3M MATERIAL SAFETY DATA SHEET 3M(TM) Acryl-Blue Glazing Putty, P.N. 05964 10/02/2006 _________________________________________________________________________________________________ Page 1 of 10 Material Safety Data Sheet Copyright, 2006, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M(TM) Acryl-Blue Glazing Putty, P.N. 05964 MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 10/02/2006 Supercedes Date: 11/18/2005 Document Group: 10-2850-5 Product Use: Specific Use: Filler for Automotive Low Areas or Deeper Sand Scratches SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt TALC 14807-96-6 15 - 40 TITANIUM DIOXIDE 13463-67-7 7 - 13 CELLULOSE ACETATE BUTYRATE 9004-36-8 5 - 10 XYLENE 1330-20-7 5 - 10 TOLUENE 108-88-3 5 - 10 N-BUTYL ACETATE 123-86-4 5 - 10 MAGNESIUM CARBONATE 546-93-0 5 - 10 ACRYLIC POLYMER Trade Secret 3 - 7 BUTYL BENZYL PHTHALATE 85-68-7 1 - 5 ISOPROPYL ALCOHOL 67-63-0 1 - 5 ETHYLBENZENE 100-41-4 1 - 5 TREATED CLAY 71011-26-2 0.5 - 1.5 DOLOMITE 16389-88-1 0.5 - 1.5 QUARTZ SILICA 14808-60-7 <= 0.276 ETHYL ACRYLATE 140-88-5 <= 0.06476 BENZENE 71-43-2 <= 0.0236 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW 3M MATERIAL SAFETY DATA SHEET 3M(TM) Acryl-Blue Glazing Putty, P.N. 05964 10/02/2006 _________________________________________________________________________________________________ Page 2 of 10 Odor, Color, Grade: viscous blue, solvent odor General Physical Form: Liquid Immediate health, physical, and environmental hazards: Flammable liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Contains a chemical or chemicals which can cause cancer. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. May be absorbed through skin and cause target organ effects. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. During grinding, scraping, sanding: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause: Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination. Central Neuropathy: Signs/symptoms may include irritability, memory impairment, personality changes, sleep disorders, and decreased ability to concentrate. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or 3M MATERIAL SAFETY DATA SHEET 3M(TM) Acryl-Blue Glazing Putty, P.N. 05964 10/02/2006 _________________________________________________________________________________________________ Page 3 of 10 numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation BENZENE 71-43-2 Group 1 International Agency for Research on Cancer BENZENE 71-43-2 Known human carcinogen National Toxicology Program Carcinogens BENZENE 71-43-2 Cancer hazard OSHA Carcinogens ETHYL ACRYLATE 140-88-5 Group 2B International Agency for Research on Cancer ETHYLBENZENE 100-41-4 Group 2B International Agency for Research on Cancer QUARTZ SILICA 14808-60-7 Group 1 International Agency for Research on Cancer QUARTZ SILICA 14808-60-7 Known human carcinogen National Toxicology Program Carcinogens SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point 63 ?F [Test Method: Closed Cup] Flammable Limits - LEL 1.00 % Flammable Limits - UEL 15.00 % 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed 3M MATERIAL SAFETY DATA SHEET 3M(TM) Acryl-Blue Glazing Putty, P.N. 05964 10/02/2006 _________________________________________________________________________________________________ Page 4 of 10 containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Flammable liquid and vapor. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non- sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Collect the resulting residue containing solution. Place in a metal container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Contents may be under pressure, open carefully. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Ground containers securely when transferring contents. Wear low static or properly grounded shoes. Avoid breathing of vapors, mists or spray. Avoid static discharge. