SDS Repository

sds

Collection
3M SDS
Description
 
Tags
Search Tag
Filename
08681_Urethane_Single_Step_Primer.pdf
Source
 
Full Text
3M? Single Step Primer, PN 08681, 08682 08/01/18 __________________________________________________________________________________________ Page 1 of 18 Safety Data Sheet Copyright,2018,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 32-7721-7 Version Number: 1.06 Issue Date: 08/01/18 Supercedes Date: 01/17/18 SECTION 1: Identification 1.1. Product identifier 3M? Single Step Primer, PN 08681, 08682 Product Identification Numbers 60-4550-8292-9, 60-4550-8293-7 7100079772, 7100084366 1.2. Recommended use and restrictions on use Recommended use Automotive, Glass Primer 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Liquid: Category 2. Serious Eye Damage/Irritation: Category 2A. Respiratory Sensitizer: Category 1A. Skin Sensitizer: Category 1A. Carcinogenicity: Category 1B. Specific Target Organ Toxicity (single exposure): Category 2. Specific Target Organ Toxicity (single exposure): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 3M? Single Step Primer, PN 08681, 08682 08/01/18 __________________________________________________________________________________________ Page 2 of 18 2.2. Label elements Signal word Danger Symbols Flame | Exclamation mark | Health Hazard | Pictograms Hazard Statements Highly flammable liquid and vapor. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause drowsiness or dizziness. May cause cancer. May cause damage to organs: respiratory system | Causes damage to organs through prolonged or repeated exposure: respiratory system | Precautionary Statements Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. In case of inadequate ventilation wear respiratory protection. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. 3M? Single Step Primer, PN 08681, 08682 08/01/18 __________________________________________________________________________________________ Page 3 of 18 If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed or concerned: Call a POISON CENTER or doctor/physician. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. Storage: Keep cool. Keep container tightly closed. Store locked up in a well-ventilated place. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Supplemental Information: Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. 3% of the mixture consists of ingredients of unknown acute oral toxicity. 3% of the mixture consists of ingredients of unknown acute dermal toxicity. 5% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Methyl Ethyl Ketone 78-93-3 40 - 70 Trade Secret * N-Butyl Acetate 123-86-4 10 - 30 Trade Secret * 1,6-Hexamethylene Diisocyanate-TDI Copolymer 63368-95-6 5 - 10 Trade Secret * P,P'-Methylenebis(phenyl isocyanate) 101-68-8 < 10 Trade Secret * Polymethylene Polyphenylene Isocyanate 9016-87-9 < 5 Trade Secret * Diphenylmethane-2,4'-diisocyanate 5873-54-1 < 5 Trade Secret * 1-methoxy-2-propyl acetate 108-65-6 < 5 Trade Secret * 3-(trimethoxysilyl)propyl glycidyl ether 2530-83-8 < 2 Trade Secret * Carbon Black 1333-86-4 1 - 5 Trade Secret * Hexamethylene diisocyanate polymer 28182-81-2 < 3 Trade Secret * Alkyl Isocyanate Silane (NJTS No. 04499600-7195) Trade Secret* < 5 Trade Secret * Adipic acid-1,4-butanediol-MDI-neopentyl glycol copolymer 56815-45-3 1 - 5 Trade Secret * Ethylbenzene 100-41-4 < 0.5 Trade Secret * Hexamethylene diisocyanate 822-06-0 < 0.5 Trade Secret * Toluene 2,4-Diisocyanate 584-84-9 < 0.5 Trade Secret * NJTS or NJTSRN: New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. 3M? Single Step Primer, PN 08681, 08682 08/01/18 __________________________________________________________________________________________ Page 4 of 18 Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Cyanide During Combustion Oxides of Nitrogen During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Pour isocyanate decontaminant solution (90% water, 8% concentrated ammonia, 2% detergent) on spill and 3M? Single Step Primer, PN 08681, 08682 08/01/18 __________________________________________________________________________________________ Page 5 of 18 allow to react for 10 minutes. Or pour water on spill and allow to react for more than 30 minutes. Cover with absorbent material. