Page: 1 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0197992 Pyroil? DOT 3 BRAKE FLUID PYBF32 Version: 1.1 1 / 22 29 CFR 1910.1200 (OSHA HazCom 2012) SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Trade name : Pyroil? DOT 3 BRAKE FLUID Recommended use of the chemical and restrictions on use Details of the supplier of the safety data sheet Niteo Products, LLC P.O. Box 191629 Dallas TX 75219 United States of America Emergency telephone number CHEMTREC DIRECT 1-800-424-9300 Product Information 1-844-696-4836 SECTION 2. HAZARDS IDENTIFICATION GHS Classification Serious eye damage : Category 1 Specific target organ systemic toxicity - repeated exposure (Oral) : Category 2 (Kidney) GHS Label element Hazard pictograms : Signal Word : Danger Hazard Statements : Causes serious eye damage. May cause damage to organs (Kidney) through prolonged or repeated exposure if swallowed. Precautionary Statements : Prevention: Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. Wear eye protection/ face protection. Response: IF IN EYES: Rinse cautiously with water for several minutes. Page: 2 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0197992 Pyroil? DOT 3 BRAKE FLUID PYBF32 Version: 1.1 2 / 22 Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Get medical advice/ attention if you feel unwell. Disposal: Dispose of contents/ container to an approved waste disposal plant. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Chemical nature : Defatter Hazardous components Chemical Name CAS-No. Classification Concentration (%) TRIETHYLENE GLYCOL MONOBUTYL ETHER 143-22-6 Eye Dam. 1; H318 25.00 TETRAETHYLENE GLYCOL 112-60-7 Not a hazardous substance or mixture. 20.00 POLYOXYETHYLENE MONOBUTYL ETHER 9004-77-7 Eye Dam. 1; H318 20.00 DIETHYLENE GLYCOL 111-46-6 Acute Tox. 4; H302 STOT RE 2; H373 10.00 PENTAETHYLENE GLYCOL 4792-15-8 Not a hazardous substance or mixture. 10.00 TRISODIUM PHOSPHATE 7601-54-9 Skin Irrit. 2; H315 Eye Irrit. 2A; H319 STOT SE 3; H335 5.00 Page: 3 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0197992 Pyroil? DOT 3 BRAKE FLUID PYBF32 Version: 1.1 3 / 22 DIETHYLENE GLYCOL MONOBUTYL ETHER 112-34-5 Eye Irrit. 2A; H319 5.00 DIISOPROPANOLAMINE 110-97-4 Eye Irrit. 2A; H319 3.00 SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : If breathed in, move person into fresh air. If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : Remove contaminated clothing. If irritation develops, get medical attention. If on skin, rinse well with water. Wash contaminated clothing before re-use. In case of eye contact : In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Continue rinsing eyes during transport to hospital. Remove contact lenses. Protect unharmed eye. If swallowed : Obtain medical attention. Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Most important symptoms and effects, both acute and delayed : Excessive levels of phosphorus can cause low blood calcium, with tetany and convulsions. Diglycol ethers may cause acidosis. Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include: stomach or intestinal upset (nausea, vomiting, diarrhea) irritation (nose, throat, airways) Cough pain in the abdomen and lower back Page: 4 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0197992 Pyroil? DOT 3 BRAKE FLUID PYBF32 Version: 1.1 4 / 22 Blurred vision lung edema (fluid buildup in the lung tissue) acute kidney failure (sudden slowing or stopping of urine production) Difficulty in breathing Causes serious eye damage. May cause damage to organs through prolonged or repeated exposure if swallowed. Notes to physician : SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray Foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : High volume water jet Specific hazards during firefighting : If product is heated above its flash point it will produce vapors sufficient to support combustion. Vapors are heavier than air and may travel along the ground and be ignited by heat, pilot lights, other flames and ignition sources at locations near the point of release. Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products : carbon dioxide and carbon monoxide various hydrocarbons Hydrocarbons Alcohols ethers Ketones Oxides of phosphorus Sodium oxides Aldehydes Organic acids Nitrogen oxides (NOx) Specific extinguishing methods : Product is compatible with standard fire-fighting agents. Further information : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Page: 5 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0197992 Pyroil? DOT 3 BRAKE FLUID PYBF32 Version: 1.1 5 / 22 Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. Other information : Comply with all applicable federal, state, and local regulations. SECTION 7. HANDLING AND STORAGE Advice on safe handling : Do not breathe vapours/dust. Do not smoke. Container hazardous when empty. Avoid contact with skin and eyes. Smoking, eating and drinking should be prohibited in the application area. For personal protection see section 8. Dispose of rinse water in accordance with local and national regulations. Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place. Electrical installations / working materials must comply with the technological safety standards. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis TETRAETHYLENE GLYCOL 112-60-7 TWA 10 mg/m3 Particulate. WEEL DIETHYLENE GLYCOL 111-46-6 TWA 10 mg/m3 WEEL Page: 6 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0197992 Pyroil? DOT 3 BRAKE FLUID PYBF32 Version: 1.1 6 / 22 PENTAETHYLENE GLYCOL 4792-15-8 TWA 10 mg/m3 Particulate. WEEL TRISODIUM PHOSPHATE 7601-54-9 STEL 5 mg/m3 WEEL DIETHYLENE GLYCOL MONOBUTYL ETHER 112-34-5 TWA 10 ppm Inhalable fraction and vapor ACGIH DIISOPROPANOLAMINE 110-97-4 TWA 10 ppm SUPLR EXP TWA 10 ppm SUPLR EXP TWA 10 ppm SUPLR EXP TWA 10 ppm SUPLR EXP Engineering measures : Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Personal protective equipment Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Wear chemical splash goggles and face shield when there is potential for exposure of the eyes or face to liquid, vapor or mist. Maintain eye wash station in immediate work area. Skin and body protection : Wear as appropriate: impervious clothing Safety shoes Choose body protection according to the amount and concentration of the dangerous substance at the work place. Wear resistant gloves (consult your safety equipment supplier). Hygiene measures : Wash hands before breaks and at the end of workday. When using do not eat or drink. When using do not smoke. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state : liquid Colour : clear, yellow Odour : mild Odour Threshold : No data available pH : +/- 1.8 9.3 Melting point/freezing point : -58 ?F / -50 ?C Page: 7 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0197992 Pyroil? DOT 3 BRAKE FLUID PYBF32 Version: 1.1 7 / 22 Boiling point/boiling range : 401 ?F / 205 ?C (1013 hPa) Flash point : 275 ?F / 135 ?C Method: Tag closed cup Evaporation rate : < 0.01 n-Butyl Acetate Flammability (solid, gas) : No data available Upper explosion limit : 36 %(V) Calculated Explosive Limit Lower explosion limit : 0.9 %(V) Calculated Explosive Limit Vapour pressure : 169.3164 hPa (25 ?C) Calculated Vapor Pressure Relative vapour density : 6AIR=1 Relative density : 1.039 (20 ?C) Density : Average 1.035 g/cm3 (4 ?C) Solubility(ies) Water solubility : soluble Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Thermal decomposition : No data available Viscosity Viscosity, dynamic : No data available Viscosity, kinematic : No data available Oxidizing properties : No data available SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. Chemical stability : Stable under recommended storage conditions. Possibility of hazardous : Product will not undergo hazardous polymerization. Page: 8 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0197992 Pyroil? DOT 3 BRAKE FLUID PYBF32 Version: 1.1 8 / 22 reactions Conditions to avoid : Avoid heat, open flame, and prolonged storage at elevated temperatures. excessive heat temperatures above 150 degrees F (66 ?C) Do not allow evaporation to dryness. Exposure to moisture Incompatible materials : Avoid contact with: Acids aluminum Amines Ammonia Bases Copper galvanized metals halogenated hydrocarbons magnesium nitrites Organic materials Reducing agents strong alkalis Strong oxidizing agents Zinc This product should not be used in conjunction with trimethylol propane or trimethylol propane-derived products. There is a possibility