3M? Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15 __________________________________________________________________________________________ Page 1 of 13 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 32-4327-6 Version Number: 1.01 Issue Date: 09/23/15 Supercedes Date: 11/24/14 SECTION 1: Identification 1.1. Product identifier 3M? Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 1.2. Recommended use and restrictions on use Recommended use Automotive, Structural Panel Bonding Adhesive 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Serious Eye Damage/Irritation: Category 2A. Skin Sensitizer: Category 1. Carcinogenicity: Category 2. 2.2. Label elements Signal word Warning Symbols Exclamation mark | Health Hazard | Pictograms 3M? Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15 __________________________________________________________________________________________ Page 2 of 13 Hazard Statements Causes serious eye irritation. May cause an allergic skin reaction. Suspected of causing cancer. Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapors/spray. Wear protective gloves and eye/face protection. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. Storage: Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified None. 34% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer 25068-38-6 30 - 60 Trade Secret * Oxide Glass Chemicals 65997-17-3 10 - 30 Trade Secret * Fused Silica 60676-86-0 7 - 13 Trade Secret * 1,4-Bis[(2,3-Epoxypropoxy)Methyl]Cyclohexane 14228-73-0 7 - 13 Trade Secret * Acrylate Polymer Trade Secret* 5 - 10 Trade Secret * Silica 7631-86-9 1 - 5 Trade Secret * 3-(Trimethoxysilyl)propyl Glycidyl Ether 2530-83-8 0.5 - 1.5 Trade Secret * Dimethyl Siloxane, Reaction Product With Silica 67762-90-7 0.5 - 1.5 Trade Secret * Carbon Black 1333-86-4 < 0.5 Trade Secret * 3M? Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15 __________________________________________________________________________________________ Page 3 of 13 Epichlorohydrin 106-89-8 < 0.02 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent 3M? Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15 __________________________________________________________________________________________ Page 4 of 13 material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Store away from acids. Store away from strong bases. Store away from oxidizing agents. Store away from amines. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Epichlorohydrin 106-89-8 ACGIH TWA:0.5 ppm A3: Confirmed animal carcin., Skin Notation Epichlorohydrin 106-89-8 OSHA TWA:19 mg/m3(5 ppm) Skin Notation Carbon Black 1333-86-4 ACGIH TWA(inhalable fraction):3 mg/m3 A3: Confirmed animal carcin. Carbon Black 1333-86-4 CMRG TWA:0.5 mg/m3 Carbon Black 1333-86-4 OSHA TWA:3.5 mg/m3 3-(Trimethoxysilyl)propyl Glycidyl Ether 2530-83-8 CMRG TWA:5 ppm SILICA, AMORPHOUS 60676-86-0 OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. Oxide Glass Chemicals 65997-17-3 Manufacturer determined TWA(as dust):10 mg/m3 Dimethyl Siloxane, Reaction Product With Silica 67762-90-7 CMRG CEIL:5 mg/m3 SILICA, AMORPHOUS 67762-90-7 OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. Silica 7631-86-9 CMRG TWA(as respirable dust):3 mg/m3 SILICA, AMORPHOUS 7631-86-9 OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit 3M? Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15 __________________________________________________________________________________________ Page 5 of 13 CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Odor, Color, Grade: Black, Viscous Liquid. Odor threshold No Data Available pH No Data Available Melting point No Data Available Boiling Point >= 95 ?F Flash Point >= 220 ?F [Test Method: Closed Cup] Evaporation rate <= 1 Units not avail. or not appl. [Ref Std: BUOAC=1] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure <= 27 psia Vapor Pressure No Data Available Vapor Density No Data Available Density 10.014 lb/gal Specific Gravity 1.2 [Ref Std: WATER=1] 3M? Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15 __________________________________________________________________________________________ Page 6 of 13 Solubility in Water Negligible Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity 100,000 centipoise - 225,000 centipoise [Test Method: Brookfield] Hazardous Air Pollutants 0.00162 lb HAPS/gal Volatile Organic Compounds 15 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 1.6 % weight [Test Method: calculated per CARB title 2] Percent volatile 1.6 % weight VOC Less H2O & Exempt Solvents 15 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Sparks and/or flames 10.5. Incompatible materials Amines Strong acids Strong bases Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition Aldehydes Not Specified Carbon monoxide Not Specified Carbon dioxide Not Specified SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: 3M? Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15 __________________________________________________________________________________________ Page 7 of 13 Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Additional Health Effects: Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation Generic: GLASS FILAMENTS 65997-17-3 Anticipated human carcinogen National Toxicology Program Carcinogens Carbon Black 1333-86-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Epichlorohydrin 106-89-8 Grp. 2A: Probable human carc. International Agency for Research on Cancer Epichlorohydrin 106-89-8 Anticipated human carcinogen National Toxicology Program Carcinogens Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE > 5,000 mg/kg Overall product Inhalation- Dust/Mist(4 hr) No data available; calculated ATE > 12.5 mg/l Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer Dermal Rat LD50 > 1,600 mg/kg 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer Ingestion Rat LD50 > 1,000 mg/kg Oxide Glass Chemicals Dermal LD50 estimated to be > 5,000 mg/kg Oxide Glass Chemicals Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg 1,4-Bis[(2,3-Epoxypropoxy)Methyl]Cyclohexane Dermal Rabbit LD50 2,500 mg/kg Fused Silica Dermal Rabbit LD50 > 5,000 mg/kg 1,4-Bis[(2,3-Epoxypropoxy)Methyl]Cyclohexane Ingestion Rat LD50 2,450 mg/kg Fused Silica Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Fused Silica Ingestion Rat LD50 > 5,110 mg/kg Acrylate Polymer Dermal Rabbit LD50 > 5,000 mg/kg Acrylate Polymer Ingestion Rat LD50 > 5,000 mg/kg Silica Dermal Rabbit LD50 > 5,000 mg/kg Silica Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Silica Ingestion Rat LD50 > 5,110 mg/kg 3-(Trimethoxysilyl)propyl Glycidyl Ether Dermal Rabbit LD50 4,000 mg/kg 3-(Trimethoxysilyl)propyl Glycidyl Ether Inhalation- Dust/Mist Rat LC50 > 5.3 mg/l 3M? Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15 __________________________________________________________________________________________ Page 8 of 13 (4 hours) 3-(Trimethoxysilyl)propyl Glycidyl Ether Ingestion Rat LD50 7,010 mg/kg Dimethyl Siloxane, Reaction Product With Silica Dermal Rabbit LD50 > 5,000 mg/kg Dimethyl Siloxane, Reaction Product With Silica Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Dimethyl Siloxane, Reaction Product With Silica Ingestion Rat LD50 > 5,110 mg/kg Carbon Black Dermal Rabbit LD50 > 3,000 mg/kg Carbon Black Ingestion Rat LD50 > 8,000 mg/kg Epichlorohydrin Dermal Rabbit LD50 755 mg/kg Epichlorohydrin Inhalation- Vapor (4 hours) Rat LC50 1.7 mg/l Epichlorohydrin Ingestion Rat LD50 260 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer Rabbit Mild irritant Oxide Glass Chemicals Professio nal judgeme nt No significant irritation 1,4-Bis[(2,3-Epoxypropoxy)Methyl]Cyclohexane Professio nal judgeme nt Mild irritant Fused Silica Rabbit No significant irritation Acrylate Polymer Professio nal judgeme nt Minimal irritation Silica Rabbit No significant irritation 3-(Trimethoxysilyl)propyl Glycidyl Ether Rabbit Mild irritant Dimethyl Siloxane, Reaction Product With Silica Rabbit No significant irritation Carbon Black Rabbit No significant irritation Epichlorohydrin Human and animal Corrosive Serious Eye Damage/Irritation Name Species Value 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer Rabbit Moderate irritant Oxide Glass Chemicals Professio nal judgeme nt No significant irritation 1,4-Bis[(2,3-Epoxypropoxy)Methyl]Cyclohexane Professio nal judgeme nt Mild irritant Fused Silica Rabbit No significant irritation Acrylate Polymer Professio nal judgeme nt Mild irritant Silica Rabbit No significant irritation 3-(Trimethoxysilyl)propyl Glycidyl Ether Rabbit Corrosive Dimethyl Siloxane, Reaction Product With Silica Rabbit No significant irritation Carbon Black Rabbit No significant irritation Epichlorohydrin Rabbit Corrosive Skin Sensitization 3M? Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15 __________________________________________________________________________________________ Page 9 of 13 Name Species Value 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer Human and animal Sensitizing 1,4-Bis[(2,3-Epoxypropoxy)Methyl]Cyclohexane similar compoun ds Sensitizing Fused Silica Human and animal Not sensitizing Silica Human and animal Not sensitizing 3-(Trimethoxysilyl)propyl Glycidyl Ether Guinea pig Some positive data exist, but the data are not sufficient for classification Dimethyl Siloxane, Reaction Product With Silica Human and animal Not sensitizing Epichlorohydrin Human and animal Sensitizing Respiratory Sensitization Name Species Value 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer Human Some positive data exist, but the data are not sufficient for classification Germ Cell Mutagenicity Name Route Value 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer In vivo Not mutagenic 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer In Vitro Some positive data exist, but the data are not sufficient for classification Oxide Glass Chemicals In Vitro Some positive data exist, but the data are not sufficient for classification Fused Silica In Vitro Not mutagenic Silica In Vitro Not mutagenic 3-(Trimethoxysilyl)propyl Glycidyl Ether In vivo Not mutagenic 3-(Trimethoxysilyl)propyl Glycidyl Ether In Vitro Some positive data exist, but the data are not sufficient for classification Dimethyl Siloxane, Reaction Product With Silica In Vitro Not mutagenic Carbon Black In Vitro Not mutagenic Carbon Black In vivo Some positive data exist, but the data are not sufficient for classification Epichlorohydrin In Vitro Some positive data exist, but the data are not sufficient for classification Epichlorohydrin In vivo Mutagenic Carcinogenicity Name Route Species Value 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer Dermal Mouse Some positive data exist, but the data are not sufficient for classification Oxide Glass Chemicals Inhalation Multiple animal species Some positive data exist, but the data are not sufficient for classification Fused Silica Not Specified Mouse Some positive data exist, but the data are not sufficient for classification Silica Not Specified Mouse Some positive data exist, but the data are not sufficient for classification 3-(Trimethoxysilyl)propyl Glycidyl Ether Dermal Mouse Not carcinogenic Dimethyl Siloxane, Reaction Product With Silica Not Specified Mouse Some positive data exist, but the data are not sufficient for classification Carbon Black Dermal Mouse Not carcinogenic Carbon Black Ingestion Mouse Not carcinogenic 3M? Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15 __________________________________________________________________________________________ Page 10 of 13 Carbon Black Inhalation Rat Carcinogenic Epichlorohydrin Dermal Mouse Not carcinogenic Epichlorohydrin Ingestion Rat Carcinogenic Epichlorohydrin Inhalation Rat Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration 4,4'-Isopropylidenediphenol- Epichlorohydrin Polymer Ingestion Not toxic to female reproduction Rat NOAEL 750 mg/kg/day 2 generation 4,4'-Isopropylidenediphenol- Epichlorohydrin Polymer Ingestion Not toxic to male reproduction Rat NOAEL 750 mg/kg/day 2 generation 4,4'-Isopropylidenediphenol- Epichlorohydrin Polymer Dermal Not toxic to development Rabbit NOAEL 300 mg/kg/day during organogenesi s 4,4'-Isopropylidenediphenol- Epichlorohydrin Polymer Ingestion Not toxic to development Rat NOAEL 750 mg/kg/day 2 generation Fused Silica Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation Fused Silica Inhalation Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Fused Silica Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s Silica Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation Silica Ingestion Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Silica Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s 3-(Trimethoxysilyl)propyl Glycidyl Ether Ingestion Not toxic to female reproduction Rat NOAEL 1,000 mg/kg/day 1 generation 3-(Trimethoxysilyl)propyl Glycidyl Ether Ingestion Not toxic to male reproduction Rat NOAEL 1,000 mg/kg/day 1 generation 3-(Trimethoxysilyl)propyl Glycidyl Ether Ingestion Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 3,000 mg/kg/day during organogenesi s Dimethyl Siloxane, Reaction Product With Silica Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation Dimethyl Siloxane, Reaction Product With Silica Ingestion Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Dimethyl Siloxane, Reaction Product With Silica Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s Epichlorohydrin Inhalation Not toxic to female reproduction Rat NOAEL 0.2 mg/l 10 weeks Epichlorohydrin Inhalation Not toxic to development Multiple animal species NOAEL 0.09 mg/l during organogenesi s Epichlorohydrin Ingestion Some positive developmental data exist, but the data are not sufficient for classification Multiple animal species NOAEL 160 mg/kg/day during gestation Epichlorohydrin Ingestion Toxic to male reproduction Rat LOAEL 6.25 mg/kg/day 23 days Epichlorohydrin Inhalation Toxic to male reproduction Rat NOAEL 0.02 mg/l 10 weeks Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration 3M? Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15 __________________________________________________________________________________________ Page 11 of 13 1,4-Bis[(2,3- Epoxypropoxy)Methyl]Cyc lohexane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Epichlorohydrin Inhalation respiratory irritation May cause respiratory irritation Human NOAEL not available occupational exposure Epichlorohydrin Inhalation liver Some positive data exist, but the data are not sufficient for classification Human NOAEL not available occupational exposure Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration 4,4'- Isopropylidenediphenol- Epichlorohydrin Polymer Dermal liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,000 mg/kg/day 2 years 4,4'- Isopropylidenediphenol- Epichlorohydrin Polymer Dermal nervous system All data are negative Rat NOAEL 1,000 mg/kg/day 13 weeks 4,4'- Isopropylidenediphenol- Epichlorohydrin Polymer Ingestion auditory system | heart | endocrine system | hematopoietic system | liver | eyes | kidney and/or bladder All data are negative Rat NOAEL 1,000 mg/kg/day 28 days Oxide Glass Chemicals Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Human NOAEL not available occupational exposure Fused Silica Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure Silica Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure 3-(Trimethoxysilyl)propyl Glycidyl Ether Ingestion heart | endocrine system | bone, teeth, nails, and/or hair | hematopoietic system | liver | immune system | nervous system | kidney and/or bladder | respiratory system All data are negative Rat NOAEL 1,000 mg/kg/day 28 days Dimethyl Siloxane, Reaction Product With Silica Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure Carbon Black Inhalation pneumoconiosis Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Epichlorohydrin Inhalation liver Causes damage to organs through prolonged or repeated exposure Rat NOAEL 0.21 mg/l 19 days Epichlorohydrin Inhalation kidney and/or bladder May cause damage to organs though prolonged or repeated exposure Rat NOAEL 0.04 mg/l 136 weeks Epichlorohydrin Inhalation endocrine system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.377 mg/l 4 weeks Epichlorohydrin Inhalation immune system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 0.211 mg/l 4 weeks Epichlorohydrin Inhalation heart Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.02 mg/l 98 days Epichlorohydrin Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.002 mg/l 98 days Epichlorohydrin Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 0.02 mg/l 13 weeks 3M? Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15 __________________________________________________________________________________________ Page 12 of 13 Epichlorohydrin Inhalation blood All data are negative Rat NOAEL 0.189 mg/l 90 days Epichlorohydrin Ingestion heart | blood Some positive data exist, but the data are not sufficient for classification Rat NOAEL 80 mg/kg/day 12 weeks Epichlorohydrin Ingestion liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 25 mg/kg/day 90 days Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes 15.2. State Regulations Contact 3M for more information. 3M? Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15 __________________________________________________________________________________________ Page 13 of 13 California Proposition 65 Ingredient C.A.S. No. Classification Epichlorohydrin 106-89-8 Male reproductive toxin Epichlorohydrin 106-89-8 Carcinogen Carbon Black 1333-86-4 Carcinogen WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. WARNING: This product contains a chemical known to the State of California to cause cancer. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 1 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 32-4327-6 Version Number: 1.01 Issue Date: 09/23/15 Supercedes Date: 11/24/14 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com MATERIAL SAFETY DATA SHEET PM-8576 (Accelerator for 3M Panel Bonding Adhesive, P/N 08115) Internal Use Only 09/19/12 _________________________________________________________________________________________________ Page 1 of 8 Material Safety Data Sheet Copyright, 2012, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: PM-8576 (Accelerator for 3M Panel Bonding Adhesive, P/N 08115) (Intermediate) MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 09/19/12 Supercedes Date: 09/10/12 Document Group: 07-6447-2 Product Use: Intended Use: Automotive Specific Use: Panel Bonding Adhesive - Accelerator SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt POLYMERIC DIAMIDE 68911-25-1 15 - 40 FUSED SILICA 60676-86-0 10 - 30 BUTADIENE ACRYLONITRILE COPOLYMER 68683-29-4 9 - 30 BIS(3-AMINOPROPYL) ETHER OF DIETHYLENE GLYCOL 4246-51-9 7 - 13 TRIS(2,4,6-DIMETHYLAMINOMONOMETHYL)PHENOL 90-72-2 5 - 10 INORGANIC SALT - NJTSRN 04499600-6317 Trade Secret 1 - 5 AMINE EPOXY CURING AGENT 288-32-4 1 - 5 DIMETHYL SILOXANE, REACTION PRODUCT WITH SILICA 67762-90-7 1 - 5 BIS[(DIMETHYLAMINO)METHYL]PHENOL 71074-89-0 0.1 - 1.5 N-AMINOETHYLPIPERAZINE 140-31-8 0.1 - 1.5 TOLUENE 108-88-3 < 0.5 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Viscous Odor, Color, Grade: Tan Liquid Minor Amine odor. General Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause chemical eye burns. May cause chemical skin burns. May cause allergic skin reaction. May cause chemical gastrointestinal burns. May cause target organ effects. Contains a chemical or MATERIAL SAFETY DATA SHEET PM-8576 (Accelerator for 3M Panel Bonding Adhesive, P/N 08115) Internal Use Only 09/19/12 _________________________________________________________________________________________________ Page 2 of 8 chemicals which can cause birth defects or other reproductive harm. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. Skin Contact: Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and tissue destruction. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain; nausea; vomiting; and diarrhea; blood in the feces and/or vomitus may also be seen. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Methemoglobinemia: Signs/symptoms may include headache, dizziness, nausea, difficulty breathing, and generalized weakness. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Contains a chemical or chemicals which can cause cancer. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water for at least 15 minutes. Get immediate medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point >=110 ?C [Test Method: Closed Cup] Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available MATERIAL SAFETY DATA SHEET PM-8576 (Accelerator for 3M Panel Bonding Adhesive, P/N 08115) Internal Use Only 09/19/12 _________________________________________________________________________________________________ Page 3 of 8 OSHA Flammability Classification: Class IIIB Combustible Liquid 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards are anticipated. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Clean-up methods Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Contents may be under pressure, open carefully. Avoid breathing of vapors, mists or spray. Avoid skin contact. Avoid eye contact with vapors, mists, or spray. Avoid contact with oxidizing agents. 7.2 STORAGE Store away from acids. Keep container in well-ventilated area. Store away from areas where product may come into contact with food or pharmaceuticals. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION MATERIAL SAFETY DATA SHEET PM-8576 (Accelerator for 3M Panel Bonding Adhesive, P/N 08115) Internal Use Only 09/19/12 _________________________________________________________________________________________________ Page 4 of 8 8.1 ENGINEERING CONTROLS Provide appropriate local exhaust ventilation on open containers. Use in an enclosed process area is recommended. Do not use in a confined area or areas with little or no air movement. For additional health and precautionary information, including air monitoring methodology, contact 3M. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields Indirect Vented Goggles . 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Neoprene Polymer laminate . 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Avoid breathing of fumes. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece air-purifying respirator suitable for organic vapors/acid gases and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information DIMETHYL SILOXANE, REACTION PRODUCT WITH SILICA CMRG CEIL 5 mg/m3 SILICA, AMORPHOUS OSHA TWA concentration 0.8 mg/m3 SILICA, AMORPHOUS OSHA TWA 20 millions of particles/cu. ft. TOLUENE ACGIH TWA 20 ppm TOLUENE CMRG STEL 75 ppm Skin Notation* TOLUENE OSHA TWA 200 ppm TOLUENE OSHA CEIL 300 ppm TRIS(2,4,6- DIMETHYLAMINOMONOMETHYL)PHEN OL CMRG TWA 5 ppm * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: MATERIAL SAFETY DATA SHEET PM-8576 (Accelerator for 3M Panel Bonding Adhesive, P/N 08115) Internal Use Only 09/19/12 _________________________________________________________________________________________________ Page 5 of 8 ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Viscous Odor, Color, Grade: Tan Liquid Minor Amine odor. General Physical Form: Liquid Autoignition temperature No Data Available Flash Point >=110 ?C [Test Method: Closed Cup] Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Boiling Point > 110 ?C Density 9.5 lb/gal Vapor Density No Data Available Vapor Pressure <=200 mmHg [@ 20 ?C] Specific Gravity 1.2 [Ref Std: WATER=1] pH No Data Available Melting point No Data Available Solubility In Water No Data Available Evaporation rate <=1 [Ref Std: BUOAC=1] Hazardous Air Pollutants 0.05 lb HAPS/gal [Test Method: Calculated] Volatile Organic Compounds 0.5 % weight [Test Method: calculated per CARB title 2] Volatile Organic Compounds 5 g/l [Test Method: calculated SCAQMD rule 443.1] Kow - Oct/Water partition coef No Data Available Percent volatile 0.5 % Percent volatile Negligible VOC Less H2O & Exempt Solvents 5 g/l [Test Method: calculated SCAQMD rule 443.1] Viscosity 100000 - 225000 centipoise [Test Method: Brookfield] SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid Not determined 10.2 Materials to avoid Strong oxidizing agents Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified MATERIAL SAFETY DATA SHEET PM-8576 (Accelerator for 3M Panel Bonding Adhesive, P/N 08115) Internal Use Only 09/19/12 _________________________________________________________________________________________________ Page 6 of 8 SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose of according to the policies/procedures contained in the 3M Waste Management Program Manual and the instructions provided on the Waste Stream Profile Reference Sheet. Consult your Waste Management (RCRA) Coordinator with any questions. Consult 3M Waste Disposal Manual for proper procedures for packaging, labelling, marking, and shipping waste. Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): LB-K100-1275-3, 41-3700-8576-7 For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt INORGANIC SALT - NJTSRN 04499600-6317 (NITRATE COMPOUNDS (WATER DISSOCIABLE; REPORTABLE ONLY WHEN IN AQUEOUS SOLUTION)) Trade Secret 1 - 5 STATE REGULATIONS MATERIAL SAFETY DATA SHEET PM-8576 (Accelerator for 3M Panel Bonding Adhesive, P/N 08115) Internal Use Only 09/19/12 _________________________________________________________________________________________________ Page 7 of 8 Contact 3M for more information. CALIFORNIA PROPOSITION 65 Ingredient C.A.S. No. Classification TOLUENE 108-88-3 *Female reproductive toxin TOLUENE 108-88-3 *Developmental Toxin * WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. WHMIS: Hazardous US LABEL INFORMATION DANGER! Causes burns to eyes. Causes burns to the gastrointestinal tract. Causes burns to skin. Irritating to respiratory system. May cause sensitization by skin contact. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. PRECAUTIONS: See MSDS for suggested first aid and precautions. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 3 Flammability: 1 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 9: Property description for optional properties was modified. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. MATERIAL SAFETY DATA SHEET PM-8576 (Accelerator for 3M Panel Bonding Adhesive, P/N 08115) Internal Use Only 09/19/12 _________________________________________________________________________________________________ Page 8 of 8 In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M PM-81333 with Kaneka MX-257 (Base for 3M Panel Bonding Adhesive, P/N 08115) 09/03/14 __________________________________________________________________________________________ Page 1 of 13 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 31-5886-2 Version Number: 2.00 Issue Date: 09/03/14 Supercedes Date: 02/06/13 SECTION 1: Identification 1.1. Product identifier PM-81333 with Kaneka MX-257 (Base for 3M Panel Bonding Adhesive, P/N 08115) Product Identification Numbers 41-3588-1333-9 1.2. Recommended use and restrictions on use Recommended use Intermediate 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Serious Eye Damage/Irritation: Category 2A. Skin Sensitizer: Category 1. Carcinogenicity: Category 2. 2.2. Label elements Signal word Warning Symbols Exclamation mark | Health Hazard | Pictograms PM-81333 with Kaneka MX-257 (Base for 3M Panel Bonding Adhesive, P/N 08115) 09/03/14 __________________________________________________________________________________________ Page 2 of 13 Hazard Statements Causes serious eye irritation. May cause an allergic skin reaction. Suspected of causing cancer. Precautionary Statements Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapors/spray. Wear eye/face protection. Wear protective gloves. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. Storage: Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified None. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer 25068-38-6 30 - 60 Trade Secret * Glass Beads 65997-17-3 10 - 30 Trade Secret * 1,4-Bis[(2,3-Epoxypropoxy)Methyl]Cyclohexane 14228-73-0 7 - 13 Trade Secret * Fused Silica 60676-86-0 7 - 13 Trade Secret * Acrylate Polymer Trade Secret* 5 - 10 Trade Secret * Silica 7631-86-9 1 - 5 Trade Secret * 3-(Trimethoxysilyl)Propyl Glycidyl Ether 2530-83-8 0.5 - 1.5 Trade Secret * Dimethyl Siloxane, Reaction Product With Silica 67762-90-7 0.5 - 1.5 Trade Secret * Carbon Black 1333-86-4 <= 0.47 Trade Secret * Epichlorohydrin 106-89-8 < 0.012 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade PM-81333 with Kaneka MX-257 (Base for 3M Panel Bonding Adhesive, P/N 08115) 09/03/14 __________________________________________________________________________________________ Page 3 of 13 secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate PM-81333 with Kaneka MX-257 (Base for 3M Panel Bonding Adhesive, P/N 08115) 09/03/14 __________________________________________________________________________________________ Page 4 of 13 solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling For industrial or professional use only. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Store away from acids. Store away from strong bases. Store away from oxidizing agents. Store away from amines. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Ingredient C.A.S. No. Agency Limit type Additional Comments Epichlorohydrin 106-89-8 ACGIH TWA:0.5 ppm A3: Confirmed animal carcin., Skin Notation Epichlorohydrin 106-89-8 OSHA TWA:19 mg/m3(5 ppm) Skin Notation Carbon Black 1333-86-4 ACGIH TWA(inhalable fraction):3 mg/m3 A3: Confirmed animal carcin. Carbon Black 1333-86-4 CMRG TWA:0.5 mg/m3 Carbon Black 1333-86-4 OSHA TWA:3.5 mg/m3 3-(Trimethoxysilyl)Propyl Glycidyl Ether 2530-83-8 CMRG TWA:5 ppm SILICA, AMORPHOUS 60676-86-0 OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. Glass Beads 65997-17-3 Manufacturer determined TWA(as dust):10 mg/m3 Dimethyl Siloxane, Reaction Product With Silica 67762-90-7 CMRG CEIL:5 mg/m3 SILICA, AMORPHOUS 67762-90-7 OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. Silica 7631-86-9 CMRG TWA(as respirable dust):3 mg/m3 SILICA, AMORPHOUS 7631-86-9 OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls PM-81333 with Kaneka MX-257 (Base for 3M Panel Bonding Adhesive, P/N 08115) 09/03/14 __________________________________________________________________________________________ Page 5 of 13 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors, acid gases and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Viscous Odor, Color, Grade: Black, Viscous Liquid. Odor threshold No Data Available pH No Data Available Melting point No Data Available Boiling Point >=95 ?F Flash Point >=220 ?F [Test Method: Closed Cup] [Details: MITS data] Evaporation rate <=1 [Ref Std: BUOAC=1] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure <=27 psia [@ 131.0000000000 ?F] [Details: MITS data] Vapor Density No Data Available Density 8.2 lb/gal Specific Gravity Approximately 1.2 Units not avail. or not appl. [Ref Std: WATER=1] Solubility In Water No Data Available Solubility in Water Negligible PM-81333 with Kaneka MX-257 (Base for 3M Panel Bonding Adhesive, P/N 08115) 09/03/14 __________________________________________________________________________________________ Page 6 of 13 Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity 100,000 - 225,000 centipoise [Test Method: Brookfield] Volatile Organic Compounds 125.04 g/l [Test Method: calculated SCAQMD rule 443.1] [Details: Excluding exempt compounds (1.04 lb/gal)] Percent volatile 10.42 % Percent volatile Negligible VOC Less H2O & Exempt Solvents 125.04 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Sparks and/or flames 10.5. Incompatible materials Amines Strong acids Strong bases Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition Aldehydes Not Specified Carbon monoxide Not Specified Carbon dioxide Not Specified SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: PM-81333 with Kaneka MX-257 (Base for 3M Panel Bonding Adhesive, P/N 08115) 09/03/14 __________________________________________________________________________________________ Page 7 of 13 Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation Generic: GLASS FILAMENTS 65997-17-3 Grp. 2B: Possible human carc. International Agency for Research on Cancer Generic: GLASS FILAMENTS 65997-17-3 Anticipated human carcinogen National Toxicology Program Carcinogens Carbon Black 1333-86-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Epichlorohydrin 106-89-8 Grp. 2A: Probable human carc. International Agency for Research on Cancer Epichlorohydrin 106-89-8 Anticipated human carcinogen National Toxicology Program Carcinogens Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE > 5,000 mg/kg Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer Dermal Rat LD50 > 1,600 mg/kg 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer Ingestion Rat LD50 > 1,000 mg/kg Glass Beads Dermal LD50 estimated to be > 5,000 mg/kg Glass Beads Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg 1,4-Bis[(2,3-Epoxypropoxy)Methyl]Cyclohexane Dermal Rabbit LD50 2,500 mg/kg Fused Silica Dermal Rabbit LD50 > 5,000 mg/kg 1,4-Bis[(2,3-Epoxypropoxy)Methyl]Cyclohexane Ingestion Rat LD50 2,450 mg/kg Fused Silica Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Fused Silica Ingestion Rat LD50 > 5,110 mg/kg Acrylate Polymer Dermal Rabbit LD50 > 5,000 mg/kg Acrylate Polymer Ingestion Rat LD50 > 5,000 mg/kg Silica Dermal Rabbit LD50 > 5,000 mg/kg Silica Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Silica Ingestion Rat LD50 > 5,110 mg/kg 3-(Trimethoxysilyl)Propyl Glycidyl Ether Dermal Rabbit LD50 4,000 mg/kg 3-(Trimethoxysilyl)Propyl Glycidyl Ether Inhalation- Dust/Mist (4 hours) Rat LC50 > 5.3 mg/l 