_____________________________________________________________________________________________ _____________________________________________________________________________________________ 2. HAZARDS IDENTIFICATION Classification This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). This product is an article which is a sealed battery and as such does not require an MSDS per the OSHA hazard communication standard unless ruptured. The hazards indicated are for a ruptured battery. Acute toxicity - Oral Category 4 Acute toxicity - Inhalation (Gases) Category 4 _____________________________________________________________________________________________ Recommended use of the chemical and restrictions on use Recommended Use Lead Acid (Non-Spillable) Battery Uses advised against No information available Details of the supplier of the safety data sheet Supplier Name Universal Product Group Supplier Address 488 S. Royal Lane Coppell Texas 75019 US Supplier Phone Number Phone:866.892.1122 Supplier Email This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone number Company Emergency Phone Number 469.892.1137 The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representations or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this information or the substance described in this SDS. The layout, appearance and format of this SDS is ? 2014 UL LLC. All rights reserved. SAFETY DATA SHEET Revision Date 17-Jun-2015 Revision Number 2Issuing Date No data available 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name SLA Battery Other means of identification Page 1 / 12 Synonyms None _____________________________________________________________________________________________ Acute toxicity - Inhalation (Vapors) Category 4 Acute toxicity - Inhalation (Dusts/Mists) Category 3 Skin corrosion/irritation Category 1 Sub-category A Serious eye damage/eye irritation Category 1 Carcinogenicity Category 1A Reproductive Toxicity Category 1A Specific target organ toxicity (repeated exposure) Category 2 GHS Label elements, including precautionary statements Emergency Overview Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Use only outdoors or in a well-ventilated area Do not breathe dust/fume/gas/mist/vapors/spray Precautionary Statements - Response Specific treatment (see .? on this label) Immediately call a POISON CENTER or doctor/physician Specific treatment (see supplemental first aid instructions on this label) Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician Skin IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing _____________________________________________________________________________________________ Revision Date 17-Jun-2015 This product is an article which contains a chemical substance. Safety information is given for exposure to the article as sold. Intended use of the product should not result in exposure to the chemical substance. This is a battery. In case of rupture: the above hazards exist. 1251816 - SLA Battery Hazard Statements Toxic if inhaled Causes severe skin burns and eye damage May cause cancer May damage fertility or the unborn child May cause damage to organs through prolonged or repeated exposure Page 2 / 12 Signal word Danger Odor NoneAppearance Black Physical state Solid _____________________________________________________________________________________________ Call a POISON CENTER or doctor/physician if you feel unwell Immediately call a POISON CENTER or doctor/physician Ingestion IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth Do NOT induce vomiting Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep container tightly closed Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity 10% of the mixture consists of ingredient(s) of unknown toxicity Other information Very toxic to aquatic life with long lasting effects Interactions with Other Chemicals No information available. 4. FIRST AID MEASURES First aid measures General Advice First aid is upon rupture of sealed battery. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Do not rub affected area. Remove contact lenses, if present and easy to do. Continue rinsing. Seek immediate medical attention/advice. Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Seek immediate medical attention/advice. Inhalation Remove to fresh air. If breathing has stopped, give artificial respiration. Get medical attention immediately. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket _____________________________________________________________________________________________ Chemical Name CAS No Weight-% Trade Secret Lead 7439-92-1 40 - 70 * Sulfuric acid 7664-93-9 10 - 30 * *The exact percentage (concentration) of composition has been withheld as a trade secret 1251816 - SLA Battery Revision Date 17-Jun-2015 3. COMPOSITION/INFORMATION ON INGREDIENTS . Page 3 / 12 _____________________________________________________________________________________________ mask equipped with a one-way valve or other proper respiratory medical device. If breathing is difficult, (trained personnel should) give oxygen. Delayed pulmonary edema may occur. Get medical attention immediately if symptoms occur. Ingestion Do NOT induce vomiting. Rinse mouth immediately and drink plenty of water. Never give anything by mouth to an unconscious person. Call a physician or poison control center immediately. Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. Avoid contact with skin, eyes or clothing. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. Use personal protective equipment as required. Wear personal protective clothing (see section 8). Most important symptoms and effects, both acute and delayed Most Important Symptoms and Effects Burning sensation. Coughing and/ or wheezing. Difficulty in breathing. Lead poisoning is characterized by a metallic taste in the mouth, loss of appetite indigestion, nausea, vomiting, constipation, sleep disturbances and overall weakness. Severe exposures can lead to shock, circulatory collapse, and death. Indication of any immediate medical attention and special treatment needed Notes to Physician Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated. Do not give chemical antidotes. Asphyxia from glottal edema may occur. Marked decrease in blood pressure may occur with moist rales, frothy sputum, and high pulse pressure. _____________________________________________________________________________________________ Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical The product causes burns of eyes, skin and mucous membranes. Thermal decomposition can lead to release of irritating gases and vapors. Uniform Fire Code Toxic: Solid Corrosive: Acid-Liquid Hazardous Combustion Products Carbon oxides. Explosion Data Sensitivity to Mechanical Impact No. Sensitivity to Static Discharge No. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Revision Date 17-Jun-20151251816 - SLA Battery 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Page 4 / 12 _____________________________________________________________________________________________ 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Lead 7439-92-1 TWA: 0.05 mg/m3 TWA: 50 ?g/m3 TWA: 50 ?g/m3 Pb Action Level: 30 ?g/m3 Poison, See 29 CFR 1910.1025 Action Level: 30 ?g/m3 Pb Poison, See IDLH: 100 mg/m3 TWA: 0.050 mg/m3 _____________________________________________________________________________________________ Methods for cleaning up Pick up and transfer to properly labeled containers. 1251816 - SLA Battery Revision Date 17-Jun-2015 7. HANDLING AND STORAGE Precautions for safe handling Handling In case of rupture: Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Use only with adequate ventilation and in closed systems. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash before reuse. Conditions for safe storage, including any incompatibilities Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from moisture. Store locked up. Keep out of the reach of children. Store away from other materials. Incompatible Products Acids. Bases. Oxidizing agent. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Attention! Corrosive material. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Other Information Refer to protective measures listed in Sections 7 and 8. Environmental precautions Environmental precautions Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage if safe to do so. Should not be released into the environment. Do not allow to enter into soil/subsoil. Prevent product from entering drains. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Page 5 / 12 _____________________________________________________________________________________________ 29 CFR 1910.1025 Sulfuric acid 7664-93-9 TWA: 0.2 mg/m3 thoracic fraction TWA: 1 mg/m3 (vacated) TWA: 1 mg/m3 IDLH: 15 mg/m3 TWA: 1 mg/m3 ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits Immediately Dangerous to Life or Health Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992) Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Face protection shield. Skin and body protection Wear protective gloves and protective clothing. Long sleeved clothing. Chemical resistant apron. Impervious gloves. Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash before reuse. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is recommended. Wash hands before breaks and immediately after handling the product. For environmental protection, remove and wash all contaminated protective equipment before re-use. Do not breathe dust. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Physical state Solid _____________________________________________________________________________________________ None known Property Flammability (solid, gas) No data available Values None known Odor Flammability Limit in Air Remarks Method None Upper flammability limit No data available pH No data available Lower flammability limit No data available 1251816 - SLA Battery Vapor pressure No data available None known None known Color Vapor density No data available Melting / freezing point None known No data available Specific Gravity No data available No information available None known None known Water Solubility Virtually insoluble Revision Date 17-Jun-2015 None known Solubility in other solvents No data available Boiling point / boiling range No data available None known Partition coefficient: n-octanol/water0 Odor Threshold None known None known Autoignition temperature No data available No information available None known Flash Point No data available Appearance None known Black Evaporation Rate No data available Page 6 / 12 _____________________________________________________________________________________________ Explosive properties No data available Oxidizing properties No data available Other Information Softening Point No data available VOC Content (%) No data available Particle Size No data available Particle Size Distribution 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Product does not present an acute toxicity hazard based on known or supplied information. In case of rupture:. Inhalation Specific test data for the substance or mixture is not available. Corrosive by inhalation. (based on components). Inhalation of corrosive fumes/gases may cause coughing, choking, headache, dizziness, and weakness for several hours. Pulmonary edema may occur with tightness in the chest, shortness of breath, bluish skin, decreased blood pressure, and increased heart rate. Inhaled corrosive substances can lead to a toxic edema of the lungs. Pulmonary edema can be fatal. May cause irritation of respiratory tract. Toxic by inhalation. Eye contact Specific test data for the substance or mixture is not available. Causes burns. (based on components). Corrosive to the eyes and may cause severe damage including blindness. Causes serious eye damage. May cause irreversible damage to eyes. Skin contact Specific test data for the substance or mixture is not available. Corrosive. (based on components). Causes burns. Ingestion Specific test data for the substance or mixture is not available. Causes burns. (based on components). Ingestion causes burns of the upper digestive and respiratory tracts. May cause severe burning pain in the mouth and stomach with vomiting and diarrhea of dark blood. Blood pressure may decrease. Brownish or yellowish stains may be seen around the mouth. Swelling of the throat may cause shortness of breath and choking. May cause lung _____________________________________________________________________________________________ Decomposition temperature Dynamic viscosity 0 No data available None known Revision Date 17-Jun-2015 None known Kinematic viscosity 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to avoid Exposure to air or moisture over prolonged periods. Excessive heat. Incompatible materials Acids. Bases. Oxidizing agent. Hazardous Decomposition Products Carbon oxides. No data available 1251816 - SLA Battery Page 7 / 12 None known No data available. _____________________________________________________________________________________________ damage if swallowed. May be fatal if swallowed and enters airways. Ingestion may cause irritation to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Harmful if swallowed. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Sulfuric acid 7664-93-9 = 2140 mg/kg ( Rat ) - = 510 mg/m3 ( Rat ) 2 h Information on toxicological effects Symptoms Erythema (skin redness). Burning. May cause blindness. Coughing and/ or wheezing. Difficulty in breathing. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Mutagenic Effects No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA Lead 7439-92-1 A3 Group 2A Reasonably Anticipated X Sulfuric acid 7664-93-9 A2 Group 1 Known X Reproductive toxicity Contains a known or suspected reproductive toxin. Product is or contains a chemical which is a known or suspected reproductive hazard. Developmental Toxicity Contains ingredients that have suspected developmental hazards. STOT - single exposure No information available. STOT - repeated exposure Causes damage to organs through prolonged or repeated exposure. Based on classification criteria from the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200), this product has been determined to cause systemic target organ toxicity from chronic or repeated exposure. (STOT RE). Chronic Toxicity Chronic exposure to corrosive fumes/gases may cause erosion of the teeth followed by jaw necrosis. Bronchial irritation with chronic cough and frequent attacks of pneumonia are common. Gastrointestinal disturbances may also be seen. Effects from this product caused by acute exposure may cause permanent damage to target organs and/or may cause chronic conditions. Contains a known or suspected carcinogen. Contains a known or suspected reproductive toxin. Possible risk of irreversible effects. Avoid repeated exposure. Prolonged exposure may cause chronic effects. Lead compounds may be absorbed by ingestion, by inhalation and through the skin. Lead may damage kidney function, the blood forming system and