that bicyclic phosphates or phosphites can be produced as a result of the thermal decomposition of this product in combination with trimethylol propane, trimethylol propane-derived products or their corresponding trimethylol propane alkane homologs. Bicyclic phosphates and phosphites are a class of materials with acute neurotoxic properties which produce characteristic convulsive seizures in test animals. Hazardous decomposition products Alcohols Aldehydes carbon dioxide and carbon monoxide ethers Hydrocarbons Nitrogen oxides (NOx) Organic acids Oxides of phosphorus Sodium oxides ketones SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of : Inhalation Page: 9 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0197992 Pyroil? DOT 3 BRAKE FLUID PYBF32 Version: 1.1 9 / 22 exposure Skin contact Eye Contact Ingestion Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Remarks: Ingestion of medications contaminated with diethylene glycol has caused kidney failure and death in humans. Products containing diethylene glycol should be considered toxic by ingestion. Acute dermal toxicity : Remarks: Skin absorption of this material (or a component) may be increased through injured skin. Components: TRIETHYLENE GLYCOL MONOBUTYL ETHER: Acute oral toxicity : LD 50 (Rat): 5,300 mg/kg Acute dermal toxicity : LD 50 (Rabbit): 3,502 mg/kg TETRAETHYLENE GLYCOL: Acute oral toxicity : LD 50 (Rat): ca. 30,000 mg/kg Acute dermal toxicity : LD 50 (Rabbit): 22,460 mg/kg POLYOXYETHYLENE MONOBUTYL ETHER: Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 401 Acute dermal toxicity : LD50 (Rabbit): 3,540 mg/kg DIETHYLENE GLYCOL: Acute oral toxicity : LD50 (Human): Expected 1,120 mg/kg Target Organs: Kidney Acute inhalation toxicity : LC50 (Rat): > 4.6 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: No adverse effect has been observed in acute inhalation toxicity tests. Acute dermal toxicity : LD 50 (Rabbit): 13,300 mg/kg TRISODIUM PHOSPHATE: Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 420 Acute inhalation toxicity : LD 50 (Rat): > 0.83 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403 Page: 10 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0197992 Pyroil? DOT 3 BRAKE FLUID PYBF32 Version: 1.1 10 / 22 Assessment: Not classified as acutely toxic by inhalation under GHS. Remarks: Information given is based on data obtained from similar substances. Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 402 Assessment: Not classified as acutely toxic by dermal absorption under GHS. Remarks: Information given is based on data obtained from similar substances. DIETHYLENE GLYCOL MONOBUTYL ETHER: Acute oral toxicity : LD 50 (Rat): 3,305 mg/kg Acute dermal toxicity : LD 50 (Rabbit): 2,734 mg/kg DIISOPROPANOLAMINE: Acute oral toxicity : LD 50 (Rat): > 2,000 mg/kg Assessment: No adverse effect has been observed in acute oral toxicity tests. Acute dermal toxicity : LD 50 (Rabbit): 8,000 mg/kg Skin corrosion/irritation Not classified based on available information. Product: Result: Repeated exposure may cause skin dryness or cracking. Components: TRIETHYLENE GLYCOL MONOBUTYL ETHER: Result: Not irritating to skin TETRAETHYLENE GLYCOL: Result: Not irritating to skin POLYOXYETHYLENE MONOBUTYL ETHER: Result: Slightly irritating to skin DIETHYLENE GLYCOL: Species: Human Result: Slightly irritating to skin PENTAETHYLENE GLYCOL: Result: Slightly irritating to skin TRISODIUM PHOSPHATE: Result: Irritating to skin DIETHYLENE GLYCOL MONOBUTYL ETHER: Result: Slightly irritating to skin Page: 11 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0197992 Pyroil? DOT 3 BRAKE FLUID PYBF32 Version: 1.1 11 / 22 DIISOPROPANOLAMINE: Result: Not irritating to skin Serious eye damage/eye irritation Causes serious eye damage. Product: Remarks: May cause irreversible eye damage. Components: TRIETHYLENE GLYCOL MONOBUTYL ETHER: Result: Corrosive to eyes TETRAETHYLENE GLYCOL: Result: Mildly irritating to eyes POLYOXYETHYLENE MONOBUTYL ETHER: Result: Corrosive to eyes DIETHYLENE GLYCOL: Species: Rabbit Result: Slightly irritating to eyes PENTAETHYLENE GLYCOL: Result: Slightly irritating to eyes TRISODIUM PHOSPHATE: Result: Irritating to eyes DIETHYLENE GLYCOL MONOBUTYL ETHER: Result: Severely irritating to eyes