3M? Glass Cleaner, P.N. 08888, 39888, 46600 05/21/18 __________________________________________________________________________________________ Page 1 of 11 Safety Data Sheet Copyright,2018,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 08-3027-3 Version Number: 15.00 Issue Date: 05/21/18 Supercedes Date: 09/29/16 SECTION 1: Identification 1.1. Product identifier 3M? Glass Cleaner, P.N. 08888, 39888, 46600 Product Identification Numbers 60-4550-3014-2, 60-4550-4507-4, 60-4550-6504-9, 60-4550-7145-0 1.2. Recommended use and restrictions on use Recommended use Automotive, Automotive Glass Cleaner 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Aerosol: Category 2. Gas Under Pressure: Liquefied gas. Specific Target Organ Toxicity (single exposure): Category 1. 2.2. Label elements Signal word Danger Symbols Flame | Gas cylinder | Health Hazard | 3M? Glass Cleaner, P.N. 08888, 39888, 46600 05/21/18 __________________________________________________________________________________________ Page 2 of 11 Pictograms Hazard Statements Flammable aerosol. Contains gas under pressure; may explode if heated. Causes damage to organs: cardiovascular system | Precautionary Statements General: Keep out of reach of children. Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF exposed: Call a POISON CENTER or doctor/physician. Specific treatment (see Notes to Physician on this label). Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 5% of the mixture consists of ingredients of unknown acute dermal toxicity. 5% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Water 7732-18-5 60 - 100 Trade Secret * 2-Butoxyethanol 111-76-2 3 - 7 Trade Secret * Isobutane 75-28-5 3 - 7 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. 3M? Glass Cleaner, P.N. 08888, 39888, 46600 05/21/18 __________________________________________________________________________________________ Page 3 of 11 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. Get medical attention. Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with water. Seal the container. Dispose of collected material as soon as possible in accordance with 3M? Glass Cleaner, P.N. 08888, 39888, 46600 05/21/18 __________________________________________________________________________________________ Page 4 of 11 applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. 7.2. Conditions for safe storage including any incompatibilities Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Protect from sunlight. Store in a well- ventilated place. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments 2-Butoxyethanol 111-76-2 ACGIH TWA:20 ppm A3: Confirmed animal carcin. 2-Butoxyethanol 111-76-2 OSHA TWA:240 mg/m3(50 ppm) SKIN Isobutane 75-28-5 ACGIH STEL:1000 ppm Natural gas 75-28-5 ACGIH Limit value not established: simple asphyxiant ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety Glasses with side shields Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Butyl Rubber 3M? Glass Cleaner, P.N. 08888, 39888, 46600 05/21/18 __________________________________________________________________________________________ Page 5 of 11 Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Aerosol Odor, Color, Grade: clear solvent odor. Odor threshold No Data Available pH 11 Melting point No Data Available Boiling Point No Data Available Flash Point No flash point Evaporation rate Approximately 45 Units not avail. or not appl. [Ref Std:ETHER=1] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure No Data Available Vapor Density 4.07 [Ref Std:AIR=1] Density 0.96 g/ml Specific Gravity 0.96 [Ref Std:WATER=1] [Details:CONDITIONS: @ 70F] Solubility in Water Complete Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity Not Applicable Hazardous Air Pollutants 0 % weight [Test Method:Calculated] Molecular weight No Data Available Volatile Organic Compounds 94 g/l [Test Method:calculated SCAQMD rule 443.1] Volatile Organic Compounds 9.9 % weight [Test Method:calculated per CARB title 2] VOC Less H2O & Exempt Solvents 947 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid 3M? Glass Cleaner, P.N. 08888, 39888, 46600 05/21/18 __________________________________________________________________________________________ Page 6 of 11 None known. 10.5. Incompatible materials None known. 