3M(TM) Tire Restorer PN 39042, 46604 05/07/15 __________________________________________________________________________________________ Page 1 of 10 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 24-6256-2 Version Number: 3.00 Issue Date: 05/07/15 Supercedes Date: 09/10/13 SECTION 1: Identification 1.1. Product identifier 3M(TM) Tire Restorer PN 39042, 46604 Product Identification Numbers LB-K100-0440-3, LB-K100-1277-8, 60-4550-3482-1, 60-4550-3573-7, 60-4550-3580-2, 60-4550-6506-4, 60-4550-6729-2, 60-4550-7147-6 1.2. Recommended use and restrictions on use Recommended use Automotive, Appearance Enhancement 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Not classified as hazardous according to OSHA Hazard Communication Standard, 29 CFR 1910.1200. 2.2. Label elements Signal word Not applicable. Symbols Not applicable. Pictograms Not applicable. 3M(TM) Tire Restorer PN 39042, 46604 05/07/15 __________________________________________________________________________________________ Page 2 of 10 2.3. Hazards not otherwise classified None. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Water 7732-18-5 60 - 90 Trade Secret * Poly(Dimethylsiloxane) 63148-62-9 10 - 30 Trade Secret * Glycerin 56-81-5 3 - 7 Trade Secret * Poly(Oxy-1,2-Ethanediyl), .Alpha.-(2-Propylheptyl)- .Omega.-Hydroxy- 160875-66-1 < 2 Trade Secret * Formaldehyde 50-00-0 < 0.1 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Material will not burn. Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Formaldehyde During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion 3M(TM) Tire Restorer PN 39042, 46604 05/07/15 __________________________________________________________________________________________ Page 3 of 10 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Ventilate the area with fresh air. Observe precautions from other sections. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with water. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. 7.2. Conditions for safe storage including any incompatibilities No special storage requirements. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Formaldehyde 50-00-0 CMRG TWA:0.5 ppm Formaldehyde 50-00-0 OSHA TWA:0.75 ppm;STEL:2 ppm 29 CFR 1910.1048 Formaldehyde 50-00-0 ACGIH CEIL:0.3 ppm A2: Suspected human carcin., Sensitizer Glycerin 56-81-5 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 3M(TM) Tire Restorer PN 39042, 46604 05/07/15 __________________________________________________________________________________________ Page 4 of 10 8.2.2. Personal protective equipment (PPE) Eye/face protection None required. Skin/hand protection No protective gloves required. Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Emulsion Odor, Color, Grade: White Emulsion, Odor threshold No Data Available Melting point Not Applicable Boiling Point 212 ?F Flash Point No flash point Evaporation rate Not Applicable Flammability (solid, gas) Not Applicable Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Vapor Pressure No Data Available Vapor Density Not Applicable Density 1 g/ml Specific Gravity 1 [Ref Std: WATER=1] Solubility in Water Complete Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature Not Applicable Decomposition temperature No Data Available Viscosity 1 - 50 centipoise Hazardous Air Pollutants 0.0233 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 0.1 % weight [Test Method: calculated per CARB title 2] Volatile Organic Compounds 1 g/l [Test Method: calculated SCAQMD rule 443.1] Percent volatile 81 % VOC Less H2O & Exempt Solvents 2 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability 3M(TM) Tire Restorer PN 39042, 46604 05/07/15 __________________________________________________________________________________________ Page 5 of 10 Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 10.5. Incompatible materials None known. 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Skin Contact: Contact with the skin during product use is not expected to result in significant irritation. Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Carcinogenicity: Ingredient CAS No. Class Description Regulation Formaldehyde 50-00-0 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Formaldehyde 50-00-0 Known human carcinogen National Toxicology Program Carcinogens Formaldehyde 50-00-0 Cancer hazard OSHA Carcinogens Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or 3M(TM) Tire Restorer PN 39042, 46604 05/07/15 __________________________________________________________________________________________ Page 6 of 10 the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Poly(Dimethylsiloxane) Dermal Rabbit LD50 > 19,400 mg/kg Poly(Dimethylsiloxane) Ingestion Rat LD50 > 17,000 mg/kg Glycerin Dermal Rabbit LD50 estimated to be > 5,000 mg/kg Glycerin Ingestion Rat LD50 > 5,000 mg/kg Formaldehyde Dermal Rabbit LD50 270 mg/kg Formaldehyde Inhalation- Gas (4 hours) Rat LC50 470 ppm Formaldehyde Ingestion Rat LD50 800 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Poly(Dimethylsiloxane) Rabbit No significant irritation Glycerin Rabbit No