Spray SAFETY DATA SHEET Product name Other means of identification Product type Section 1. Identification : : : Lucas Oil Products, Inc 302 N Sheridan St Corona, California 92880 ChemTel, 1-800-255-3924 Relevant identified uses of the substance or mixture and uses advised against Not applicable. Product code : Red'N'Tacky Aerosol Spray Grease : 11025 : Not available. : Not available. : ChemTel, 1-800-255-3924 Manufacturer Emergency telephone number of the company Regulatory Information Telephone Number Transportation Emergency Telephone Number : ChemTel, 1-800-255-3924 Section 2. Hazards identification FLAMMABLE AEROSOLS - Category 1 GASES UNDER PRESSURE - Compressed gas SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A TOXIC TO REPRODUCTION (Fertility) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs) - Category 1 ASPIRATION HAZARD - Category 1 Classification of the substance or mixture : Signal word : Danger Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 16.1% Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 24% Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 22. 9% OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision : 10/6/2017 Date of previous issue : No previous validation Version : 1 1/16 Section 2. Hazards identification Precautionary statements Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Pressurized container: Do not pierce or burn, even after use. Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F. Store in a well-ventilated place. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Hazards not otherwise classified : None known. Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Causes skin irritation. Suspected of damaging fertility. May be fatal if swallowed and enters airways. May cause respiratory irritation. May cause drowsiness or dizziness. Causes damage to organs through prolonged or repeated exposure. (lungs) :Hazard statements Please refer to the SDS for additional information. Keep out of reach of children. Keep upright in a cool, dry place. Do not discard empty can in trash compactor. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. : Section 3. Composition/information on ingredients Heavy Paraffinic Oil 23.91 64742-54-7 Paraffin Oil 17.23 64742-62-7 Methyl Acetate 10 79-20-9 Hexane 7.87 110-54-3 Propane 6.8 74-98-6 2-Methylpentane 3.64 107-83-5 Fumed Amorphous Silica 3.64 112945-52-5 Butane 3.2 106-97-8 Ingredient name CAS number% by weight Other means of identification : Not available. Substance/mixture CAS number/other identifiers : Mixture Date of issue/Date of revision : 10/6/2017 Date of previous issue : No previous validation Version : 1 2/16 Section 3. Composition/information on ingredients 3-Methylpentane 1.35 96-14-0 Talc 1.3 14807-96-6 2,3-Dimethylbutane 1.15 79-29-8 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. Get medical attention immediately. Call a poison center or physician. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. Get medical attention. Continue to rinse for at least 10 minutes. Get medical attention. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Skin contact : Causes skin irritation. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Skin contact Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects Date of issue/Date of revision : 10/6/2017 Date of previous issue : No previous validation Version : 1 3/16 Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Ingestion Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations : See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide halogenated compounds metal oxide/oxides Extremely flammable aerosol. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures : In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Shut off all ignition sources. No flares, smoking or flames in hazard area. For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision : 10/6/2017 Date of previous issue : No previous validation Version : 1 4/16 Section 6. Accidental release measures Environmental precautions Use spark-proof tools and explosion-proof equipment. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : Water polluting material. May be harmful to the environment if released in large quantities. Large spill : Use spark-proof tools and explosion-proof equipment.Small spill : Methods and materials for containment and cleaning up Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Protect from sunlight. Store locked up. Eliminate all ignition sources. See Section 10 for incompatible materials before handling or use. : : Protective measures Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50?C. Do not pierce or burn, even after use. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not swallow. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. : Precautions for safe handling Heavy Paraffinic Oil OSHA PEL (United States, 6/2016). TWA: 5 mg/m? 8 hours. ACGIH TLV (United States, 3/2016). TWA: 5 mg/m? 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2016). TWA: 5 mg/m? 10 hours. Form: Mist STEL: 10 mg/m? 15 minutes. Form: Mist Paraffin Oil OSHA PEL (United States, 6/2016). TWA: 5 mg/m? 8 hours. ACGIH TLV (United States, 3/2016). TWA: 5 mg/m? 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2016). TWA: 5 mg/m? 10 hours. Form: Mist STEL: 10 mg/m? 15 minutes. Form: Mist Methyl Acetate ACGIH TLV (United States, 3/2016). TWA: 200 ppm 8 hours. TWA: 606 mg/m? 8 hours. STEL: 250 ppm 15 minutes. STEL: 757 mg/m? 15 minutes. NIOSH REL (United States, 10/2016). TWA: 200 ppm 10 hours. TWA: 610 mg/m? 10 hours. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) Date of issue/Date of revision : 10/6/2017 Date of previous issue : No previous validation Version : 1 5/16 Section 8. Exposure controls/personal protection STEL: 250 ppm 15 minutes. STEL: 760 mg/m? 15 minutes. OSHA PEL (United States, 6/2016). TWA: 200 ppm 8 hours. TWA: 610 mg/m? 8 hours. Hexane ACGIH TLV (United States, 3/2016). Absorbed through skin. TWA: 50 ppm 8 hours. NIOSH REL (United States, 10/2016). TWA: 50 ppm 10 hours. TWA: 180 mg/m? 10 hours. OSHA PEL (United States, 6/2016). TWA: 500 ppm 8 hours. TWA: 1800 mg/m? 8 hours. Propane NIOSH REL (United States, 10/2016). TWA: 1000 ppm 10 hours. TWA: 1800 mg/m? 10 hours. OSHA PEL (United States, 6/2016). TWA: 1000 ppm 8 hours. TWA: 1800 mg/m? 8 hours. 2-Methylpentane ACGIH TLV (United States, 3/2016). TWA: 500 ppm 8 hours. TWA: 1760 mg/m? 8 hours. STEL: 1000 ppm 15 minutes. STEL: 3500 mg/m? 15 minutes. NIOSH REL (United States, 10/2016). TWA: 100 ppm 10 hours. TWA: 350 mg/m? 10 hours. CEIL: 510 ppm 15 minutes. CEIL: 1800 mg/m? 15 minutes. Fumed Amorphous Silica NIOSH REL (United States, 10/2016). TWA: 6 mg/m? 10 hours. Butane NIOSH REL (United States, 10/2016). TWA: 800 ppm 10 hours. TWA: 1900 mg/m? 10 hours. ACGIH TLV (United States, 3/2016). STEL: 1000 ppm 15 minutes. 3-Methylpentane ACGIH TLV (United States, 3/2016). TWA: 500 ppm 8 hours. TWA: 1760 mg/m? 8 hours. STEL: 1000 ppm 15 minutes. STEL: 3500 mg/m? 15 minutes. NIOSH REL (United States, 10/2016). TWA: 100 ppm 10 hours. TWA: 350 mg/m? 10 hours. CEIL: 510 ppm 15 minutes. CEIL: 1800 mg/m? 15 minutes. Talc NIOSH REL (United States, 10/2016). TWA: 2 mg/m? 10 hours. Form: Respirable fraction ACGIH TLV (United States, 3/2016). TWA: 2 mg/m? 8 hours. Form: Respirable fraction 2,3-Dimethylbutane ACGIH TLV (United States, 3/2016). TWA: 500 ppm 8 hours. TWA: 1760 mg/m? 8 hours. STEL: 1000 ppm 15 minutes. STEL: 3500 mg/m? 15 minutes. NIOSH REL (United States, 10/2016). Date of issue/Date of revision : 10/6/2017 Date of previous issue : No previous validation Version : 1 6/16 Section 8. Exposure controls/personal protection TWA: 100 ppm 10 hours. TWA: 350 mg/m? 10 hours. CEIL: 510 ppm 15 minutes. CEIL: 1800 mg/m? 15 minutes. Methyl Acetate CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 606 mg/m? 8 hours. 15 min OEL: 757 mg/m? 15 minutes. 