Lucas &RPSOHWH?(QJLQH?7UHDWPHQW Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 05/11/2016 Version: 1.0 05/11/2016 EN (English) SDS ID: LO1605001 Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Identification Product form Product name : Mixture : Lucas &RPSOHWH?(QJLQH?7UHDWPHQW? Other means of identification : Part number: 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Fuel System Cleaner and Lubricant 1.3. Details of the supplier of the safety data sheet Lucas Oil Products, Inc 302 North Sheridan Street Corona, California 92880-2067 - USA T (951) 270-0154 - F (951) 270-1902 This email address is being protected from spambots. You need JavaScript enabled to view it. - www.LucasOil.com 1.4. Emergency telephone number Emergency number : (951) 493-1149 (951) 847-5949 7:00A.M. to 5:00P.M. Monday thru Friday SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Flam. Liq. 4 H227 - Combustible liquid Asp. Tox. 1 H304 - May be fatal if swallowed and enters airways Full text of H statements : see section 16 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H227 - Combustible liquid H304 - May be fatal if swallowed and enters airways Precautionary statements (GHS-US) : P210 - Keep away from heat, sparks, open flames. - No smoking P280 - Wear eye protection, protective gloves P301+P310 - If swallowed: Immediately call a doctor P331 - Do NOT induce vomiting P370+P378 - In case of fire: Use carbon dioxide (CO2), Dry chemical, foam to extinguish P403+P235 - Store in a well-ventilated place. Keep cool P405 - Store locked up P501 - Dispose of contents/container to an approved waste disposal plant 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 10016 Lucas &RPSOHWH?(QJLQH?7UHDWPHQW Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2016 EN (English) SDS ID: LO1605001 2/7 3.2. Mixture Name Product identifier % GHS-US classification Distillates (petroleum), hydrotreated light (CAS No) 64742-47-8 35 ? 45 Flam. Liq. 4, H227 Asp. Tox. 1, H304 Hydrocarbyl amine 0.5 ? 5 Aquatic Chronic 3, H412 *Chemical name, CAS number and/or exact concentration have been withheld as a trade secret Full text of H-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : If medical advice is needed, have product container or label at hand. Never give anything by mouth to an unconscious person. First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. First-aid measures after skin contact : Gently wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention. First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. First-aid measures after ingestion : Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. Risk of aspiration pneumonia. If vomiting occurs have person lean forward. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. Abdominal cramps. Risk of aspiration pneumonia. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Carbon dioxide. Dry chemical. Foam. Unsuitable extinguishing media : Do not use a solid water stream as it may scatter and spread fire. 5.2. Special hazards arising from the substance or mixture Fire hazard : Combustible liquid. Flammable vapours may accumulate in the container. Heavier than air, vapours may travel long distances along ground, ignite and flash back to source. Explosion hazard : May form flammable/explosive vapour-air mixture. Flammable vapours heavier than air/can accumulate. Reactivity : No dangerous reactions known. 5.3. Advice for firefighters Firefighting instructions : Cool adjacent structures and containers with water spray to protect and prevent ignition. Protection during firefighting : Wear a self contained breathing apparatus. Wear fire/flame resistant/retardant clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. Avoid all eye and skin contact and do not breathe vapour and mist. 6.1.1. For non-emergency personnel Protective equipment : Refer to section 8.2. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Refer to section 8.2. Emergency procedures : Ventilate area. Stop leak if safe to do so. 6.2. Environmental precautions Do not discharge into drains or the environment. 6.3. Methods and material for containment and cleaning up For containment : Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Stop leak if safe to do so. Lucas &RPSOHWH?(QJLQH?7UHDWPHQW Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2016 EN (English) SDS ID: LO1605001 3/7 Methods for cleaning up : Absorb and/or contain spill with inert material, then place in suitable container. 6.4. Reference to other sections Section 7: safe handling. Section 8: personal protective equipment. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapours are flammable. Keep away from Sources of ignition. - No smoking. Flammable vapours heavier than air/can accumulate. Vapour could travel to source of ignition and flash back. Precautions for safe handling : No open flames. No smoking. Avoid all eye and skin contact and do not breathe vapour and mist. Use personal protective equipment as required. Use only outdoors or in a well-ventilated area. Handle in accordance with good industrial hygiene and safety procedures. Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Do not eat, drink or smoke when using this product. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Storage conditions : Keep in fireproof place. Keep container closed when not in use. Incompatible products : Oxidizer. Incompatible materials : Heat sources. Heat and ignition sources : Keep away from heat, sparks and flame. Prohibitions on mixed storage : Incompatible materials. Storage area : Store in dry, cool, well-ventilated area. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Lucas &RPSOHWH?(QJLQH?7UHDWPHQW ACGIH Not applicable OSHA Not applicable Hydrocarbyl amine ACGIH Not applicable OSHA Not applicable Distillates (petroleum), hydrotreated light (64742-47-8) ACGIH Not applicable OSHA Not applicable 8.2. Exposure controls Appropriate engineering controls : Avoid splashing. Ensure good ventilation of the work station. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Use rubber gloves. nitrile rubber gloves. neoprene gloves. Eye protection : Chemical goggles or safety glasses. Respiratory protection : No special respiratory protection equipment is recommended under normal conditions of use with adequate ventilation. Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. Disposable half mask. Use an approved respirator equipped with oil/mist cartridges. Appropriate self-contained breathing apparatus may be required. Environmental exposure controls : Prevent leakage or spillage. Prevent contaminated water run-off. Other information : Do not eat, drink or smoke when using this product. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : amber Odour : petroleum Odour threshold : No data available Lucas &RPSOHWH?(QJLQH?7UHDWPHQW Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2016 EN (English) SDS ID: LO1605001 4/7 pH : No data available Melting point : No data available Freezing point : No data available Boiling point : No data available Flash point : >= 71.1 ?C Relative evaporation rate (butyl acetate=1) : No data available Flammability (solid, gas) : No data available Explosive limits : No data available Explosive properties : No data available Oxidising properties : No data available Vapour pressure : No data available Relative density : 0.837 Relative vapour density at 20 ?C : No data available Solubility : insoluble in water. Log Pow : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity : No data available Viscosity, kinematic : 8.52 cSt @ 40 ?C Viscosity, dynamic : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reactions known. 10.2. Chemical stability Combustible liquid. May form flammable/explosive vapour-air mixture. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Open flame. Overheating. Direct sunlight. Heat. Sparks. 10.5. Incompatible materials Oxidizer. 10.6. Hazardous decomposition products May release flammable gases. Incomplete combustion will generate : Carbon oxides (CO, CO2). Aldehydes. hydrogen sulphide. Mercaptans. SECTION 11: Toxicological information 11.1. Information on toxicological effects Likely routes of exposure : Inhalation; Skin and eye contact Acute toxicity : Not classified Distillates (petroleum), hydrotreated light (64742-47-8) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitisation : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Distillates (petroleum), hydrotreated light (64742-47-8) IARC group Not listed in carcinogenicity class National Toxicology Program (NTP) Status Not listed in carcinogenicity class Lucas &RPSOHWH?(QJLQH?7UHDWPHQW Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2016 EN (English) SDS ID: LO1605001 5/7 Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : May be fatal if swallowed and enters airways. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. Abdominal cramps. Risk of aspiration pneumonia. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : No ecotoxicological data about this product are known. Hydrocarbyl amine LC50 fish 1 31 mg/l 96 h EC50 Daphnia 1 > 100 mg/l 48 h 12.2. Persistence and degradability Lucas &RPSOHWH?(QJLQH?7UHDWPHQW Persistence and degradability Not established. Hydrocarbyl amine Persistence and degradability Not readily biodegradable. 12.3. Bioaccumulative potential Lucas &RPSOHWH?(QJLQH?7UHDWPHQW Bioaccumulative potential Not established. Distillates (petroleum), hydrotreated light (64742-47-8) Log Kow 2.1 - 5 Bioaccumulative potential Bioaccumulative potential. 12.4. Mobility in soil Lucas &RPSOHWH?(QJLQH?7UHDWPHQW Ecology - soil No additional information available. 