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Page: 1 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0326703 Pyroil? GAS TREAT GAS TREATMENT PYAG12P Version: 1.1 1 / 16 29 CFR 1910.1200 (OSHA HazCom 2012) SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Trade name : Pyroil? GAS TREAT GAS TREATMENT Recommended use of the chemical and restrictions on use Use of the Substance/Mixture : Personal care Details of the supplier of the safety data sheet Niteo Products, LLC P.O. Box 191629 Dallas TX 75219 United States of America Emergency telephone number CHEMTREC DIRECT 1-800-424-9300 Product Information 1-844-696-4836 SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids : Category 3 Skin irritation : Category 2 Specific target organ systemic toxicity - single exposure : Category 3 (Central nervous system) Aspiration hazard : Category 1 GHS Label element Hazard pictograms : Signal Word : Danger Hazard Statements : Flammable liquid and vapor. May be fatal if swallowed and enters airways. Causes skin irritation. Page: 2 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0326703 Pyroil? GAS TREAT GAS TREATMENT PYAG12P Version: 1.1 2 / 16 May cause drowsiness or dizziness. Precautionary Statements : Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ ventilating/ lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. Wash skin thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/ eye protection/ face protection. Response: IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/ attention. Take off contaminated clothing and wash before reuse. In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. Storage: Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up. Disposal: Dispose of contents/ container to an approved waste disposal plant. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Chemical nature : Defatter Hazardous components Chemical Name CAS-No. Classification Concentration (%) KEROSENE 8008-20-6 Flam. Liq. 3; H226 Skin Irrit. 2; H315 97.22 Page: 3 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0326703 Pyroil? GAS TREAT GAS TREATMENT PYAG12P Version: 1.1 3 / 16 STOT SE 3; H336 Asp. Tox. 1; H304 SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Call a POISON CENTRE or doctor/physician if exposed or you feel unwell. Show this safety data sheet to the doctor in attendance. Symptoms of poisoning may appear several hours later. Do not leave the victim unattended. If inhaled : Move to fresh air. If unconscious place in recovery position and seek medical advice. Consult a physician after significant exposure. In case of skin contact : Remove contaminated clothing. If irritation develops, get medical attention. If on skin, rinse well with water. Wash contaminated clothing before re-use. If on clothes, remove clothes. In case of eye contact : Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. If eye irritation persists, consult a specialist. If swallowed : Obtain medical attention. Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Most important symptoms and effects, both acute and delayed : Inhalation of high concentrations of this material, as could occur in enclosed spaces or during deliberate abuse, may be associated with cardiac arrhythmias. Sympathomimetic drugs may initiate cardiac arrhythmias in persons exposed to this material. Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include: stomach or intestinal upset (nausea, vomiting, diarrhea) irritation (nose, throat, airways) Lung irritation Page: 4 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0326703 Pyroil? GAS TREAT GAS TREATMENT PYAG12P Version: 1.1 4 / 16 confusion irregular heartbeat Convulsions May be fatal if swallowed and enters airways. Causes skin irritation. May cause drowsiness or dizziness. Notes to physician : No hazards which require special first aid measures. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray Foam Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : High volume water jet Specific hazards during firefighting : Never use welding or cutting torch on or near drum (even empty) because product (even just residue) can ignite explosively. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products : Aldehydes carbon dioxide and carbon monoxide Hydrocarbons Nitrogen oxides (NOx) sulfur oxides Specific extinguishing methods : Product is compatible with standard fire-fighting agents. Further information : Do not use a solid water stream as it may scatter and spread fire. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Use a water spray to cool fully closed containers. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. Page: 5 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0326703 Pyroil? GAS TREAT GAS TREATMENT PYAG12P Version: 1.1 5 / 16 SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Evacuate personnel to safe areas. Remove all sources of ignition. Use personal protective equipment. Ensure adequate ventilation. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Other information : Comply with all applicable federal, state, and local regulations. Suppress (knock down) gases/vapours/mists with a water spray jet. SECTION 7. HANDLING AND STORAGE Advice on safe handling : Open drum carefully as content may be under pressure. Avoid formation of aerosol. Provide sufficient air exchange and/or exhaust in work rooms. Do not breathe vapours/dust. Do not smoke. Container hazardous when empty. Take precautionary measures against static discharges. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. Smoking, eating and drinking should be prohibited in the application area. For personal protection see section 8. Dispose of rinse water in accordance with local and national regulations. Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. No smoking. Electrical installations / working materials must comply with the technological safety standards. Page: 6 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0326703 Pyroil? GAS TREAT GAS TREATMENT PYAG12P Version: 1.1 6 / 16 SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis KEROSENE 8008-20-6 TWA 200 mg/m3 Non-aerosol (as total hydrocarbon vapor) ACGIH REL 100 mg/m3 NIOSH/GUID E Engineering measures : Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Personal protective equipment Respiratory protection : In the case of vapour formation use a respirator with an approved filter. A NIOSH-approved air-purifying respirator with an appropriate cartridge and/or filter may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits (if applicable) or if overexposure has otherwise been determined. Protection provided by air- purifying respirators is limited. Use a positive pressure, air- supplied respirator if there is any potential for uncontrolled release, exposure levels are not known or any other circumstances where an air-purifying respirator may not provide adequate protection. Hand protection Material : nitrile rubber Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Not required under normal conditions of use. Wear splash- proof safety goggles if material could be misted or splashed into eyes. Skin and body protection : Wear as appropriate: impervious clothing Safety shoes Flame-resistant clothing Page: 7 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0326703 Pyroil? GAS TREAT GAS TREATMENT PYAG12P Version: 1.1 7 / 16 Choose body protection according to the amount and concentration of the dangerous substance at the work place. Discard gloves that show tears, pinholes, or signs of wear. Wear resistant gloves (consult your safety equipment supplier). Hygiene measures : Wash hands before breaks and at the end of workday. When using do not eat or drink. When using do not smoke. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state : liquid Colour : yellow Odour : hydrocarbon-like Odour Threshold : No data available pH : No data available Melting point/freezing point : No data available No data available Boiling point/boiling range : > 293 ?F / 145 ?C Flash point : 120.00 ?F / 48.89 ?C Calculated Flash Point Evaporation rate : < 1 Flammability (solid, gas) : No data available Upper explosion limit : 5 %(V) Calculated Explosive Limit Lower explosion limit : 0.7 %(V) Calculated Explosive Limit Vapour pressure : 0.63994 hPa (20 ?C) Calculated Vapor Pressure Relative vapour density : No data available Relative density : No data available Density : 0.8051 g/cm3 (15.56 ?C) Solubility(ies) Water solubility : insoluble Page: 8 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0326703 Pyroil? GAS TREAT GAS TREATMENT PYAG12P Version: 1.1 8 / 16 Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Thermal decomposition : No data available Viscosity Viscosity, dynamic : No data available Viscosity, kinematic : No data available Oxidizing properties : No data available SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. Chemical stability : Stable under recommended storage conditions. Possibility of hazardous reactions : Vapours may form explosive mixture with air. Conditions to avoid : Heat, flames and sparks. excessive heat Incompatible materials : Strong oxidizing agents Hazardous decomposition products carbon dioxide and carbon monoxide Hydrocarbons Nitrogen oxides (NOx) Sulphur oxides SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation Skin contact Eye Contact Ingestion Acute toxicity Not classified based on available information. Components: KEROSENE: Acute oral toxicity : LD 50 (Rat): > 5,000 mg/kg Method: OECD Test Guideline 420 Page: 9 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0326703 Pyroil? GAS TREAT GAS TREATMENT PYAG12P Version: 1.1 9 / 16 Acute inhalation toxicity : LC 50 (Rat): > 5.28 mg/l Exposure time: 4 h Test atmosphere: vapour Method: OECD Test Guideline 403 Assessment: Not classified as acutely toxic by inhalation under GHS. Acute dermal toxicity : LD 50 (Rabbit): > 2,000 mg/kg Method: OECD Test Guideline 402 Assessment: Not classified as acutely toxic by dermal absorption under GHS. Skin corrosion/irritation Causes skin irritation. Product: Remarks: May cause skin irritation and/or dermatitis. Result: Repeated exposure may cause skin dryness or cracking. Components: KEROSENE: Result: Irritating to skin Serious eye damage/eye irritation Not classified based on available information. Product: Remarks: Vapours may cause irritation to the eyes, respiratory system and the skin. Components: KEROSENE: Result: Slightly irritating to eyes Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information. Germ cell mutagenicity Not classified based on available information. Carcinogenicity Not classified based on available information. Reproductive toxicity Not classified based on available information. STOT - single exposure May cause drowsiness or dizziness. Components: KEROSENE: Assessment: May cause drowsiness or dizziness. STOT - repeated exposure Not classified based on available information. Aspiration toxicity May be fatal if swallowed and enters airways. Page: 10 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0326703 Pyroil? GAS TREAT GAS TREATMENT PYAG12P Version: 1.1 10 / 16 Components: KEROSENE: May be fatal if swallowed and enters airways. Further information Product: Remarks: Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting., Concentrations substantially above the TLV value may cause