15 min OEL: 250 ppm 15 minutes. 8 hrs OEL: 200 ppm 8 hours. CA British Columbia Provincial (Canada, 7/2016). TWA: 200 ppm 8 hours. STEL: 250 ppm 15 minutes. CA Ontario Provincial (Canada, 7/2015). TWA: 200 ppm 8 hours. STEL: 250 ppm 15 minutes. CA Qu?bec Provincial (Canada, 1/2014). TWAEV: 200 ppm 8 hours. TWAEV: 606 mg/m? 8 hours. STEV: 250 ppm 15 minutes. STEV: 757 mg/m? 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 250 ppm 15 minutes. TWA: 200 ppm 8 hours. Hexane CA Alberta Provincial (Canada, 4/2009). Absorbed through skin. 8 hrs OEL: 50 ppm 8 hours. 8 hrs OEL: 176 mg/m? 8 hours. CA British Columbia Provincial (Canada, 7/2016). Absorbed through skin. TWA: 20 ppm 8 hours. CA Ontario Provincial (Canada, 7/2015). Absorbed through skin. TWA: 50 ppm 8 hours. CA Qu?bec Provincial (Canada, 1/2014). Absorbed through skin. TWAEV: 50 ppm 8 hours. TWAEV: 176 mg/m? 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). Absorbed through skin. STEL: 62.5 ppm 15 minutes. TWA: 50 ppm 8 hours. Propane CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 1000 ppm 8 hours. CA British Columbia Provincial (Canada, 7/2016). TWA: 1000 ppm 8 hours. CA Qu?bec Provincial (Canada, 1/2014). TWAEV: 1000 ppm 8 hours. TWAEV: 1800 mg/m? 8 hours. CA Ontario Provincial (Canada, 7/2015). TWA: 1000 ppm 8 hours. Ingredient name Exposure limits Occupational exposure limits (Canada) Date of issue/Date of revision : 10/6/2017 Date of previous issue : No previous validation Version : 1 7/16 Section 8. Exposure controls/personal protection CA Saskatchewan Provincial (Canada, 7/2013). STEL: 1250 ppm 15 minutes. TWA: 1000 ppm 8 hours. 2-Methylpentane CA Alberta Provincial (Canada, 4/2009). 15 min OEL: 3500 mg/m? 15 minutes. 8 hrs OEL: 1760 mg/m? 8 hours. 15 min OEL: 1000 ppm 15 minutes. 8 hrs OEL: 500 ppm 8 hours. CA British Columbia Provincial (Canada, 7/2016). TWA: 200 ppm 8 hours. CA Ontario Provincial (Canada, 7/2015). TWA: 500 ppm 8 hours. STEL: 1000 ppm 15 minutes. CA Qu?bec Provincial (Canada, 1/2014). TWAEV: 500 ppm 8 hours. TWAEV: 1760 mg/m? 8 hours. STEV: 1000 ppm 15 minutes. STEV: 3500 mg/m? 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 1000 ppm 15 minutes. TWA: 500 ppm 8 hours. Butane CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 1000 ppm 8 hours. CA British Columbia Provincial (Canada, 7/2016). TWA: 600 ppm 8 hours. STEL: 750 ppm 15 minutes. CA Qu?bec Provincial (Canada, 1/2014). TWAEV: 800 ppm 8 hours. TWAEV: 1900 mg/m? 8 hours. CA Ontario Provincial (Canada, 7/2015). TWA: 800 ppm 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 1250 ppm 15 minutes. TWA: 1000 ppm 8 hours. 3-Methylpentane CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 500 ppm 8 hours. 15 min OEL: 1000 ppm 15 minutes. 15 min OEL: 3500 mg/m? 15 minutes. 8 hrs OEL: 1760 mg/m? 8 hours. CA British Columbia Provincial (Canada, 7/2016). TWA: 200 ppm 8 hours. CA Ontario Provincial (Canada, 7/2015). TWA: 500 ppm 8 hours. STEL: 1000 ppm 15 minutes. CA Qu?bec Provincial (Canada, 1/2014). TWAEV: 500 ppm 8 hours. TWAEV: 1760 mg/m? 8 hours. STEV: 1000 ppm 15 minutes. STEV: 3500 mg/m? 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 1000 ppm 15 minutes. TWA: 500 ppm 8 hours. Date of issue/Date of revision : 10/6/2017 Date of previous issue : No previous validation Version : 1 8/16 Section 8. Exposure controls/personal protection Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Individual protection measures 2,3-Dimethylbutane CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 1760 mg/m? 8 hours. 15 min OEL: 1000 ppm 15 minutes. 15 min OEL: 3500 mg/m? 15 minutes. 8 hrs OEL: 500 ppm 8 hours. CA British Columbia Provincial (Canada, 7/2016). TWA: 200 ppm 8 hours. CA Ontario Provincial (Canada, 7/2015). TWA: 500 ppm 8 hours. STEL: 1000 ppm 15 minutes. CA Qu?bec Provincial (Canada, 1/2014). TWAEV: 500 ppm 8 hours. TWAEV: 1760 mg/m? 8 hours. STEV: 1000 ppm 15 minutes. STEV: 3500 mg/m? 