MATERIAL SAFETY 3M DATA SHEET 3M Center St. Paul, Minnesota 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) Copyright, 2000, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. DIVISION: AUTOMOTIVE AFTERMARKET TRADE NAME: 3M Perfect-It (TM) II Paste Rubbing Compound Fine Cut, P.N. 38502, 39502, 39502S ID NUMBER/U.P.C.: 60-9800-2321-6 00-51131-39502-2 60-9800-2929-6 00-51131-39502-2 60-9800-2967-6 00-51131-38502-3 ISSUED: October 18, 2000 SUPERSEDES: September 29, 2000 DOCUMENT: 07-0552-5 ----------------------------------------------------------------------------- 1. INGREDIENT C.A.S. NO. PERCENT ----------------------------------------------------------------------------- WATER................................... 7732-18-5 30.0 - 60.0 QUARTZ SILICA (CRYSTALLINE SILICA)...... 14808-60-7 15.0 - 25.0 HYDROTREATED LIGHT PETROLEUM DISTILLATES........................... 64742-47-8 10.0 - 30.0 KAOLINITE............................... 1318-74-7 5.0 - 15.0 GLYCERIN................................ 56-81-5 1.0 - 5.0 SOLVENT-REFINED HEAVY PARAFFINIC PETROLEUM DISTILLATES................. 64741-88-4 1.0 - 5.0 OLEIC ACID.............................. 112-80-1 1.0 - 5.0 POLY(OXYETHYLENE)SORBITAN MONOSTEARATE.. 9005-67-8 1.0 - 5.0 DIETHANOLAMINE.......................... 111-42-2 < 1.0 The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. This product contains the following toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Emergency Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372: DIETHANOLAMINE ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Perfect-It (TM) II Paste Rubbing Compound Fine Cut, P.N. 38502, 39502, 39502S October 18, 2000 PAGE 2 1 of 7 2/8/01 5:46 PM http://multimedia.mmm.com/mws/mediawebser...KKKKKKeKGPlsfPZsh8EiyTTp&vZWDpSkTPlKGr8-- ----------------------------------------------------------------------------- 2. PHYSICAL DATA ----------------------------------------------------------------------------- BOILING POINT:................. 150 - 212 F VAPOR PRESSURE:................ < 1 Air=1 VAPOR DENSITY:................. > 1.00 Air=1 EVAPORATION RATE:.............. 1.00 Water=1 SOLUBILITY IN WATER:........... complete SPECIFIC GRAVITY:.............. 1.0 - 1.2 Water=1 PERCENT VOLATILE:.............. 60 - 65 % pH:............................ 7.8 - 8.5 VISCOSITY:..................... 80000 - 120000 centipoise MELTING POINT:................. N/D APPEARANCE AND ODOR: Liquid, Mild Solvent Odor, Cream Color ----------------------------------------------------------------------------- 3. FIRE AND EXPLOSION HAZARD DATA ----------------------------------------------------------------------------- FLASH POINT:................... 155 F PMCC Firepoint: 150 F. FLAMMABLE LIMITS - LEL:........ N/D FLAMMABLE LIMITS - UEL:........ N/D AUTOIGNITION TEMPERATURE:...... N/D EXTINGUISHING MEDIA: Water, Dry chemical SPECIAL FIRE FIGHTING PROCEDURES: Water may be used to blanket the fire. UNUSUAL FIRE AND EXPLOSION HAZARDS: No unusual fire or explosion hazards are anticipated. NFPA HAZARD CODES: HEALTH: 2 FIRE: 1 REACTIVITY: 0 UNUSUAL REACTION HAZARD: none OSHA FIRE HAZARD CLASS: Not applicable ----------------------------------------------------------------------------- 4. REACTIVITY DATA ----------------------------------------------------------------------------- STABILITY: Stable INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID: Strong Oxidizing Agents. HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Perfect-It (TM) II Paste Rubbing Compound Fine Cut, P.N. 38502, 39502, 39502S October 18, 2000 PAGE 3 ----------------------------------------------------------------------------- 4. REACTIVITY DATA (continued) ----------------------------------------------------------------------------- 2 of 7 2/8/01 5:46 PM http://multimedia.mmm.com/mws/mediawebser...KKKKKKeKGPlsfPZsh8EiyTTp&vZWDpSkTPlKGr8-- HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide. ----------------------------------------------------------------------------- 