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. Avoid breathing of dust created by cutting, sanding, grinding or machining. Avoid contact with oxidizing agents. Avoid skin contact. 7.2 STORAGE Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Keep container tightly closed. Store away from oxidizing agents. Keep from freezing. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Provide appropriate local exhaust ventilation on open containers. Provide appropriate local exhaust for cutting, grinding, sanding or machining. If exhaust ventilation is not available, use appropriate respiratory protection. For additional health and precautionary information, including air monitoring methodology, contact 3M. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 3M MATERIAL SAFETY DATA SHEET 3M(TM) Acryl-Blue Glazing Putty, P.N. 05964 10/02/2006 _________________________________________________________________________________________________ Page 5 of 10 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. To minimize the risk of injury to face and eyes, always wear eye and face protection when working at sanding or grinding operations or when near such operations. The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles. 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Nitrile Rubber, Polyethylene/Ethylene Vinyl Alcohol. 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Avoid breathing of dust created by cutting, sanding, grinding or machining. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges and P95 particulate prefilters. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information BENZENE ACGIH TWA 0.5 ppm Skin Notation*; Table A1 BENZENE ACGIH STEL 2.5 ppm Skin Notation*; Table A1 BENZENE OSHA TWA 1 ppm Standard Appendix BENZENE OSHA STEL 5 ppm Standard Appendix COPPER COMPOUNDS ACGIH TWA, as Cu dust or mist 1 mg/m3 COPPER COMPOUNDS OSHA TWA, as dust or mist 1 mg/m3 Table Z-1A ETHYL ACRYLATE ACGIH TWA 5 ppm Table A4 ETHYL ACRYLATE ACGIH STEL 15 ppm Table A4 ETHYL ACRYLATE OSHA TWA 5 ppm Skin Notation*; Table Z-1A ETHYL ACRYLATE OSHA STEL 25 ppm Skin Notation*; Table Z-1A ETHYLBENZENE ACGIH TWA 100 ppm Table A3 ETHYLBENZENE ACGIH STEL 125 ppm Table A3 ETHYLBENZENE OSHA TWA 100 ppm Table Z-1A ETHYLBENZENE OSHA STEL 125 ppm Table Z-1A ISOPROPYL ALCOHOL ACGIH TWA 200 ppm Table A4 ISOPROPYL ALCOHOL ACGIH STEL 400 ppm Table A4 ISOPROPYL ALCOHOL OSHA TWA 400 ppm Table Z-1A ISOPROPYL ALCOHOL OSHA STEL 500 ppm Table Z-1A MAGNESIUM CARBONATE ACGIH TWA 10 mg/m3 MAGNESIUM CARBONATE OSHA TWA, respirable 5 mg/m3 Table Z-1 MAGNESIUM CARBONATE OSHA TWA, as total dust 15 mg/m3 Table Z-1 N-BUTYL ACETATE ACGIH TWA 150 ppm N-BUTYL ACETATE ACGIH STEL 200 ppm N-BUTYL ACETATE OSHA TWA 150 ppm Table Z-1A N-BUTYL ACETATE OSHA STEL 200 ppm Table Z-1A POLYETHYLENE GLYCOLS AIHA TWA, as aerosol 10 mg/m3 QUARTZ SILICA ACGIH TWA, respirable 0.025 mg/m3 Table A2 QUARTZ SILICA OSHA TWA, respirable 0.1 mg/m3 Table Z-1A SELENIUM COMPOUNDS ACGIH TWA, as Se 0.2 mg/m3 SELENIUM COMPOUNDS OSHA TWA, as Se 0.2 mg/m3 Table Z-1 3M MATERIAL SAFETY DATA SHEET 3M(TM) Acryl-Blue Glazing Putty, P.N. 05964 10/02/2006 _________________________________________________________________________________________________ Page 6 of 10 TALC ACGIH TWA, respirable 2 mg/m3 Table A4 TALC CMRG TWA, as respirable dust 0.5 mg/m3 TALC OSHA TWA, respirable 2 mg/m3 Table Z-1A TITANIUM DIOXIDE ACGIH TWA 10 mg/m3 Table A4 TITANIUM DIOXIDE CMRG TWA, as respirable dust 5 mg/m3 TITANIUM DIOXIDE OSHA TWA, Vacated, as dust 10 mg/m3 TITANIUM DIOXIDE OSHA TWA, as total dust 15 mg/m3 Table Z-1 TOLUENE ACGIH TWA 50 ppm Skin Notation*; Table A4 TOLUENE CMRG STEL 75 ppm Skin Notation* TOLUENE OSHA TWA, Vacated 100 ppm TOLUENE OSHA STEL, Vacated 150 ppm TOLUENE OSHA TWA 200 ppm Table Z-2 TOLUENE OSHA CEIL 300 ppm Table Z-2 XYLENE ACGIH TWA 100 ppm Table A4 XYLENE ACGIH STEL 150 ppm Table A4 XYLENE OSHA TWA 100 ppm Table Z-1A XYLENE OSHA STEL 150 ppm Table Z-1A * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local regulatory agency. