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3M(TM) Chrome & Metal Polish, P/N 39527, 38527 06/03/16 __________________________________________________________________________________________ Page 1 of 10 Safety Data Sheet Copyright,2016,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 06-8551-1 Version Number: 23.01 Issue Date: 06/03/16 Supercedes Date: 05/11/15 SECTION 1: Identification 1.1. Product identifier 3M(TM) Chrome & Metal Polish, P/N 39527, 38527 Product Identification Numbers 60-4550-6725-0, 60-9800-2332-3 1.2. Recommended use and restrictions on use Recommended use Automotive, Chrome and Metal Polish 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Serious Eye Damage/Irritation: Category 1. Skin Corrosion/Irritation: Category 2. Specific Target Organ Toxicity (single exposure): Category 3. 2.2. Label elements Signal word Danger Symbols Corrosion | Exclamation mark | 3M(TM) Chrome & Metal Polish, P/N 39527, 38527 06/03/16 __________________________________________________________________________________________ Page 2 of 10 Pictograms Hazard Statements Causes serious eye damage. Causes skin irritation. May cause drowsiness or dizziness. Precautionary Statements General: Keep out of reach of children. Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN: Wash with plenty of soap and water. Immediately call a POISON CENTER or doctor/physician. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified None. 1% of the mixture consists of ingredients of unknown acute oral toxicity. 4% of the mixture consists of ingredients of unknown acute dermal toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Aluminum Oxide (non-fibrous) 1344-28-1 30 - 60 Trade Secret * Water 7732-18-5 30 - 60 Trade Secret * Hydrotreated Light Petroleum Distillates 64742-47-8 10 - 30 Trade Secret * Oleic Acid 112-80-1 5 - 15 Trade Secret * Ammonium Hydroxide 1336-21-6 1 - 5 Trade Secret * Iron Oxide (FE2O3) 1309-37-1 < 1 Trade Secret * Amides, rape-oil Trade Secret* < 1 Trade Secret * 3M(TM) Chrome & Metal Polish, P/N 39527, 38527 06/03/16 __________________________________________________________________________________________ Page 3 of 10 *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 3M(TM) Chrome & Metal Polish, P/N 39527, 38527 06/03/16 __________________________________________________________________________________________ Page 4 of 10 6.3. Methods and material for containment and cleaning up Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Store away from oxidizing agents. Store away from areas where product may come into contact with food or pharmaceuticals. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Iron Oxide (FE2O3) 1309-37-1 ACGIH TWA(respirable fraction):5 mg/m3 A4: Not class. as human carcin Iron Oxide (FE2O3) 1309-37-1 OSHA TWA(as fume):10 mg/m3 AMMONIA RELEASED FROM AMMONIUM HYDROXIDE/AQUEOUS AMMONIA SOLUTIONS 1336-21-6 ACGIH TWA:25 ppm;STEL:35 ppm AMMONIA RELEASED FROM AMMONIUM HYDROXIDE/AQUEOUS AMMONIA SOLUTIONS 1336-21-6 OSHA TWA:35 mg/m3(50 ppm) Ammonium Hydroxide 1336-21-6 CMRG TWA(as ammonia):10 ppm;STEL(as ammonia):20 ppm Aluminum Oxide (non-fibrous) 1344-28-1 CMRG TWA:1 fiber/cc Aluminum Oxide (non-fibrous) 1344-28-1 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Aluminum, insoluble compounds 1344-28-1 ACGIH TWA(respirable fraction):1 mg/m3 A4: Not class. as human carcin Hydrotreated Light Petroleum Distillates 64742-47-8 CMRG TWA:165 ppm Kerosine (petroleum) 64742-47-8 ACGIH TWA(as total hydrocarbon vapor, non-aerosol):200 mg/m3 A3: Confirmed animal carcin., SKIN ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 3M(TM) Chrome & Metal Polish, P/N 39527, 38527 06/03/16 __________________________________________________________________________________________ Page 5 of 10 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Full Face Shield Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Neoprene Nitrile Rubber Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Solid Specific Physical Form: Paste Odor, Color, Grade: Slight ammonia odor pink paste. Odor threshold No Data Available pH Approximately 9.4 Units not avail. or not appl. Melting point No Data Available Boiling Point 158 ?F Flash Point >=200 ?F [Test Method: Closed Cup] Evaporation rate >=1 [Ref Std: WATER=1] Flammability (solid, gas) Not Classified Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure No Data Available Vapor Density No Data Available Density 1.09 g/ml Specific Gravity 1.09 [Ref Std: WATER=1] Solubility in Water Moderate Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available 3M(TM) Chrome & Metal Polish, P/N 39527, 38527 06/03/16 __________________________________________________________________________________________ Page 6 of 10 Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity 629,225 - 943,975 Saybolt Universal Second [@ 100 ?F ] Hazardous Air Pollutants 0 lb HAPS/lb solids [Test Method: Calculated] Molecular weight No Data Available Volatile Organic Compounds 197 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 18 % weight [Test Method: calculated per CARB title 2] Percent volatile 58 % weight VOC Less H2O & Exempt Solvents 349 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 10.5. Incompatible materials Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May cause additional health effects (see below). Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. 3M(TM) Chrome & Metal Polish, P/N 39527, 38527 06/03/16 __________________________________________________________________________________________ Page 7 of 10 Eye Contact: Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE > 5,000 mg/kg Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Aluminum Oxide (non-fibrous) Dermal LD50 estimated to be > 5,000 mg/kg Aluminum Oxide (non-fibrous) Inhalation- Dust/Mist (4 hours) Rat LC50 > 2.3 mg/l Aluminum Oxide (non-fibrous) Ingestion Rat LD50 > 5,000 mg/kg Hydrotreated Light Petroleum Distillates Dermal Rabbit LD50 > 3,160 mg/kg Hydrotreated Light Petroleum Distillates Inhalation- Dust/Mist (4 hours) Rat LC50 > 3 mg/l Hydrotreated Light Petroleum Distillates Ingestion Rat LD50 > 5,000 mg/kg Oleic Acid Dermal Guinea pig LD50 > 3,000 mg/kg Oleic Acid Ingestion Rat LD50 57,000 mg/kg Ammonium Hydroxide Ingestion Rat LD50 350 mg/kg Iron Oxide (FE2O3) Dermal Not available LD50 3,100 mg/kg Iron Oxide (FE2O3) Ingestion Not available LD50 3,700 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Aluminum Oxide (non-fibrous) Rabbit No significant irritation Hydrotreated Light Petroleum Distillates Rabbit Mild irritant Oleic Acid Rabbit Minimal irritation Ammonium Hydroxide Rabbit Corrosive Iron Oxide (FE2O3) Rabbit No significant irritation Serious Eye Damage/Irritation Name Species Value Aluminum Oxide (non-fibrous) Rabbit No significant irritation Hydrotreated Light Petroleum Distillates Rabbit Mild irritant Oleic Acid Rabbit Mild irritant Ammonium Hydroxide Rabbit Corrosive Iron Oxide (FE2O3) Rabbit No significant irritation 3M(TM) Chrome & Metal Polish, P/N 39527, 38527 06/03/16 __________________________________________________________________________________________ Page 8 of 10 Skin Sensitization Name Species Value Hydrotreated Light Petroleum Distillates Guinea pig Not sensitizing Iron Oxide (FE2O3) Human Some positive data exist, but the data are not sufficient for classification Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Aluminum Oxide (non-fibrous) In Vitro Not mutagenic Hydrotreated Light Petroleum Distillates In Vitro Not mutagenic Oleic Acid In Vitro Some positive data exist, but the data are not sufficient for classification Iron Oxide (FE2O3) In Vitro Not mutagenic Carcinogenicity Name Route Species Value Aluminum Oxide (non-fibrous) Inhalation Rat Not carcinogenic Hydrotreated Light Petroleum Distillates Dermal Mouse Some positive data exist, but the data are not sufficient for classification Oleic Acid Dermal Mouse Not carcinogenic Oleic Acid Ingestion Rat Not carcinogenic Oleic Acid Not Specified Multiple animal species Not carcinogenic Iron Oxide (FE2O3) Inhalation Human Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects For the component/components, either no data are currently available or the data are not sufficient for classification. Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Hydrotreated Light Petroleum Distillates Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Hydrotreated Light Petroleum Distillates Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Hydrotreated Light Petroleum Distillates Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Notavailable Ammonium Hydroxide Inhalation respiratory irritation May cause respiratory irritation Human NOAEL not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Aluminum Oxide (non- fibrous) Inhalation pneumoconiosis | pulmonary fibrosis Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure 3M(TM) Chrome & Metal Polish, P/N 39527, 38527 06/03/16 __________________________________________________________________________________________ Page 9 of 10 Oleic Acid Ingestion liver | immune system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 2,250 mg/kg/day 108 weeks Oleic Acid Ingestion hematopoietic system All data are negative Rat NOAEL 2,550 mg/kg/day 108 weeks Iron Oxide (FE2O3) Inhalation pulmonary fibrosis | pneumoconiosis Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Aspiration Hazard Name Value Hydrotreated Light Petroleum Distillates Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. If no other disposal options are available, waste product that has been completely cured or polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): 3M(TM) Chrome & Metal Polish, P/N 39527, 38527 06/03/16 __________________________________________________________________________________________ Page 10 of 10 Ingredient C.A.S. No % by Wt Ammonium Hydroxide (AMMONIA COMPOUNDS) 1336-21-6 1 - 5 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 3 Flammability: 1 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 06-8551-1 Version Number: 23.01 Issue Date: 06/03/16 Supercedes Date: 05/11/15 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com