3M(TM) Perfect-It(TM) Clean & Shine PN 06084 & 06088 12/02/14 __________________________________________________________________________________________ Page 1 of 8 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 20-6340-2 Version Number: 2.00 Issue Date: 12/02/14 Supercedes Date: 10/13/08 SECTION 1: Identification 1.1. Product identifier 3M(TM) Perfect-It(TM) Clean & Shine PN 06084 & 06088 Product Identification Numbers 60-4550-3484-7 1.2. Recommended use and restrictions on use Recommended use Automotive, Automotive surface shine restoration 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Not classified as hazardous according to OSHA Hazard Communication Standard, 29 CFR 1910.1200. 2.2. Label elements Signal word Not applicable. Symbols Not applicable. Pictograms Not applicable. 3M(TM) Perfect-It(TM) Clean & Shine PN 06084 & 06088 12/02/14 __________________________________________________________________________________________ Page 2 of 8 2.3. Hazards not otherwise classified None. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Water 7732-18-5 70 - 97 Trade Secret * Isopropyl Alcohol 67-63-0 1 - 5 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 3M(TM) Perfect-It(TM) Clean & Shine PN 06084 & 06088 12/02/14 __________________________________________________________________________________________ Page 3 of 8 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with detergent and water. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. 7.2. Conditions for safe storage including any incompatibilities Keep container tightly closed. Protect from sunlight. Store away from heat. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Isopropyl Alcohol 67-63-0 ACGIH TWA:200 ppm;STEL:400 ppm A4: Not class. as human carcin Isopropyl Alcohol 67-63-0 OSHA TWA:980 mg/m3(400 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety Glasses with side shields Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the 3M(TM) Perfect-It(TM) Clean & Shine PN 06084 & 06088 12/02/14 __________________________________________________________________________________________ Page 4 of 8 substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Nitrile Rubber Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Odor, Color, Grade: fruit scent, off white color Odor threshold No Data Available pH 7 - 8.5 Melting point Not Applicable Boiling Point 212 ?F Flash Point > 212 ?F [Test Method: Closed Cup] Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Vapor Pressure No Data Available Vapor Density No Data Available Density 1 g/ml Specific Gravity 1 [Ref Std: WATER=1] Solubility in Water Appreciable Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity 1 - 20 centipoise Hazardous Air Pollutants 0.30001 % weight [Test Method: Calculated] Volatile Organic Compounds 2.5 % weight [Test Method: calculated per CARB title 2] Volatile Organic Compounds 29 g/l [Test Method: calculated SCAQMD rule 443.1] Percent volatile 99.8 % weight VOC Less H2O & Exempt Solvents 963 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 3M(TM) Perfect-It(TM) Clean & Shine PN 06084 & 06088 12/02/14 __________________________________________________________________________________________ Page 5 of 8 10.4. Conditions to avoid None known. 10.5. Incompatible materials None known. 10.6. Hazardous decomposition products Substance Condition Carbon monoxide At Elevated Temperatures Carbon dioxide At Elevated Temperatures SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Skin Contact: Contact with the skin during product use is not expected to result in significant irritation. Eye Contact: Sprayed material may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Isopropyl Alcohol Dermal Rabbit LD50 12,870 mg/kg Isopropyl Alcohol Inhalation- Vapor (4 hours) Rat LC50 72.6 mg/l Isopropyl Alcohol Ingestion Rat LD50 4,710 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation 3M(TM) Perfect-It(TM) Clean & Shine PN 06084 & 06088 12/02/14 __________________________________________________________________________________________ Page 6 of 8 Name Species Value Isopropyl Alcohol Multiple animal species No significant irritation Serious Eye Damage/Irritation Name Species Value Isopropyl Alcohol Rabbit Severe irritant Skin Sensitization Name Species Value Isopropyl Alcohol Guinea pig Not sensitizing Respiratory Sensitization Name Species Value Germ Cell Mutagenicity Name Route Value Isopropyl Alcohol In Vitro Not mutagenic Isopropyl Alcohol In vivo Not mutagenic Carcinogenicity Name Route Species Value Isopropyl Alcohol Inhalation Rat Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Isopropyl Alcohol Ingestion Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 400 mg/kg/day during organogenesi s Isopropyl Alcohol Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat LOAEL 9 mg/l during gestation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Isopropyl Alcohol Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Isopropyl Alcohol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Isopropyl Alcohol Inhalation auditory system Some positive data exist, but the data are not sufficient for classification Guinea pig NOAEL 13.4 mg/l 24 hours Isopropyl Alcohol Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Isopropyl Alcohol Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 12.3 mg/l 24 months Isopropyl Alcohol Inhalation nervous system All data are negative Rat NOAEL 12 mg/l 13 weeks 3M(TM) Perfect-It(TM) Clean & Shine PN 06084 & 06088 12/02/14 __________________________________________________________________________________________ Page 7 of 8 Isopropyl Alcohol Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 400 mg/kg/day 12 weeks Aspiration Hazard Name Value Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty and clean product containers may be disposed as non-hazardous waste. Consult your specific regulations and service providers to determine available options and requirements. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations 3M(TM) Perfect-It(TM) Clean & Shine PN 06084 & 06088 12/02/14 __________________________________________________________________________________________ Page 8 of 8 Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 1 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 20-6340-2 Version Number: 2.00 Issue Date: 12/02/14 Supercedes Date: 10/13/08 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com