MATERIAL SAFETY 3M DATA SHEET 3M Center St. Paul, Minnesota 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) Copyright, 1997, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. DIVISION: AUTOMOTIVE AFTERMARKET TRADE NAME: 3M Fuel System Kit, P.N. 08910 ID NUMBER/U.P.C.: 60-9800-3034-4 00-51135-08910-1 ISSUED: July 02, 1997 SUPERSEDES: April 04, 1997 DOCUMENT: 07-7738-3 This product is a kit or a multipart product which consists of multiple, independently packaged components. An MSDS for each of these components is included. Please do not separate the component MSDSs from this cover page. The document numbers of the MSDSs for components of this product are: 07-7565-0 07-7400-0 07-6352-4 ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately ----------------------------------------------------------------------------- The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. MATERIAL SAFETY 3M DATA SHEET 3M Center St. Paul, Minnesota 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) Copyright, 2000, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. DIVISION: AUTOMOTIVE AFTERMARKET TRADE NAME: 3M Throttle Plate and Intake Cleaner, P.N. 08866 ID NUMBER/U.P.C.: 60-9800-3076-5 00-51135-08866-1 60-9800-3321-5 00-51131-16823-7 ISSUED: October 20, 2000 SUPERSEDES: October 02, 2000 DOCUMENT: 07-6352-4 ----------------------------------------------------------------------------- 1. INGREDIENT C.A.S. NO. PERCENT ----------------------------------------------------------------------------- XYLENE.................................. 1330-20-7 30.0 - 55.0 PETROLEUM GASES, LIQUEFIED, SWEETENED... 68476-86-8 10.0 - 25.0 METHYL ETHYL KETONE..................... 78-93-3 5.0 - 10.0 2-BUTOXYETHANOL......................... 111-76-2 1.0 - 5.0 ETHYL ACETATE........................... 141-78-6 1.0 - 5.0 DIACETONE ALCOHOL....................... 123-42-2 1.0 - 5.0 HYDROTREATED HEAVY PARAFFINIC DISTILLATE (PETROLEUM)................ 64742-54-7 1.0 - 5.0 MEDIUM ALIPHATIC SOLVENT NAPHTHA........ 64742-88-7 1.0 - 5.0 POLYOLEFIN AMINE........................ 68891-84-9 1.0 - 5.0 NONANE.................................. 111-84-2 < 0.1 This product contains the following toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Emergency Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372: XYLENE METHYL ETHYL KETONE 2-BUTOXYETHANOL ----------------------------------------------------------------------------- 2. PHYSICAL DATA ----------------------------------------------------------------------------- BOILING POINT:................. 93 - 351 F VAPOR PRESSURE:................ 65 - 70 Air=1 VAPOR DENSITY:................. > 1 Air=1 EVAPORATION RATE:.............. > 1 Water=1 SOLUBILITY IN WATER:........... neglig. SPECIFIC GRAVITY:.............. 0.76 Water=1 ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Throttle Plate and Intake Cleaner, P.N. 08866 October 20, 2000 PAGE 2 ----------------------------------------------------------------------------- 2. PHYSICAL DATA (continued) ----------------------------------------------------------------------------- PERCENT VOLATILE:.............. 96 % pH:............................ N/A VISCOSITY:..................... N/A MELTING POINT:................. N/A APPEARANCE AND ODOR: Liquid, lacquer appearance, solvent odor ----------------------------------------------------------------------------- 3. FIRE AND EXPLOSION HAZARD DATA ----------------------------------------------------------------------------- FLASH POINT:................... -142.5 F FLAMMABLE LIMITS - LEL:........ N/A FLAMMABLE LIMITS - UEL:........ N/A AUTOIGNITION TEMPERATURE:...... N/D EXTINGUISHING MEDIA: Water spray, Carbon dioxide, Dry chemical SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers exposed to heat from fire may build pressure and explode. NFPA HAZARD CODES: HEALTH: 2 FIRE: 3 REACTIVITY: 0 UNUSUAL REACTION HAZARD: none ----------------------------------------------------------------------------- 4. REACTIVITY DATA ----------------------------------------------------------------------------- STABILITY: Stable INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID: Strong Acids, Strong Bases, Strong Oxidizing Agents. HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Throttle Plate