significant irritation Formaldehyde official classifica tion Corrosive Serious Eye Damage/Irritation Name Species Value Poly(Dimethylsiloxane) Rabbit No significant irritation Glycerin Rabbit No significant irritation Formaldehyde official classifica tion Corrosive Skin Sensitization Name Species Value Glycerin Guinea pig Not sensitizing Formaldehyde Guinea pig Sensitizing Respiratory Sensitization Name Species Value Formaldehyde Human Some positive data exist, but the data are not sufficient for classification Germ Cell Mutagenicity Name Route Value Formaldehyde In Vitro Some positive data exist, but the data are not sufficient for classification Formaldehyde In vivo Mutagenic Carcinogenicity Name Route Species Value Glycerin Ingestion Mouse Some positive data exist, but the data are not sufficient for classification Formaldehyde Not Specified Human and animal Carcinogenic Reproductive Toxicity 3M(TM) Tire Restorer PN 39042, 46604 05/07/15 __________________________________________________________________________________________ Page 7 of 10 Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Glycerin Ingestion Not toxic to female reproduction Rat NOAEL 2,000 mg/kg/day 2 generation Glycerin Ingestion Not toxic to male reproduction Rat NOAEL 2,000 mg/kg/day 2 generation Glycerin Ingestion Not toxic to development Rat NOAEL 2,000 mg/kg/day 2 generation Formaldehyde Ingestion Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 100 mg/kg not applicable Formaldehyde Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 10 ppm during gestation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Formaldehyde Inhalation respiratory system Causes damage to organs Rat LOAEL 128 ppm 6 hours Formaldehyde Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Glycerin Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 3.91 mg/l 14 days Glycerin Inhalation heart | liver | kidney and/or bladder All data are negative Rat NOAEL 3.91 mg/l 14 days Glycerin Ingestion endocrine system | hematopoietic system | liver | kidney and/or bladder All data are negative Rat NOAEL 10,000 mg/kg/day 2 years Formaldehyde Dermal respiratory system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 80 mg/kg/day 60 weeks Formaldehyde Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Rat NOAEL 0.3 ppm 28 months Formaldehyde Inhalation liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 20 ppm 13 weeks Formaldehyde Inhalation hematopoietic system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 15 ppm 3 weeks Formaldehyde Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 10 ppm 13 weeks Formaldehyde Inhalation endocrine system | immune system | muscles | kidney and/or bladder All data are negative Rat NOAEL 15 ppm 28 months Formaldehyde Inhalation eyes | vascular system All data are negative Rat NOAEL 14.3 ppm 2 years Formaldehyde Inhalation heart All data are negative Mouse NOAEL 14.3 2 years 3M(TM) Tire Restorer PN 39042, 46604 05/07/15 __________________________________________________________________________________________ Page 8 of 10 ppm Formaldehyde Ingestion liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 300 mg/kg/day 2 years Formaldehyde Ingestion immune system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 20 mg/kg/day 4 weeks Formaldehyde Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 15 mg/kg/day 24 months Formaldehyde Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 109 mg/kg/day 2 years Formaldehyde Ingestion heart | endocrine system | hematopoietic system | respiratory system | vascular system All data are negative Rat NOAEL 300 mg/kg/day 2 years Formaldehyde Ingestion skin | muscles | eyes All data are negative Rat NOAEL 109 mg/kg/day 2 years Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Prior to disposal, consult all applicable authorities and regulations to insure proper classification. Dispose of waste product in a permitted industrial waste facility. If no other disposal options are available, waste product may be placed in a landfill properly designed for industrial waste. Empty and clean product containers may be disposed as non-hazardous waste. Consult your specific regulations and service providers to determine available options and requirements. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations 3M(TM) Tire Restorer PN 39042, 46604 05/07/15 __________________________________________________________________________________________ Page 9 of 10 Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification Formaldehyde 50-00-0 Carcinogen WARNING: This product contains a chemical known to the State of California to cause cancer. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 1 Flammability: 0 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 24-6256-2 Version Number: 3.00 Issue Date: 05/07/15 Supercedes Date: 09/10/13 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M(TM) Tire Restorer PN 39042, 46604 05/07/15 __________________________________________________________________________________________ Page 10 of 10 3M USA SDSs are available at www.3M.com