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 1000 ppm 15 minutes. TWA: 500 ppm 8 hours. Environmental exposure controls : Methyl Acetate NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 200 ppm 8 hours. STEL: 250 ppm 15 minutes. Hexane NOM-010-STPS-2014 (Mexico, 4/2016). Absorbed through skin. TWA: 50 ppm 8 hours. Propane NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 1000 ppm 8 hours. 2-Methylpentane NOM-010-STPS-2014 (Mexico, 4/2016). STEL: 1000 ppm 15 minutes. TWA: 500 ppm 8 hours. Butane NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 1000 ppm 8 hours. 3-Methylpentane NOM-010-STPS-2014 (Mexico, 4/2016). STEL: 1000 ppm 15 minutes. TWA: 500 ppm 8 hours. 2,3-Dimethylbutane NOM-010-STPS-2014 (Mexico, 4/2016). STEL: 1000 ppm 15 minutes. TWA: 500 ppm 8 hours. Ingredient name Exposure limits Occupational exposure limits (Mexico) Date of issue/Date of revision : 10/6/2017 Date of previous issue : No previous validation Version : 1 9/16 Section 8. Exposure controls/personal protection Hand protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Relative density Vapor density Solubility Liquid. Not available. 0.83 1.55 [Air = 1] 101.3 kPa (760 mm Hg) [at 20?C] Not available. Not available.Odor pH VariousColor Evaporation rate 9.1 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: -29?C (-20.2?F) [Pensky-Martens Closed Cup] Not available. Not available. Viscosity Kinematic (40?C (104?F)): <0.205 cm2/s (<20.5 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Appearance Boiling point : Not available. Flammability (solid, gas) : Not available. Lower and upper explosive (flammable) limits : Lower: 1% Upper: 16% Decomposition temperature : Not available. Type of aerosol : Spray Heat of combustion : 29.076 kJ/g Aerosol product Molecular weight : Not applicable. Date of issue/Date of revision : 10/6/2017 Date of previous issue : No previous validation Version : 1 10/16 Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Methyl Acetate LD50 Dermal Rabbit >5 g/kg - LD50 Oral Rat >5 g/kg - Hexane LC50 Inhalation Gas. Rat 48000 ppm 4 hours LD50 Oral Rat 15840 mg/kg - Fumed Amorphous Silica LD50 Oral Rat 3160 mg/kg - Butane LC50 Inhalation Vapor Rat 658000 mg/m? 4 hours Product/ingredient name Result Species Dose Exposure Carcinogenicity Not available. Mutagenicity Not available. Reproductive toxicity Not available. Irritation/Corrosion Methyl Acetate Eyes - Moderate irritant Rabbit - 24 hours 100 milligrams - Skin - Mild irritant Rabbit - 24 hours 500 milligrams - Skin - Moderate irritant Rabbit - 24 hours 20 milligrams - Hexane Eyes - Mild irritant Rabbit - 10 milligrams - Talc Skin - Mild irritant Human - 72 hours 300 Micrograms Intermittent - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Information on toxicological effects Classification Fumed Amorphous Silica - 3 - Talc - 3 - Product/ingredient name NTPIARCOSHA Date of issue/Date of revision : 10/6/2017 Date of previous issue : No previous validation Version : 1 11/16 Section 11. Toxicological information Teratogenicity Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Methyl Acetate Category 3 Not applicable. Narcotic effects Hexane Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Propane Category 3 Not applicable. Respiratory tract irritation and Narcotic effects 2-Methylpentane Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Butane Category 3 Not applicable. Respiratory tract irritation and Narcotic effects 3-Methylpentane Category 3 Not applicable. Respiratory tract irritation and Narcotic effects 2,3-Dimethylbutane Category 3 Not applicable. Respiratory tract irritation and Narcotic effects Name Category Name Category Hexane Category 2 Not determined Not determined Propane Category 2 Not determined Not determined 2-Methylpentane Category 2 Not determined Not determined Butane Category 2 Not determined Not determined 3-Methylpentane Category 2 Not determined Not determined Talc Category 1 Inhalation