the reproductive system. Target Organ Effects Respiratory system. Eyes. Skin. Gastrointestinal tract (GI). Systemic Toxicity. Reproductive System. Blood. May damage the unborn child. Aspiration Hazard No information available. Numerical measures of toxicity Product Information The following values are calculated based on chapter 3.1 of the GHS document _____________________________________________________________________________________________ 1251816 - SLA Battery Revision Date 17-Jun-2015 Page 8 / 12 _____________________________________________________________________________________________ ATEmix (oral) 677.00 mg/kg ATEmix (inhalation-gas) 6,522.00 ppm (4 hr) ATEmix (inhalation-dust/mist) 0.78 mg/l ATEmix (inhalation-vapor) 16.00 ATEmix _____________________________________________________________________________________________ Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Microorganisms Daphnia Magna (Water Flea) Lead 7439-92-1 96h LC50: = 0.44 mg/L (Cyprinus carpio) 96h LC50: = 1.17 mg/L (Oncorhynchus mykiss) 96h LC50: = 1.32 mg/L (Oncorhynchus mykiss) 48h EC50: = 600 ?g/L Sulfuric acid 7664-93-9 96h LC50: > 500 mg/L (Brachydanio rerio) 24h EC50: = 29 mg/L Persistence and Degradability No information available. Bioaccumulation No information available Other adverse effects No information available. 1251816 - SLA Battery Revision Date 17-Jun-2015 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life. Very toxic to aquatic life with long lasting effects. Page 9 / 12 _____________________________________________________________________________________________ 14. TRANSPORT INFORMATION DOT NOT REGULATED Proper Shipping Name NON REGULATED Hazard Class N/A TDG Not regulated MEX Not regulated ICAO Not regulated IATA Not regulated Proper Shipping Name NON REGULATED Hazard Class N/A IMDG/IMO Not regulated Hazard Class N/A RID Not regulated ADR Not regulated Tunnel restriction code (E) ADN Not regulated 15. REGULATORY INFORMATION _____________________________________________________________________________________________ Included in waste streams: F035, F037, F038, F039, K002, K003, K005, K046, K048, K049, K051, K052, K061, K062, K064, K065, K066, K069, K086, K100, K176 = 5.0 mg/L regulatory level California Hazardous Waste Codes 792 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Lead 7439-92-1 Toxic Sulfuric acid 7664-93-9 Toxic Corrosive Revision Date 17-Jun-20151251816 - SLA Battery 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal methods This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated Packaging Dispose of contents/containers in accordance with local regulations. US EPA Waste Number D002 D008 Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes Page 10 / 12 Lead 7439-92-1 (hazardous constituent - no waste number) _____________________________________________________________________________________________ International Inventories TSCA Complies DSL All components are listed either on the DSL or NDSL. TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name CAS No Weight-% SARA 313 - Threshold Values % Lead - 7439-92-1 7439-92-1 40 - 70 0.1 Sulfuric acid - 7664-93-9 7664-93-9 10 - 30 1.0 SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard No Fire Hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Lead 7439-92-1 X X Sulfuric acid 7664-93-9 1000 lb X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs RQ Lead 7439-92-1 10 lb RQ 10 lb final RQ RQ 4.54 kg final RQ Sulfuric acid 7664-93-9 1000 lb 1000 lb RQ 1000 lb final RQ RQ 454 kg final RQ US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals. Chemical Name California Proposition 65 Lead - 7439-92-1 Carcinogen Developmental Female Reproductive Male Reproductive Sulfuric acid - 7664-93-9 Carcinogen U.S. State Right-to-Know Regulations . _____________________________________________________________________________________________ Revision Date 17-Jun-2015 Page 11 / 12 1251816 - SLA Battery _____________________________________________________________________________________________ Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois Lead 7439-92-1 X X X X X Sulfuric acid 7664-93-9 X X X X X International Regulations Mexico National occupational exposure limits Component Carcinogen Status Exposure Limits Lead 7439-92-1 ( 40 - 70 ) A3 Mexico: TWA= 0.15 mg/m3 Sulfuric acid 7664-93-9 ( 10 - 30 ) A2 Mexico: TWA 1 mg/m3 Mexico - Occupational Exposure Limits - Carcinogens Canada WHMIS Hazard Class Not determined 16. OTHER INFORMATION Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-800-572-6501 Revision Date 17-Jun-2015 Revision Note No information available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of Safety Data Sheet _____________________________________________________________________________________________ Physical and Chemical Hazards - Revision Date 17-Jun-2015 HMIS NFPA Health Hazards 0 Flammability 0 Physical Hazard 0 Personal Protection X Health Hazards 3 Flammability 0 1251816 - SLA Battery Page 12 / 12 Instability 0