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Odor, Color, Grade: viscous blue, solvent odor General Physical Form: Liquid Autoignition temperature No Data Available Flash Point 63 ?F [Test Method: Closed Cup] Flammable Limits - LEL 1.00 % Flammable Limits - UEL 15.00 % Boiling point 180 ?F [Details: CONDITIONS: Isopropyl Alcohol] Density 1.515 kg/l Vapor Density 4.00 [Ref Std: AIR=1] Vapor Pressure <=27 psia [@ 131.0000000000 ?F] [Details: MITS data] Specific Gravity 1.480 - 1.530 [Ref Std: WATER=1] pH No Data Available Melting point No Data Available Volatile Organic Compounds 3.58 lb/gal [Test Method: calculated SCAQMD rule 443.1] Percent volatile 28.37 % VOC Less H2O & Exempt Solvents 428.76 g/l [Test Method: calculated SCAQMD rule 443.1] 3M MATERIAL SAFETY DATA SHEET 3M(TM) Acryl-Blue Glazing Putty, P.N. 05964 10/02/2006 _________________________________________________________________________________________________ Page 7 of 10 Viscosity 100000 - 200000 centipoise [@ 73.4000000000 ?F] [Details: MITS data] SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: Sparks and/or flames Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified Toxic Vapor, Gas, Particulate Not Specified SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. EPA Hazardous Waste Number (RCRA): D001 (Ignitable), D018 (Benzene) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION 3M MATERIAL SAFETY DATA SHEET 3M(TM) Acryl-Blue Glazing Putty, P.N. 05964 10/02/2006 _________________________________________________________________________________________________ Page 8 of 10 ID Number(s): 60-9800-0597-3 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt TOLUENE 108-88-3 5 - 10 XYLENE 1330-20-7 5 - 10 ETHYLBENZENE 100-41-4 1 - 5 This material contains a chemical which requires export notification under TSCA Section 12[b]: Ingredient (Category if applicable) C.A.S. No Regulation Status N-BUTYL ACETATE 123-86-4 Toxic Substances Control Act (TSCA) 4 Test Rule Chemicals Applicable STATE REGULATIONS Contact 3M for more information. CALIFORNIA PROPOSITION 65 Ingredient C.A.S. No. Classification BENZENE 71-43-2 *Male reproductive toxin BENZENE 71-43-2 **Carcinogen BENZENE 71-43-2 *Developmental Toxin ETHYL ACRYLATE 140-88-5 **Carcinogen ETHYLBENZENE 100-41-4 **Carcinogen SILICA, CRYSTALLINE (AIRBORNE PARTICLES OF RESPIRABLE SIZE) NONE **Carcinogen TOLUENE 108-88-3 *Developmental Toxin * WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm. ** WARNING: contains a chemical which can cause cancer. CHEMICAL INVENTORIES 3M MATERIAL SAFETY DATA SHEET 3M(TM) Acryl-Blue Glazing Putty, P.N. 05964 10/02/2006 _________________________________________________________________________________________________ Page 9 of 10 The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 2 Flammability: 3 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Copyright was modified. Section 15: California proposition 65 ingredient information was modified. Section 8: Exposure guidelines ingredient information was modified. Section 9: Property description for optional properties was modified. Section 16: Reason for reissue heading was deleted. Section 16: Reason for reissue phrase was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at www.3M.com 3M MATERIAL SAFETY DATA SHEET 3M(TM) Acryl-Blue Glazing Putty, P.N. 05964 10/02/2006 _________________________________________________________________________________________________ Page 10 of 10