lungs 2,3-Dimethylbutane Category 2 Not determined Not determined Aspiration hazard Name Result Hexane ASPIRATION HAZARD - Category 1 Propane ASPIRATION HAZARD - Category 1 2-Methylpentane ASPIRATION HAZARD - Category 1 Butane ASPIRATION HAZARD - Category 1 3-Methylpentane ASPIRATION HAZARD - Category 1 2,3-Dimethylbutane ASPIRATION HAZARD - Category 1 Route of exposure Target organs Route of exposure Target organs Information on the likely routes of exposure Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Skin contact : Causes skin irritation. Causes serious eye irritation.:Eye contact : Not available. Potential acute health effects Date of issue/Date of revision : 10/6/2017 Date of previous issue : No previous validation Version : 1 12/16 Not available. Causes damage to organs through prolonged or repeated exposure.General : No known significant effects or critical hazards.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : Suspected of damaging fertility. Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 72799.4 mg/kg Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Date of issue/Date of revision : 10/6/2017 Date of previous issue : No previous validation Version : 1 13/16 Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Hexane - 501.187 high Toxicity Methyl Acetate Acute LC50 320000 ?g/l Fresh water Fish - Pimephales promelas 96 hours Hexane Acute LC50 2500 ?g/l Fresh water Fish - Pimephales promelas 96 hours Product/ingredient name SpeciesResult Exposure Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Not available. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. :Disposal methods Section 14. Transport information Section 15. Regulatory information SARA 313 SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 Section 16. Other information Hazardous Material Information System (U.S.A.) 2 3 0 *Health Flammability Physical hazards The customer is responsible for determining the PPE code for this material. For more information on HMIS? Personal Protective Equipment (PPE) codes, consult the HMIS? Implementation Manual. Date of issue/Date of revision : 10/6/2017 Date of previous issue : No previous validation Version : 1 14/16 Lori Catherasoo Typewritten Text Lori Catherasoo Typewritten Text Lori Catherasoo Typewritten Text Lori Catherasoo Typewritten Text Lori Catherasoo Typewritten Text Lori Catherasoo Typewritten Text Lori Catherasoo Typewritten Text Lori Catherasoo Typewritten Text Lori Catherasoo Typewritten Text DOT, IMDG and IATA: UN1950, Aerosols 2.1 LTD QTY Section 16. Other information 10/6/2017 History Date of printing Date of issue/Date of revision Version It is recommended that each customer or recipient of this Safety Data Sheet (SDS study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Notice to reader Date of previous issue : : : : Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 10/6/2017 No previous validation 1 Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS? ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered trademark and service mark of the American Coatings Association, Inc. FLAMMABLE AEROSOLS - Category 1 On basis of test data GASES UNDER PRESSURE - Compressed gas Calculation method SKIN CORROSION/IRRITATION - Category 2 Calculation method SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method TOXIC TO REPRODUCTION (Fertility) - Category 2 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs) - Category 1 Calculation method ASPIRATION HAZARD - Category 1 Calculation method Procedure used to derive the classification Classification Justification Date of issue/Date of revision : 10/6/2017 Date of previous issue : No previous validation Version : 1 15/16 Date of issue/Date of revision : 10/6/2017 Date of previous issue : No previous validation Version : 1 16/16 SDS_US_English_Z2B102218-EXP Page 1 Page 2 Page 3 Page 4 Page 5 Page 6 Page 7 Page 8 Page 9 Page 10 Page 11 Page 12 Page 13 Page 14 Page 15 Page 16