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non- sparking tools. Place in a metal container approved for transportation by appropriate authorities. Cover, but do not seal for 48 hours. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling For industrial or professional use only. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Keep away from reactive metals (eg. Aluminum, zinc etc.) to avoid the formation of hydrogen gas that could create an explosion hazard. Wear low static or properly grounded shoes. Use personal protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep cool. Keep container tightly closed to prevent contamination with water or air. If contamination is suspected, do not reseal container. Store away from heat. Store away from acids. Store away from strong bases. Store away from oxidizing agents. Store away from amines. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Ethylbenzene 100-41-4 ACGIH TWA:20 ppm A3: Confirmed animal carcin. Ethylbenzene 100-41-4 OSHA TWA:435 mg/m3(100 ppm) P,P'-Methylenebis(phenyl isocyanate) 101-68-8 ACGIH TWA:0.005 ppm P,P'-Methylenebis(phenyl isocyanate) 101-68-8 OSHA CEIL:0.2 mg/m3(0.02 ppm) 1-methoxy-2-propyl acetate 108-65-6 AIHA TWA:50 ppm N-Butyl Acetate 123-86-4 ACGIH TWA:50 ppm;STEL:150 ppm N-Butyl Acetate 123-86-4 OSHA TWA:710 mg/m3(150 ppm) Carbon Black 1333-86-4 ACGIH TWA(inhalable fraction):3 mg/m3 A3: Confirmed animal carcin. Carbon Black 1333-86-4 OSHA TWA:3.5 mg/m3 Toluene 2,4-Diisocyanate 584-84-9 ACGIH TWA(inhalable fraction and vapor):0.001 ppm;STEL(inhalable fraction and vapor):0.005 ppm A3: Confirmed animal carcin., SKIN; Resp+Dermal sensitizer Toluene 2,4-Diisocyanate 584-84-9 OSHA CEIL:0.14 mg/m3(0.02 ppm) 3M? Single Step Primer, PN 08681, 08682 08/01/18 __________________________________________________________________________________________ Page 6 of 18 Methyl Ethyl Ketone 78-93-3 ACGIH TWA:200 ppm;STEL:300 ppm Methyl Ethyl Ketone 78-93-3 OSHA TWA:590 mg/m3(200 ppm) Hexamethylene diisocyanate 822-06-0 ACGIH TWA:0.005 ppm ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Odor, Color, Grade: Pungent odor Black liquid. Odor threshold No Data Available pH No Data Available Melting point No Data Available Boiling Point 174 ?F 3M? Single Step Primer, PN 08681, 08682 08/01/18 __________________________________________________________________________________________ Page 7 of 18 Flash Point 17.6 ?F [Test Method:Closed Cup] Evaporation rate 3.5 [Ref Std:BUOAC=1] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) 1.8 % volume Flammable Limits(UEL) 11.5 % volume Vapor Pressure 80 mmHg [@ 20 ?C] Vapor Density No Data Available Density 0.95 g/ml Specific Gravity 0.95 [@ 20 ?C] [Ref Std:WATER=1] Solubility In Water 14 g/100 ml Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature 392 ?F Decomposition temperature No Data Available Viscosity 20 mPa-s [@ 20 ?C ] Hazardous Air Pollutants 0.56 lb HAPS/lb solids Volatile Organic Compounds 70.25 % weight Volatile Organic Compounds 664 g/l Percent volatile 70.25 % weight VOC Less H2O & Exempt Solvents 664 g/l [Test Method:tested per EPA method 24] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat High shear and high temperature conditions Sparks and/or flames Temperatures above the boiling point 10.5. Incompatible materials Accelerators Al or Mg powder and high/shear temperature conditions Alcohols Alkali and alkaline earth metals Amines Combustibles Finely divided active metals Reaction with water, alcohols, and amines is not hazardous if container can vent to the atmosphere to prevent pressure buildup. Reactive metals Strong acids Strong bases Strong oxidizing agents Water 3M? Single Step Primer, PN 08681, 08682 08/01/18 __________________________________________________________________________________________ Page 8 of 18 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest. May cause additional health effects (see below). Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: May be harmful if swallowed. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. Prolonged or repeated exposure may cause target organ effects: 3M? Single Step Primer, PN 08681, 08682 08/01/18 __________________________________________________________________________________________ Page 9 of 18 Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation Generic: Benzene, 1,3-diisocyanatomethyl- 584-84-9 Anticipated human carcinogen National Toxicology Program Carcinogens Carbon Black 1333-86-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Ethylbenzene 100-41-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Toluene 2,4-Diisocyanate 584-84-9 Grp. 2B: Possible human carc. International Agency for Research on Cancer Additional Information: Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE20 - 50 mg/l Overall product Ingestion No data available; calculated ATE2,000 - 5,000 mg/kg Methyl Ethyl Ketone Dermal Rabbit LD50 > 8,050 mg/kg Methyl Ethyl Ketone Inhalation- Vapor (4 hours) Rat LC50 34.5 mg/l Methyl Ethyl Ketone Ingestion Rat LD50 2,737 mg/kg N-Butyl Acetate Dermal Rabbit LD50 > 5,000 mg/kg N-Butyl Acetate Inhalation- Dust/Mist (4 hours) Rat LC50 1.4 mg/l N-Butyl Acetate Inhalation- Vapor (4 hours) Rat LC50 > 20 mg/l N-Butyl Acetate Ingestion Rat LD50 > 8,800 mg/kg 1,6-Hexamethylene Diisocyanate-TDI Copolymer Dermal LD50 estimated to be > 5,000 mg/kg 1,6-Hexamethylene Diisocyanate-TDI Copolymer Inhalation- Dust/Mist (4 hours) Rat LC50 > 3 mg/l 1,6-Hexamethylene Diisocyanate-TDI Copolymer Ingestion Rat LD50 > 5,000 mg/kg P,P'-Methylenebis(phenyl isocyanate) Dermal Rabbit LD50 > 5,000 mg/kg P,P'-Methylenebis(phenyl isocyanate) Inhalation- Dust/Mist (4 hours) Rat LC50 0.368 mg/l P,P'-Methylenebis(phenyl isocyanate) Ingestion Rat LD50 31,600 mg/kg Carbon Black Dermal Rabbit LD50 > 3,000 mg/kg Carbon Black Ingestion Rat LD50 > 8,000 mg/kg Adipic acid-1,4-butanediol-MDI-neopentyl glycol copolymer Dermal LD50 estimated to be > 5,000 mg/kg Adipic acid-1,4-butanediol-MDI-neopentyl glycol copolymer Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg 1-methoxy-2-propyl acetate Dermal Rabbit LD50 > 5,000 mg/kg 1-methoxy-2-propyl acetate Inhalation- Vapor (4 hours) Rat LC50 > 28.8 mg/l 1-methoxy-2-propyl acetate Ingestion Rat LD50 8,532 mg/kg Hexamethylene diisocyanate polymer Inhalation- Dust/Mist (4 hours) Professio nal judgeme nt LC50 estimated to be 1 - 5 mg/l Hexamethylene diisocyanate polymer Dermal Rabbit LD50 > 5,000 mg/kg 3M? Single Step Primer, PN 08681, 08682 08/01/18 __________________________________________________________________________________________ Page 10 of 18 Hexamethylene diisocyanate polymer Ingestion Rat LD50 > 5,000 mg/kg 3-(trimethoxysilyl)propyl glycidyl ether Dermal Rabbit LD50 4,000 mg/kg 3-(trimethoxysilyl)propyl glycidyl ether Inhalation- Dust/Mist (4 hours) Rat LC50 > 5.3 mg/l 3-(trimethoxysilyl)propyl glycidyl ether Ingestion Rat LD50 7,010 mg/kg Diphenylmethane-2,4'-diisocyanate Dermal Rabbit LD50 > 5,000 mg/kg Polymethylene Polyphenylene Isocyanate Dermal Rabbit LD50 > 5,000 mg/kg Diphenylmethane-2,4'-diisocyanate Inhalation- Dust/Mist (4 hours) Rat LC50 0.368 mg/l Diphenylmethane-2,4'-diisocyanate Ingestion Rat LD50 31,600 mg/kg Polymethylene Polyphenylene Isocyanate Inhalation- Dust/Mist (4 hours) Rat LC50 0.368 mg/l Polymethylene Polyphenylene Isocyanate Ingestion Rat LD50 31,600 mg/kg Hexamethylene diisocyanate Dermal Rabbit LD50 570 mg/kg Hexamethylene diisocyanate Inhalation- Dust/Mist (4 hours) Rat LC50 0.12 mg/l Hexamethylene diisocyanate Ingestion Rat LD50 710 mg/kg Ethylbenzene Dermal Rabbit LD50 15,433 mg/kg Ethylbenzene Inhalation- Vapor (4 hours) Rat LC50 17.4 mg/l Ethylbenzene Ingestion Rat LD50 4,769 mg/kg Toluene 2,4-Diisocyanate Inhalation- Vapor (4 hours) Mouse LC50 0.12 mg/l Toluene 2,4-Diisocyanate Dermal Rabbit LD50 > 9,400 mg/kg Toluene 2,4-Diisocyanate Inhalation- Dust/Mist (4 