5. ENVIRONMENTAL INFORMATION ----------------------------------------------------------------------------- SPILL RESPONSE: Observe precautions from other sections. Ventilate area. Contain spill. Cover with absorbent material. Collect spilled material. Clean up residue with water. Place in a closed container. RECOMMENDED DISPOSAL: Incinerate in an industrial or commercial facility in the presence of a combustible material. ENVIRONMENTAL DATA: Not determined. REGULATORY INFORMATION: Volatile Organic Compounds: 22.3 % by wt. Volatile Organic Compounds: 2.0 lb/gal calculated per SCAQMD rule 443.1. Volatile Organic Compounds: 243 gms/liter calculated per SCAQMD rule 443.1. VOC Less H2O & Exempt Solvents: 377 gms/liter calculated per SCAQMD rule 443.1. Since regulations vary, consult applicable regulations or authorities before disposal. In the event of an uncontrolled release of this material, the user should determine if the release qualifies as a reportable quantity. U.S. EPA Hazardous Waste Number = None (Not U.S. EPA Hazardous). EPCRA HAZARD CLASS: FIRE HAZARD: Yes PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID ----------------------------------------------------------------------------- EYE CONTACT: Immediately flush eyes with large amounts of water. Get immediate medical attention. SKIN CONTACT: Flush skin with large amounts of water. If irritation persists, get medical attention. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Perfect-It (TM) II Paste Rubbing Compound Fine Cut, P.N. 38502, 39502, 39502S October 18, 2000 PAGE 4 ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID (continued) ----------------------------------------------------------------------------- INHALATION: If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. 3 of 7 2/8/01 5:46 PM http://multimedia.mmm.com/mws/mediawebser...KKKKKKeKGPlsfPZsh8EiyTTp&vZWDpSkTPlKGr8-- IF SWALLOWED: Do not induce vomiting. Drink two glasses of water. Call a physician. ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION ----------------------------------------------------------------------------- EYE PROTECTION: Avoid eye contact. SKIN PROTECTION: Avoid skin contact. Wear appropriate gloves when handling this material. A pair of gloves made from the following material(s) are recommended: nitrile rubber. RECOMMENDED VENTILATION: Use in a well-ventilated area. If exhaust ventilation is not adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: Avoid breathing of vapors. Avoid prolonged breathing of dust. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: half-mask dust and mist respirator, Half-mask organic vapor respirator with dust/mist prefilter, full-face dust and mist respirator, full-face organic vapor respirator with dust/mist prefilter The use of a proper government approved respirator is required if contaminant concentrations exceed the OSHA Permissible Exposure Limit (PEL) or Threshold Limit Value (TLV). PREVENTION OF ACCIDENTAL INGESTION: Wash hands after handling and before eating. Do not ingest. RECOMMENDED STORAGE: Store in a cool place. Store out of direct sunlight. Keep container closed when not in use. Keep out of the reach of children. FIRE AND EXPLOSION AVOIDANCE: Keep container tightly closed. Keep away from heat, sparks, open flame, and other sources of ignition. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Perfect-It (TM) II Paste Rubbing Compound Fine Cut, P.N. 38502, 39502, 39502S October 18, 2000 PAGE 5 ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION (continued) ----------------------------------------------------------------------------- EXPOSURE LIMITS INGREDIENT VALUE UNIT TYPE AUTH SKIN* ----------------------------------------------------------------------------- WATER................................ NONE NONE NONE NONE QUARTZ SILICA (CRYSTALLINE SILICA)... 