1. IDENTIFICATION Product identifier Product Name SUPER GLUE GEL 2 GR Other means of identification Product Code 82191 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use This product is a cyanoacrylate-based adhesive Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) NOTE: This product is a consumer product and is labeled in accordance with the US Consumer Product Safety Commission regulations which take precedence over OSHA Hazard Communication labeling. The actual container label will not include the label elements below. The labeling below applies to industrial/professional products. Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Skin sensitization Category 1 Specific target organ toxicity (single exposure) Category 3 Label elements Emergency Overview _____________________________________________________________________________________________ Page 1 / 8 Version 2 Warning Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Revision Date 31-Jul-2015 SAFETY DATA SHEET _____________________________________________________________________________________________ Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace Use only outdoors or in a well-ventilated area IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water Take off contaminated clothing and wash before reuse If skin irritation or rash occurs: Get medical advice/attention IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell Precautionary Statements - Storage Store in a well-ventilated place. Keep container tightly closed Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information - Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children Unknown acute toxicity 7.3 % of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret ETHYL-2-CYANOACRYLATE 7085-85-0 60 - 100 * POLY (METHYL METHACRYLATE) 9011-14-7 5 - 10 * AMORPHOUS SILICA 7631-86-9 3 - 7 * 1,4-DIHYDROXYBENZENE 123-31-9 0.1 - 1 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures _____________________________________________________________________________________________ Page 2 / 8 Causes skin irritation Causes serious eye irritation May cause an allergic skin reaction May cause respiratory irritation Revision Date 31-Jul-201582191 - SUPER GLUE GEL 2 GR Physical state Gel Odor IrritatingAppearance Clear _____________________________________________________________________________________________ General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eyelids are bonded closed, release eyelashes with warm water by covering with a wet pad. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash skin with soap and water. Allow warm water to penetrate the bond and gently attempt to move bonded areas without pulling the skin away from bonded area. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion Not an expected route of exposure. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical Polymerizes with evolution of heat. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. _____________________________________________________________________________________________ Page 3 / 8 82191 - SUPER GLUE GEL 2 GR Revision Date 31-Jul-2015 _____________________________________________________________________________________________ Methods for cleaning up Ensure adequate ventilation. Flood with water to complete polymerization and scrape off floor. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Incompatible materials Alcohols, Amines, Alkalis, Polymerization can occur 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH ETHYL-2-CYANOACRYLATE 7085-85-0 TWA: 0.2 ppm - - AMORPHOUS SILICA 7631-86-9 - (vacated) TWA: 6 mg/m3 <1% Crystalline silica TWA: 20 mppcf : (80)/(% SiO2) mg/m3 TWA IDLH: 3000 mg/m3 TWA: 6 mg/m3 1,4-DIHYDROXYBENZENE 123-31-9 TWA: 1 mg/m3 TWA: 2 mg/m3 (vacated) TWA: 2 mg/m3 IDLH: 50 mg/m3 Ceiling: 2 mg/m3 15 min NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skinand body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Gel Appearance Clear _____________________________________________________________________________________________ Page 4 / 8 Revision Date 31-Jul-201582191 - SUPER GLUE GEL 2 GR _____________________________________________________________________________________________ Odor Irritating Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) <20 g/L Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions Polymerizes with evolution of heat. Conditions to avoid Excessive heat. Incompatible materials Alcohols, Amines, Alkalis, Polymerization can occur Hazardous Decomposition Products Carbon oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. _____________________________________________________________________________________________ Page 5 / 8 Butyl acetate = 1 82191 - SUPER GLUE GEL 2 GR Kinematic viscosity No information available Flammability (solid, gas) No information available Dynamic viscosity No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available Values Lower flammability limit: No information available Revision Date 31-Jul-2015 Vapor pressure 1 mm Hg @ 20?C Boiling point / boiling range 185 ?C / 365 ?F No data available Vapor density <1 Remarks ? Method Air = 1 Relative density 1.05 Flash point Water solubility Insoluble 85 ?C / 185 ?F Solubility in other solvents No information available Tag Closed Cup pH Partition coefficient No information available Does not apply Evaporation rate < 1 Autoignition temperature No information available Decomposition temperature No information available _____________________________________________________________________________________________ Skin contact Will bond to skin. May cause burns. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. Ingestion Not an expected route of exposure. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 ETHYL-2-CYANOACRYLATE 7085-85-0 > 5 mL/kg ( Rat ) - - AMORPHOUS SILICA 7631-86-9 > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 2.2 mg/L ( Rat ) 1 h 1,4-DIHYDROXYBENZENE 123-31-9 = 298 mg/kg ( Rat ) = 74800 mg/kg ( Rabbit ) - Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA POLY (METHYL METHACRYLATE) 9011-14-7 - Group 3 - - AMORPHOUS SILICA 7631-86-9 - Group 3 - - 1,4-DIHYDROXYBENZENE 123-31-9 A3 Group 3 - - ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Not classifiable as a human carcinogen The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 5231 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity 99.8 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea AMORPHOUS SILICA 7631-86-9 440: 72 h Pseudokirchneriella subcapitata mg/L EC50 5000: 96 h Brachydanio rerio mg/L LC50 static 7600: 48 h Ceriodaphnia dubia mg/L EC50 1,4-DIHYDROXYBENZENE 123-31-9 0.335: 72 h Pseudokirchneriella subcapitata mg/L EC50 13.5: 120 h Desmodesmus subspicatus mg/L EC50 0.044: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 0.1 - 0.18: 96 h Pimephales promelas mg/L LC50 static 0.17: 96 h Brachydanio rerio mg/L LC50 0.044: 96 h Pimephales promelas mg/L LC50 flow-through 0.29: 48 h Daphnia magna mg/L EC50 Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient _____________________________________________________________________________________________ Page 6 / 8 82191 - SUPER GLUE GEL 2 GR Revision Date 31-Jul-2015 _____________________________________________________________________________________________ 1,4-DIHYDROXYBENZENE 123-31-9 0.5 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes 1,4-DIHYDROXYBENZENE 123-31-9 - Included in waste stream: K060 - - 14. TRANSPORT INFORMATION DOT Proper shipping name: Not regulated IATA Proper shipping name: Not regulated IMDG Proper shipping name: Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Not Listed. ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 _____________________________________________________________________________________________ Page 7 / 8 Revision Date 31-Jul-201582191 - SUPER GLUE GEL 2 GR _____________________________________________________________________________________________ SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) 1,4-DIHYDROXYBENZENE 123-31-9 100 lb 100 lb RQ 100 lb final RQ RQ 45.4 kg final RQ US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania ETHYL-2-CYANOACRYLATE 7085-85-0 X - - 1,4-DIHYDROXYBENZENE 123-31-9 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 31-Jul-2015 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 8 / 8 Revision Date 31-Jul-2015 - HMIS NFPA Health hazards 2 Flammability 2 Physical hazards 0 Personal protection B Health hazards 2 82191 - SUPER GLUE GEL 2 GR Flammability 2 Instability 0