hours) Rat LC50 0.35 mg/l Toluene 2,4-Diisocyanate Ingestion Rat LD50 > 5,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Methyl Ethyl Ketone Rabbit Minimal irritation N-Butyl Acetate Rabbit Minimal irritation 1,6-Hexamethylene Diisocyanate-TDI Copolymer Rabbit Minimal irritation P,P'-Methylenebis(phenyl isocyanate) official classifica tion Irritant Carbon Black Rabbit No significant irritation 1-methoxy-2-propyl acetate Rabbit No significant irritation Hexamethylene diisocyanate polymer Rabbit Mild irritant 3-(trimethoxysilyl)propyl glycidyl ether Rabbit Mild irritant Diphenylmethane-2,4'-diisocyanate official classifica tion Irritant Polymethylene Polyphenylene Isocyanate official classifica tion Irritant Hexamethylene diisocyanate Rabbit Corrosive Ethylbenzene Rabbit Mild irritant Toluene 2,4-Diisocyanate Rabbit Irritant Serious Eye Damage/Irritation Name Species Value Methyl Ethyl Ketone Rabbit Severe irritant N-Butyl Acetate Rabbit Moderate irritant 3M? Single Step Primer, PN 08681, 08682 08/01/18 __________________________________________________________________________________________ Page 11 of 18 1,6-Hexamethylene Diisocyanate-TDI Copolymer Rabbit Moderate irritant P,P'-Methylenebis(phenyl isocyanate) official classifica tion Severe irritant Carbon Black Rabbit No significant irritation 1-methoxy-2-propyl acetate Rabbit Mild irritant Hexamethylene diisocyanate polymer Rabbit Mild irritant 3-(trimethoxysilyl)propyl glycidyl ether Rabbit Corrosive Diphenylmethane-2,4'-diisocyanate official classifica tion Severe irritant Polymethylene Polyphenylene Isocyanate official classifica tion Severe irritant Hexamethylene diisocyanate Rabbit Corrosive Ethylbenzene Rabbit Moderate irritant Toluene 2,4-Diisocyanate Rabbit Corrosive Skin Sensitization Name Species Value N-Butyl Acetate Multiple animal species Not classified 1,6-Hexamethylene Diisocyanate-TDI Copolymer Guinea pig Sensitizing P,P'-Methylenebis(phenyl isocyanate) official classifica tion Sensitizing 1-methoxy-2-propyl acetate Guinea pig Not classified Hexamethylene diisocyanate polymer Guinea pig Sensitizing 3-(trimethoxysilyl)propyl glycidyl ether Guinea pig Not classified Diphenylmethane-2,4'-diisocyanate official classifica tion Sensitizing Polymethylene Polyphenylene Isocyanate official classifica tion Sensitizing Hexamethylene diisocyanate Multiple animal species Sensitizing Ethylbenzene Human Not classified Toluene 2,4-Diisocyanate Human and animal Sensitizing Respiratory Sensitization Name Species Value 1,6-Hexamethylene Diisocyanate-TDI Copolymer Sensitizing P,P'-Methylenebis(phenyl isocyanate) Human Sensitizing Hexamethylene diisocyanate polymer similar compoun ds Not classified Diphenylmethane-2,4'-diisocyanate Human Sensitizing Polymethylene Polyphenylene Isocyanate Human Sensitizing Hexamethylene diisocyanate Human and animal Sensitizing Toluene 2,4-Diisocyanate Human Sensitizing Germ Cell Mutagenicity 3M? Single Step Primer, PN 08681, 08682 08/01/18 __________________________________________________________________________________________ Page 12 of 18 Name Route Value Methyl Ethyl Ketone In Vitro Not mutagenic N-Butyl Acetate In Vitro Not mutagenic P,P'-Methylenebis(phenyl isocyanate) In Vitro Some positive data exist, but the data are not sufficient for classification Carbon Black In Vitro Not mutagenic Carbon Black In vivo Some positive data exist, but the data are not sufficient for classification 1-methoxy-2-propyl acetate In Vitro Not mutagenic Hexamethylene diisocyanate polymer In Vitro Not mutagenic Hexamethylene diisocyanate polymer In vivo Not mutagenic 3-(trimethoxysilyl)propyl glycidyl ether In vivo Not mutagenic 3-(trimethoxysilyl)propyl glycidyl ether In Vitro Some positive data exist, but the data are not sufficient for classification Diphenylmethane-2,4'-diisocyanate In Vitro Some positive data exist, but the data are not sufficient for classification Polymethylene Polyphenylene Isocyanate In Vitro Some positive data exist, but the data are not sufficient for classification Hexamethylene diisocyanate