FVP FOAMING ENGINE DEGREASER 14.5 OZ. according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 07/11/18 : Version: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : FVP FOAMING ENGINE DEGREASER 14.5 OZ. Product code : FVPED-14.5 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Degreaser 1.3. Details of the supplier of the safety data sheet Factory Motor Parts 1380 Corporate center Curve Ste. 200 Eagan, MN 55121 (866) 387-3343 1.4. Emergency telephone number Emergency number :Infotrac 24 Hour 1-800-535-5053, 1-703-527-3887 (International) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Compressed gas H280 Skin Irrit. 2 H315 Eye Irrit. 2B H320 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS04 GHS07 Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H280 - Contains gas under pressure; may explode if heated H315 - Causes skin irritation H320 - Causes eye irritation Precautionary statements (GHS-US) : P264 - Wash affected areas thoroughly after handling P280 - Wear protective gloves,protective clothing,eye protection,face protection P302+P352 - If on skin: Wash with plenty of soap and water P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P321 - Specific treatment: See section 4.1 on SDS P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse P410+P403 - Protect from sunlight. Store in a well-ventilated place 2.3. Other hazards Other hazards not contributing to the classification 2.4. Unknown acute toxicity (GHS-US) No data available : Contains gas under pressure; may explode if heated. SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification (GHS-US) Water (CAS No) ?7732-18-5 85 - 95 Not classified Petroleum Gases, Liquefied, Sweetened (CAS No) ?68476-86-8 1 - 5 Flam. Gas 1, H220 Flam. Liq. 1, H224 11/02/2015 EN (English US) 1/9 Name Product identifier % Classification (GHS-US) 2-Butoxyethanol (CAS No) ?111-76-2 1 - 5 Flam. Liq. 4, H227 Acute Tox. 4 (Oral), H302 Acute Tox. 3 (Dermal), H311 Acute Tox. 4 (Inhalation:dust,mist), H332 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Nonlyphenol Ethoxylate (CAS No) ?127087-87-0 < 1 Eye Irrit. 2B, H320 Ammonium Hydroxide, Aqueous Solution, Conc=25% (CAS No) ?1336-21-6 < 1 Skin Corr. 1B, H314 Aquatic Acute 1, H400 Sodium Hydroxide, Conc=50%, Aqueous Solution (CAS No) ?1310-73-2 0.0132 - 0.1236 Acute Tox. 4 (Dermal), H312 Skin Corr. 1A, H314 Eye Dam. 1, H318 STOT SE 3, H335 Aquatic Acute 2, H401 Polyethylene Glycol 200-600 (CAS No) ?25322-68-3 <= 0.0288 Not classified Nonyl Nonoxynol-5 (CAS No) ?9014-93-1 <= 0.0192 Not classified Sodium Chloride (CAS No) ?7647-14-5 0 - 0.012 Not classified SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. First-aid measures after eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause irritation or asthma-like symptoms. Symptoms/injuries after skin contact : Itching. Red skin. Skin rash/inflammation. Causes skin irritation. Symptoms/injuries after eye contact : Irritation of the eye tissue. Redness of the eye tissue. Inflammation/damage of the eye tissue. Causes eye irritation. Symptoms/injuries after ingestion : May be harmful if swallowed and enters airways. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Other information : NFPA Aerosol Level 1. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. 6.1.1. For non-emergency personnel Protective equipment : Gloves. Safety glasses. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers. Plug the leak, cut off the supply. Methods for cleaning up : Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Pressurized container: Do not pierce or burn, even after use. Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Hygiene measures : Do not eat, drink or smoke when using this product. Wash affected areas thoroughly after handling. Wash contaminated clothing before reuse. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Comply with applicable regulations. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Storage area : Store in a well-ventilated place. 7.3. Specific end use(s) Follow Label Directions. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Petroleum Gases, Liquefied, Sweetened (68476-86-8) USA ACGIH ACGIH TWA (ppm) 1000 ppm Listed under Aliphatic hydrocarbon gases alkane C1-C4 USA OSHA OSHA PEL (TWA) (mg/m?) 1800 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm 2-Butoxyethanol (111-76-2) USA ACGIH ACGIH TWA (mg/m?) 97 mg/m? USA ACGIH ACGIH TWA (ppm) 20 ppm USA ACGIH ACGIH STEL (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 240 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 50 ppm 8.2. Exposure controls Appropriate engineering controls : Local exhaust venilation, vent hoods. Personal protective equipment : Gloves. Safety glasses. Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : Wear appropriate mask. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Gas Appearance : Liquid. Color : Milky. Odor : Mild . Characteristic. Odor threshold : No data available pH : 10 Relative evaporation rate (butyl acetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : -31.1 ?C (Lowest Component) Flash point : -128.9 ?C (Lowest Component) Auto-ignition temperature : 237.8 ?C (Lowest Component) Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : No data available Relative vapor density at 20 ?C : No data available Relative density : 0.99 Solubility : Soluble in water. Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information VOC content : 7.7 % SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Toxic fume. . Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified 2-Butoxyethanol (111-76-2) LD50 oral rat 530 mg/kg (Rat; Equivalent or similar to OECD 401; Literature study; 1746 mg/kg bodyweight; Rat; Experimental value) LD50 dermal rat > 2000 mg/kg body weight (Rat; Experimental value; OECD 402: Acute Dermal Toxicity) LD50 dermal rabbit 435 mg/kg (435 mg/kg bodyweight; Rabbit; Rabbit; Experimental value,435 mg/kg bodyweight; Rabbit; Rabbit; Experimental value) LC50 inhalation rat (mg/l) 2.17 mg/l/4h (Rat; Experimental value; 2.35 mg/l/4h; Rat; Experimental value) LC50 inhalation rat (ppm) 450-486,Rat; Weight of evidence Polyethylene Glycol 200-600 (25322-68-3) LD50 oral rat > 15000 mg/kg (Rat) LD50 dermal rabbit > 20000 mg/kg (Rabbit) Sodium Chloride (7647-14-5) LD50 oral rat 3000 mg/kg (Rat; Experimental value; 3550 mg/kg bodyweight; Rat; Experimental value) LD50 dermal rabbit > 10000 mg/kg (Rabbit; Experimental value) Skin corrosion/irritation : Causes skin irritation. pH: 10 Serious eye damage/irritation : Causes eye irritation. pH: 10 Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified 2-Butoxyethanol (111-76-2) IARC group 3 Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Symptoms/injuries after inhalation : May cause irritation or asthma-like symptoms. Symptoms/injuries after skin contact : Itching. Red skin. Skin rash/inflammation. Causes skin irritation. Symptoms/injuries after eye contact : Irritation of the eye tissue. Redness of the eye tissue. Inflammation/damage of the eye tissue. Causes eye irritation. Symptoms/injuries after ingestion : May be harmful if swallowed and enters airways. SECTION 12: Ecological information 12.1. Toxicity 2-Butoxyethanol (111-76-2) LC50 fish 1 116 ppm (96 h; Cyprinodon variegatus; Nominal concentration) EC50 Daphnia 1 1700 mg/l (48 h; Daphnia sp.; Nominal concentration) LC50 fish 2 1341 ppm (96 h; Lepomis macrochirus) EC50 Daphnia 2 1720 mg/l (24 h; Daphnia magna) TLM fish 1 100 - 1000,96 h; Pisces TLM other aquatic organisms 1 100 - 1000,96 h Threshold limit algae 1 900 mg/l (168 h; Scenedesmus quadricauda) Threshold limit algae 2 35 mg/l (192 h; Microcystis aeruginosa) Polyethylene Glycol 200-600 (25322-68-3) LC50 fish 1 > 1000 mg/l (96 h; Pisces) LC50 other aquatic organisms 1 > 1000 mg/l (96 h) LC50 fish 2 > 5000 mg/l (24 h; Carassius auratus) Threshold limit other aquatic organisms 1 <= 100 mg/l (96 h; Plankton) Threshold limit other aquatic organisms 2 > 1000 mg/l Threshold limit algae 2 500 mg/l (720 h; Algae; No effect) Sodium Chloride (7647-14-5) LC50 fish 1 11100 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) EC50 Daphnia 1 1000 mg/l (48 h; Daphnia magna) LC50 fish 2 5840 mg/l (96 h; Lepomis macrochirus) EC50 Daphnia 2 340.7 mg/l (48 h; Daphnia magna) Threshold limit algae 1 4967 mg/l (72 h; Algae; Inhibitory) Threshold limit algae 2 2430 mg/l (120 h; Algae) 12.2. Persistence and degradability FVP FOAMING ENGINE DEGREASER 14.5 OZ. Persistence and degradability Not established. Petroleum Gases, Liquefied, Sweetened (68476-86-8) Persistence and degradability Not established. 2-Butoxyethanol (111-76-2) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Photodegradation in the air. Biochemical oxygen demand (BOD) 0.71 g O?? ?/g substance Chemical oxygen demand (COD) 2.20 g O?? ?/g substance ThOD 2.305 g O?? ?/g substance BOD (% of ThOD) 0.31 % ThOD Polyethylene Glycol 200-600 (25322-68-3) Persistence and degradability Biodegradability in water: no data available. Nonyl Nonoxynol-5 (9014-93-1) Persistence and degradability Not established. Nonlyphenol Ethoxylate (127087-87-0) Persistence and degradability Not established. Ammonium Hydroxide, Aqueous Solution, Conc=25% (1336-21-6) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. No (test)data on mobility of the components available. Ozonation in the air. Water (7732-18-5) Persistence and degradability Not established. Sodium Hydroxide, Conc=50%, Aqueous Solution (1310-73-2) Persistence and degradability Biodegradability: not applicable. No (test)data on mobility of the components available. Sodium Chloride (7647-14-5) Persistence and degradability Biodegradability: not applicable. No (test)data on mobility of the substance available. Biochemical oxygen demand (BOD) Not applicable Chemical oxygen demand (COD) Not applicable ThOD Not applicable BOD (% of ThOD) Not applicable 12.3. Bioaccumulative potential FVP FOAMING ENGINE DEGREASER 14.5 OZ. Bioaccumulative potential Not established. Petroleum Gases, Liquefied, Sweetened (68476-86-8) Bioaccumulative potential Not established. 