MATERIAL SAFETY DATA SHEET 3M(TM) Tire Dressing, P.N. 38127, 38128, 38129 05/06/11 _________________________________________________________________________________________________ Page 1 of 9 Material Safety Data Sheet Copyright, 2011, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M(TM) Tire Dressing, P.N. 38127, 38128, 38129 MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 05/06/11 Supercedes Date: 03/20/07 Document Group: 08-7486-7 Product Use: Intended Use: Automotive Limitations on Use: This product is a VOC regulated product. Consult State and Local Regulations. Specific Use: Tire Dressing SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC 64742-89-8 60 - 90 POLY(DIMETHYLSILOXANE) 63148-62-9 10 - 30 ISOPROPYL ALCOHOL 67-63-0 3 - 7 TOLUENE 108-88-3 <= 0.07 ETHYLBENZENE 100-41-4 <= 0.07 BENZENE 71-43-2 <= 0.07 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Odor, Color, Grade: Purple Color, Solvent Odor General Physical Form: Liquid Immediate health, physical, and environmental hazards: Flammable liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Contains a chemical or chemicals which can cause cancer. May cause target organ effects. MATERIAL SAFETY DATA SHEET 3M(TM) Tire Dressing, P.N. 38127, 38128, 38129 05/06/11 _________________________________________________________________________________________________ Page 2 of 9 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Inhalation: Intentional concentration and inhalation may be harmful or fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Chemical (Aspiration) Pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth, difficulty breathing, bluish colored skin (cyanosis), and may be fatal. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause: Dermal Effects: Signs/symptoms may include localized redness, itching, drying and cracking of skin. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation BENZENE 71-43-2 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer BENZENE 71-43-2 Known human carcinogen National Toxicology Program Carcinogens BENZENE 71-43-2 Cancer hazard OSHA Carcinogens ETHYLBENZENE 100-41-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. MATERIAL SAFETY DATA SHEET 3M(TM) Tire Dressing, P.N. 38127, 38128, 38129 05/06/11 _________________________________________________________________________________________________ Page 3 of 9 SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point 50 ?F Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Flammable liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Place in a metal container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Clean-up methods Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Seal the container. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. MATERIAL SAFETY DATA SHEET 3M(TM) Tire Dressing, P.N. 38127, 38128, 38129 05/06/11 _________________________________________________________________________________________________ Page 4 of 9 SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Contents may be under pressure, open carefully. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Ground containers securely when transferring contents. Wear low static or properly grounded shoes. No smoking while handling this material. Avoid breathing of vapors, mists or spray. Avoid static discharge. Avoid eye contact with vapors, mists, or spray. For industrial or professional use only. Avoid contact with oxidizing agents. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment. 7.2 STORAGE Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Keep container tightly closed. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Provide appropriate local exhaust ventilation on open containers. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields Indirect Vented Goggles . 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Fluoroelastomer . 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges . Select and use respiratory protection to prevent an inhalation exposure based on the results of an exposure assessment. Consult with your respirator manufacturer for selection of appropriate types of respirators. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Do not ingest. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information BENZENE ACGIH TWA 0.5 ppm Skin Notation* BENZENE ACGIH STEL 2.5 ppm Skin Notation* BENZENE OSHA TWA 1 ppm 29 CFR 1910.1028 BENZENE OSHA STEL 5 ppm 29 CFR 1910.1028 MATERIAL SAFETY DATA SHEET 3M(TM) Tire Dressing, P.N. 38127, 38128, 38129 05/06/11 _________________________________________________________________________________________________ Page 5 of 9 BENZENE OSHA TWA 10 ppm BENZENE OSHA CEIL 25 ppm ETHYLBENZENE ACGIH TWA 100 ppm ETHYLBENZENE ACGIH STEL 125 ppm ETHYLBENZENE CMRG TWA 25 ppm ETHYLBENZENE CMRG STEL 75 ppm ETHYLBENZENE OSHA TWA 435 mg/m3 ISOPROPYL ALCOHOL ACGIH TWA 200 ppm ISOPROPYL ALCOHOL ACGIH STEL 400 ppm ISOPROPYL ALCOHOL OSHA TWA 980 mg/m3 PETROLEUM DISTILLATES OSHA TWA 2000 mg/m3 SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC CMRG TWA 300 ppm TOLUENE ACGIH TWA 20 ppm TOLUENE CMRG STEL 75 ppm Skin Notation* TOLUENE OSHA TWA 200 ppm TOLUENE OSHA CEIL 300 ppm * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Odor, Color, Grade: Purple Color, Solvent Odor General Physical Form: Liquid Autoignition temperature No Data Available Flash Point 50 ?F Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Boiling Point 