3M(TM) Perfect-It(TM) Paste Wax PN 39526, 38526, 39526S, 33526 05/12/15 __________________________________________________________________________________________ Page 1 of 10 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 16-2888-2 Version Number: 13.00 Issue Date: 05/12/15 Supercedes Date: 06/08/12 SECTION 1: Identification 1.1. Product identifier 3M(TM) Perfect-It(TM) Paste Wax PN 39526, 38526, 39526S, 33526 Product Identification Numbers 60-4550-3090-2, 60-9800-4373-5, 60-9801-0783-7 1.2. Recommended use and restrictions on use Recommended use Automotive, Wax for Automotive paint 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Solid: Category 1. Skin Corrosion/Irritation: Category 2. Specific Target Organ Toxicity (central nervous system): Category 3. 2.2. Label elements Signal word Danger Symbols Flame | Exclamation mark | Pictograms 3M(TM) Perfect-It(TM) Paste Wax PN 39526, 38526, 39526S, 33526 05/12/15 __________________________________________________________________________________________ Page 2 of 10 Hazard Statements Flammable solid. Causes skin irritation. May cause drowsiness or dizziness. Precautionary Statements General: Keep out of reach of children. Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified None. 4% of the mixture consists of ingredients of unknown acute oral toxicity. 21% of the mixture consists of ingredients of unknown acute dermal toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Hydrotreated Heavy Naphtha (Petroleum) 64742-48-9 15 - 40 Trade Secret * Hydrotreated Light Petroleum Distillates 64742-47-8 15 - 40 Trade Secret * Carnauba Wax 8015-86-9 10 - 30 Trade Secret * Siloxanes And Silicones, Di-Me 63148-62-9 7 - 13 Trade Secret * Montan Wax 68476-03-9 3 - 7 Trade Secret * Synthetic Hydrocarbon Mixture Trade Secret* 1 - 5 Trade Secret * 3M(TM) Perfect-It(TM) Paste Wax PN 39526, 38526, 39526S, 33526 05/12/15 __________________________________________________________________________________________ Page 3 of 10 *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Eliminate all ignition sources if safe to do so. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 3M(TM) Perfect-It(TM) Paste Wax PN 39526, 38526, 39526S, 33526 05/12/15 __________________________________________________________________________________________ Page 4 of 10 6.3. Methods and material for containment and cleaning up Collect as much of the spilled material as possible using non-sparking tools. Place in a closed container approved for transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Hydrotreated Light Petroleum Distillates 64742-47-8 CMRG TWA:165 ppm JET FUELS (NON-AEROSOL), AS TOTAL HYDROCARBON VAPOR 64742-47-8 ACGIH TWA(as total hydrocarbon vapor, non-aerosol):200 mg/m3 A3: Confirmed animal carcin., Skin Notation Kerosine (petroleum) 64742-47-8 ACGIH TWA(as total hydrocarbon vapor, non-aerosol):200 mg/m3 A3: Confirmed animal carcin., Skin Notation Hydrotreated Heavy Naphtha (Petroleum) 64742-48-9 Manufacturer determined TWA:100 ppm ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection 3M(TM) Perfect-It(TM) Paste Wax PN 39526, 38526, 39526S, 33526 05/12/15 __________________________________________________________________________________________ Page 5 of 10 Eye protection not required. Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Solid Specific Physical Form: Paste Odor, Color, Grade: Coconut Scent, Light Yellow Odor threshold No Data Available pH No Data Available Melting point 95 ?C Boiling Point 150 ?C Flash Point 150 ?F [Details: FLAMMABLE SOLID] Evaporation rate 1 [Ref Std: WATER=1] Flammability (solid, gas) Flammable Solid: Category 1. Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure No Data Available Vapor Density >=1.00 [Ref Std: AIR=1] Density 0.8309 g/cm3 Specific Gravity 0.8309 [Ref Std: WATER=1] Solubility in Water Nil Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity No Data Available Hazardous Air Pollutants 0.0004 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 563 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 33.8 % weight [Test Method: calculated per CARB title 2] Percent volatile 67.7 % weight VOC Less H2O & Exempt Solvents 563 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 3M(TM) Perfect-It(TM) Paste Wax PN 39526, 38526, 39526S, 33526 05/12/15 __________________________________________________________________________________________ Page 6 of 10 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Sparks and/or flames 10.5. Incompatible materials Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: May be harmful in contact with skin. Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: 3M(TM) Perfect-It(TM) Paste Wax PN 39526, 38526, 39526S, 33526 05/12/15 __________________________________________________________________________________________ Page 7 of 10 Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE 2,000 - 5,000 mg/kg Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Hydrotreated Heavy Naphtha (Petroleum) Inhalation- Vapor LC50 estimated to be 20 - 50 mg/l Hydrotreated Heavy Naphtha (Petroleum) Dermal Rabbit LD50 > 3,000 mg/kg Hydrotreated Light Petroleum Distillates Dermal Rabbit LD50 > 3,160 mg/kg Hydrotreated Heavy Naphtha (Petroleum) Ingestion Rat LD50 > 5,000 mg/kg Hydrotreated Light Petroleum Distillates Inhalation- Dust/Mist (4 hours) Rat LC50 > 3.0 mg/l Hydrotreated Light Petroleum Distillates Ingestion Rat LD50 > 5,000 mg/kg Carnauba Wax Dermal LD50 estimated to be > 5,000 mg/kg Carnauba Wax Ingestion Rat LD50 > 8,800 mg/kg Siloxanes And Silicones, Di-Me Dermal Rabbit LD50 > 19,400 mg/kg Siloxanes And Silicones, Di-Me Ingestion Rat LD50 > 17,000 mg/kg Montan Wax Ingestion Rat LD50 > 15,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Hydrotreated Heavy Naphtha (Petroleum) Rabbit Irritant Hydrotreated Light Petroleum Distillates Rabbit Mild irritant Carnauba Wax Professio nal judgeme nt No significant irritation Siloxanes And Silicones, Di-Me Rabbit No significant irritation Serious Eye Damage/Irritation Name Species Value Hydrotreated Heavy Naphtha (Petroleum) Rabbit No significant irritation Hydrotreated Light Petroleum Distillates Rabbit Mild irritant Carnauba Wax Professio nal judgeme nt No significant irritation Siloxanes And Silicones, Di-Me Rabbit No significant irritation Skin Sensitization Name Species Value Hydrotreated Heavy Naphtha (Petroleum) Guinea pig Not sensitizing Hydrotreated Light Petroleum Distillates Guinea pig Not sensitizing Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value 3M(TM) Perfect-It(TM) Paste Wax PN 39526, 38526, 39526S, 33526 05/12/15 __________________________________________________________________________________________ Page 8 of 10 Hydrotreated Heavy Naphtha (Petroleum) In vivo Not mutagenic Hydrotreated Heavy Naphtha (Petroleum) In Vitro Some positive data exist, but the data are not sufficient for classification Hydrotreated Light Petroleum Distillates In Vitro Not mutagenic Carcinogenicity Name Route Species Value Hydrotreated Heavy Naphtha (Petroleum) Dermal Mouse Some positive data exist, but the data are not sufficient for classification Hydrotreated Heavy Naphtha (Petroleum) Inhalation Human and animal Some positive data exist, but the data are not sufficient for classification Hydrotreated Light Petroleum Distillates Dermal Mouse Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Hydrotreated Heavy Naphtha (Petroleum) Inhalation Not toxic to development Rat NOAEL 2.4 mg/l during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Hydrotreated Heavy Naphtha (Petroleum) Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Hydrotreated Heavy Naphtha (Petroleum) Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Hydrotreated Heavy Naphtha (Petroleum) Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Dog NOAEL 6.5 mg/l 4 hours Hydrotreated Light Petroleum Distillates Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Hydrotreated Light Petroleum Distillates Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Hydrotreated Heavy Naphtha (Petroleum) Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 4.6 mg/l 6 months Hydrotreated Heavy Naphtha (Petroleum) Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat LOAEL 1.9 mg/l 13 weeks Hydrotreated Heavy Naphtha (Petroleum) Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 0.6 mg/l 90 days Hydrotreated Heavy Naphtha (Petroleum) Inhalation bone, teeth, nails, and/or hair | blood | liver | muscles All data are negative Rat NOAEL 5.6 mg/l 12 weeks Hydrotreated Heavy Naphtha (Petroleum) Inhalation heart All data are negative Multiple animal species NOAEL 1.3 mg/l 90 days 3M(TM) Perfect-It(TM) Paste Wax PN 39526, 38526, 39526S, 33526 05/12/15 __________________________________________________________________________________________ Page 9 of 10 Aspiration Hazard Name Value Hydrotreated Heavy Naphtha (Petroleum) Aspiration hazard Hydrotreated Light Petroleum Distillates Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. EPA Hazardous Waste Number (RCRA): Not regulated SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 3M(TM) Perfect-It(TM) Paste Wax PN 39526, 38526, 39526S, 33526 05/12/15 __________________________________________________________________________________________ Page 10 of 10 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 2 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 16-2888-2 Version Number: 13.00 Issue Date: 05/12/15 Supercedes Date: 06/08/12 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com