12.5. Other adverse effects Other information : No additional information available. SECTION 13: Disposal considerations 13.1. Waste treatment methods Sewage disposal recommendations : Do not dispose of waste into sewer. Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Additional information : Handle empty containers with care because residual vapours are flammable. Ecology - waste materials : Hazardous waste due to toxicity. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Transport document description : NA1993 Combustible liquid, n.o.s. (Distillates, petroleum, hydrotreated light), 3, III UN-No.(DOT) : NA1993 Proper Shipping Name (DOT) : Combustible liquid, n.o.s. Distillates, petroleum, hydrotreated light Transport hazard class(es) (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120 Packing group (DOT) : III - Minor Danger DOT Packaging Non Bulk (49 CFR 173.xxx) : 203 DOT Packaging Bulk (49 CFR 173.xxx) : 241 DOT Symbols : D - Proper shipping name for domestic use only, or to and from Canada,G - Identifies PSN requiring a technical name Lucas &RPSOHWH?(QJLQH?7UHDWPHQW Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2016 EN (English) SDS ID: LO1605001 6/7 DOT Special Provisions (49 CFR 172.102) : IB3 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized, except for UN2672 (also see Special Provision IP8 in Table 2 for UN2672) T1 - 1.5 178.274(d)(2) Normal............. 178.275(d)(2) T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3) TP1 - The maximum degree of filling must not exceed the degree of filling determined by the following: Degree of filling = 97 / (1 + a (tr - tf)) Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling DOT Packaging Exceptions (49 CFR 173.xxx) : 150 DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : 60 L DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : 220 L DOT Vessel Stowage Location : A - The material may be stowed ??on deck?? or ??under deck?? on a cargo vessel and on a passenger vessel Emergency Response Guide (ERG) Number : 128 Other information : No supplementary information available. TDG No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations Hydrocarbyl amine Listed on the United States TSCA (Toxic Substances Control Act) inventory Distillates (petroleum), hydrotreated light (64742-47-8) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA Hydrocarbyl amine Listed on the Canadian DSL (Domestic Substances List) inventory Distillates (petroleum), hydrotreated light (64742-47-8) Listed on the Canadian DSL (Domestic Substances List) inventory EU-Regulations Distillates (petroleum), hydrotreated light (64742-47-8) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) National regulations Distillates (petroleum), hydrotreated light (64742-47-8) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the AICS (Australian Inventory of Chemical Substances) Listed on Taiwan National Chemical Inventory Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on KECI (Korean Existing Chemicals Inventory) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) 15.3. US State regulations No additional information available Lucas &RPSOHWH?(QJLQH?7UHDWPHQW Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/11/2016 EN (English) SDS ID: LO1605001 7/7 SECTION 16: Other information Data sources : ACGIH (American Conference of Government Industrial Hygienists). Component Supplier SDSs. European Chemicals Agency (ECHA) C&L Inventory database. Accessed at http://echa.europa.eu/web/guest/information-on-chemicals/cl-inventory-database. Krister Forsberg and S.Z. Mansdorf, "Quick Selection Guide to Chemical Protective Clothing", Fifth Edition. Manufacturer Information. National Fire Protection Association. Fire Protection Guide to Hazardous Materials; 10th edition. OSHA 29CFR 1910.1200 Hazard Communication Standard. Abbreviations and acronyms : ATE: Acute Toxicity Estimate. CAS (Chemical Abstracts Service) number. EC50: Environmental Concentration associated with a response by 50% of the test population. GHS: Globally Harmonized System (of Classification and Labeling of Chemicals). LD50: Lethal Dose for 50% of the test population. OSHA: Occupational Safety & Health Administration. STEL: Short Term Exposure Limits. TSCA: Toxic Substances Control Act. TWA: Time Weighted Average. Other information : None. Full text of H-statements: ------ H227 Combustible liquid ------ H304 May be fatal if swallowed and enters airways ------ H412 Harmful to aquatic life with long lasting effects NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA fire hazard : 2 - Must be moderately heated or exposed to relatively high temperature before ignition can occur. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and not reactive with water. Redstone SDS US GHS for Lucas Oil SDS Prepared by: The Redstone Group, LLC. 6077 Frantz Rd. Suite 206 Dublin, Ohio, USA 43016 614.923.7472 www.redstonegrp.com This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product