149 ?F Density 0.79 g/ml Vapor Density No Data Available Vapor Pressure <=27 psia [@ 131.0000000000 ?F] [Details: MITS data] Specific Gravity 0.79 [Ref Std: WATER=1] pH Not Applicable Melting point No Data Available Solubility in Water Nil Evaporation rate No Data Available Hazardous Air Pollutants 0.0139 lb HAPS/gal [Test Method: Calculated] Volatile Organic Compounds 595 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 75.3 % weight [Test Method: calculated per CARB title 2] Kow - Oct/Water partition coef No Data Available Percent volatile 70 - 90 % weight VOC Less H2O & Exempt Solvents 595 g/l [Test Method: calculated SCAQMD rule 443.1] Viscosity 100 centistoke MATERIAL SAFETY DATA SHEET 3M(TM) Tire Dressing, P.N. 38127, 38128, 38129 05/06/11 _________________________________________________________________________________________________ Page 6 of 9 SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid Heat 10.2 Materials to avoid None known Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Formaldehyde Not Specified Carbon monoxide Not Specified Carbon dioxide Not Specified SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. EPA Hazardous Waste Number (RCRA): D001 (Ignitable), D018 (Benzene) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): 60-9800-3536-8, 60-9800-3566-5, 60-9800-3567-3 MATERIAL SAFETY DATA SHEET 3M(TM) Tire Dressing, P.N. 38127, 38128, 38129 05/06/11 _________________________________________________________________________________________________ Page 7 of 9 For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes STATE REGULATIONS Contact 3M for more information. CALIFORNIA PROPOSITION 65 Ingredient C.A.S. No. Classification BENZENE 71-43-2 *Male reproductive toxin BENZENE 71-43-2 **Carcinogen BENZENE 71-43-2 *Developmental Toxin ETHYLBENZENE 100-41-4 **Carcinogen TOLUENE 108-88-3 *Developmental Toxin * WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm. ** WARNING: contains a chemical which can cause cancer. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 2 Flammability: 3 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Reason for Reissue: To update Potential Health Effects (Inhalation). Revision Changes: Section 16: Disclaimer (second paragraph) was modified. Section 8: Eye/face protection information was modified. Section 8: Skin protection - recommended gloves information was modified. MATERIAL SAFETY DATA SHEET 3M(TM) Tire Dressing, P.N. 38127, 38128, 38129 05/06/11 _________________________________________________________________________________________________ Page 8 of 9 Section 8: Respiratory protection - recommended respirators information was modified. Section 14: Transportation legal text was modified. Section 15: Inventories information was modified. Section 9: Vapor pressure value was modified. Section 9: Boiling point information was modified. Section 5: Flammable limits (UE) information was modified. Section 5: Flammable limits (LEL) information was modified. Section 9: Property description for optional properties was modified. Section 8: Respiratory protection - recommended respirators guide was modified. Section 9: Flammable limits (LEL) information was modified. Section 9: Flammable limits (UEL) information was modified. Section 9: Density information was added. Section 14: ID Number Heading Template 1 was added. Section 14: ID Number(s) Template 1 was added. Section 2: Ingredient table was added. Section 8: Exposure guidelines ingredient information was added. Section 8: Exposure guideline note was added. Section 8: Exposure guidelines data source legend was added. Section 3: Carcinogenicity table was added. Section 3: Carcinogenicity heading was added. Section 15: California proposition 65 ingredient information was added. Section 15: California proposition 65 heading was added. Section 15: California proposition 65 cancer warning was added. Section 6: 6.2. Environmental precautions heading was added. Section 6: 6.1. Personal precautions, protective equipment and emergency procedures heading was added. Section 10.1 Conditions to avoid heading was added. Section 10.2 Materials to avoid heading was added. Section 16: Web address was added. Section 6: Personal precautions information was added. Section 6: Environmental procedures information was added. Section 6: Methods for cleaning up information was added. Section 10: Materials to avoid physical property was added. Section 10: Conditions to avoid physical property was added. Section 1: Address was added. Copyright was added. Company logo was added. Section 6: Clean-up methods heading was added. Telephone header was added. Company Telephone was added. Section 1: Emergency phone information was added. Section 1: Emergency phone information was deleted. Company Logo was deleted. Copyright was deleted. Section 16: Web address heading was deleted. Section 6: Release measures information was deleted. Section 6: Release measures heading was deleted. Section 10: Materials and conditions to avoid physical property was deleted. Section 1: Address line 1 was deleted. Section 1: Address line 2 was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a MATERIAL SAFETY DATA SHEET 3M(TM) Tire Dressing, P.N. 38127, 38128, 38129 05/06/11 _________________________________________________________________________________________________ Page 9 of 9 particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M 3M USA MSDSs are available at www.3M.com