3M? Machine Polish, PN 05986, 05996, 39009, 39809 __________________________________________________________________________________________ Page: 1 of 11 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 31-0071-6 Version Number: 1.00 Issue Date: 24/02/2015 Supercedes Date: Initial Issue This Safety Data Sheet has been prepared in accordance with the Malaysia Occupational Safety and Health (Chemical Classification, Labelling and Safety Data Sheets) Regulations 2013. SECTION 1: Identification 1.1. Product identifier 3M? Machine Polish, PN 05986, 05996, 39009, 39809 Product Identification Numbers 60-4550-6917-3 60-4550-6926-4 60-4550-6928-0 60-4550-6937-1 1.2. Recommended use and restrictions on use Recommended use Automotive, Automotive Polish 1.3. Supplier?s details ADDRESS: 3M Malaysia Sdn. Bhd., Level 8, Block F, Oasis Square, No.2, Jalan PJU 1A/7A, Ara Damansara 47301 Petaling, Jaya, Selangor Telephone: 03-7884 2888 E Mail: This email address is being protected from spambots. You need JavaScript enabled to view it. Website: www.3M.com.my 1.4. Emergency telephone number +60 03-7884 2888 SECTION 2: Hazard identification 2.1. Classification of the substance or mixture Chronic Aquatic Toxicity: Category 3. 2.2. Label elements Signal word Not applicable Symbols Not applicable Pictograms Not applicable 3M? Machine Polish, PN 05986, 05996, 39009, 39809 __________________________________________________________________________________________ Page: 2 of 11 Hazard Statements H412 Harmful to aquatic life with long lasting effects. Precautionary statements General: P102 Keep out of reach of children. P101 If medical advice is needed, have product container or label at hand. Disposal: P501 Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Other hazards None known SECTION 3: Composition/information on ingredients This material is a mixture. Ingredient C.A.S. No. % by Wt Water 7732-18-5 60 - 100 Hydrotreated Light Petroleum Distillates 64742-47-8 10 - 30 Aluminum Oxide 1344-28-1 3 - 7 Decamethylcyclopentasiloxane 541-02-6 < 7 Dodecamethylcyclohexasiloxane 540-97-6 < 5 Ceramic Materials and Wares, Chemicals 66402-68-4 1 - 5 Ethylene Oxide, Polymer with Ethylenediamine and Propylene Oxide 26316-40-5 0.1 - 1 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 3M? Machine Polish, PN 05986, 05996, 39009, 39809 __________________________________________________________________________________________ Page: 3 of 11 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Hydrocarbons During Combustion Formaldehyde During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits 3M? Machine Polish, PN 05986, 05996, 39009, 39809 __________________________________________________________________________________________ Page: 4 of 11 If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Aluminum Oxide 1344-28-1 Malaysia OELs TWA (proposed)(8 hours):10 mg/m3 Aluminum, insoluble compounds 1344-28-1 ACGIH TWA(respirable fraction):1 mg/m3 A4: Not class. as human carcin Aluminum Oxide 1344-28-1 CMRG TWA:1 fiber/cc Decamethylcyclopentasiloxane 541-02-6 CMRG TWA:10 ppm Kerosine (petroleum) 64742-47-8 ACGIH TWA(as total hydrocarbon vapor, non-aerosol):200 mg/m3 A3: Confirmed animal carcin., Skin Notation Hydrotreated Light Petroleum Distillates 64742-47-8 CMRG TWA:165 ppm ACGIH : American Conference of Governmental Industrial Hygienists CMRG : Chemical Manufacturer's Recommended Guidelines Malaysia OELs : Malaysia. Occupational Safety and Health (Use and Standards of Exposure of Chemicals Hazardous to Health) Regulations TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety Glasses with side shields Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Neoprene Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid Appearance/Odor Slight solvent odor. Grey liquid. 3M? Machine Polish, PN 05986, 05996, 39009, 39809 __________________________________________________________________________________________ Page: 5 of 11 Odor threshold No Data Available pH 7.5 - 8.5 Melting point/Freezing point No Data Available Boiling point/Initial boiling point/Boiling range 100 ?C Flash Point >=93.3 ?C [Test Method: Closed Cup] Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure 2,399.8 Pa Vapor Density No Data Available Density 0.958 - 1.006 g/ml Relative Density 0.958 - 1.006 [Ref Std: WATER=1] Water solubility No Data Available Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity 16 - 20 Pa-s [Test Method: Brookfield] Volatile Organic Compounds 14.7 % weight [Test Method: calculated per CARB title 2] Percent volatile 81.6 % weight VOC Less H2O & Exempt Solvents 453 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Light 10.5. Incompatible materials Strong acids Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be 3M? Machine Polish, PN 05986, 05996, 39009, 39809 __________________________________________________________________________________________ Page: 6 of 11 relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE > 5,000 mg/kg Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Hydrotreated Light Petroleum Distillates Dermal Rabbit LD50 > 3,160 mg/kg Hydrotreated Light Petroleum Distillates Inhalation- Dust/Mist (4 hours) Rat LC50 > 3.0 mg/l Hydrotreated Light Petroleum Distillates Ingestion Rat LD50 > 5,000 mg/kg Aluminum Oxide Dermal LD50 estimated to be > 5,000 mg/kg Aluminum Oxide Inhalation- Dust/Mist (4 hours) Rat LC50 > 2.3 mg/l Aluminum Oxide Ingestion Rat LD50 > 5,000 mg/kg Decamethylcyclopentasiloxane Dermal Rabbit LD50 > 15,000 mg/kg Decamethylcyclopentasiloxane Inhalation- Dust/Mist (4 hours) Rat LC50 8.7 mg/l Decamethylcyclopentasiloxane Ingestion Rat LD50 > 24,134 mg/kg Dodecamethylcyclohexasiloxane Dermal Rat LD50 > 2,000 mg/kg Dodecamethylcyclohexasiloxane Ingestion Rat LD50 > 50,000 mg/kg Ceramic Materials and Wares, Chemicals Dermal LD50 estimated to be > 5,000 mg/kg Ceramic Materials and Wares, Chemicals Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Hydrotreated Light Petroleum Distillates Rabbit Mild irritant Aluminum Oxide Rabbit No significant irritation Dodecamethylcyclohexasiloxane Rabbit No significant irritation Ceramic Materials and Wares, Chemicals Rabbit No significant irritation Serious Eye Damage/Irritation 3M? Machine Polish, PN 05986, 05996, 39009, 39809 __________________________________________________________________________________________ Page: 7 of 11 Name Species Value Hydrotreated Light Petroleum Distillates Rabbit Mild irritant Aluminum Oxide Rabbit No significant irritation Dodecamethylcyclohexasiloxane Rabbit No significant irritation Ceramic Materials and Wares, Chemicals Rabbit Mild irritant Skin Sensitization Name Species Value Hydrotreated Light Petroleum Distillates Guinea pig Not sensitizing Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Hydrotreated Light Petroleum Distillates In Vitro Not mutagenic Aluminum Oxide In Vitro Not mutagenic Ceramic Materials and Wares, Chemicals In Vitro Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Hydrotreated Light Petroleum Distillates Dermal Mouse Some positive data exist, but the data are not sufficient for classification Aluminum Oxide Inhalation Rat Not carcinogenic Ceramic Materials and Wares, Chemicals Inhalation Multiple animal species Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Dodecamethylcyclohexasiloxane Ingestion Not toxic to female reproduction Rat NOAEL 1,000 mg/kg/day premating & during gestation Dodecamethylcyclohexasiloxane Ingestion Not toxic to male reproduction Rat NOAEL 1,000 mg/kg/day 28 days Dodecamethylcyclohexasiloxane Ingestion Not toxic to development Rat NOAEL 1,000 mg/kg/day premating & during gestation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Hydrotreated Light Petroleum Distillates Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Hydrotreated Light Petroleum Distillates Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Aluminum Oxide Inhalation pneumoconiosis | Some positive data exist, but the Human NOAEL Not occupational 3M? Machine Polish, PN 05986, 05996, 39009, 39809 __________________________________________________________________________________________ Page: 8 of 11 pulmonary fibrosis data are not sufficient for classification available exposure Dodecamethylcyclohexasil oxane Ingestion endocrine system | liver | respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,000 mg/kg/day 28 days Dodecamethylcyclohexasil oxane Ingestion nervous system All data are negative Rat NOAEL 1,000 mg/kg/day 28 days Ceramic Materials and Wares, Chemicals Inhalation pulmonary fibrosis Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL not available Ceramic Materials and Wares, Chemicals Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Human NOAEL not available occupational exposure Aspiration Hazard Name Value Hydrotreated Light Petroleum Distillates Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labeling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole. 12.1. Toxicity Acute aquatic hazard: GHS Acute 3: Harmful to aquatic life. Chronic aquatic hazard: GHS Chronic 3: Harmful to aquatic life with long lasting effects No product test data available Material Cas # Organism Type Exposure Test Endpoint Test Result Aluminum Oxide 1344-28-1 Water flea Experimental 48 hours Effect Concentration 50% >100 mg/l Aluminum Oxide 1344-28-1 Fish Experimental 96 hours Lethal Concentration 50% >100 mg/l Aluminum Oxide 1344-28-1 Green algae Experimental 72 hours Effect Concentration 50% >100 mg/l Aluminum Oxide 1344-28-1 Green algae Experimental 72 hours No obs Effect Conc >100 mg/l Ceramic Materials and Wares, Chemicals 66402-68-4 Data not available or insufficient for classification Decamethylcyc lopentasiloxan 541-02-6 Data not available or 3M? Machine Polish, PN 05986, 05996, 39009, 39809 __________________________________________________________________________________________ Page: 9 of 11 e insufficient for classification Dodecamethyl