and Intake Cleaner, P.N. 08866 October 20, 2000 PAGE 3 ----------------------------------------------------------------------------- 5. ENVIRONMENTAL INFORMATION ----------------------------------------------------------------------------- SPILL RESPONSE: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Ventilate area. Extinguish all ignition sources. Contain spill. Evacuate unprotected personnel from hazard area. Cover with absorbent material. Cover spill area with Light Water Brand or other AFFF foam. (For further information on AFFF foam usage, contact 3M Fire Protection Systems.) Collect using non-sparking tools. Clean up residue with an appropriate organic solvent. Read and follow safety precautions on the solvent label and MSDS. Place in an approved metal container. Seal the container. RECOMMENDED DISPOSAL: Incinerate in a permitted hazardous waste incinerator. ENVIRONMENTAL DATA: Not determined. REGULATORY INFORMATION: Volatile Organic Compounds: 96 % by wt. Volatile Organic Compounds: 6 lb/gal calculated. Volatile Organic Compounds: 729 gms/liter calculated per SCAQMD rule 443.1. VOC Less H2O & Exempt Solvents: 729 gms/liter calculated per SCAQMD rule 443.1. Since regulations vary, consult applicable regulations or authorities before disposal. In the event of an uncontrolled release of this material, the user should determine if the release qualifies as a reportable quantity. U.S. EPA Hazardous Waste Number = D001 (Ignitable) D035 (Methyl ethyl ketone) EPCRA HAZARD CLASS: FIRE HAZARD: Yes PRESSURE: Yes REACTIVITY: No ACUTE: Yes CHRONIC: Yes ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID ----------------------------------------------------------------------------- EYE CONTACT: Immediately flush eyes with large amounts of water. Get immediate medical attention. SKIN CONTACT: Flush skin with large amounts of water. If irritation persists, get medical attention. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Throttle Plate and Intake Cleaner, P.N. 08866 October 20, 2000 PAGE 4 ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID (continued) ----------------------------------------------------------------------------- INHALATION: Remove person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, get immediate medical attention. IF SWALLOWED: Do not induce vomiting. Drink two glasses of water. Call a physician. ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION ----------------------------------------------------------------------------- EYE PROTECTION: Avoid eye contact with vapor, spray, or mist. SKIN PROTECTION: Avoid prolonged or repeated skin contact. Wear appropriate gloves when handling this material. RECOMMENDED VENTILATION: Do not use in a confined area or areas with little or no air movement. Use in a well-ventilated area. If exhaust ventilation is not adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: Avoid prolonged breathing of vapors. half-mask organic vapor respirator. PREVENTION OF ACCIDENTAL INGESTION: Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Wash hands after handling and before eating. Do not ingest. RECOMMENDED STORAGE: Store in a cool place. Store away from acids. Store away from heat. Store at temperatures below 120 degrees F (49 degrees C). Store out of direct sunlight. FIRE AND EXPLOSION AVOIDANCE: Aerosol container contains flammable gas under pressure. Keep away from heat, sparks, open flame, and other sources of ignition. Prevent all sources of ignition. Extremely flammable liquid and vapor. Do not pierce or burn container, even after use. No smoking while handling this material. Do not heat under confinement. Avoid static discharge. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Throttle Plate and Intake Cleaner, P.N. 08866 October 20, 2000 PAGE 5 ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION (continued) ----------------------------------------------------------------------------- EXPOSURE LIMITS INGREDIENT VALUE UNIT TYPE AUTH SKIN* ----------------------------------------------------------------------------- XYLENE............................... 100 PPM TWA ACGIH XYLENE............................... 150 PPM STEL ACGIH XYLENE............................... 100 PPM TWA OSHA XYLENE............................... 