DIISOPROPANOLAMINE: Result: Severely irritating to eyes Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information. Components: POLYOXYETHYLENE MONOBUTYL ETHER: Test Type: Maximisation Test (GPMT) Species: Guinea pig Method: OECD Test Guideline 406 Result: Did not cause sensitisation on laboratory animals. DIETHYLENE GLYCOL: Test Type: Maximisation Test (GPMT) Species: Guinea pig Method: Directive 67/548/EEC, Annex V, B.6. Result: Did not cause sensitisation on laboratory animals. TRISODIUM PHOSPHATE: Test Type: Local lymph node assay Species: Mouse Page: 12 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0197992 Pyroil? DOT 3 BRAKE FLUID PYBF32 Version: 1.1 12 / 22 Assessment: Did not cause sensitisation on laboratory animals. Method: OECD Test Guideline 429 DIETHYLENE GLYCOL MONOBUTYL ETHER: Test Type: Maximisation Test (GPMT) Species: Guinea pig Result: Did not cause sensitisation on laboratory animals. Germ cell mutagenicity Not classified based on available information. Components: DIETHYLENE GLYCOL: Genotoxicity in vitro : Test Type: Ames test Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative GLP: yes : Test species: Chinese hamster ovary cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 479 Result: negative GLP: yes Genotoxicity in vivo : Test Type: In vivo micronucleus test Test species: Mouse Method: OECD Test Guideline 474 Result: negative GLP: yes PENTAETHYLENE GLYCOL: Genotoxicity in vitro : Test Type: Chromosome aberration test in vitro Result: negative Genotoxicity in vivo : Test Type: In vivo micronucleus test Test species: Mouse Cell type: Bone marrow Result: negative TRISODIUM PHOSPHATE: Genotoxicity in vitro : Test Type: Ames test Test species: Salmonella typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative Remarks: Information given is based on data obtained from similar substances. DIETHYLENE GLYCOL MONOBUTYL ETHER: Genotoxicity in vitro : Remarks: In vitro tests did not show mutagenic effects Genotoxicity in vivo : Result: In vivo tests did not show mutagenic effects Page: 13 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0197992 Pyroil? DOT 3 BRAKE FLUID PYBF32 Version: 1.1 13 / 22 Carcinogenicity Not classified based on available information. Reproductive toxicity Not classified based on available information. Components: DIETHYLENE GLYCOL MONOBUTYL ETHER: Effects on fertility : Symptoms: No effects on fertility STOT - single exposure Not classified based on available information. Components: TRISODIUM PHOSPHATE: Exposure routes: Inhalation Target Organs: Respiratory Tract Assessment: May cause respiratory irritation. STOT - repeated exposure May cause damage to organs (Kidney) through prolonged or repeated exposure if swallowed. Components: DIETHYLENE GLYCOL: Exposure routes: Ingestion Target Organs: Kidney Assessment: May cause damage to organs through prolonged or repeated exposure. Repeated dose toxicity Components: DIETHYLENE GLYCOL MONOBUTYL ETHER: NOAEL: 250 mg/kg LOAEL: 1,000 mg/kg Application Route: Oral Target Organs: Blood Aspiration toxicity Not classified based on available information. Experience with human exposure Components: DIETHYLENE GLYCOL: Liver Further information Product: Remarks: No data available Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen Page: 14 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0197992 Pyroil? DOT 3 BRAKE FLUID PYBF32 Version: 1.1 14 / 22 by NTP. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity TETRAETHYLENE GLYCOL: Toxicity to fish : LC 50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : LC 50 (Water flea (Daphnia magna)): 7,746 mg/l Exposure time: 48 h Toxicity to algae : IC50 (Pseudokirchneriella subcapitata (green algae)): > 1,000 mg/l POLYOXYETHYLENE MONOBUTYL ETHER: Toxicity to fish : LC50 (Flatfish, flounder (Scophthalmus maximus)): > 1,800 mg/l Exposure time: 96 h Test Type: semi-static test Method: OECD Test Guideline 203 Toxicity to algae : ErC50 (Skeletonema costatum (marine diatom)): 391 mg/l Exposure time: 72 h DIETHYLENE GLYCOL: Toxicity to fish : LC 50 (Fathead minnow (Pimephales promelas)): 75,210 mg/l Exposure time: 96 h Test Type: flow-through test Toxicity to daphnia and other aquatic invertebrates : LC 50 (Water flea (Daphnia magna)): > 10,000 