3-(Trimethoxysilyl)Propyl Glycidyl Ether Ingestion Rat LD50 7,010 mg/kg Dimethyl Siloxane, Reaction Product With Silica Dermal Rabbit LD50 > 5,000 mg/kg Dimethyl Siloxane, Reaction Product With Silica Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Dimethyl Siloxane, Reaction Product With Silica Ingestion Rat LD50 > 5,110 mg/kg Carbon Black Dermal Rabbit LD50 > 3,000 mg/kg Carbon Black Ingestion Rat LD50 > 8,000 mg/kg PM-81333 with Kaneka MX-257 (Base for 3M Panel Bonding Adhesive, P/N 08115) 09/03/14 __________________________________________________________________________________________ Page 8 of 13 Epichlorohydrin Dermal Rabbit LD50 755 mg/kg Epichlorohydrin Inhalation- Vapor (4 hours) Rat LC50 1.7 mg/l Epichlorohydrin Ingestion Rat LD50 260 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer Rabbit Mild irritant Glass Beads No significant irritation 1,4-Bis[(2,3-Epoxypropoxy)Methyl]Cyclohexane Mild irritant Fused Silica Rabbit No significant irritation Acrylate Polymer Minimal irritation Silica Rabbit No significant irritation 3-(Trimethoxysilyl)Propyl Glycidyl Ether Rabbit Mild irritant Dimethyl Siloxane, Reaction Product With Silica Rabbit No significant irritation Carbon Black Rabbit No significant irritation Epichlorohydrin Human and animal Corrosive Serious Eye Damage/Irritation Name Species Value 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer Rabbit Moderate irritant Glass Beads No significant irritation 1,4-Bis[(2,3-Epoxypropoxy)Methyl]Cyclohexane Mild irritant Fused Silica Rabbit No significant irritation Acrylate Polymer Mild irritant Silica Rabbit No significant irritation 3-(Trimethoxysilyl)Propyl Glycidyl Ether Rabbit Corrosive Dimethyl Siloxane, Reaction Product With Silica Rabbit No significant irritation Carbon Black Rabbit No significant irritation Epichlorohydrin Rabbit Corrosive Skin Sensitization Name Species Value 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer Human and animal Sensitizing 1,4-Bis[(2,3-Epoxypropoxy)Methyl]Cyclohexane similar compoun ds Sensitizing Fused Silica Human and animal Not sensitizing Silica Human and animal Not sensitizing 3-(Trimethoxysilyl)Propyl Glycidyl Ether Guinea pig Some positive data exist, but the data are not sufficient for classification Dimethyl Siloxane, Reaction Product With Silica Human and animal Not sensitizing Epichlorohydrin Human and animal Sensitizing Respiratory Sensitization Name Species Value 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer Human Some positive data exist, but the data are not sufficient for classification Germ Cell Mutagenicity Name Route Value PM-81333 with Kaneka MX-257 (Base for 3M Panel Bonding Adhesive, P/N 08115) 09/03/14 __________________________________________________________________________________________ Page 9 of 13 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer In vivo Not mutagenic 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer In Vitro Some positive data exist, but the data are not sufficient for classification Glass Beads In Vitro Some positive data exist, but the data are not sufficient for classification Fused Silica In Vitro Not mutagenic Silica In Vitro Not mutagenic 3-(Trimethoxysilyl)Propyl Glycidyl Ether In vivo Not mutagenic 3-(Trimethoxysilyl)Propyl Glycidyl Ether In Vitro Some positive data exist, but the data are not sufficient for classification Dimethyl Siloxane, Reaction Product With Silica In Vitro Not mutagenic Carbon Black In Vitro Not mutagenic Carbon Black In vivo Some positive data exist, but the data are not sufficient for classification Epichlorohydrin In Vitro Some positive data exist, but the data are not sufficient for classification Epichlorohydrin In vivo Mutagenic Carcinogenicity Name Route Species Value 4,4'-Isopropylidenediphenol-Epichlorohydrin Polymer Dermal Mouse Some positive data exist, but the data are not sufficient for classification Glass Beads Inhalation Multiple animal species Some positive data exist, but the data are not sufficient for classification Fused Silica Not Specified Mouse Some positive data exist, but the data are not sufficient for classification Silica Not Specified Mouse Some positive data exist, but the data are not sufficient for classification 3-(Trimethoxysilyl)Propyl Glycidyl Ether Dermal Mouse Not carcinogenic Dimethyl Siloxane, Reaction Product With Silica Not Specified Mouse Some positive data exist, but the data are not sufficient for classification Carbon Black Dermal Mouse Not carcinogenic Carbon Black Ingestion Mouse Not carcinogenic Carbon Black Inhalation Rat Carcinogenic Epichlorohydrin Dermal Mouse Not carcinogenic Epichlorohydrin Ingestion Rat Carcinogenic Epichlorohydrin Inhalation Rat Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration 4,4'-Isopropylidenediphenol- Epichlorohydrin Polymer Ingestion Not toxic to female reproduction Rat NOAEL 750 mg/kg/day 2 generation 4,4'-Isopropylidenediphenol- Epichlorohydrin Polymer Ingestion Not toxic to male reproduction Rat NOAEL 750 mg/kg/day 2 generation 4,4'-Isopropylidenediphenol- Epichlorohydrin Polymer Dermal Not toxic to development Rabbit NOAEL 300 mg/kg/day during organogenesi s 4,4'-Isopropylidenediphenol- Epichlorohydrin Polymer Ingestion Not toxic to development Rat NOAEL 750 mg/kg/day 2 generation Fused Silica Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation Fused Silica Inhalation Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Fused Silica Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s Silica Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation Silica Ingestion Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Silica Ingestion Not