cyclohexasilox ane 540-97-6 Data not available or insufficient for classification Ethylene Oxide, Polymer with Ethylenediami ne and Propylene Oxide 26316-40-5 Data not available or insufficient for classification Hydrotreated Light Petroleum Distillates 64742-47-8 Data not available or insufficient for classification 12.2. Persistence and degradability Material CAS No. Test Type Duration Study Type Test Result Protocol Ethylene Oxide, Polymer with Ethylenediami ne and Propylene Oxide 26316-40-5 Data not available or insufficient for classification N/A N/A N/A N/A Decamethylcyc lopentasiloxan e 541-02-6 Experimental Photolysis Photolytic half- life (in air) 20.4 days (t 1/2) Other methods Decamethylcyc lopentasiloxan e 541-02-6 Experimental Biodegradation 28 days Percent degraded 0.14 % weight Other methods Dodecamethyl cyclohexasilox ane 540-97-6 Experimental Biodegradation 28 days Carbon dioxide evolution 4.46 % weight Other methods Aluminum Oxide 1344-28-1 Data not available or insufficient for classification N/A N/A N/A N/A Hydrotreated Light Petroleum Distillates 64742-47-8 Data not available or insufficient for classification N/A N/A N/A N/A Ceramic Materials and Wares, Chemicals 66402-68-4 Data not available or insufficient for classification N/A N/A N/A N/A 12.3. Bioaccumulative potential Material CAS No. Test Type Duration Study Type Test Result Protocol Ethylene Oxide, 26316-40-5 Data not available or N/A N/A N/A N/A 3M? Machine Polish, PN 05986, 05996, 39009, 39809 __________________________________________________________________________________________ Page: 10 of 11 Polymer with Ethylenediami ne and Propylene Oxide insufficient for classification Decamethylcyc lopentasiloxan e 541-02-6 Experimental BCF - Fathead Mi 105 days Bioaccumulati on Factor 13300 Other methods Dodecamethyl cyclohexasilox ane 540-97-6 Experimental BCF - Fathead Mi 49 days Bioaccumulati on Factor 1160 OECD 305E-Bioaccum Fl-thru fis Aluminum Oxide 1344-28-1 Data not available or insufficient for classification N/A N/A N/A N/A Hydrotreated Light Petroleum Distillates 64742-47-8 Data not available or insufficient for classification N/A N/A N/A N/A Ceramic Materials and Wares, Chemicals 66402-68-4 Data not available or insufficient for classification N/A N/A N/A N/A 12.4. Mobility in soil Please contact manufacturer for more details 12.5 Other adverse effects No information available SECTION 13: Disposal considerations 13.1. Disposal methods According to the Environmental Quality (Scheduled Wastes) Regulations 2005, scheduled waste has to be sent to a prescribed premise for recycling, treatment or disposal. Please approach Kualiti Alam for proper schedule waste classification and disposal. SECTION 14: Transport Information Not hazardous for transportation. Marine Transport (IMDG) UN Number: None assigned. Proper Shipping Name: None assigned. Technical Name: None assigned. Hazard Class/Division: None assigned. Subsidiary Risk: None assigned. Packing Group: None assigned. Limited Quantity: None assigned. Marine Pollutant: None assigned. Marine Pollutant Technical Name: None assigned. Other Dangerous Goods Descriptions: 3M? Machine Polish, PN 05986, 05996, 39009, 39809 __________________________________________________________________________________________ Page: 11 of 11 None assigned. Air Transport (IATA) UN Number: None assigned. Proper Shipping Name: None assigned. Technical Name: None assigned. Hazard Class/Division: None assigned. Subsidiary Risk: None assigned. Packing Group: None assigned. Limited Quantity: None assigned. Marine Pollutant: None assigned. Marine Pollutant Technical Name: None assigned. Other Dangerous Goods Descriptions: None assigned. Transportation classifications are provided as a customer service. As for shipping, YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M's transportation classifications are based on product formulation, packaging, 3M policies and 3M's understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling or marking requirements. The above information is only for reference. If you are shipping by air or ocean, YOU are advised to check & meet applicable regulatory requirements. SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Global inventory status All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information. The components of this material are in compliance with the China "Measures on Environmental Management of New Chemical Substance". Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Japan Chemical Substance Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Philippines RA 6969 requirements. Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the new substance notification requirements of CEPA. The components of this product are in compliance with the chemical notification requirements of TSCA. SECTION 16: Other information DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications. 3M Malaysia SDSs are available at www.3M.com.my