0.1 MG/M3 TWA OSHA as quartz resp. dust 4 of 7 2/8/01 5:46 PM http://multimedia.mmm.com/mws/mediawebser...KKKKKKeKGPlsfPZsh8EiyTTp&vZWDpSkTPlKGr8-- QUARTZ SILICA (CRYSTALLINE SILICA)... 0.05 MG/M3 TWA ACGIH as quartz resp. dust HYDROTREATED LIGHT PETROLEUM DISTILLATES........................ 300 PPM TWA CMRG KAOLINITE............................ NONE NONE NONE NONE GLYCERIN............................. 10 MG/M3 TWA ACGIH AS MIST GLYCERIN............................. 10 MG/M3 TWA OSHAV AS MIST OSHA VACATED PEL: TOTAL DUST GLYCERIN............................. 15 MG/M3 TWA OSHA AS MIST TOTAL DUST GLYCERIN............................. 5 MG/M3 TWA OSHA AS MIST RESPIRABLE FRACTION SOLVENT-REFINED HEAVY PARAFFINIC PETROLEUM DISTILLATES.............. 5 MG/M3 TWA CMRG OLEIC ACID........................... NONE NONE NONE NONE POLY(OXYETHYLENE)SORBITAN MONOSTEARATE....................... NONE NONE NONE NONE DIETHANOLAMINE....................... 2 MG/M3 TWA ACGIH Y DIETHANOLAMINE....................... 3 PPM TWA OSHA * SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: American Conference of Governmental Industrial Hygienists - CMRG: Chemical Manufacturer Recommended Exposure Guidelines - OSHA: Occupational Safety and Health Administration - OSHAV: Occupational Safety and Health Administration Vacated PEL. Vacated Permissible Exposure Limits (PEL) are enforced as the OSHA PEL in some states. Check with your local regulatory authority. - NONE: None Established ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Perfect-It (TM) II Paste Rubbing Compound Fine Cut, P.N. 38502, 39502, 39502S October 18, 2000 PAGE 6 ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA ----------------------------------------------------------------------------- EYE CONTACT: Mild Eye Irritation: signs/symptoms can include redness, swelling, pain, and tearing. SKIN CONTACT: Mild Skin Irritation (after prolonged or repeated contact): signs/symptoms can include redness, swelling, and itching. INHALATION: Irritation (upper respiratory): signs/symptoms can include soreness of the nose and throat, coughing and sneezing. 5 of 7 2/8/01 5:46 PM http://multimedia.mmm.com/mws/mediawebser...KKKKKKeKGPlsfPZsh8EiyTTp&vZWDpSkTPlKGr8-- Prolonged or repeated overexposure, above recommended guidelines, may cause: Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. During buffing pad spurring: Silicosis: signs/symptoms can include shortness of breath and persistent coughing. WARNING: Airborne crystalline silica generated from the dry buff pads may produce dust conditions in excess of the OSHA Permissible Exposure Limit (PEL) or Threshold Limit Value (TLV) for crystalline silica. The use of a proper government approved respirator is required if contaminant concentrations exceed the PEL or TLV. IF SWALLOWED: Ingestion may cause: Irritation of Gastrointestinal Tissues: signs/symptoms can include pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and blood in feces. Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue, blurred vision, slurred speech, giddiness, tremors and convulsions. CANCER: WARNING: Contains a chemical which can cause cancer. (14808-60-7) (NTP known human carcinogen, IARC human carcinogen 1, Calif. Pr oposition 65) ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Perfect-It (TM) II Paste Rubbing Compound Fine Cut, P.N. 38502, 39502, 39502S October 18, 2000 PAGE 7 ----------------------------------------------------------------------------- SECTION CHANGE DATES ----------------------------------------------------------------------------- PRECAUTIONARY INFO. SECTION CHANGED SINCE September 29, 2000 ISSUE 6 of 7 2/8/01 5:46 PM http://multimedia.mmm.com/mws/mediawebser...KKKKKKeKGPlsfPZsh8EiyTTp&vZWDpSkTPlKGr8-- ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately ----------------------------------------------------------------------------- The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 7 of 7 2/8/01 5:46 PM http://multimedia.mmm.com/mws/mediawebser...KKKKKKeKGPlsfPZsh8EiyTTp&vZWDpSkTPlKGr8--