toxic to development Rat NOAEL 1,350 during organogenesi PM-81333 with Kaneka MX-257 (Base for 3M Panel Bonding Adhesive, P/N 08115) 09/03/14 __________________________________________________________________________________________ Page 10 of 13 mg/kg/day s 3-(Trimethoxysilyl)Propyl Glycidyl Ether Ingestion Not toxic to female reproduction Rat NOAEL 1,000 mg/kg/day 1 generation 3-(Trimethoxysilyl)Propyl Glycidyl Ether Ingestion Not toxic to male reproduction Rat NOAEL 1,000 mg/kg/day 1 generation 3-(Trimethoxysilyl)Propyl Glycidyl Ether Ingestion Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 3,000 mg/kg/day during organogenesi s Dimethyl Siloxane, Reaction Product With Silica Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation Dimethyl Siloxane, Reaction Product With Silica Ingestion Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Dimethyl Siloxane, Reaction Product With Silica Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s Epichlorohydrin Inhalation Not toxic to female reproduction Rat NOAEL 0.2 mg/l 10 weeks Epichlorohydrin Inhalation Not toxic to development Multiple animal species NOAEL 0.09 mg/l during organogenesi s Epichlorohydrin Ingestion Some positive developmental data exist, but the data are not sufficient for classification Multiple animal species NOAEL 160 mg/kg/day during gestation Epichlorohydrin Ingestion Toxic to male reproduction Rat LOAEL 6.25 mg/kg/day 23 days Epichlorohydrin Inhalation Toxic to male reproduction Rat NOAEL 0.02 mg/l 10 weeks Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration 1,4-Bis[(2,3- Epoxypropoxy)Methyl]Cyc lohexane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Epichlorohydrin Inhalation respiratory irritation May cause respiratory irritation Human NOAEL not available occupational exposure Epichlorohydrin Inhalation liver Some positive data exist, but the data are not sufficient for classification Human NOAEL not available occupational exposure Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration 4,4'- Isopropylidenediphenol- Epichlorohydrin Polymer Dermal liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,000 mg/kg/day 2 years 4,4'- Isopropylidenediphenol- Epichlorohydrin Polymer Dermal nervous system All data are negative Rat NOAEL 1,000 mg/kg/day 13 weeks 4,4'- Isopropylidenediphenol- Epichlorohydrin Polymer Ingestion auditory system | heart | endocrine system | hematopoietic system | liver | eyes | kidney and/or bladder All data are negative Rat NOAEL 1,000 mg/kg/day 28 days Glass Beads Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Human NOAEL not available occupational exposure Fused Silica Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure Silica Inhalation respiratory system | All data are negative Human NOAEL Not occupational PM-81333 with Kaneka MX-257 (Base for 3M Panel Bonding Adhesive, P/N 08115) 09/03/14 __________________________________________________________________________________________ Page 11 of 13 silicosis available exposure 3-(Trimethoxysilyl)Propyl Glycidyl Ether Ingestion heart | endocrine system | bone, teeth, nails, and/or hair | hematopoietic system | liver | immune system | nervous system | kidney and/or bladder | respiratory system All data are negative Rat NOAEL 1,000 mg/kg/day 28 days Dimethyl Siloxane, Reaction Product With Silica Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure Carbon Black Inhalation pneumoconiosis Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Epichlorohydrin Inhalation liver Causes damage to organs through prolonged or repeated exposure Rat NOAEL 0.21 mg/l 19 days Epichlorohydrin Inhalation kidney and/or bladder May cause damage to organs though prolonged or repeated exposure Rat NOAEL 0.04 mg/l 136 weeks Epichlorohydrin Inhalation endocrine system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.377 mg/l 4 weeks Epichlorohydrin Inhalation immune system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 0.211 mg/l 4 weeks Epichlorohydrin Inhalation heart Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.02 mg/l 98 days Epichlorohydrin Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL .002 mg/l 98 days Epichlorohydrin Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 0.02 mg/l 13 weeks Epichlorohydrin Inhalation blood All data are negative Rat NOAEL 0.189 mg/l 90 days Epichlorohydrin Ingestion heart | blood Some positive data exist, but the data are not sufficient for classification Rat NOAEL 80 mg/kg/day 12 weeks Epichlorohydrin Ingestion liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 25 mg/kg/day 90 days Aspiration Hazard Name Value Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. PM-81333 with Kaneka MX-257 (Base for 3M Panel Bonding Adhesive, P/N 08115) 09/03/14 __________________________________________________________________________________________ Page 12 of 13 SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification Epichlorohydrin 106-89-8 Male reproductive toxin Epichlorohydrin 106-89-8 Carcinogen Carbon Black 1333-86-4 Carcinogen WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. WARNING: This product contains a chemical known to the State of California to cause cancer. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification PM-81333 with Kaneka MX-257 (Base for 3M Panel Bonding Adhesive, P/N 08115) 09/03/14 __________________________________________________________________________________________ Page 13 of 13 Health: 2 Flammability: 1 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 31-5886-2 Version Number: 2.00 Issue Date: 09/03/14 Supercedes Date: 02/06/13 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com