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SAFETY DATA SHEET Revision Date 08-May-2018 Version 3 1. IDENTIFICATION Product identifier Product Name SPRAY SEALANT 9.25 OZ Other means of identification Product Code 82099 Recommended use of the chemical and restrictions on use Recommended Use Sealant. Uses advised against No information available Details of the supplier of the safety data sheet 24-hour emergency phone number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Carcinogenicity Category 2 Reproductive toxicity Category 2 Specific target organ toxicity (single exposure) Category 3 Specific target organ toxicity (repeated exposure) Category 2 Aspiration toxicity Category 1 Label elements Emergency Overview Manufacturer Address ITW Permatex 6875 Parkland Blvd. Solon, OH 44139 USA May Also Be Distributed by: ITW Permatex Canada 101-2360 Bristol Circle Oakville, ON Canada L6H 6M5 Telephone: (800) 924-6994 Flammable aerosols Category 1 Gases under pressure Liquefied gas Signal word Danger _____________________________________________________________________________________________ Page 1 / 11 Causes skin irritation Causes serious eye irritation _____________________________________________________________________________________________ 82099 - SPRAY SEALANT 9.25 OZ Revision Date 08-May-2018 Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection Do not breathe dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. - No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting Precautionary Statements - Storage Store locked up Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information - Not applicable Unknown acute toxicity 15.58 % of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance(s) Suspected of causing cancer Suspected of damaging fertility or the unborn child May cause drowsiness or dizziness May cause damage to organs through prolonged or repeated exposure May be fatal if swallowed and enters airways Extremely flammable aerosol Contains gas under pressure; may explode if heated Appearance Clear Physical state Liquid Flammable Aerosol _____________________________________________________________________________________________ Page 2 / 11 Odor Solvent _____________________________________________________________________________________________ 82099 - SPRAY SEALANT 9.25 OZ Revision Date 08-May-2018 Chemical Name CAS No Weight-% ACETONE 67-64-1 15 - 40 TOLUENE 108-88-3 7 - 13 DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 7 - 13 2-PROPANOL 67-63-0 7 - 13 PROPANE 74-98-6 5 - 10 BUTANE 106-97-8 5 - 10 XYLENE 1330-20-7 1 - 5 N-HEXANE 110-54-3 <3 ETHYL BENZENE 100-41-4 0.1 - 1 Any concentration shown as a range is due to batch variation. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Take off contaminated clothing and wash before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Call a physician or poison control center immediately. Do NOT induce vomiting. Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical Extremely flammable. Contains gas under pressure; may explode if heated. Vapors may travel to source of ignition and flash back. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. _____________________________________________________________________________________________ Page 3 / 11 Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. _____________________________________________________________________________________________ 82099 - SPRAY SEALANT 9.25 OZ Revision Date 08-May-2018 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Contents under pressure. Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Wash thoroughly after handling. Other Information Ventilate the area. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Use personal protective equipment as required. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Ensure adequate ventilation, especially in confined areas. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Contents under pressure. Do not puncture or incinerate cans. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F. Store locked up. Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH ACETONE 67-64-1 STEL: 500 ppm TWA: 250 ppm TWA: 1000 ppm TWA: 2400 mg/m3 (vacated) TWA: 750 ppm (vacated) TWA: 1800 mg/m3 (vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors (vacated) STEL: 1000 ppm IDLH: 2500 ppm TWA: 250 ppm TWA: 590 mg/m3 TOLUENE 108-88-3 TWA: 20 ppm TWA: 200 ppm (vacated) TWA: 100 ppm (vacated) TWA: 375 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 560 mg/m3 Ceiling: 300 ppm IDLH: 500 ppm TWA: 100 ppm TWA: 375 mg/m3 STEL: 150 ppm STEL: 560 mg/m3 2-PROPANOL 67-63-0 STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m3 IDLH: 2000 ppm TWA: 400 ppm _____________________________________________________________________________________________ Page 4 / 11 _____________________________________________________________________________________________ 82099 - SPRAY SEALANT 9.25 OZ Revision Date 08-May-2018 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3 TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 PROPANE 74-98-6 : See Appendix F: Minimal Oxygen Content TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 BUTANE 106-97-8 STEL: 1000 ppm (vacated) TWA: 800 ppm (vacated) TWA: 1900 mg/m3 TWA: 800 ppm TWA: 1900 mg/m3 XYLENE 1330-20-7 STEL: 150 ppm TWA: 100 ppm TWA: 100 ppm TWA: 435 mg/m3 (vacated) TWA: 100 ppm (vacated) TWA: 435 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 655 mg/m3 - N-HEXANE 110-54-3 TWA: 50 ppm S* TWA: 500 ppm TWA: 1800 mg/m3 (vacated) TWA: 50 ppm (vacated) TWA: 180 mg/m3 IDLH: 1100 ppm TWA: 50 ppm TWA: 180 mg/m3 ETHYL BENZENE 100-41-4 TWA: 20 ppm TWA: 100 ppm TWA: 435 mg/m3 (vacated) TWA: 100 ppm (vacated) TWA: 435 mg/m3 (vacated) STEL: 125 ppm (vacated) STEL: 545 mg/m3 IDLH: 800 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 125 ppm STEL: 545 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective natural rubber, nitrile rubber, Neoprene? or PVC gloves. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid; Flammable Aerosol Appearance Clear Odor Solvent Odor threshold No information available Property Values Remarks ? Method pH No information available Melting point / freezing point No information available Boiling point / boiling range No information available Flash point -29 ?C / -20 ?F Gives a flame projection at full valve opening or flashback at any degree of valve opening Evaporation rate 9.1 Butyl acetate = 1 _____________________________________________________________________________________________ Page 5 / 11 _____________________________________________________________________________________________ 82099 - SPRAY SEALANT 9.25 OZ Revision Date 08-May-2018 Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 54.4% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause damage to organs through prolonged or repeated exposure if inhaled. May cause drowsiness or dizziness. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Potential for aspiration if swallowed. Aspiration may cause pulmonary edema and pneumonitis. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 ACETONE 67-64-1 = 5800 mg/kg ( Rat ) - = 50100 mg/m3 ( Rat ) 8 h Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: 12.8% Lower flammability limit: 1.0% Vapor pressure 101.3 kPa (760mm Hg)@20?C Vapor density 1.55 Air = 1 Relative density 0.76 Water solubility No information available Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity <0.205 cm2/s Dynamic viscosity No information available Stable under normal conditions _____________________________________________________________________________________________ Page 6 / 11 _____________________________________________________________________________________________ 82099 - SPRAY SEALANT 9.25 OZ Revision Date 08-May-2018 TOLUENE 108-88-3 = 2600 mg/kg ( Rat ) = 12000 mg/kg ( Rabbit ) = 12.5 mg/L ( Rat ) 4 h DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 5.2 mg/L ( Rat ) 4 h 2-PROPANOL 67-63-0 5050 mg/kg 12800 mg/kg = 72600 mg/m3 ( Rat ) 4 h PROPANE 74-98-6 - - = 658 mg/L ( Rat ) 4 h BUTANE 106-97-8 - - = 658 g/m3 ( Rat ) 4 h XYLENE 1330-20-7 = 3500 mg/kg ( Rat ) > 4350 mg/kg ( Rabbit ) > 1700 mg/kg ( Rabbit ) = 29.08 mg/L ( Rat ) 4 h = 5000 ppm ( Rat ) 4 h N-HEXANE 110-54-3 = 25 g/kg ( Rat ) = 3000 mg/kg ( Rabbit ) = 48000 ppm ( Rat ) 4 h ETHYL BENZENE 100-41-4 = 3500 mg/kg ( Rat ) = 15400 mg/kg ( Rabbit ) = 17.2 mg/L ( Rat ) 4 h Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA TOLUENE 108-88-3 - Group 3 - - XYLENE 1330-20-7 - Group 3 - - ETHYL BENZENE 100-41-4 A3 Group 2B - X ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans Not classifiable as a human carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Chronic toxicity May cause adverse liver effects. Target Organ Effects Central nervous system, Eyes, kidney, Liver, Peripheral Nervous System (PNS), Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 5538 mg/kg ATEmix (dermal) 7471 mg/kg ATEmix (inhalation-gas) 1771490 mg/l ATEmix (inhalation-dust/mist) 29.9 mg/l ATEmix (inhalation-vapor) 2155404 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 30.63 % of the mixture consists of component(s) of unknown hazards to the aquatic environment Persistence and degradability No information available. Bioaccumulation No information available. _____________________________________________________________________________________________ Page 7 / 11 Mobility _____________________________________________________________________________________________ 82099 - SPRAY SEALANT 9.25 OZ Revision Date 08-May-2018 No information available. Chemical Name Partition coefficient ACETONE 67-64-1 -0.24 TOLUENE 108-88-3 2.7 2-PROPANOL 67-63-0 0.05 PROPANE 74-98-6 2.3 BUTANE 106-97-8 2.89 XYLENE 1330-20-7 2.77 - 3.15 ETHYL BENZENE 100-41-4 3.2 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not reuse container. US EPA Waste Number D001 Chemical Name RCRA - Halogenated Organic Compounds RCRA - P Series Wastes RCRA - F Series Wastes RCRA - K Series Wastes TOLUENE 108-88-3 - - Toxic waste waste number F025 Waste description: Condensed light ends, spent filters and filter aids, and spent desiccant wastes from the production of certain chlorinated aliphatic hydrocarbons, by free radical catalyzed processes. These chlorinated aliphatic hydrocarbons are those having carbon chain lengths ranging from one to and including five, with varying amounts and positions of chlorine substitution. - This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status ACETONE 67-64-1 Ignitable TOLUENE 108-88-3 Toxic Ignitable 2-PROPANOL 67-63-0 Toxic Ignitable XYLENE 1330-20-7 Toxic Ignitable N-HEXANE 110-54-3 Toxic Ignitable _____________________________________________________________________________________________ Page 8 / 11 _____________________________________________________________________________________________ 82099 - SPRAY SEALANT 9.25 OZ Revision Date 08-May-2018 ETHYL BENZENE 100-41-4 Toxic Ignitable 14. TRANSPORT INFORMATION DOT UN/ID no 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.1 Emergency Response Guide Number 126 IATA UN/ID no ID 8000 Proper shipping name: Consumer commodity Hazard Class 9 ERG Code 9L IMDG UN/ID no 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.1 EmS-No F-D, S-U 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % TOLUENE - 108-88-3 1.0 2-PROPANOL - 67-63-0 1.0 XYLENE - 1330-20-7 1.0 N-HEXANE - 110-54-3 1.0 ETHYL BENZENE - 100-41-4 0.1 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard Yes _____________________________________________________________________________________________ Page 9 / 11 _____________________________________________________________________________________________ 82099 - SPRAY SEALANT 9.25 OZ Revision Date 08-May-2018 Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances TOLUENE 108-88-3 1000 lb X X X XYLENE 1330-20-7 100 lb - - X ETHYL BENZENE 100-41-4 1000 lb X X X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) ACETONE 67-64-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ TOLUENE 108-88-3 1000 lb 1 lb - RQ 1000 lb final RQ RQ 454 kg final RQ RQ 1 lb final RQ RQ 0.454 kg final RQ XYLENE 1330-20-7 100 lb - RQ 100 lb final RQ RQ 45.4 kg final RQ N-HEXANE 110-54-3 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ ETHYL BENZENE 100-41-4 1000 lb - RQ 1000 lb final RQ RQ 454 kg final RQ US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 TOLUENE - 108-88-3 Developmental N-HEXANE - 110-54-3 Developmental ETHYL BENZENE - 100-41-4 Carcinogen U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania ACETONE 67-64-1 X X X TOLUENE 108-88-3 X X X 2-PROPANOL 67-63-0 X X X PROPANE 74-98-6 X X X BUTANE 106-97-8 X X X XYLENE 1330-20-7 X X X N-HEXANE 110-54-3 X X X ETHYL BENZENE 100-41-4 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable WHMIS Hazard Class A Compressed gases, B5 - Flammable aerosol, D2B - Toxic materials _____________________________________________________________________________________________ Page 10 / 11 _____________________________________________________________________________________________ 82099 - SPRAY SEALANT 9.25 OZ Revision Date 08-May-2018 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 08-May-2018 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health hazards 2 Flammability 3 Instability 0 - HMIS Health hazards 2 Flammability 3 Physical hazards 0 Personal protection B _____________________________________________________________________________________________ Page 11 / 11