In Vitro Not mutagenic Hexamethylene diisocyanate In vivo Not mutagenic Ethylbenzene In vivo Not mutagenic Ethylbenzene In Vitro Some positive data exist, but the data are not sufficient for classification Toluene 2,4-Diisocyanate In Vitro Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Methyl Ethyl Ketone Inhalation Human Not carcinogenic P,P'-Methylenebis(phenyl isocyanate) Inhalation Rat Some positive data exist, but the data are not sufficient for classification Carbon Black Dermal Mouse Not carcinogenic Carbon Black Ingestion Mouse Not carcinogenic Carbon Black Inhalation Rat Carcinogenic 3-(trimethoxysilyl)propyl glycidyl ether Dermal Mouse Not carcinogenic Diphenylmethane-2,4'-diisocyanate Inhalation Rat Some positive data exist, but the data are not sufficient for classification Polymethylene Polyphenylene Isocyanate Inhalation Rat Some positive data exist, but the data are not sufficient for classification Hexamethylene diisocyanate Inhalation Rat Not carcinogenic Ethylbenzene Inhalation Multiple animal species Carcinogenic Toluene 2,4-Diisocyanate Inhalation Human and animal Not carcinogenic Toluene 2,4-Diisocyanate Ingestion Multiple animal species Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Methyl Ethyl Ketone Inhalation Not classified for development Rat LOAEL 8.8 mg/l during gestation N-Butyl Acetate Inhalation Not classified for female reproduction Rat NOAEL 7.1 mg/l premating & during gestation N-Butyl Acetate Inhalation Not classified for development Rat NOAEL 7.1 mg/l premating & during gestation 3M? Single Step Primer, PN 08681, 08682 08/01/18 __________________________________________________________________________________________ Page 13 of 18 P,P'-Methylenebis(phenyl isocyanate) Inhalation Not classified for development Rat NOAEL 0.004 mg/l during organogenesi s 1-methoxy-2-propyl acetate Ingestion Not classified for female reproduction Rat NOAEL 1,000 mg/kg/day premating & during gestation 1-methoxy-2-propyl acetate Ingestion Not classified for male reproduction Rat NOAEL 1,000 mg/kg/day premating & during gestation 1-methoxy-2-propyl acetate Ingestion Not classified for development Rat NOAEL 1,000 mg/kg/day premating & during gestation 1-methoxy-2-propyl acetate Inhalation Not classified for development Rat NOAEL 21.6 mg/l during organogenesi s 3-(trimethoxysilyl)propyl glycidyl ether Ingestion Not classified for female reproduction Rat NOAEL 1,000 mg/kg/day 1 generation 3-(trimethoxysilyl)propyl glycidyl ether Ingestion Not classified for male reproduction Rat NOAEL 1,000 mg/kg/day 1 generation 3-(trimethoxysilyl)propyl glycidyl ether Ingestion Not classified for development Rat NOAEL 3,000 mg/kg/day during organogenesi s Diphenylmethane-2,4'-diisocyanate Inhalation Not classified for development Rat NOAEL 0.004 mg/l during organogenesi s Polymethylene Polyphenylene Isocyanate Inhalation Not classified for development Rat NOAEL 0.004 mg/l during organogenesi s Hexamethylene diisocyanate Inhalation Not classified for female reproduction Rat NOAEL 0.002 mg/l 7 weeks Hexamethylene diisocyanate Inhalation Not classified for development Rat NOAEL 0.002 mg/l 7 weeks Hexamethylene diisocyanate Inhalation Not classified for male reproduction Rat NOAEL 0.014 mg/l 4 weeks Ethylbenzene Inhalation Not classified for development Rat NOAEL 4.3 mg/l premating & during gestation Toluene 2,4-Diisocyanate Inhalation Not classified for female reproduction Rat NOAEL 0.002 mg/l 2 generation Toluene 2,4-Diisocyanate Inhalation Not classified for male reproduction Rat NOAEL 0.002 mg/l 2 generation Toluene 2,4-Diisocyanate Inhalation Not classified for development Rat NOAEL 0.004 mg/l during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Methyl Ethyl Ketone Inhalation central nervous system depression May cause drowsiness or dizziness official classifica tion NOAEL Not available Methyl Ethyl Ketone Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Methyl Ethyl Ketone Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Methyl Ethyl Ketone Ingestion liver Not classified