2-Butoxyethanol (111-76-2) Log Pow 0.81 (Experimental value; BASF test; 25 ?C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Polyethylene Glycol 200-600 (25322-68-3) Log Pow -1.2 Bioaccumulative potential Bioaccumulation: not applicable. Nonyl Nonoxynol-5 (9014-93-1) Bioaccumulative potential Not established. Nonlyphenol Ethoxylate (127087-87-0) Bioaccumulative potential Not established. Ammonium Hydroxide, Aqueous Solution, Conc=25% (1336-21-6) Bioaccumulative potential Not bioaccumulative. Water (7732-18-5) Bioaccumulative potential Not established. Sodium Hydroxide, Conc=50%, Aqueous Solution (1310-73-2) Bioaccumulative potential Does not contain bioaccumulative component(s). Sodium Chloride (7647-14-5) Log Pow -3.0 (Calculated) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). 12.4. Mobility in soil 2-Butoxyethanol (111-76-2) Surface tension 0.027 N/m (25 ?C) 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN US DOT (ground): UN1950, Aerosols, 2.2, Limited Quantity ICAO/IATA (air): UN1950, Aerosols, 2.2 , Limited Quantity IMO/IMDG (water): UN1950, Aerosols, 2.2 , Limited Quantity 14.2. UN proper shipping name Proper Shipping Name (DOT) : Aerosols non-flammable, (each not exceeding 1 L capacity) Department of Transportation (DOT) Hazard Classes : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115 Hazard labels (DOT) : 2.2 - Non-flammable gas DOT Packaging Exceptions (49 CFR 173.xxx) : 306 DOT Packaging Non Bulk (49 CFR 173.xxx) : None DOT Packaging Bulk (49 CFR 173.xxx) : None 14.3. Additional information Other information : No supplementary information available. Overland transport No additional information available Transport by sea DOT Vessel Stowage Location : A - The material may be stowed ??on deck?? or ??under deck?? on a cargo vessel and on a passenger vessel. DOT Vessel Stowage Other : 48 - Stow ??away from?? sources of heat,87 - Stow ??separated from?? Class 1 (explosives) except Division 14,126 - Segregation same as for Class 9, miscellaneous hazardous materials Air transport DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : 75 kg : 150 kg SECTION 15: Regulatory information 15.1. US Federal regulations FVP FOAMING ENGINE DEGREASER 14.5 OZ. SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard Immediate (acute) health hazard Sudden release of pressure hazard Petroleum Gases, Liquefied, Sweetened (68476-86-8) SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Fire hazard Sudden release of pressure hazard Nonlyphenol Ethoxylate (127087-87-0) Listed on United States SARA Section 313 SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard Immediate (acute) health hazard Nonlyphenol Ethoxylate (127087-87-0) SARA Section 313 - Emission Reporting 5 % Glycol Ethers Sodium Hydroxide, Conc=50%, Aqueous Solution (1310-73-2) Listed on the United States SARA Section 302 SARA Section 311/312 Hazard Classes Immediate (acute) health hazard 15.2. International regulations CANADA FVP FOAMING ENGINE DEGREASER 14.5 OZ. WHMIS Classification Class A - Compressed Gas Sodium Hydroxide, Conc=50%, Aqueous Solution (1310-73-2) Listed on the Canadian DSL (Domestic Sustances List) WHMIS Classification Class E - Corrosive Material EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Carc.Cat.1; R45 Muta.Cat.2; R46 F+; R12 Xi; R36/38 Full text of R-phrases: see section 16 15.2.2. National regulations No additional information available 15.3. US State regulations 2-Butoxyethanol (111-76-2) U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - New Jersey - Right to Know Hazardous Substance List Sodium Hydroxide, Conc=50%, Aqueous Solution (1310-73-2) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) - Special Hazardous Substances Rhode Island Right to Know SECTION 16: Other information Other information : None. Full text of H-phrases: see section 16: Skin Corr. 1A Skin corrosion/irritation Category 1A Skin Corr. 1B Skin corrosion/irritation Category 1B Skin Irrit. 2 Skin corrosion/irritation Category 2 STOT SE 3 Specific target organ toxicity (single exposure) Category 3 H220 Extremely flammable gas H224 Extremely flammable liquid and vapor H227 Combustible liquid H280 Contains gas under pressure; may explode if heated H302 Harmful if swallowed H311 Toxic in contact with skin H312 Harmful in contact with skin H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H319 Causes serious eye irritation H320 Causes eye irritation H332 Harmful if inhaled H335 May cause respiratory irritation H400 Very toxic to aquatic life H401 Toxic to aquatic life NFPA health hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health : 2 Moderate Hazard - Temporary or minor injury may occur Flammability : 1 Slight Hazard Physical : 1 Slight Hazard Personal Protection : B SDS US (GHS HazCom 2012) - TCC The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in c ompliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these d ata. No warranty against infringement of any patent, copyright or trademark is made or implied.