150 PPM STEL OSHA PETROLEUM GASES, LIQUEFIED, SWEETENED.......................... NONE NONE NONE NONE METHYL ETHYL KETONE.................. 200 PPM TWA OSHA METHYL ETHYL KETONE.................. 300 PPM STEL OSHA METHYL ETHYL KETONE.................. 200 PPM TWA ACGIH METHYL ETHYL KETONE.................. 300 PPM STEL ACGIH 2-BUTOXYETHANOL...................... 25 PPM TWA ACGIH Y 2-BUTOXYETHANOL...................... 25 PPM TWA OSHAV Y OSHA VACATED PEL 2-BUTOXYETHANOL...................... 50 PPM TWA OSHA Y ETHYL ACETATE........................ 400 PPM TWA ACGIH ETHYL ACETATE........................ 400 PPM TWA OSHA DIACETONE ALCOHOL.................... 50 PPM TWA ACGIH DIACETONE ALCOHOL.................... 50 PPM TWA OSHA HYDROTREATED HEAVY PARAFFINIC DISTILLATE (PETROLEUM)............. NONE NONE NONE NONE MEDIUM ALIPHATIC SOLVENT NAPHTHA..... 100 PPM TWA CMRG POLYOLEFIN AMINE..................... NONE NONE NONE NONE NONANE............................... 200 PPM TWA ACGIH NONANE............................... 200 PPM TWA OSHA * SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: American Conference of Governmental Industrial Hygienists - CMRG: Chemical Manufacturer Recommended Exposure Guidelines - OSHA: Occupational Safety and Health Administration - OSHAV: Occupational Safety and Health Administration Vacated PEL. Vacated Permissible Exposure Limits (PEL) are enforced as the OSHA PEL in some states. Check with your local regulatory authority. - NONE: None Established ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Throttle Plate and Intake Cleaner, P.N. 08866 October 20, 2000 PAGE 6 ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA ----------------------------------------------------------------------------- EYE CONTACT: Moderate Eye Irritation: signs/symptoms can include redness, swelling, pain, tearing, and hazy vision. SKIN CONTACT: Moderate Skin Irritation (after prolonged or repeated contact): signs/symptoms can include redness, swelling, itching, and dryness. May be absorbed through the skin and produce effects similiar to those caused by inhalation and/or ingestion. WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD, THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT. Blood disorders: signs/symptoms can include prolonged weakness and fatigue. INHALATION: Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. Irritation (upper respiratory): signs/symptoms can include soreness of the nose and throat, coughing and sneezing. WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD, THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT. Liver Effects: signs/symptoms can include yellow skin(jaundice) and tenderness of upper abdomen. IF SWALLOWED: Ingestion is not a likely route of exposure to this product. WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD, THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT. Irritation of Gastrointestinal Tissues: signs/symptoms can include pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and blood in feces. Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue, blurred vision, slurred speech, ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Throttle Plate and Intake Cleaner, P.N. 08866 October 20, 2000 PAGE 7 ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA (continued) ----------------------------------------------------------------------------- giddiness, tremors and convulsions. Aspiration Pneumonitis: signs/symptoms can include coughing, difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal. ----------------------------------------------------------------------------- SECTION CHANGE DATES ----------------------------------------------------------------------------- PRECAUTIONARY INFO. SECTION CHANGED SINCE October 02, 2000 ISSUE ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately ----------------------------------------------------------------------------- The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. MATERIAL SAFETY 3M DATA SHEET 3M Center St. Paul, Minnesota 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) Copyright, 2001, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. DIVISION: AUTOMOTIVE AFTERMARKET TRADE NAME: 3M(TM) Fuel System Cleaner Tank Additive, P.N. 08813, 08815 ID NUMBER/U.P.C.: 60-9800-3033-6 00-51135-08813-5 60-9800-3318-1 00-51131-16820-6 60-9800-3469-2 00-51135-08815-9 60-9800-3529-3 00-51135-08815-9 ISSUED: February 27, 2001 SUPERSEDES: August 30, 1999 DOCUMENT: 07-7565-0 ----------------------------------------------------------------------------- 1. INGREDIENT C.A.S. NO. PERCENT ----------------------------------------------------------------------------- HYDROTREATED LIGHT NAPHTHENIC PETROLEUM DISTILLATES........................... 