Rat NOAEL Not available not applicable Methyl Ethyl Ketone Ingestion kidney and/or bladder Not classified Rat LOAEL 1,080 mg/kg not applicable N-Butyl Acetate Inhalation respiratory system May cause damage to organs Rat LOAEL 2.6 mg/l 4 hours 3M? Single Step Primer, PN 08681, 08682 08/01/18 __________________________________________________________________________________________ Page 14 of 18 N-Butyl Acetate Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available not available N-Butyl Acetate Inhalation respiratory irritation May cause respiratory irritation Human NOAEL Not available not available N-Butyl Acetate Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available 1,6-Hexamethylene Diisocyanate-TDI Copolymer Inhalation respiratory irritation May cause respiratory irritation NOAEL Not available P,P'-Methylenebis(phenyl isocyanate) Inhalation respiratory irritation May cause respiratory irritation official classifica tion NOAEL Not available 1-methoxy-2-propyl acetate Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Hexamethylene diisocyanate polymer Inhalation respiratory irritation May cause respiratory irritation NOAEL Not available Diphenylmethane-2,4'- diisocyanate Inhalation respiratory irritation May cause respiratory irritation official classifica tion NOAEL Not available Polymethylene Polyphenylene Isocyanate Inhalation respiratory irritation May cause respiratory irritation official classifica tion NOAEL Not available Hexamethylene diisocyanate Inhalation respiratory irritation May cause respiratory irritation Human and animal NOAEL Not available Hexamethylene diisocyanate Inhalation blood Not classified Human NOAEL Not available occupational exposure Ethylbenzene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Ethylbenzene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available Ethylbenzene Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Toluene 2,4-Diisocyanate Inhalation respiratory irritation May cause respiratory irritation Human NOAEL Not available occupational exposure Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Methyl Ethyl Ketone Dermal nervous system Not classified Guinea pig NOAEL Not available 31 weeks Methyl Ethyl Ketone Inhalation liver | kidney and/or bladder | heart | endocrine system | gastrointestinal tract | bone, teeth, nails, and/or hair | hematopoietic system | immune system | muscles Not classified Rat NOAEL 14.7 mg/l 90 days Methyl Ethyl Ketone Ingestion liver Not classified Rat NOAEL Not available 7 days Methyl Ethyl Ketone Ingestion nervous system Not classified Rat NOAEL 173 mg/kg/day 90 days N-Butyl Acetate Inhalation olfactory system Not classified Rat NOAEL 2.4 mg/l 14 weeks N-Butyl Acetate Inhalation liver | kidney and/or bladder Not classified Rabbit NOAEL 7.26 mg/l 13 days P,P'-Methylenebis(phenyl isocyanate) Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.004 mg/l 13 weeks Carbon Black Inhalation pneumoconiosis Not classified Human NOAEL Not occupational 3M? Single Step Primer, PN 08681, 08682 08/01/18 __________________________________________________________________________________________ Page 15 of 18 available exposure 1-methoxy-2-propyl acetate Inhalation kidney and/or bladder Not classified Rat NOAEL 16.2 mg/l 9 days 1-methoxy-2-propyl acetate Inhalation olfactory system Not classified Mouse LOAEL 1.62 mg/l 9 days 1-methoxy-2-propyl acetate Inhalation blood Not classified Multiple animal species NOAEL 16.2 mg/l 9 days 1-methoxy-2-propyl acetate Ingestion endocrine system Not classified Rat NOAEL 1,000 mg/kg/day 44 days Hexamethylene diisocyanate polymer Inhalation immune system | blood Not classified Rat NOAEL 0.084 mg/l 2 weeks 3-(trimethoxysilyl)propyl glycidyl ether Ingestion heart | endocrine system | bone, teeth, nails, and/or hair | hematopoietic system | liver | immune system | nervous system | kidney and/or bladder | respiratory system Not classified Rat NOAEL 1,000 mg/kg/day 28 days Diphenylmethane-2,4'- diisocyanate Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.004 mg/l 13 weeks