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MATERIAL SAFETY DATA SHEET 3M? Scotch-Weld? Neoprene High Performance Contact Adhesive 1357 11/28/12 _________________________________________________________________________________________________ Page 1 of 9 Material Safety Data Sheet Copyright, 2012, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M? Scotch-Weld? Neoprene High Performance Contact Adhesive 1357 MANUFACTURER: 3M DIVISION: Industrial Adhesives and Tapes Division ADDRESS: 3M Center, St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 11/28/12 Supercedes Date: 03/09/11 Document Group: 10-2789-5 Product Use: Intended Use: Adhesive Specific Use: Contact Adhesive SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt Petroleum distillate 64741-84-0 30 - 60 Acetone 67-64-1 10 - 30 n-Hexane 110-54-3 5 - 20 Magnesium resinate 68037-42-3 7 - 13 Polychloroprene 9010-98-4 7 - 13 Methyl ethyl ketone 78-93-3 7 - 13 Toluene 108-88-3 3 - 7 Rosin 8050-09-7 0.1 - 1 Zinc oxide 1314-13-2 0.1 - 1 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Odor, Color, Grade: Grey/green, strong petroleum odor. General Physical Form: Liquid Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and MATERIAL SAFETY DATA SHEET 3M? Scotch-Weld? Neoprene High Performance Contact Adhesive 1357 11/28/12 _________________________________________________________________________________________________ Page 2 of 9 explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. May cause allergic skin reaction. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Prolonged or repeated exposure may cause: Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause: Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell. Peripheral Neuropathy: Signs/symptoms may include tingling or numbness of the extremities, incoordination, weakness of the hands and feet, tremors and muscle atrophy. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are MATERIAL SAFETY DATA SHEET 3M? Scotch-Weld? Neoprene High Performance Contact Adhesive 1357 11/28/12 _________________________________________________________________________________________________ Page 3 of 9 followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature 404 ?C Flash Point -14 ?F [Test Method: Closed Cup] [Details: Acetone] Flammable Limits(LEL) 1.0 % volume Flammable Limits(UEL) 12.8 % volume OSHA Flammability Classification: Class IB Flammable Liquid 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Collect the resulting residue containing solution. Place in a metal container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Clean-up methods Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. MATERIAL SAFETY DATA SHEET 3M? Scotch-Weld? Neoprene High Performance Contact Adhesive 1357 11/28/12 _________________________________________________________________________________________________ Page 4 of 9 Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Seal the container. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Contents may be under pressure, open carefully. Ground containers securely when transferring contents. Wear low static or properly grounded shoes. Vapors may ignite explosively. May cause flash fire. Prevent build-up of vapors - open all windows and doors. Maintain vapor concentrations below recommended exposure limits. Use only with cross-ventilation. Without adequate ventilation, vapors may settle in low-lying areas. Keep away from heat, sparks, and open flame. Do not smoke or ignite matches, lighters, etc. Extinguish pilot lights and turn off stoves, ovens and other gas and electric appliances (space and water heaters, furnaces, etc.), electric motors, and other sources of ignition during adhesive use and until all vapors are gone; i.e., until the odor of vapors at the floor level has disappeared. Do not use electric light switches. Do not generate static sparks (such as by walking on carpet, etc.). Use the same precautions in the work area and all connected areas. Be sure that any people in the area follow the precautions. Attach a copy of the precautions to any other container to which this product may by transferred. Avoid prolonged breathing of vapors. Avoid eye and skin contact. Keep container closed when not in use. If work area conditions prevent compliance with any of the above precautions, do not use the product. Keep out of the reach of children. For industrial or professional use only. Not intended for consumer sale or use. Do not breathe vapors. 7.2 STORAGE Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Keep container tightly closed. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Provide local exhaust ventilation at transfer points. Provide appropriate local exhaust ventilation on open containers. Use in an enclosed process area is recommended. If exhaust ventilation is not available, use appropriate respiratory protection. Do not use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Indirect Vented Goggles . 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Butyl Rubber Polymer laminate . MATERIAL SAFETY DATA SHEET 3M? Scotch-Weld? Neoprene High Performance Contact Adhesive 1357 11/28/12 _________________________________________________________________________________________________ Page 5 of 9 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Do not breathe vapors. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors For questions about suitability for a specific application, consult with your respirator manufacturer. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information Acetone ACGIH TWA 500 ppm Acetone ACGIH STEL 750 ppm Acetone OSHA TWA 2400 mg/m3 n-Hexane ACGIH TWA 50 ppm Skin Notation* n-Hexane OSHA TWA 1800 mg/m3 Methyl ethyl ketone ACGIH TWA 200 ppm Methyl ethyl ketone ACGIH STEL 300 ppm Methyl ethyl ketone OSHA TWA 590 mg/m3 Toluene ACGIH TWA 20 ppm Toluene CMRG STEL 75 ppm Skin Notation* Toluene OSHA TWA 200 ppm Toluene OSHA CEIL 300 ppm Zinc oxide ACGIH TWA, respirable fraction 2 mg/m3 Zinc oxide ACGIH STEL, respirable fraction 10 mg/m3 Zinc oxide OSHA TWA, as fume 5 mg/m3 Zinc oxide OSHA TWA, respirable fraction 5 mg/m3 Zinc oxide OSHA TWA, as total dust 15 mg/m3 * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Odor, Color, Grade: Grey/green, strong petroleum odor. General Physical Form: Liquid Autoignition temperature 404 ?C Flash Point -14 ?F [Test Method: Closed Cup] [Details: Acetone] Flammable Limits(LEL) 1.0 % volume Flammable Limits(UEL) 12.8 % volume Boiling Point >=80 ?C [Details: Acetone] MATERIAL SAFETY DATA SHEET 3M? Scotch-Weld? Neoprene High Performance Contact Adhesive 1357 11/28/12 _________________________________________________________________________________________________ Page 6 of 9 Density 0.815 g/ml Vapor Density 2.0 [Ref Std: AIR=1] Vapor Pressure <=185 mmHg [@ 68 ?F] Specific Gravity .815 [Ref Std: WATER=1] pH Not Applicable Melting point Not Applicable Solubility in Water Slight (less than 10%) Evaporation rate >=2.0 [Ref Std: WATER=1] Hazardous Air Pollutants <=13.2 % weight [Test Method: Calculated] Volatile Organic Compounds <=674 g/l [Details: EU VOC content] Kow - Oct/Water partition coef No Data Available Percent volatile 70 - 80 % VOC Less H2O & Exempt Solvents <=582 g/l [Test Method: tested per EPA method 24A] VOC Less H2O & Exempt Solvents <=5.44 lb/gal [Test Method: calculated SCAQMD rule 443.1] VOC Less H2O & Exempt Solvents <=66.2 % [Test Method: calculated per CARB title 2] Viscosity 200 - 450 centipoise [@ 73.4 ?F] Solids Content >=16.8 % SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid Heat Sparks and/or flames 10.2 Materials to avoid Strong oxidizing agents Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Hydrocarbons During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION MATERIAL SAFETY DATA SHEET 3M? Scotch-Weld? Neoprene High Performance Contact Adhesive 1357 11/28/12 _________________________________________________________________________________________________ Page 7 of 9 Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose of completely cured (or polymerized) wastes in a sanitary landfill. Incinerate uncured product in a permitted hazardous waste incinerator. EPA Hazardous Waste Number (RCRA): D001 (Ignitable), D035 (Methyl ethyl ketone) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): 62-1357-2630-5, 62-1357-2631-3, 62-1357-5530-4, 62-1357-5535-3, 62-1357-6530-3, 62-1357-7530-2, 62-1357-8530-1, 62-1357- 8540-0, 62-1357-9530-0, 62-1357-9531-8, 62-1357-9532-6, 78-8990-0393-9 For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Toluene 108-88-3 3 - 7 n-Hexane 110-54-3 5 - 20 STATE REGULATIONS Contact 3M for more information. CALIFORNIA PROPOSITION 65 Ingredient C.A.S. No. Classification Toluene 108-88-3 *Female reproductive toxin Toluene 108-88-3 *Developmental Toxin * WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), MATERIAL SAFETY DATA SHEET 3M? Scotch-Weld? Neoprene High Performance Contact Adhesive 1357 11/28/12 _________________________________________________________________________________________________ Page 8 of 9 or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. WHMIS: Hazardous This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 2 Flammability: 3 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 1: Product use information was modified. Section 16: Disclaimer (second paragraph) was modified. Section 10: Hazardous decomposition or by-products table was modified. Section 8: Respiratory protection - recommended respirators information was modified. Section 8: Respiratory protection - recommended respirators was modified. Section 9: Density information was modified. Section 9: Vapor density value was modified. Section 9: Vapor pressure value was modified. Section 9: Boiling point information was modified. Section 5: Flammable limits (UE) information was modified. Section 5: Flammable limits (LEL) information was modified. Section 5: Autoignition temperature information was modified. Section 5: Flash point information was modified. Section 9: Property description for required properties was modified. Section 9: Property description for optional properties was modified. Section 9: Specific gravity information was modified. Section 9: pH information was modified. Section 9: Melting point information was modified. Section 9: Solubility in water text was modified. Section 8: Respiratory protection - recommended respirators guide was modified. Section 9: Flash point information was modified. Section 9: Flammable limits (LEL) information was modified. Section 9: Flammable limits (UEL) information was modified. Section 9: Autoignition temperature information was modified. Section 2: Ingredient table was modified. Section 15: EPCRA 313 information was modified. Section 8: Exposure guidelines ingredient information was modified. Section 15: California proposition 65 ingredient information was modified. Section 16: Web address was added. Section 1: Address was added. Copyright was added. Company logo was added. MATERIAL SAFETY DATA SHEET 3M? Scotch-Weld? Neoprene High Performance Contact Adhesive 1357 11/28/12 _________________________________________________________________________________________________ Page 9 of 9 Telephone header was added. Company Telephone was added. Section 1: Emergency phone information was added. Section 1: Emergency phone information was deleted. Company Logo was deleted. Copyright was deleted. Section 16: Web address heading was deleted. Section 1: Address line 1 was deleted. Section 1: Address line 2 was deleted. Section 8: Respiratory protection - recommended respirators punctuation was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M 3M USA MSDSs are available at www.3M.com