narcotic effects., Solvents may degrease the skin. Components: KEROSENE: Remarks: Skin Remarks: Central nervous system Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Components: KEROSENE: Toxicity to fish : LL50 (Oncorhynchus mykiss (rainbow trout)): 2 - 5 mg/l Exposure time: 96 h Test Type: semi-static test Test substance: WAF Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EL50 (Water flea (Daphnia magna)): 1.4 mg/l Exposure time: 48 h Test Type: static test Test substance: WAF Method: OECD Test Guideline 202 Toxicity to algae : EL50 (Pseudokirchneriella subcapitata (green algae)): 1 - 3 mg/l Exposure time: 72 h Page: 11 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0326703 Pyroil? GAS TREAT GAS TREATMENT PYAG12P Version: 1.1 11 / 16 Test Type: static test Test substance: WAF Method: OECD Test Guideline 201 Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : (Water flea (Daphnia magna)): 0.89 mg/l Exposure time: 21 d End point: Reproduction Test Test Type: semi-static test Test substance: WAF Method: OECD Test Guideline 211 Persistence and degradability Components: KEROSENE: Biodegradability : Biodegradation: 58.6 % Exposure time: 28 d Method: OECD Test Guideline 301F Bioaccumulative potential Components: No data available Mobility in soil Components: No data available Other adverse effects No data available Product: Additional ecological information : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal., Toxic to aquatic life with long lasting effects. Components: SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods General advice : The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. Dispose of in accordance with all applicable local, state and federal regulations. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Page: 12 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0326703 Pyroil? GAS TREAT GAS TREATMENT PYAG12P Version: 1.1 12 / 16 Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION International transport regulations REGULATION ID NUMBER PROPER SHIPPING NAME *HAZARD CLASS SUBSIDIARY HAZARDS PACKING GROUP MARINE POLLUTANT / LTD. QTY. U.S. DOT - ROAD Not dangerous goods U.S. DOT - RAIL Not dangerous goods U.S. DOT - INLAND WATERWAYS Not dangerous goods TRANSPORT CANADA - ROAD Not dangerous goods TRANSPORT CANADA - RAIL Not dangerous goods TRANSPORT CANADA - INLAND WATERWAYS Not dangerous goods INTERNATIONAL MARITIME DANGEROUS GOODS UN 1993 FLAMMABLE LIQUID, N.O.S. (KEROSENE) 3 III LIMITED QUANTITY INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO UN 1993 Flammable liquid, n.o.s. (KEROSENE) 3 III INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER UN 1993 Flammable liquid, n.o.s. (KEROSENE) 3 III Page: 13 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0326703 Pyroil? GAS TREAT GAS TREATMENT PYAG12P Version: 1.1 13 / 16 MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND WASTES UN 1993 LIQUIDO INFLAMABLE, N.E.P. (KEROSENE) 3 III *ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Marine pollutant yes Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) NAPHTHALENE 91-20-3 100 214132.762313 SARA 311/312 Hazards : Fire Hazard Acute Health Hazard SARA 313 Component(s)SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Pennsylvania Right To Know KEROSENE 8008-20-6 90.00 - 100.00 % New Jersey Right To Know KEROSENE 8008-20-6 90.00 - 100.00 % POLYMER Not Assigned 1.00 - 5.00 % California Prop 65 Proposition 65 warnings are not required for this product based on the results of a risk assessment. The components of this product are reported in the following inventories: TSCA : On TSCA Inventory DSL : All components of this product are on the Canadian DSL. AICS : On the inventory, or in compliance with the inventory Page: 14 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0326703 Pyroil? GAS TREAT GAS TREATMENT PYAG12P Version: 1.1 14 / 16 NZIOC : Not in compliance with the inventory ENCS : Not in compliance with the inventory KECI : On the inventory, or in compliance with the inventory PICCS : On the inventory, or in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) SECTION 16. OTHER INFORMATION Further information Revision Date: 07/31/2015 NFPA: HMIS III: NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class II Full text of H-Statements referred to under sections 2 and 3. H226 Flammable liquid and vapor. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H318 Causes serious eye damage. Sources of key data used to compile the Safety Data Sheet Flammability H e a lt h In s ta b ility 1 2 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 2 0 2 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Page: 15 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0326703 Pyroil? GAS TREAT GAS TREATMENT PYAG12P Version: 1.1 15 / 16 Internal data including own and sponsored test reports The UNECE administers regional agreements implementing harmonised classification for labelling (GHS) and transport. Cefic, the European Chemical Industry Council. ESIS European Chemical Substances Information System The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Niteo's Environmental Health and Safety Department (1-844-696-4836). List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the ?International Air Transport Association? (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the ?International Civil Aviation Organization? IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health Page: 16 SAFETY DATA SHEET Revision Date: 07/31/2015 Print Date: 4/11/2016 SDS Number: R0326703 Pyroil? GAS TREAT GAS TREATMENT PYAG12P Version: 1.1 16 / 16 OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System