10.6. Hazardous decomposition products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified Toxic Vapor, Gas, Particulate Not Specified SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Eye Contact: Sprayed material may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value 3M? Glass Cleaner, P.N. 08888, 39888, 46600 05/21/18 __________________________________________________________________________________________ Page 7 of 11 Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE >50 mg/l Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Isobutane Inhalation- Gas (4 hours) Rat LC50 276,000 ppm 2-Butoxyethanol Dermal Guinea pig LD50 > 2,000 mg/kg 2-Butoxyethanol Inhalation- Vapor (4 hours) Guinea pig LC50 > 2.6 mg/l 2-Butoxyethanol Ingestion Guinea pig LD50 1,414 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Isobutane Professio nal judgeme nt No significant irritation 2-Butoxyethanol Rabbit Irritant Serious Eye Damage/Irritation Name Species Value Isobutane Professio nal judgeme nt No significant irritation 2-Butoxyethanol Rabbit Severe irritant Skin Sensitization Name Species Value 2-Butoxyethanol Guinea pig Not classified Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Isobutane In Vitro Not mutagenic 2-Butoxyethanol In Vitro Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value 2-Butoxyethanol Inhalation Multiple animal species Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration 2-Butoxyethanol Dermal Not classified for development Rat NOAEL 1,760 during 3M? Glass Cleaner, P.N. 08888, 39888, 46600 05/21/18 __________________________________________________________________________________________ Page 8 of 11 mg/kg/day gestation 2-Butoxyethanol Ingestion Not classified for development Rat NOAEL 100 mg/kg/day during organogenesi s 2-Butoxyethanol Inhalation Not classified for development Multiple animal species NOAEL 0.48 mg/l during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Isobutane Inhalation cardiac sensitization Causes damage to organs Multiple animal species NOAEL Not available Isobutane Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Isobutane Inhalation respiratory irritation Not classified Mouse NOAEL Not available 2-Butoxyethanol Dermal endocrine system Not classified Rabbit NOAEL 902 mg/kg 6 hours 2-Butoxyethanol Dermal liver Not classified Rabbit LOAEL 72 mg/kg not available 2-Butoxyethanol Dermal kidney and/or bladder Not classified Rabbit LOAEL 451 mg/kg 6 hours 2-Butoxyethanol Dermal blood Not classified Multiple animal species NOAEL Not available 2-Butoxyethanol Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available 2-Butoxyethanol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available 2-Butoxyethanol Inhalation blood Not classified Multiple animal species NOAEL Not available 2-Butoxyethanol Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available 2-Butoxyethanol Ingestion blood Not classified Multiple animal species NOAEL Not available 2-Butoxyethanol Ingestion kidney and/or bladder Not classified Human NOAEL Not available poisoning and/or abuse Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Isobutane Inhalation kidney and/or bladder Not classified Rat NOAEL 4,500 ppm 13 weeks 2-Butoxyethanol Dermal blood Not classified Multiple animal species NOAEL Not available not available 2-Butoxyethanol Dermal endocrine system Not classified Rabbit NOAEL 150 mg/kg/day 90 days 2-Butoxyethanol Inhalation liver Not classified Rat NOAEL 2.4 mg/l 14 weeks 2-Butoxyethanol Inhalation kidney and/or bladder Not classified Rat NOAEL 0.15 mg/l 14 weeks 2-Butoxyethanol Inhalation blood Not classified Rat LOAEL 0.15 mg/l 6 months 2-Butoxyethanol Inhalation endocrine system Not classified Dog LOAEL 1.9 mg/l 8 days 3M? Glass Cleaner, P.N. 08888, 39888, 46600 05/21/18 __________________________________________________________________________________________ Page 9 of 11 2-Butoxyethanol Ingestion blood Not classified Rat LOAEL 69 mg/kg/day 13 weeks 2-Butoxyethanol Ingestion kidney and/or bladder Not classified Multiple animal species NOAEL Not available not available Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of waste product in a permitted industrial waste facility. Facility must be capable of handling aerosol cans. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Flammable (gases, aerosols, liquids, or solids) Gas under pressure Health Hazards Specific target organ toxicity (single or repeated exposure) Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): 3M? Glass Cleaner, P.N. 08888, 39888, 46600 05/21/18 __________________________________________________________________________________________ Page 10 of 11 Ingredient C.A.S. No % by Wt 2-Butoxyethanol (GLYCOL ETHERS) 111-76-2 3 - 7 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 1 Flammability: 2 Instability: 0 Special Hazards: None Aerosol Storage Code: 1 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: *1 Flammability: 2 Physical Hazard: 0 Personal Protection: G Hazardous Material Identification System (HMIS? IV) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS? IV ratings are to be used with a fully implemented HMIS? IV program. HMIS? is a registered mark of the American Coatings Association (ACA). Document Group: 08-3027-3 Version Number: 15.00 Issue Date: 05/21/18 Supercedes Date: 09/29/16 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from3M 3M USA SDSs are available at www.3M.com 3M? Glass Cleaner, P.N. 08888, 39888, 46600 05/21/18 __________________________________________________________________________________________ Page 11 of 11