64742-53-6 30.0 - 60.0 HYDROTREATED HEAVY PARAFFINIC DISTILLATE (PETROLEUM)................ 64742-54-7 10.0 - 30.0 MEDIUM ALIPHATIC SOLVENT NAPHTHA........ 64742-88-7 10.0 - 30.0 ALKYLAMINE - NJ Trade Secret Registry No. 800967-5502P...................... TradeSecret 5.0 - 10.0 ALKENYLAMINE - NJ Trade Secret Registry No. 800967-5501P...................... TradeSecret 1.0 - 5.0 2-ETHYLHEXANOL.......................... 104-76-7 1.0 - 5.0 NONANE.................................. 111-84-2 0.5 - 1.5 1,2,4-TRIMETHYLBENZENE.................. 95-63-6 0.1 - 1.0 The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. This product contains the following toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Emergency Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372: 1,2,4-TRIMETHYLBENZENE ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M(TM) Fuel System Cleaner Tank Additive, P.N. 08813, 08815 February 27, 2001 PAGE 2 ----------------------------------------------------------------------------- 2. PHYSICAL DATA ----------------------------------------------------------------------------- BOILING POINT:................. N/D VAPOR PRESSURE:................ N/D VAPOR DENSITY:................. N/D EVAPORATION RATE:.............. N/D SOLUBILITY IN WATER:........... Insoluble SPECIFIC GRAVITY:.............. 0.88 Water=1 PERCENT VOLATILE:.............. 100 % by wt pH:............................ N/A VISCOSITY:..................... N/D MELTING POINT:................. N/D APPEARANCE AND ODOR: Dark Amber Liquid, Solvent Odor ----------------------------------------------------------------------------- 3. FIRE AND EXPLOSION HAZARD DATA ----------------------------------------------------------------------------- FLASH POINT:................... 168 F TCC ASTM D56 FLAMMABLE LIMITS - LEL:........ N/D FLAMMABLE LIMITS - UEL:........ N/D AUTOIGNITION TEMPERATURE:...... N/D EXTINGUISHING MEDIA: Water spray, Carbon dioxide, Dry chemical, Foam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. NFPA HAZARD CODES: HEALTH: 2 FIRE: 2 REACTIVITY: 0 UNUSUAL REACTION HAZARD: none OSHA FIRE HAZARD CLASS: Class IIIA Combustible Liquid ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M(TM) Fuel System Cleaner Tank Additive, P.N. 08813, 08815 February 27, 2001 PAGE 3 ----------------------------------------------------------------------------- 4. REACTIVITY DATA ----------------------------------------------------------------------------- STABILITY: Stable INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID: Strong Oxidizing Agents. HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Aldehydes. ----------------------------------------------------------------------------- 5. ENVIRONMENTAL INFORMATION ----------------------------------------------------------------------------- SPILL RESPONSE: Observe precautions from other sections. Ventilate area. Contain spill. Cover with absorbent material. Collect spilled material. Clean up residue with an appropriate organic solvent. Read and follow safety precautions on the solvent label and MSDS. Place in a closed container. RECOMMENDED DISPOSAL: Incinerate in an industrial or commercial facility. ENVIRONMENTAL DATA: Not determined. REGULATORY INFORMATION: Volatile Organic Compounds: N/D. VOC Less H2O & Exempt Solvents: N/D. Since regulations vary, consult applicable regulations or authorities before disposal. In the event of an uncontrolled release of this material, the user should determine if the release qualifies as a reportable quantity. U.S. EPA Hazardous Waste Number = None (Not U.S. EPA Hazardous). EPCRA HAZARD CLASS: FIRE HAZARD: Yes PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID ----------------------------------------------------------------------------- EYE CONTACT: Immediately flush eyes with large amounts of water. Get immediate medical attention. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M(TM) Fuel System Cleaner Tank Additive, P.N. 08813, 08815 February 27, 2001 PAGE 4 ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID (continued) ----------------------------------------------------------------------------- SKIN CONTACT: Immediately wash skin with soap and large amounts of water. Remove contaminated clothing. If signs/symptoms occur, call a physician. Wash contaminated clothing before reuse and dispose of contaminated shoes. INHALATION: Remove person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, get immediate medical attention. IF SWALLOWED: If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person. ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION ----------------------------------------------------------------------------- EYE PROTECTION: Avoid eye contact. Wear vented goggles. Wear safety glasses with side shields. SKIN PROTECTION: Avoid skin contact. Wear appropriate gloves when handling this material. A pair of gloves made from the following material(s) are recommended: fluoroelastomer (Viton). RECOMMENDED VENTILATION: Do not use in a confined area or areas with little or no air movement. Use in a well-ventilated area. Provide sufficient ventilation to maintain emissions below recommended exposure limits. If exhaust ventilation is not adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: Avoid breathing of vapors. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: full-face organic vapor respirator. PREVENTION OF ACCIDENTAL INGESTION: Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Do not ingest. RECOMMENDED STORAGE: Store in a cool place. Store away from heat. Keep container in well- ventilated area. Keep out of the reach of children. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M(TM) Fuel System Cleaner Tank Additive, P.N. 08813, 08815 February 27, 2001 PAGE 5 ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION (continued) ----------------------------------------------------------------------------- FIRE AND EXPLOSION AVOIDANCE: Keep container tightly closed. Keep away from heat, sparks, open flame, and other sources of ignition. Combustible liquid and vapor. No smoking while handling this material. EXPOSURE LIMITS INGREDIENT VALUE UNIT TYPE AUTH SKIN* ----------------------------------------------------------------------------- HYDROTREATED LIGHT NAPHTHENIC PETROLEUM DISTILLATES.............. 5 MG/M3 TWA CMRG HYDROTREATED HEAVY PARAFFINIC DISTILLATE (PETROLEUM)............. NONE NONE NONE NONE MEDIUM ALIPHATIC SOLVENT NAPHTHA..... 100 PPM TWA CMRG ALKYLAMINE - NJ Trade Secret Registry No. 800967-5502P.......... NONE NONE NONE NONE ALKENYLAMINE - NJ Trade Secret Registry No. 800967-5501P.......... NONE NONE NONE NONE 2-ETHYLHEXANOL....................... NONE NONE NONE NONE NONANE............................... 200 PPM TWA ACGIH NONANE............................... 200 PPM TWA OSHA 1,2,4-TRIMETHYLBENZENE............... NONE NONE NONE NONE * SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: American Conference of Governmental Industrial Hygienists - CMRG: Chemical Manufacturer Recommended Exposure Guidelines - OSHA: Occupational Safety and Health Administration - NONE: None Established ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA ----------------------------------------------------------------------------- EYE CONTACT: Moderate Eye Irritation: signs/symptoms can include redness, swelling, pain, tearing, and hazy vision. SKIN CONTACT: Moderate Skin Irritation (after prolonged or repeated contact): signs/symptoms can include redness, swelling, itching, and dryness. Prolonged or repeated exposure may cause: ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M(TM) Fuel System Cleaner Tank Additive, P.N. 08813, 08815 February 27, 2001 PAGE 6 ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA (continued) ----------------------------------------------------------------------------- Allergic Skin Reaction: signs/symptoms can include redness, swelling, blistering, and itching. INHALATION: Irritation (upper respiratory): signs/symptoms can include soreness of the nose and throat, coughing and sneezing. Single overexposure, above recommended guidelines, may cause: Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. IF SWALLOWED: Irritation of Gastrointestinal Tissues: signs/symptoms can include pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and blood in feces. Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue, blurred vision, slurred speech, giddiness, tremors and convulsions. Aspiration Pneumonitis: signs/symptoms can include coughing, difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal. ----------------------------------------------------------------------------- SECTION CHANGE DATES ----------------------------------------------------------------------------- HEADING SECTION CHANGED SINCE August 30, 1999 ISSUE INGREDIENTS SECTION CHANGED SINCE August 30, 1999 ISSUE PRECAUTIONARY INFO. SECTION CHANGED SINCE August 30, 1999 ISSUE ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M(TM) Fuel System Cleaner Tank Additive, P.N. 08813, 08815 February 27, 2001 PAGE 7 ----------------------------------------------------------------------------- The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. MATERIAL SAFETY 3M DATA SHEET 3M Center St. Paul, Minnesota 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) Copyright, 2001, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. DIVISION: AUTOMOTIVE AFTERMARKET TRADE NAME: 3M Fuel System Cleaner, P.N. 08913 ID NUMBER/U.P.C.: 60-9800-3035-1 00-51135-08913-2 60-9800-3322-3 00-51131-16824-4 ISSUED: November 12, 2001 SUPERSEDES: October 20, 2000 DOCUMENT: 07-7400-0 ----------------------------------------------------------------------------- 1. INGREDIENT C.A.S. NO. PERCENT ----------------------------------------------------------------------------- 2,2,4-TRIMETHYLPENTANE.................. 540-84-1 20.0 - 40.0 TOLUENE................................. 108-88-3 10.0 - 30.0 ISOALKANES.............................. 64365-06-6 10.0 - 30.0 XYLENE.................................. 1330-20-7 7.0 - 13.0 LIQUEFIED PETROLEUM GAS................. 68476-85-7 5.0 - 10.0 DIACETONE ALCOHOL....................... 123-42-2 1.0 - 10.0 MEDIUM ALIPHATIC SOLVENT NAPHTHA........ 64742-88-7 1.0 - 5.0 4-METHYL-2-PENTANOL..................... 108-11-2 3.0 - 7.0 2-BUTOXYETHANOL......................... 111-76-2 1.0 - 5.0 The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. ++ Propellant (isobutane, propane) is separate from other ingredients; propellant is not released from can. This product contains the following toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Emergency Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372: TOLUENE XYLENE 2-BUTOXYETHANOL ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Fuel System Cleaner, P.N. 08913 November 12, 2001 PAGE 2 ----------------------------------------------------------------------------- 2. PHYSICAL DATA ----------------------------------------------------------------------------- BOILING POINT:................. 100 - 400 F VAPOR PRESSURE:................ 100 psi @ 70 F VAPOR DENSITY:................. > 1 Air=1 EVAPORATION RATE:.............. > 1 Water=1 SOLUBILITY IN WATER:........... Yes SPECIFIC GRAVITY:.............. 0.813 Water=1 PERCENT VOLATILE:.............. N/D pH:............................ N/A VISCOSITY:..................... N/D MELTING POINT:................. N/D APPEARANCE AND ODOR: Semi-Opaque Liquid, Solvent Odor ----------------------------------------------------------------------------- 3. FIRE AND EXPLOSION HAZARD DATA ----------------------------------------------------------------------------- FLASH POINT:................... -50 F (Propellant) FLAMMABLE LIMITS - LEL:........ N/A FLAMMABLE LIMITS - UEL:........ N/A AUTOIGNITION TEMPERATURE:...... N/D EXTINGUISHING MEDIA: Water spray, Carbon dioxide, Dry chemical, Foam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers exposed to heat from fire may build pressure and explode. NFPA HAZARD CODES: HEALTH: 2 FIRE: 2 REACTIVITY: 0 AEROSOL STORAGE: 3 UNUSUAL REACTION HAZARD: none ----------------------------------------------------------------------------- 4. REACTIVITY DATA ----------------------------------------------------------------------------- STABILITY: Stable ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Fuel System Cleaner, P.N. 08913 November 12, 2001 PAGE 3 ----------------------------------------------------------------------------- 4. REACTIVITY DATA (continued) ----------------------------------------------------------------------------- INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID: Strong Acids, Strong Oxidizing Agents Alkalis and Some Metals. HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of Carbon and Organics. ----------------------------------------------------------------------------- 5. ENVIRONMENTAL INFORMATION ----------------------------------------------------------------------------- SPILL RESPONSE: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Ventilate area. Extinguish all ignition sources. Contain spill. Evacuate unprotected personnel from hazard area. Cover with absorbent material. Cover spill area with Light Water Brand or other ATC foam. (For further information on ATC foam usage, contact 3M Fire Protection Systems.) Collect using non-sparking tools. Clean up residue with water. Place in an approved metal container. Seal the container. Place leaking containers in a well-ventilated area, preferrably in an exhaust hood, if available, or outdoors. RECOMMENDED DISPOSAL: Incinerate in a permitted hazardous waste incinerator. Facility must be capable of handling aerosol cans. ENVIRONMENTAL DATA: Not determined. REGULATORY INFORMATION: Volatile Organic Compounds: N/D. VOC Less H2O & Exempt Solvents: N/D. Since regulations vary, consult applicable regulations or authorities before disposal. In the event of an uncontrolled release of this material, the user should determine if the release qualifies as a reportable quantity. U.S. EPA Hazardous Waste Number = D001 (Ignitable) EPCRA HAZARD CLASS: FIRE HAZARD: Yes PRESSURE: Yes REACTIVITY: No ACUTE: Yes CHRONIC: Yes ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Fuel System Cleaner, P.N. 08913 November 12, 2001 PAGE 4 ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID ----------------------------------------------------------------------------- EYE CONTACT: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: Flush skin with large amounts of water. If irritation persists, get medical attention. INHALATION: Remove person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, get immediate medical attention. IF SWALLOWED: If swallowed, do NOT induce vomiting. Give victim two glasses of water. Call a physician immediately. Never give anything by mouth to an unconscious person. ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION ----------------------------------------------------------------------------- EYE PROTECTION: Avoid eye contact. SKIN PROTECTION: Avoid skin contact. RECOMMENDED VENTILATION: Do not use in a confined area or areas with little or no air movement. If exhaust ventilation is not adequate, use appropriate respiratory protection. Provide ventilation adequate to control vapor concentrations below recommended exposure limits and/or control spray or mist. RESPIRATORY PROTECTION: Avoid breathing of vapors, mists or spray. PREVENTION OF ACCIDENTAL INGESTION: Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. RECOMMENDED STORAGE: Store in a cool place. Store away from heat. Contents may be under pressure, open carefully. FIRE AND EXPLOSION AVOIDANCE: Keep away from heat, sparks, open flame, and other sources of ignition. Prevent all sources of ignition. Combustible liquid and vapor. Do not pierce or burn container, even after use. No smoking ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Fuel System Cleaner, P.N. 08913 November 12, 2001 PAGE 5 ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION (continued) ----------------------------------------------------------------------------- while handling this material. EXPOSURE LIMITS INGREDIENT VALUE UNIT TYPE AUTH SKIN* ----------------------------------------------------------------------------- 2,2,4-TRIMETHYLPENTANE............... 300 PPM TWA ACGIH 2,2,4-TRIMETHYLPENTANE............... 375 PPM STEL ACGIH TOLUENE.............................. 50 PPM TWA ACGIH Y TOLUENE.............................. 100 PPM TWA OSHAV OSHA VACATED PEL TOLUENE.............................. 150 PPM STEL OSHAV OSHA VACATED PEL TOLUENE.............................. 