mg/l Exposure time: 24 h Test Type: static test Method: DIN 38412 TRISODIUM PHOSPHATE: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l Exposure time: 96 h Test Type: semi-static test Method: OECD Test Guideline 203 Remarks: Information given is based on data obtained from similar substances. Toxicity to daphnia and other aquatic invertebrates : EC50 (Water flea (Daphnia magna)): > 100 mg/l Exposure time: 48 h Test Type: static test Method: OECD Test Guideline 202 Remarks: Information given is based on data obtained from similar substances. Page: 15 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0197992 Pyroil? DOT 3 BRAKE FLUID PYBF32 Version: 1.1 15 / 22 Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): > 100 mg/l End point: Growth inhibition Exposure time: 72 h Test Type: static test Method: OECD Test Guideline 201 Remarks: Information given is based on data obtained from similar substances. NOEC (Desmodesmus subspicatus (green algae)): > 100 mg/l End point: Growth inhibition Exposure time: 72 h Test Type: static test Method: OECD Test Guideline 201 Remarks: Information given is based on data obtained from similar substances. DIETHYLENE GLYCOL MONOBUTYL ETHER: Toxicity to fish : LC 50 (Bluegill (Lepomis macrochirus)): 1,300 mg/l Exposure time: 96 h Test Type: static test Toxicity to daphnia and other aquatic invertebrates : LC 50 (Water flea (Daphnia magna)): 2,850 mg/l Exposure time: 24 h Method: Static Remarks: Mortality EC 50 (Water flea (Daphnia magna)): > 100 mg/l Exposure time: 48 h Test Type: static test Toxicity to algae : (Desmodesmus subspicatus (green algae)): > 100 mg/l End point: EC 50 Exposure time: 96 h Test Type: static test Toxicity to bacteria : EC 50 (Bacteria): > 100 mg/l Exposure time: 96 h Test Type: Static DIISOPROPANOLAMINE: Toxicity to fish : LC 50 (Carassius auratus (goldfish)): 1,100 mg/l Exposure time: 24 h Test Type: static test Persistence and degradability TETRAETHYLENE GLYCOL: Biodegradability : Biodegradation: 40 % Exposure time: 28 d Method: OECD Test Guideline 301D DIETHYLENE GLYCOL: Page: 16 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0197992 Pyroil? DOT 3 BRAKE FLUID PYBF32 Version: 1.1 16 / 22 Biodegradability : Result: Readily biodegradable Biodegradation: 70 - 80 % Exposure time: 28 d Method: OECD Test Guideline 301B TRISODIUM PHOSPHATE: Biodegradability : Remarks: The methods for determining biodegradability are not applicable to inorganic substances. DIETHYLENE GLYCOL MONOBUTYL ETHER: Biodegradability : Biodegradation: 89 % Exposure time: 28 d Method: OECD Test Guideline 301C Remarks: Readily biodegradable Bioaccumulative potential TETRAETHYLENE GLYCOL: Partition coefficient: n- octanol/water : log Pow: Estimated -2.30 DIETHYLENE GLYCOL: Bioaccumulation : Species: Leuciscus idus (Golden orfe) Bioconcentration factor (BCF): 100 Partition coefficient: n- octanol/water : log Pow: -1.47 PENTAETHYLENE GLYCOL: Partition coefficient: n- octanol/water : log Pow: -2.3 DIETHYLENE GLYCOL MONOBUTYL ETHER: Bioaccumulation : Remarks: Bioaccumulation is unlikely. Partition coefficient: n- octanol/water : log Pow: 1 DIISOPROPANOLAMINE: Partition coefficient: n- octanol/water : log Pow: -0.82 Mobility in soil No data available Other adverse effects No data available Product: Additional ecological information : No data available Page: 17 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0197992 Pyroil? DOT 3 BRAKE FLUID PYBF32 Version: 1.1 17 / 22 SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods General advice : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. Dispose of in accordance with all applicable local, state and federal regulations. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. SECTION 14. TRANSPORT INFORMATION International transport regulations REGULATION ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS SUBSIDIARY HAZARDS PACKING GROUP MARINE POLLUTANT / LTD. QTY. U.S. DOT - ROAD Not dangerous goods U.S. DOT - RAIL Not dangerous goods U.S. DOT - INLAND WATERWAYS Not dangerous goods TRANSPORT CANADA - ROAD Not dangerous goods TRANSPORT CANADA - RAIL Not dangerous goods TRANSPORT CANADA - INLAND WATERWAYS Not dangerous goods Page: 18 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0197992 Pyroil? DOT 3 BRAKE FLUID PYBF32 Version: 1.1 18 / 22 INTERNATIONAL MARITIME DANGEROUS GOODS Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO Not dangerous goods INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER Not dangerous goods MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND WASTES Not dangerous goods *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Marine pollutant no Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) TRISODIUM PHOSPHATE 7601-54-9 5000 100000 SARA 311/312 Hazards : Acute Health Hazard Chronic Health Hazard SARA 313 Component(s) TRIETHYLENE GLYCOL MONOETHYL ETHER 112-50-5 40.00 % TRIETHYLENE GLYCOL MONOMETHYL ETHER 112-35-6 30.00 % TRIETHYLENE GLYCOL MONOBUTYL ETHER 143-22-6 25.00 % Page: 19 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0197992 Pyroil? DOT 3 BRAKE FLUID PYBF32 Version: 1.1 19 / 22 DIETHYLENE GLYCOL MONOBUTYL ETHER 112-34-5 5.00 % Pennsylvania Right To Know POLYETHYLENE GLYCOL MONOMETHYL ETHER 9004-74-4 50.00 - 70.00 % TRIETHYLENE GLYCOL MONOETHYL ETHER 112-50-5 30.00 - 50.00 % TRIETHYLENE GLYCOL MONOMETHYL ETHER 112-35-6 30.00 - 50.00 % TRIETHYLENE GLYCOL MONOBUTYL ETHER 143-22-6 20.00 - 30.00 % TETRAETHYLENE GLYCOL 112-60-7 20.00 - 30.00 % POLYOXYETHYLENE MONOBUTYL ETHER 9004-77-7 20.00 - 30.00 % DIETHYLENE GLYCOL 111-46-6 10.00 - 20.00 % PENTAETHYLENE GLYCOL 4792-15-8 10.00 - 20.00 % POLYETHYLENE GLYCOL 25322-68-3 5.00 - 10.00 % TRISODIUM PHOSPHATE 7601-54-9 5.00 - 10.00 % DIETHYLENE GLYCOL MONOBUTYL ETHER 112-34-5 5.00 - 10.00 % DIISOPROPANOLAMINE 110-97-4 1.00 - 5.00 % New Jersey Right To Know POLYETHYLENE GLYCOL MONOMETHYL ETHER 9004-74-4 50.00 - 70.00 % TRIETHYLENE GLYCOL MONOETHYL ETHER 112-50-5 30.00 - 50.00 % TRIETHYLENE GLYCOL MONOMETHYL ETHER 112-35-6 30.00 - 50.00 % TRIETHYLENE GLYCOL MONOBUTYL ETHER 143-22-6 20.00 - 30.00 % TETRAETHYLENE GLYCOL 112-60-7 20.00 - 30.00 % POLYOXYETHYLENE MONOBUTYL ETHER 9004-77-7 20.00 - 30.00 % TRISODIUM PHOSPHATE 7601-54-9 5.00 - 10.00 % Page: 20 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0197992 Pyroil? DOT 3 BRAKE FLUID PYBF32 Version: 1.1 20 / 22 DIETHYLENE GLYCOL MONOBUTYL ETHER 112-34-5 5.00 - 10.00 % California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: ENCS : On the inventory, or in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory AICS : On the inventory, or in compliance with the inventory TSCA : On TSCA Inventory KECI : Not in compliance with the inventory PICCS : Not in compliance with the inventory DSL : All components of this product are on the Canadian DSL. Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) SECTION 16. OTHER INFORMATION Further information Revision Date: 07/31/2015 NFPA: HMIS III: NFPA Flammable and Combustible Liquids Classification Flammability H e a lt h In s ta b ility 2 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 2* Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page: 21 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0197992 Pyroil? DOT 3 BRAKE FLUID PYBF32 Version: 1.1 21 / 22 Combustible Liquid Class IIIB Full text of H-Statements referred to under sections 2 and 3. H302 Harmful if swallowed. H303 May be harmful if swallowed. H313 May be harmful in contact with skin. H315 Causes skin irritation. H318 Causes serious eye damage. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure if swallowed. Sources of key data used to compile the Safety Data Sheet Internal data including own and sponsored test reports The UNECE administers regional agreements implementing harmonised classification for labelling (GHS) and transport. Cefic, the European Chemical Industry Council. ESIS European Chemical Substances Information System The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Niteo's Environmental Health and Safety Department (1-844-696-4836). List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the ?International Air Transport Association? (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the ?International Civil Aviation Organization? IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit Page: 22 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0197992 Pyroil? DOT 3 BRAKE FLUID PYBF32 Version: 1.1 22 / 22 P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System