Polymethylene Polyphenylene Isocyanate Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.004 mg/l 13 weeks Hexamethylene diisocyanate Inhalation liver | kidney and/or bladder Not classified Rat NOAEL 0.002 mg/l 3 weeks Hexamethylene diisocyanate Inhalation endocrine system Not classified Rat NOAEL 0.0014 mg/l 4 weeks Hexamethylene diisocyanate Inhalation blood Not classified Rat NOAEL 0.0012 mg/l 2 years Hexamethylene diisocyanate Inhalation nervous system Not classified Rat NOAEL 0.002 mg/l 7 weeks Hexamethylene diisocyanate Inhalation heart Not classified Rat NOAEL 0.001 mg/l 90 days Ethylbenzene Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 2 years Ethylbenzene Inhalation liver Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 1.1 mg/l 103 weeks Ethylbenzene Inhalation hematopoietic system Not classified Rat NOAEL 3.4 mg/l 28 days Ethylbenzene Inhalation auditory system Not classified Rat NOAEL 2.4 mg/l 5 days Ethylbenzene Inhalation endocrine system Not classified Mouse NOAEL 3.3 mg/l 103 weeks Ethylbenzene Inhalation gastrointestinal tract Not classified Rat NOAEL 3.3 mg/l 2 years Ethylbenzene Inhalation bone, teeth, nails, and/or hair | muscles Not classified Multiple animal species NOAEL 4.2 mg/l 90 days Ethylbenzene Inhalation heart | immune system | respiratory system Not classified Multiple animal species NOAEL 3.3 mg/l 2 years Ethylbenzene Ingestion liver | kidney and/or bladder Not classified Rat NOAEL 680 mg/kg/day 6 months Toluene 2,4-Diisocyanate Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Human NOAEL 0 mg/l occupational exposure Aspiration Hazard Name Value Ethylbenzene Aspiration hazard 3M? Single Step Primer, PN 08681, 08682 08/01/18 __________________________________________________________________________________________ Page 16 of 18 Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Flammable (gases, aerosols, liquids, or solids) Health Hazards Carcinogenicity Respiratory or Skin Sensitization Serious eye damage or eye irritation Specific target organ toxicity (single or repeated exposure) Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt P,P'-Methylenebis(phenyl isocyanate) 101-68-8 Trade Secret < 10 P,P'-Methylenebis(phenyl isocyanate) (Benzene, 1,1'- methylenebis[4-isocyanato-) 101-68-8 < 10 P,P'-Methylenebis(phenyl isocyanate) 101-68-8 < 10 3M? Single Step Primer, PN 08681, 08682 08/01/18 __________________________________________________________________________________________ Page 17 of 18 (DIISOCYANATES (CERTAIN CHEMICALS ONLY)) Polymethylene Polyphenylene Isocyanate 9016-87-9 Trade Secret < 5 Polymethylene Polyphenylene Isocyanate (DIISOCYANATES (CERTAIN CHEMICALS ONLY)) 9016-87-9 < 5 Hexamethylene diisocyanate (DIISOCYANATES (CERTAIN CHEMICALS ONLY)) 822-06-0 < 0.5 Ethylbenzene 100-41-4 Trade Secret < 0.5 Toluene 2,4-Diisocyanate 584-84-9 Trade Secret < 0.5 Toluene 2,4-Diisocyanate (Benzene, 1,3- diisocyanatomethyl-) 584-84-9 < 0.5 This material contains a chemical which requires export notification under TSCA Section 12[b]: Ingredient (Category if applicable) C.A.S. No Regulation Status Toluene 2,4-Diisocyanate (Benzene, 1,3- diisocyanatomethyl-) 584-84-9 Toxic Substances Control Act (TSCA) 5 SNUR or Consent Order Chemicals Proposed Toluene 2,4-Diisocyanate 584-84-9 Toxic Substances Control Act (TSCA) 5 SNUR or Consent Order Chemicals Proposed This material contains a chemical subject to a proposed EPA Significant New Use Rule (TSCA Section 5) Ingredient (Category if applicable) C.A.S. No Reference Toluene 2,4-Diisocyanate 584-84-9 80 FR 2068 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 3 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 32-7721-7 Version Number: 1.06 Issue Date: 08/01/18 Supercedes Date: 01/17/18 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY 3M? Single Step Primer, PN 08681, 08682 08/01/18 __________________________________________________________________________________________ Page 18 of 18 OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from3M 3M USA SDSs are available at www.3M.com