200 PPM TWA OSHA TOLUENE.............................. 300 PPM CEIL OSHA TOLUENE.............................. 75 PPM STEL CMRG Y ISOALKANES........................... NONE NONE NONE NONE XYLENE............................... 100 PPM TWA ACGIH XYLENE............................... 150 PPM STEL ACGIH XYLENE............................... 100 PPM TWA OSHA XYLENE............................... 150 PPM STEL OSHA LIQUEFIED PETROLEUM GAS.............. 1000 PPM TWA ACGIH LIQUEFIED PETROLEUM GAS.............. 1000 PPM TWA OSHA DIACETONE ALCOHOL.................... 50 PPM TWA ACGIH DIACETONE ALCOHOL.................... 50 PPM TWA OSHA MEDIUM ALIPHATIC SOLVENT NAPHTHA..... 100 PPM TWA CMRG 4-METHYL-2-PENTANOL.................. 25 PPM TWA OSHA Y 4-METHYL-2-PENTANOL.................. 40 PPM STEL OSHA Y 4-METHYL-2-PENTANOL.................. 25 PPM TWA ACGIH Y 4-METHYL-2-PENTANOL.................. 40 PPM STEL ACGIH Y 2-BUTOXYETHANOL...................... 25 PPM TWA ACGIH Y 2-BUTOXYETHANOL...................... 25 PPM TWA OSHAV Y OSHA VACATED PEL 2-BUTOXYETHANOL...................... 50 PPM TWA OSHA Y * SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: American Conference of Governmental Industrial Hygienists - CMRG: Chemical Manufacturer Recommended Exposure Guidelines - OSHA: Occupational Safety and Health Administration - OSHAV: Occupational Safety and Health Administration Vacated PEL. Vacated Permissible Exposure Limits (PEL) are enforced as the OSHA PEL in some states. Check with your local regulatory authority. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Fuel System Cleaner, P.N. 08913 November 12, 2001 PAGE 6 EXPOSURE LIMITS (continued) INGREDIENT VALUE UNIT TYPE AUTH SKIN* ----------------------------------------------------------------------------- - NONE: None Established ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA ----------------------------------------------------------------------------- EYE CONTACT: Moderate Eye Irritation: signs/symptoms can include redness, swelling, pain, tearing, and hazy vision. SKIN CONTACT: Blood disorders: signs/symptoms can include prolonged weakness and fatigue. Moderate Skin Irritation (after prolonged or repeated contact): signs/symptoms can include redness, swelling, itching, and dryness. May be absorbed through the skin and produce effects similiar to those caused by inhalation and/or ingestion. INHALATION: Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. Irritation (upper respiratory): signs/symptoms can include soreness of the nose and throat, coughing and sneezing. WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD, THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT. Blood disorders: signs/symptoms can include prolonged weakness and fatigue. Kidney Effects: signs/symptoms can include reduced urine volume, blood in urine and back pain. Liver Effects: signs/symptoms can include yellow skin(jaundice) and tenderness of upper abdomen. IF SWALLOWED: Irritation of Gastrointestinal Tissues: signs/symptoms can include pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and blood in feces. Aspiration Pneumonitis: signs/symptoms can include coughing, difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Fuel System Cleaner, P.N. 08913 November 12, 2001 PAGE 7 ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA (continued) ----------------------------------------------------------------------------- WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD, THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT. Blood disorders: signs/symptoms can include prolonged weakness and fatigue. Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue, blurred vision, slurred speech, giddiness, tremors and convulsions. REPRODUCTIVE/DEVELOPMENTAL TOXINS: WARNING: Contains a chemical which can cause birth defects. (108-88- 3) ----------------------------------------------------------------------------- SECTION CHANGE DATES ----------------------------------------------------------------------------- PRECAUTIONARY INFO. SECTION CHANGED SINCE October 20, 2000 ISSUE ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately ----------------------------------------------------------------------------- The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.