENE 100-41-4 OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Page: 16 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 16 / 24 SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Components: ACETONE: Toxicity to fish : LC 50 (Rainbow trout,donaldson trout (Oncorhynchus mykiss)): 4,740 - 6,330 mg/l Exposure time: 96 h Test Type: static test LC 50 (Fathead minnow (Pimephales promelas)): 8,733 - 9,482 mg/l Exposure time: 96 h Test Type: flow-through test Toxicity to algae : NOEC (Microcystis aeruginosa): 530 mg/l Exposure time: 8 d Test Type: static test Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 2,112 mg/l Exposure time: 28 d Test Type: flow-through test METHANOL: Toxicity to fish : LC 50 (Rainbow trout,donaldson trout (Oncorhynchus mykiss)): 18,000 - 20,000 mg/l Exposure time: 96 h Test Type: static test Toxicity to daphnia and other aquatic invertebrates : EC 50 (Water flea (Daphnia magna)): > 10,000 mg/l Exposure time: 48 h Test Type: static test XYLENE: Toxicity to fish : LC 50 (Fathead minnow (Pimephales promelas)): 23.53 - 29.97 mg/l Exposure time: 96 h Test Type: static test Toxicity to daphnia and other aquatic invertebrates : LC 50 (Water flea (Daphnia magna)): > 100 - < 1,000 mg/l Exposure time: 24 h Test Type: static test ETHYL BENZENE: Toxicity to fish : LC 50 (Fathead minnow (Pimephales promelas)): 9.1 - 15.6 mg/l Exposure time: 96 h Test Type: static test Page: 17 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 17 / 24 LC 50 (Rainbow trout,donaldson trout (Oncorhynchus mykiss)): 4.2 mg/l Exposure time: 96 h Test Type: Renewal Toxicity to daphnia and other aquatic invertebrates : EC 50 (Water flea (Daphnia magna)): 1.37 - 4.4 mg/l Exposure time: 48 h Test Type: static test Toxicity to algae : (Pseudokirchneriella subcapitata (green algae)): 3.6 mg/l End point: EC 50 Exposure time: 96 h Test Type: Growth inhibition Persistence and degradability Components: ACETONE: Biodegradability : Result: Readily biodegradable Biodegradation: 90.9 % Exposure time: 28 d Method: OECD Test Guideline 301B METHANOL: Biodegradability : Biodegradation: 99 % Exposure time: 28 d Method: OECD Test Guideline 301D XYLENE: Physico-chemical removability : Remarks: The product evaporates readily. ETHYL BENZENE: Biodegradability : Result: Readily biodegradable Biodegradation: 70 - 80 % Exposure time: 28 d Bioaccumulative potential Components: ACETONE: Partition coefficient: n- octanol/water : log Pow: -0.24 METHANOL: Partition coefficient: n- octanol/water : log Pow: -0.77 XYLENE: Page: 18 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 18 / 24 Partition coefficient: n- octanol/water : log Pow: 3.16 ETHYL BENZENE: Partition coefficient: n- octanol/water : log Pow: 3.15 Mobility in soil Components: No data available Other adverse effects No data available Product: Additional ecological information : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal., Harmful to aquatic life. Components: SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods General advice : The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. Dispose of in accordance with all applicable local, state and federal regulations. Contaminated packaging : Empty remaining contents. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION International transport regulations REGULATION ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS SUBSIDIARY HAZARDS PACKING GROUP MARINE POLLUTANT / LTD. QTY. U.S. DOT - ROAD Page: 19 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 19 / 24 UN 1950 Aerosols 2.1 LIMITED QUANTITY U.S. DOT - RAIL UN 1950 Aerosols 2.1 LIMITED QUANTITY U.S. DOT - INLAND WATERWAYS UN 1950 Aerosols 2.1 LIMITED QUANTITY TRANSPORT CANADA - ROAD UN 1950 AEROSOLS 2.1 LIMITED QUANTITY TRANSPORT CANADA - RAIL UN 1950 AEROSOLS 2.1 LIMITED QUANTITY TRANSPORT CANADA - INLAND WATERWAYS UN 1950 AEROSOLS 2.1 LIMITED QUANTITY INTERNATIONAL MARITIME DANGEROUS GOODS UN 1950 AEROSOLS 2.1 LIMITED QUANTITY INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO UN 1950 Aerosols, flammable 2.1 INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER UN 1950 Aerosols, flammable 2.1 MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND WASTES UN 1950 AEROSOLES 2 *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Page: 20 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 20 / 24 Marine pollutant no Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) XYLENE 1330-20-7 100 496.985781 SARA 311/312 Hazards : Acute Health Hazard Fire Hazard Chronic Health Hazard SARA 313 Component(s) METHANOL 67-56-1 22.07 % XYLENE 1330-20-7 20.12 % ETHYL BENZENE 100-41-4 6.03 % Pennsylvania Right To Know ACETONE 67-64-1 50.00 - 70.00 % METHANOL 67-56-1 20.00 - 30.00 % XYLENE 1330-20-7 20.00 - 30.00 % ETHYL BENZENE 100-41-4 5.00 - 10.00 % CARBON DIOXIDE 124-38-9 5.00 - 10.00 % New Jersey Right To Know ACETONE 67-64-1 50.00 - 70.00 % METHANOL 67-56-1 20.00 - 30.00 % XYLENE 1330-20-7 20.00 - 30.00 % ETHYL BENZENE 100-41-4 5.00 - 10.00 % CARBON DIOXIDE 124-38-9 5.00 - 10.00 % Page: 21 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 21 / 24 California Prop 65 WARNING! This product contains a chemical known to the State of California to cause cancer. ETHYL BENZENE 100-41-4 BENZENE 71-43-2 WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. METHANOL 67-56-1 TOLUENE 108-88-3 BENZENE 71-43-2 The components of this product are reported in the following inventories: TSCA : On TSCA Inventory DSL : All components of this product are on the Canadian DSL. AICS : On the inventory, or in compliance with the inventory NZIOC : On the inventory, or in compliance with the inventory ENCS : On the inventory, or in compliance with the inventory KECI : On the inventory, or in compliance with the inventory PICCS : On the inventory, or in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) Page: 22 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 22 / 24 SECTION 16. OTHER INFORMATION Further information Revision Date: 07/31/2015 NFPA: HMIS III: NFPA Flammable and Combustible Liquids Classification Not applicable Full text of H-Statements referred to under sections 2 and 3. H225 Highly flammable liquid and vapor. H226 Flammable liquid and vapor. H280 Contains gas under pressure; may explode if heated. H301 Toxic if swallowed. H303 May be harmful if swallowed. H304 May be fatal if swallowed and enters airways. H305 May be harmful if swallowed and enters airways. H311 Toxic in contact with skin. H312 Harmful in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H331 Toxic if inhaled. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H370 Causes damage to organs. H373 May cause damage to organs through prolonged or repeated exposure. H401 Toxic to aquatic life. H402 Harmful to aquatic life. Sources of key data used to compile the Safety Data Sheet Internal data including own and sponsored test reports Flammability H e a lt h In s ta b ility 2 4 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 4 0 2* Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page: 23 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 23 / 24 The UNECE administers regional agreements implementing harmonised classification for labelling (GHS) and transport. Cefic, the European Chemical Industry Council. ESIS European Chemical Substances Information System The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Niteo's Environmental Health and Safety Department (1-844-696-4836). List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the ?International Air Transport Association? (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the ?International Civil Aviation Organization? IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health Page: 24 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0328421 Pyroil? LOW VOC NON-CHLR BRAKE PARTS CLEANER PYNCBPC13 Version: 1.1 24 / 24 OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System